I.

DATA PENGAMATAN
a. Kalibrasi dengan KCl 0,1 N
Suhu (T) = 25C
Daya hantar jenis (K) = 12,88 mS/cm
Tetapan Sel (Cell Const.) = 0,888

b. Penentuan Konsentrasi HCl 0,1 N

Volume HCl : 15 mL

no NaOH (mL) K (mS/cm)

1 0 14.18 26 25 5.48
2 1 13.03 27 26 5.72
3 2 11.95 28 27 5.93
4 3 11.12 29 28 6.11
5 4 10.26 30 29 6.33
6 5 9.45 31 30 6.53
7 6 8.64 32 31 6.75
8 7 7.88 33 32 6.93
9 8 7.18
10 9 6.5
11 10 5.21
12 11 5.18
13 12 4.64
14 13 4.06
15 14 3.48
16 15 3.03
17 16 3.13
18 17 3.4
19 18 3.71
20 19 3.98
21 20 4.24
22 21 4.51
23 22 4.76
24 23 5.02
25 24 5.23
 Volume NaOH vs K (mS/cm)
16
14
12
10
8
6
4
2
0
0 5 10 15 20 25 30 35

Volume NaOH vs K (mS/cm)

16
14
12
10
8
6 14 ; 2,5

4
2
0
0 5 10 15 20 25 30 35

c. Penentuan Konsentrasi CH3COOH 1 N

Volume CH3COOH : 15 mL

NaOH
no (mL) K (Ms/cm)
1 0 1.23
2 1 0.93
3 2 0.91
4 3 0.99
5 4 1.11
6 5 1.23
7 6 1.36
8 7 1.49
9 8 1.62
10 9 1.74
11 10 1.86
 Volume NaOH vs K (mS/cm)
2
1.8
1.6
1.4
1.2
1
0.8
0.6
0.4
0.2
0
0 2 4 6 8 10 12

K (Ms/cm)
2
1.8
1.6
1.4
1.2
1
0.8
1,8 ; 0,84
0.6
0.4
0.2
0
0 2 4 6 8 10 12

d. Penentuan Konsentrasi CH3COOH 0,1N

Volume CH3COOH : 15 mL

NaOH
no (mL) K (Ms/cm)
1 0 0.45
2 0.5 0.32
3 1 0.34
4 1.5 0.41
 5 2 0.48
6 2.5 0.57
7 3 0.65
8 3.5 0.73
9 4 0.8
10 4.5 0.88
11 5 0.96

Volume NaOH vs K (mS/cm)

1.2

0.8

0.6

0.4

0.2

0
0 1 2 3 4 5 6

Volume NaOH vs K (mS/cm)

1.2

0.8

0.6

0.4

0,6 ; 0,28
0.2

0
0 1 2 3 4 5 6
 e. Standardisasi NaOH menggunakan Asam Oksalat

No. Volume H2C2O4.2H2O Volume NaOH

1 15 mL 16.4 mL

2 15 mL 16.5 mL

Rata-rara 15 mL 16.45 mL

II. PENGOLAHAN DATA

a. Standardisasi NaOH
Perhitungan Konsentrasi NaOH Menggunakan Indikator Penolphtalein

Konsentrasi Asam Oksalat Awal :

N = gram/(Mr : 2 ) x 1000/v

= 0,63/(126 : 2) x 1000/100

= 0,1 N

Volume H2C2O4: 15 mL

Volume rata-rata NaOH : 16,45 mL

Konsentrasi Asam Oksalat : 0,1 N

Konsentrasi NaOH :

VNaOH x NNaOH = VH2C2O4 x N H2C2O4

16,45 mL x NNaOH = 15 x 0,1

NNaOH = 0,0912N

b. Titrasi NaOH 0,1 N - HCl 0,1 N

Penentuan Konsentrasi HCl
V NaOH x N NaOH = V HCl x N HCl
Volume HCl = 15 ml
Berdasarkan grafik volume NaOH pada titik ekivalen = 14 Ml
 NNaOH . VNaOH = NHCl . VHCl

0,0912 N . 14 mL = NHCl . 15 mL

NHCl = 0,0851 N

c. Titrasi NaOH 0,1 N - CH3COOH 1 N

Penentuan Konsentrasi CH3COOH :

V NaOH x N NaOH = VCH3COOH x N CH3COOH

Volume CH3COOH = 15 ml
Berdasarkan grafik volume NaOH pada titik ekivalen = 1,8 mL
NNaOH . VNaOH = NCH3COOH . VCH3COOH

0,0912 N . 1,8 mL = NCH3COOH . 15 mL

NCH3COOH = 0,0109 N

d. Titrasi NaOH 0,1N CH3COOH 0,1 N

Penentuan Konsentrasi CH3COOH :

V NaOH x N NaOH = VCH3COOH x N CH3COOH

Volume CH3COOH = 15 ml
Berdasarkan grafik volume NaOH pada titik ekivalen = 0,6 mL
NNaOH . VNaOH = NCH3COOH . VCH3COOH

0,0912 N . 0,6 mL = NCH3COOH . 15 mL

NCH3COOH = 3,65 . 10-3 N