ort Figures and Tables for Kinetics Rate Equations and Examples of Simple Reactions (Perry, Chemical Engineering Handbook, 6" Edition, Table 4.1) Rate Equations and Examples for Typical Complex Reactions (Perry, Chemical Engineering Handbook, 6" Edition, Table 4.2) Rate Equations for Fluid-Solid Reections (Perry, Chemical Engineering Handbook, 6! Edition, Table 4.4). . Typical Values of Arshenius Parameters (Perry, Chemical Engineering Handbook, 6" Edition, Table 4.20). Comparison of performance of single CSTR and plug flow reactor for the nth-order reactions (Levenspiel, Chemical Reaction Engineering, Second Edition). Comparison of performance of a series of N equel-size CSTR reactors with a plug flow reactor for the first-order reaction (Levenspiel, Chemical Reaction Engineering, Second Edition). Comparison of performance of a series of N equal-size CSTR reactors with @ plug flow reactor for elementary second-order reactions with negligible expansion (Levenspiel, Chemical Reaction Engineering, Second Edition). Distribution of materials in a batch or plug flow reactor for the elementary series-parallel reactions (Levenspiel, Chemical Reaction Engineering, Second Edition). Comparison of performance of recycle and plug flow for first-order reactions (Levenspiel, Chemical Reaction Engineering, Second Edition), Comparison of performance of recycle with plug flow for elementary second-order reactions (Levenspiel, Chemical Reaction Engineering, Second Edition). (0810599 16:04M19 = 19 = Ny 9 999 = HY 3604 0) fsaba pou on oy opFYOP = ¥3 = 5 = Oty 19 to = Ya prow es390 a4. 3h rye saoma4ao! Jo i 296, BO apeagunye 4°79) aun +O 745) vottg tee + 9) y%5 Jo ssqyousd (2-y) 208 rh 24 jossios ror = ageg%oy = yore eo¥2y = vor = by aayloe-vi aT pes tal i ‘ servo — = nyery = 99) 179 + "9 Tey SE GS =o ae DW =D oer ery = Moh 4 By 2. D+ ey! ") on Fa v on My 2) gy PO) ~ (HD + ON =D (oreo) = or Lage Jo 4924 — YH = = ayagty = OY = 3058 — VN = He 85% — Yoty 2 agiagiy FEO Em patoat =U = agty — vot a a5ty 201 gh He Bovgty = a 65°94 FON we aoty + Yoh = te #204249)24 Jo 4 295, ata?TABLE 4-4 Rate Equations for Fluid-Solid Reactions (Unreacted-core model) (Guid) + bB(s) — products Case Controlling step Rate equation Fixed-size particles Diffusion through gas lm | Diffusion through ash order with et to A) Particle size varies: no Diffusion through ach formation gas film” ie 8 ° BBDCA, For large particle: | oy py? e iad | 8 Chemical reaction (ath order with. respect to A) @ are times required for complete conversion for individual controlling steps. Tim and ky are mass tively, based on unit surfac (Erst-order reaction) D, is effective difusivi ,concentration of A in mai “Adapted from Ref constant. sfer coefficient and reaction rate constant respec: m/s (ft/h) for km and also for k, when a = 1 of A in a porous structure in m?/s (ft8/h). Cay is fluid stream in mol/m® (mol/ft°). -10; y is mole fraction of A in uid, and K is aTABLE 4-20 Typical Values of Arrhenius Parameters” Tactivation energy.| Frequency Reaction system keal./g.-mole factor First-order gaseous decompositions: | | see.-* Nitrogen tetroxide 60 x 104 1 chlorocarbonate 9.2 x 108 | peroxide 3.1 x 10 Ethylidene dibutyrate 1.8 x 10" Acetic anhydride 1.0 x 10% Ethyt nitrite 14x 10% tert-Butyl chloride 25x 10% Methyl iodide | | 39x 10% Paracetaldehyde + 13 x 10% Ethylidene dichloride 12 x 10% Nitromethane 4a x 108 Azomethane 33 x 10° Propylene oxide 12 x 104 thylethylacetie acid j 33 x 109 5% 10" | 4.8 x 10" p-Xylene 5.0 x 109 Toluene ueceeaeee Second-order guseous reactions between stable molecules: mil. /mole-see. NO + 0, = NO, +0; 8x 10! Cyclopentadiene ans Cyclopentadiene + crotonaldehyde 1x 10° Isoprene + acrolein It 1.0 x Ine Butadiene + acrolein | 15 x 108 Butadiene + crotonaldehyde 8.0 x 108 Isobutylene + HBr \ 1.6 x 19le 2NOCI — 2NO + Cl, 9 x 10" i itadiene 47x lore .3-Pentadiene ceaeatsenee Isobutylene + HCI 10x 100 Ethylene Tx 198 Propylene 18 x 10" H, +1, — 2H1 | 1x 10% Isobutylene 2.0 x 10%" Ethylene + He : 40 x 1088 2HI— Hy + I, 6 x 10% Sec reactions i involving atoms or radicals: I H + HBr — H, + Br 12 H + Br, — HBr + Br | 1 CH, + -CHyo \ 7 CH, + -CiHig | 83 CH, + C,H, t 104 i Third-order gaseous reactions: Jnole?-see 2NO + 0, — 2NO, 0 or negative 8 x 10° 2NO + Br, + 2NOBr ~t ~ 107 ~i ~ 10° 0 0.34 x 10% {| 0 | 0.72 x 10% | 0 | 0.95 x 10 1 oO 1 2.7 x 108 * adapted from Frost and Pearson, Kinetics and Mechanism, 24 ed., Wiley, New York, 1961First ord Figure 8.8 rrr LSU S§$§E|"—l = nth-order reactions A — products, —r, = KCi The ordinate becomes the volume ratio Vesrn/Vorn oF the space time ratio teapltera if the same quantities of identical feed are used. (Adapted from Chemical Reaction Engineering, Second Edition, by O. Levenspiel. Copyright © 1972. Reprinted by permission of John Wiley and Sons, Inc.)First—order] | | reaction | I Li I oo i oo 1 I LT t ae 1 f | I 1 tt i Co | Corn =r ai ss PoE | LT Babe { Lit : we = R R+B—235fc Moly Bnjd pue aj>A9a4 yo a2uewsojied jo uostuedwos SUO}}3 294 JAP1O-Isuy ‘91 AUN DIS %o/9 10 100 Moly and O= a) e774 T --T GO=4y uonoeas 4aps0-}Si14 | MO}] PAX!L ‘com Y pc100 T Too T Second-order | H reaction {| | | { | { T fof | Ke 0.01 1 *IGURE 17. Comparison of performance of recycle with plug flow for lementary second-order reactions 2A— products, © =0 A+B-+products, Cay = Cao with e = 0