Professional Documents
Culture Documents
Ironsteel Piacs 00007 0511
Ironsteel Piacs 00007 0511
Steel is and will remain the most important engineering and The process of steelmaking has undergone many changes
construction material in the modern world. With an actual because of technological and economical reasons. Large,
steel production of over 100 million tons per month, the integrated steel mills were built in the 1950s and 1960s at
global iron and steel industry is a very dynamic industrial high capital costs and limited flexibility. They produced steel
sector. Further steps are ongoing towards increasing resource in batches by refining iron ore in several steps.
and energy efficiency, reducing emissions and providing safe
and healthy work environments. Increasing energy costs made thermal efficiency in steel mills a
priority. The furnaces used in integrated plants were already
Process automation equipment including gas analysis very efficient; however, the production processes needed to be
instrumentation contributes essentially to that. improved. To help reduce energy consumption, continuous
casting methods were developed. By keeping blast furnaces
Siemens Sensors and Communication, a leader in process continually feed with iron ore, heat is used more efficiently.
analytics, has proven worldwide its competence to plan, With increasing environmental concerns relevant regulations
engineer, manufacture, implement and service analyzer have become more stringent, again affecting the steel making
systems for use in iron and steel making plants. This case industry. Global competition is another factor that has forced
study provides detailed information. steelmaking facilities to optimize processes and to reduce
expenses and increase quality.
Iron and steel
Process analytical equipment, mainly continuous gas
Steel is an alloy of iron usually containing less than 1% analyzers, support the steel making industry to master
carbon. Because of its versatile properties and its recycling successfully these challenging changes. Siemens Sensors and
possibilities, steel is the basic material for sustained Communication provides efficient analyzers, expertise and
development in modern industrial society. It provides a broad solutions to this analysis task.
range of uses in almost all important sectors of industry such
as apparatus and machinery manufacture, bridge and
building construction, power and environmental engineering,
and automotive and transportation industries.
www.usa.siemens.com/processanalytics
The Iron and steel making process
Steel making basics is coke, which is produced in coking plants blast furnace and leave from there at a
using a dry distillation process in a coke temperature of approximately 1500° C via
Steel production involves four basic steps oven. Volatile components of the coal a tap hole into ladles. The limestone
(fig. 1): pyrolized and set free by heating the coal impurities mixtures float to the top of the
to 900 to 1400° C. Very often coking molten iron and are skimmed off after
First, fuel and/or electricity, iron ore, plants are located very close to the steel melting is complete.
reducing agents e.g. coke, additives and plant so that the coke oven can be heated
if so, scrap are prepared (Inputs) using a mixture of blast furnace gas (low Sintering products may also be added
Next, iron ore is converted to pig iron calorific value) and coke oven gas (high to the furnace. Sintering is a process in
through chemical reduction at high calorific value). which solid wastes are combined into a
temperatures using a reducing agent. porous mass that can then be added to
Three different routes are available Hot air (blast) with a temperature of the blast furnace. These wastes include
Next, raw steel is produced from pig iron 1200° C is blown into the lower part of the iron ore fines, pollution control dust,
using oxygen to remove carbon and blast furnace via a hot blast stove. This coke breeze, water treatment plant
other components from pig iron. Two consists of a combustion chamber and a sludge, and flux. Sintering plants help
different routes (basic oxygen vessel and heat storage zone. Blast furnace gas reduce solid waste by combusting waste
electric arc) are in use enriched by natural gas is burnt in the products and capturing trace iron present
Finally, raw steel is further treated and stove. The off gas is directed over heat in the mixture.
refined (secondary metallurgy) storing stones which absorb the heat.
When switching to fresh air feed, the To optimize the process and lower the
Reduction routes stones release the heat to warm up the production costs, other carbon carriers
fresh air. such as coal, oil, gas or processed waste
Blast furnace plastics may be injected as a coke
A blast furnace is a shaft-like unit The coke carbon gasifies with the oxygen substitute.
(fig. 2) that operates according to the contained in the blast to form reducing
countercurrent principle. Iron ore, coke, gas (carbon monoxide). The gas rises in Direct and Smelt Reduction
heated air and limestone or other fluxes the furnace, binds the oxygen, and there- Direct and Smelt reduction are alternative
are fed into the blast furnace. All iron ore by causes the reduction of the ores to technologies to the conventional blast
carriers contain oxygen, which has to be iron. Limestone or other fluxes are added furnace process avoiding the use of
removed through reduction in the blast to react with and remove the acidic expensive coke. Direct reduction
furnace by using carbon as a reducing impurities from the molten iron. Hot metal technology was developed first as a
agent. The most important carbon carrier and slag collect in the lower region of the possible replacement for the dominant
blast furnace to allow economic
production even on a smaller scale. Later,
Inputs Reduction Steel production Secondary metallurgy it was followed by the smelting reduction
technology.
Basic Oxygen Furnace (BOF) Steelmaking from scrap metals involves This production step primarily follows
The hot iron still contains impurities melting scrap metal, removing impurities the objective of reducing the carbon,
such as carbon, silicon, sulphur and and casting it into the desired shapes. nitrogen, hydrogen, phosphorus and
phosphorus at concentrations higher Production of steel from scrap can also be several other elements in the steel, in
than desired. These unwanted economical on a much smaller scale. addition to homogenizing the liquid
constituents are removed in basic oxygen. Frequently mills producing steel with EAF steel and keeping the temperature
Furnaces also known as steel converters technology are called mini-mills. within tight and precise limits.
(fig. 3). The impurities are oxidized
in the converter by top-blowing oxygen To charge the furnace, the roof of the After the molten metal is released from
through a water-cooled lance. Certain EAF is lifted and the scrap charged into the secondary metallurgy treatment it
quantities of scrap are added as cooling the furnace. The roof is moved back is formed into its final shape and finished
agents, since the oxidation process and the electrodes lowered, igniting to prevent corrosion.
generates a strong amount of heat. an arc on the cold scrap. During the
A converter holds up to 400 t crude melt-down process, temperatures in
steel. Lime is also added for slag forming the arc reach as high as 3500° C, and
purposes, and alloying agents. The in the steel bath as high as 1800° C.
blowing process takes approximately The high temperatures also enable the
20 minutes. Also practiced nowadays dissolution of difficult-to-melt scrap
besides pure top-blowing with oxygen alloy constituents. Additional injection
is combined blowing, in which inert of oxygen or of other fuel-gas mixtures
stirring gases or oxygen is additionally accelerates the melt-down process.
injected through the converter bottom.
Fig. 2: Blast furnace Fig. 3: Steel converter Fig. 4: Ladle furnace (Secondary metallurgy)
Gas analyzer
Fig. 5 shows, an example, how a steel • In particular, the energy content of the Small dimensions and rugged design
plant based on the blast furnace and basic gases, as described by their calorific (IP65, NEMA4X, pressure-resistant
oxygen furnace route including a coke gas value, provides the user with important enclosure) enable MicroSAM and SITRANS
plant, is typically equipped with process information about efficient firing of CV to be installed right at the sampling
analytical instrumentation. Table 1 different plants in the steel mill (coking point even under difficult ambient
shows sampling points together with the plant, sinter plant, rolling mill, etc.) or a conditions. Special and air conditioned
corresponding measuring components, nearby power plant. analyzer houses or rooms are not required
measuring tasks and suitable analyzers. • High-calorific coke or natural gas is anymore. The concept "change
Other steel plants, of course, will differ mixed with low-calorific converter or components rather than repair the device"
from this example depending on process blast furnace gas in mixing stations. together with extremely low consumption
routes, local conditions and technological This is to adjust the calorific value of the rates of auxiliary media reduces operating
issues. mixture to the requirements of the costs and increases availability of the
subsequent consumer and to avoid chromatographs.
Gas chromatography discharging of valuable gases into the
At sampling points 6, 13 and 14 the use off gas. MicroSAM and SITRANS CV are
of process gas chromatographs is very • The knowledge of the calorific value characterized by a remarkable high
reasonable in order to analyze the fuel together with information about accuracy in determining the quality
gases (blast furnace gas, converter gas, pressure and flow rate of the fuel gas parameters of blast furnace, coke and
coke oven gas) by measuring the enables the user to adjust a constant natural gas.
concentration of e.g. CO, CO2, O2, N2, CH4, energy content of the mixed gas using
H2. There from the calorific value and the an intelligent control system.
Wobbe index can be calculated. • Furthermore, analysis data of the gas
chromatographs (MicroSAM or SITRANS
In modern steel plants, also natural gas CV) are also used to determine the
(not shown in fig, 5) is increasingly used equivalent amount of oxygen that is
due to its high calorific value. required to run the combustion process.
This results in a stoichiometric and
uniform combustion and prevents soot
production.
Oxygen converter process Lime based fluxes and other substances Gas analysis and "melting curve"
The oxygen based converter process is a may be charged as well to combine with The converter off-gas mainly consists of
common method to make steel from pig impurities to form slags and/or to give the carbon monoxide and carbon dioxide from
iron. The converter vessel is first charged steel the desired properties. Finally the the oxidation process. Their concentration
with molten pig iron from the blast converter is emptied into ladles. The levels and concentration variations over
furnace. Then a water cooled lance is whole process is completed in 15 to the process runtime directly provide
lowered into the vessel through which 20 min. important information about progress
pure oxygen is blown into the melt at high and endpoint of decarbonization, the
pressure (Fig. 7). The oxygen, through temperature of the liquid metal and
oxidation, combines with the carbon details about the slagging process. That
contained in the molten iron to form way the CO and CO2 operation curves act
gaseous CO and CO2, which are separated just like a "fingerprint" of the melting
from the molten metal and released from cycle details.
the melt as part of the off-gas.
90 50
Fig. 6 shows typical concentration Gain on response time: 22 s
recordings of CO and CO2 in converter gas
75
over a full decarbonization cycle of 40
approximately 20 minutes from both
From demanding analysis tasks in the Fig. 12: MAXUM edition II Process GC
chemical, oil & gas and petrochemical
industry to combustion control in power
plants to emission monitoring at waste
incineration plants, the highly accurate
and reliable Siemens gas chromatographs
and continuous analyzers will always do
the job.
Analyzers and chromatographs are Fig. 10: LDS 6 in-situ laser gas analyzer Fig. 14: SITRANS CV natural gas analyzer
available in different versions for rack or
field mounting, explosion protection,
corrosion resistant, etc.
$QDO\]HU 6\VWHP
0DQDJHU$60
,QGXVWULDO(WKHUQHW
*DV&KURPDWRJUDSKV
Global support 10
Siemens Process Analytics – Our Services