PERHITUNGAN

1. Pembuatan Larutan
Larutan NaCl 3% b/b 100 ml
3
b = 100 100 = 3 gram air = 100 ml 3 = 97 ml

Larutan NaCl 6% b/b 100 ml

6
b = 100 100 = 6 gram air = 100 ml 6 = 94 ml

Larutan NaCl 9% b/b 100 ml

9
b = 100 100 = 9 gram air = 100 ml 9 = 91 ml

Larutan NaCl 12% b/b 100 ml

12
b = 100 100 = 12 gram air = 100 ml 12 = 88 ml

Larutan NaCl 15% b/b 100 ml

15
b = 100 100 = 15 gram air = 100 ml 15= 85 ml

Larutan NaCl 18% b/b 100 ml

18
b = 100 100 = 18 gram air = 100 ml 18 = 82 ml

2. Volume Piknometer

+
Vpikno =

71,1339 21,1223
Vpikno = = 50,1118 ml
0,998 /

+
3. lar =

72,2155 21,1223
NaCl 3% = = 1,0196 gram/ml
50,1118

73,3635 21,1223
NaCl 6% = = 1,0425 gram/ml
50,1118

74,3574 21,1223
NaCl 9% = = 1,0623 gram/ml
50,1118

75,5688 21,1223
NaCl 12% = = 1,0865 gram/ml
50,1118

76,6282 21,1223
NaCl 15% = = 1,1076 gram/ml
50,1118
 77,941721,1223
NaCl 18% = = 1,1338 gram/ml
50,1118

72,4703 21,1223
Isotonik = = 1,0247 gram/ml
50,1118

4. Massa Larutan = x V
MNaCl 3% = 1,0196 gram/ml x 100 ml = 101,96 gram
MNaCl 6% = 1,0425 gram/ml x 100 ml = 104,25 gram
MNaCl 9% = 1,0623 gram/ml x 100 ml = 106,23 gram
MNaCl 12% = 1,0865 gram/ml x 100 ml = 108,65 gram
MNaCl 15% = 1,1076 gram/ml x 100 ml = 110,76 gram
MNaCl 18% = 1,1338 gram/ml x 100 ml = 113,38 gram
MIsotonik = 1,0247 gram/ml x 100 ml = 102,47 gram

5. Massa Pelarut

Mpelarut = Mlarutan Mzat terlarut

MpNaCl 3% = 101,96 gram 3,0009 gram = 98,9591 gram

MpNaCl 6% = 104,25 gram 6,0008 gram = 98,2592 gram

MpNaCl 9% = 106,23 gram 9,0011 gram = 97,2289 gram

MpNaCl 12% = 108,65 gram 12,0006 gram = 96,6494 gram

MpNaCl 15%= 110,76 gram 15,0015 gram = 95,7585 gram

MpNaCl 18% = 113,38 gram 18,0012 gram = 95,3788 gram

6. Mobilitas Larutan NaCl

1000
M=

3,0009 1000
[NaCl 3%] = = 0,5184
58,5 98,9591

6,0008 1000
[NaCl 6%] = = 1,0439
58,5 98,2592

9,0011 1000
[NaCl 9%] = = 1,5825
58,5 97,2289

12,0006 1000
[NaCl 12%] = = 2,1225
58,5 96,6494

 15,0015 1000
[NaCl 15%] = = 2,6779
58,5 95,7585

18,0012 1000
[NaCl 18%] = = 3,2262
58,5 985,3788

7. Perhitungan Tf tiap larutan

Tf = T f - Tf

Tf NaCl 3% = 1,5 C 13 C = -11,5 C

Tf NaCl 6% = 1,5 C 11 C = -9,5 C

Tf NaCl 9% = 1,5 C 10,5 C = -9 C

Tf NaCl 12% = 1,5 C 12 C = -10,5 C

Tf NaCl 15% = 1,5 C 4,5 C = -3 C

Tf NaCl 18% = 1,5 C 3 C = -1,5 C

Tf Isotonik = 1,5 C 18 C = -16,5 C

8. Nilai Tf teoritis NaCl

Tf = m . Kf . i
dimana, Kfair = 1,86 C/m
NaCl = 2

Tf NaCl 3% = 0,5184 M x 1,86 C/m x 2 = 1,93 C

Tf NaCl 6% = 1,0439 M x 1,86 C/m x 2 = 3,88 C

Tf NaCl 9% = 1,5825 M x 1,86 C/m x 2 = 5,89 C

Tf NaCl 12% = 2,1225 M x 1,86 C/m x 2 = 2,89 C

Tf NaCl 15% = 2,6779 M x 1,86 C/m x 2 = 9,96 C

Tf NaCl 18% = 3,2262 M x 1,86 C/m x 2 = 12 C

9.