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Laboratorio de Fisicoqumica II
INTEGRANTES:
PROFESOR:
28 DE JUNIO DE 2017
UNIVERSIDAD NACIONAL DEL CALLAO
FACULTAD DE INGENIERA QUMICA
I. INTRODUCCION
+ +
[] []
= =
Puesto que los reactivos desaparecen ser negativo y por tanto la definicin
implica un valor positivo de la velocidad de reaccin.
[] [] [] []
= = = =
[]
Velocidad media formacin de B =+
La velocidad instantnea se obtiene de la tangente que toca la curva en el punto
de inters. Esto nos da la velocidad a cualquier tiempo.
[]
=+
Ley de la Velocidad
= = [] []
La velocidad es:
[]
=
Velocidad = k[A]
[] /
= = =
[]
[]
=
[]
[]
= []
Reordenando llegamos a:
[] = + []
IV. MATERIALES
MATERIALES
REACTIVOS
EXPERIMENTO A:
ANALISIS SIN CATALIZADOR.
KMnO4
(0.0025M)
5ml de solucin A
+ 2 ml de H2SO4
EXPERIMENTO B: EXPERIMENTO C:
ANALISIS CON CATALIZADOR ANALISIS CON CATALIZADOR MAS
UN PROMOTOR.
KMnO4 KMnO4
(0.0025M) (0.0025M)
5ml de solucin C +
5ml de solucin B 2 ml de H2SO4
+ 2 ml de H2SO4
Al determinar los volmenes de permanganato se registra los datos en una tabla como esta:
TIEMPO(min)
0 10 20 40 60
Solucion A
Solucion B
Solucion C
VI. CLCULOS Y RESULTADOS
SIN CATALIZADOR
KMnO4 (0,02N)
H2O2 (75ml)
+
H2O (15ml)
54
[2 2 ] = [4 ] (1)
22 2
(puro ) ( )
75ml 90ml
x 5ml
2 2 () = = 4,17
Reemplazando en la ecuacin (1)
532
[] = [2 2 ] = [0.02] [2 2 ] = 0.3837
2 4.17
530.8
[] = [2 2 ] = [0.02] [2 2 ] = 0.3693
2 4.17
530.6
[] = [2 2 ] = [0.02] [2 2 ] = 0.3669
2 4.17
: 2 KMnO4 : 29.4 2 2 = = 4,17
529.4
[] = [2 2 ] = [0.02] [2 2 ] = 0.3525
2 4.17
528
[] = [2 2 ] = [0.02] [2 2 ] = 0.3357
2 4.17
: 3 KMnO4: 27 2 2 = = 4,17
527
[] = [2 2 ] = [0.02] [2 2 ] = 0.3237
2 4.17
Tabla de dato N1
Tiempo Gasto KMnO4 (ml) [A] [A] [A]/[A] Ln([A]/[A])
(hora)
0 32.6 0.3909 0.3909 1 0
0.5 32.0 0.3909 0.3837 0.9816 -0.0186
1.0 30.8 0.3909 0.3693 0.9447 -0.0569
1.5 30.6 0.3909 0.3669 0.9386 -0.0634
2.0 29.4 0.3909 0.3525 0.9018 -0.1034
2.5 28.0 0.3909 0.3357 0.8588 -0.1522
3.0 27.0 0.3909 0.3237 0.8281 -0.1886
0
TIEMPO(HORA) In[A] 0 0.5 1 1.5 2 2.5 3 3.5
-0.2
0 -0.9393
y = -0.0628x - 0.9283
1 -0.9961 -0.6
R = 0.9708
1.5 -1.0027
-0.8
-0.9393 -0.9579
2 -1.0427 -0.9961 -1.0027
-1.0427
-1 -1.0915
2.5 -1.0915 -1.1279
3 -1.1279 -1.2
TIEMPO (HORAS)
KMnO4 (0,02N)
H2O2 (75ml)
+
FeCl3 (15ml)
54
[2 2 ] = [4 ] (1)
22 2
(puro ) ( )
75ml 90ml
x 5ml
2 2 () = = 4,17
Reemplazando en la ecuacin (1)
530.4
[] = [2 2 ] = [0.02] [2 2 ] = 0.3645
2 4.17
526.7
[] = [2 2 ] = [0.02] [2 2 ] = 0.3201
2 4.17
522.5
[] = [2 2 ] = [0.02] [2 2 ] = 0.2697
2 4.17
519.2
[] = [2 2 ] = [0.02] [2 2 ] = 0.2302
2 4.17
515.5
[] = [2 2 ] = [0.02] [2 2 ] = 0.1858
2 4.17
512.6
[] = [2 2 ] = [0.02] [2 2 ] = 0.1510
2 4.17
Tabla de dato N1
Tiempo Gasto KMnO4 (ml) [A] [A] [A]/[A] Ln([A]/[A])
(hora)
0 30.4 0.3645 0.3645 1 0
0.5 26.7 0.3645 0.3201 0.8782 -0.1298
1.0 22.5 0.3645 0.2697 0.7399 -0.3012
1.5 19.2 0.3645 0.2302 0.6316 -0.4594
2.0 15.5 0.3645 0.1858 0.5097 -0.6739
2.5 12.6 0.3645 0.1510 0.4143 -0.8812
TIEMPO
(HORA) Ln([A]/[A]) Ln([A]/[A]) Vs. TIEMPO
0
0 0 0 -0.1298
0 0.5 1 1.5 2 2.5 3
-0.2 -0.3012
0.5 -0.1298
-0.4594
Ln([A]/[A])
-0.4
1 -0.3012
-0.6 -0.6739
2 -0.6739 -1
TIEMPO (HORAS)
2.5 -0.8812
KMnO4 (0,02N)
H2O2 (75ml)
+
FeCl3 y CuCl2 (15ml)
54
[2 2 ] = [4 ] (1)
22 2
(puro ) ( )
75ml 90ml
x 5ml
2 2 () = = 4,17
Reemplazando en la ecuacin (1)
530.7
[] = [2 2 ] = [0.02] [2 2 ] = 0.3681
2 4.17
513.3
[] = [2 2 ] = [0.02] [2 2 ] = 0.1595
2 4.17
56.2
[] = [2 2 ] = [0.02] [2 2 ] = 0.0743
2 4.17
54.5
[] = [2 2 ] = [0.02] [2 2 ] = 0.054
2 4.17
52.5
[] = [2 2 ] = [0.02] [2 2 ] = 0.03
2 4.17
51.2
[] = [2 2 ] = [0.02] [2 2 ] = 0.0144
2 4.17
Tabla de dato N1
Tiempo Gasto KMnO4 (ml) [A] [A] [A]/[A] Ln([A]/[A])
(hora)
0 30.7 0.3681 0.3681 1 0
0.5 13.3 0.3681 0.1595 0.8782 -0.8363
1.0 6.2 0.3681 0.0743 0.7399 -1.6
1.5 4.5 0.3681 0.054 0.6316 -1.9194
2.0 2.5 0.3681 0.03 0.5097 -2.5072
2.5 1.2 0.3681 0.1510 0.0144 -3.2411
TIEMPO
(HORA) Ln([A]/[A])
-1.6 -1
1
-1.5
1.5 -1.9194
-2
2 -2.5072 -2.5
-3
2.5 -3.2411
-3.5