TIU CHUN QUC GIA

TCVN 9742:2013
ISO 7514:1990
CH HA TAN DNG RN XC NH TRO TNG S
Instant tea in solid form Determination of total ash
Li ni u
TCVN 9742:2013 hon ton tng ng vi ISO 7514:1990;
TCVN 9742:2013 do Ban k thut tiu chun quc gia TCVN/TC/F20 Ch v sn phm ch bin
son, Tng cc Tiu chun o lng Cht lng thm nh, B Khoa hc v Cng ngh cng
b.

CH HA TAN DNG RN XC NH TRO TNG S

Instant tea in solid form Determination of total ash
1. Phm vi p dng
Tiu chun ny quy nh phng php xc nh tro tng s ca ch ha tan dng rn.
2. Ti liu vin dn
Cc ti liu vin dn sau rt cn thit cho vic p dng tiu chun ny. i vi cc ti liu vin
dn ghi nm cng b th p dng phin bn c nu. i vi cc ti liu vin dn khng ghi
nm cng b th p dng phin bn mi nht, bao gm c cc sa i, b sung (nu c).
TCVN 9741:2013 (ISO 7513:1990) with Amd. 1:2012), Ch ha tan dng rn Xc nh m
(hao ht khi lng 103 oC)
TCVN 9743:2013 (ISO 7516:1984), Ch ha tan dng rn Ly mu
3. Thut ng, nh ngha
Trong tiu chun ny s dng thut ng v nh ngha sau y:
3.1. Tro tng s (total ash)
Phn cn li thu c sau khi x l bng axit clohydric v nung 550 oC 25 oC theo cc iu
kin quy nh trong tiu chun ny.
4. Nguyn tc
Phn hy cht hu c bng cch x l vi dung dch axit clohydric m c v nung 550 oC.
Cn phn cn li.
5. Thuc th
5.1. Axit clohydric, dung dch m c (20 = 1,16 g/ml n 1,18 g/ml), c cng nhn loi
phn tch.
CNH BO Dung dch axit clohydric m c l cht n mn, bi hi gy kch ng v
gy chy; v vy dung dch ny phi c x l theo thc hnh phng th nghim tt.
6. Thit b, dng c
S dng cc thit b, dng c ca phng th nghim thng thng v c th cc thit b, dng c
nh sau:
6.1. Chn, dung tch khong 50 ml, bng platin, s hoc cc vt liu khc m khng lm nh
hng n kt qu ca php th.
6.2. L nung, c th duy tr c nhit 550 oC 25 oC.
6.3. Bp in, kim sot c nhit .
6.4. Bnh ht m, c cha cht ht m cn tc dng.
7. Ly mu
Vic ly mu phi c tin hnh theo TCVN 9743 (ISO 7516).
8. Chun b mu th
Trn k mu ch ha tan nhn c bng cch lc hoc o chiu vt cha mu y kn.
9. Cch tin hnh
9.1. Chun b chn
m bo rng chn (6.1) hon ton sch, sau nung t nht 30 min 550 oC 25 oC trong l
nung (6.2). Lm ngui trong bnh ht m (6.4). Sau khi ngui n nhit phng, cn chnh
xc n 0,001 g.
9.2. Phn mu th
M vt cha mu v cn ngay khong 2 g mu th c chun b (iu 8), chnh xc n
0,001 g, cho vo chn chun b (9.1). Dn mu u trn y chn.
9.3. Xc nh
Nh tng git dung dch axit clohydric m c (5.1) vo phn mu th ng trong chn (9.2),
s dng lng va (khong 1 ml) lm m ht mu.
t chn ln bp in ngui (6.3), bt bp mc trung bnh v un trong 30 min. Tng nhit
bp in n mc ci t cao nht qua ba bc lin tip, mi bc, un trong 30 min. Gi
phn mu th ti mc un cao nht cho n khi khng c khi xut hin trong t nht 5 min.
Cho chn ng phn mu th vo l nung (6.2) 550 oC 25 oC trong 16 h. Ly ra, ngui v
thm vi git nc lm m v phn tn tro. Lm bay hi n kh trn bp in (6.3) nh trn
v cho tr li l nung (6.2) ri nung thm 30 min. Ly ra, ngui n nhit phng trong bnh
ht m (6.4) v cn chnh xc n 0,001 g. Xc nh khi lng tro tng s chnh xc n 0,001
g.
CH THCH Ch ha tan tro ha trong cc iu kin ny phi cho tro mu xnh/trng.
9.4. S ln xc nh
Tin hnh hai ln xc nh trn cng mt mu th.
10. Biu th kt qu
Tro tng s c biu th theo phn trm khi lng cht kh, c tnh bng cng thc sau
y:
m1 100
100
m0 RS
Trong
m0 l khi lng phn mu th, tnh bng gam (g);
m1 l khi lng tro tng s, tnh bng gam (g);
RS l hm lng cht kh ca mu th, c biu th theo phn trm khi lng. Hm lng
ny bng 100 tr m xc nh c, s dng phng php quy nh trong TCVN 9741 (ISO
7513).
Ly kt qu l gi tr trung bnh ca hai ln xc nh, vi iu kin p ng c yu cu v
lp li (xem 11.1).
11. chm
11.1. lp li
i vi hm lng tro tng s trong di t 10% (khi lng) n 22% (khi lng), chnh lch
gia cc kt qu ca hai ln xc nh, tin hnh lin tip (hoc tin hnh ng thi) do mt ngi
thao tc, s dng trn cng mt thit b, trn cng mt vt liu th, khng c qu 0,4% (gi tr
tuyt i).
11.2. ti lp
i vi hm lng tro tng s trong di t 10% (khi lng) n 22% (khi lng), chnh lch
gia cc kt qu cui cng thu c do hai phng th nghim s dng phng php ny
phn tch trn cng mt mu th, khng c qu 1,2% (gi tr tuyt i).
12. Bo co th nghim
Bo co th nghim phi ch r phng php s dng v kt qu thu c. Bo co cng
phi cp n mi chi tit thao tc khng quy nh trong tiu chun ny hoc nhng iu c
coi l ty chn cng nh cc s c bt k c th nh hng n kt qu th nghim.
Bo co th nghim cng phi bao gm mi thng tin cn thit nhn bit y v mu.