Contoh Soal

Diketahui reaksi:
reaksi kompenen-i 1 2 3 4
j=1 : CH4 + H2O --> CO + 3H2

DHf,298 DGf,298
kompnenen vi,1 (kJ/mol) (kJ/mol) Cp/R = A + B.T + C.T2 + DT-2
A B x 103
H2O -1 -241.8 -228.6 3.47 1.45
CH4 -1 -74.52 -50.46 1.702 9.081
H2 3 0 0 3.249 0.422
CO 1 -110.525 -137.169 3.376 0.557
vj 2

a. Reaksi 1
DG298 (kJ/mol) = vi.DGf,298 = 141.891 kJ/mol R= 8.314 J/mol.K
ln (K298) = -57.27 T= 298 K
K298 = 1.3423812E-25
0
Jika DH298 = vi.DHf,298 = 205.795 kJ/mol
dianggap konstan, maka
untuk T = 600 C = 873 K Ky =
ln (KT) = -2.5607591073
K600C = 0.0772460801

epsilon trial = 0.5 YCH4 = 89.99875 YH20 = 299.99875

0.6 89.9985 299.9985
0.7 89.99825 299.99825
0.8 89.998 299.998
0.864 89.99784 299.99784
0.964 89.99759 299.99759
1.064 89.99734 299.99734
1.164 89.99709 299.99709
1.264 89.99684 299.99684
1.364 89.99659 299.99659
1.464 89.99634 299.99634
1.564 89.99609 299.99609
1.664 89.99584 299.99584

didapat epsilon = 0.864

XCH4 = 89.9904
 NAMA :
Eko Safitri (03031381419144)
Elsi Rosmalisa PP (03031381419112)
M. Daffa Rizqullah (03031181419052)

T + C.T2 + DT-2
C x 106 D x 10-5
0 0.121
-2.164 0
0 0.083
0 -0.031

0.0005505

YH2 = 1.50E+00 YCO = 0.5 Ky = 6.2501E-05

1.80E+00 0.6 0.0001296
2.10E+00 0.7 0.0002401
2.40E+00 0.8 0.0004096
2.59E+00 0.864 0.0005573
2.89E+00 0.964 0.0008636
3.19E+00 1.064 0.0012817
3.49E+00 1.164 0.0018358
3.79E+00 1.264 0.0025527
4.09E+00 1.364 0.0034616
4.39E+00 1.464 0.004594
4.69E+00 1.564 0.0059837
4.99E+00 1.664 0.0076672