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    cipw norm procedure

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    © All Rights Reserved
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    59 views10 pages

    CIPW Norm Calculation

    Uploaded by

    Tilahun Mersha
    cipw norm procedure

    Copyright:

    © All Rights Reserved
    Download as PDF or read online from Scribd
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    Appendix 1 a Chemical Calculations Appendix 1A: CIPW Norm Calculation Procedures Note: These rules have been abridged for the most common rocks. They omit certain contingent calculations which must be observed if the rock is unusual or if rigorous accuracy is required. See form on pp, 432-433 for guidance in the calculations 1. AAU Determine for each oxide the molecular number (divide Wt.% by Mol. Wt.). Multiply by 1000 to clear of decimals. Throw away any result fess than 2 unless it is K,O. . Add MnO to FeO if MnO > 2. Make normative minerals as follows. Every time you use some of an oxide, enter it as debit against the analysis. Cross off all oxides when they are used up. . Apatite (ap) All P,O, + 3.33 times as much CaO as there was P,O,. . Magnetite (mr) All Fe,O, + equal amount of FeO. . Imenite (if) All TiO, + equal amount of FeO. . Orthoclase (or) All K,O + equal amount of Al,O;. . Albite (provisional) (ab) All Na,O + equal amount of Al,O;. . Anorthite (an) Ail the remaining Al,O, + equal amount of CaO. "If the CaO is gone before the Al,Os, the excess Al,O, is called corundum (c). 428. Appendix | Chemical Calculations 9. Assign SiO, = 6or, 6ab, 2an. In the following calculations, M = all remaining MgO + FeO, Xu. = MgO/M N_ = initial Na,O, K = initial K,O XS = (SiO, used — SiO, inital) 10. di. Make remaining CaO into di, with M = CaO. Assign SiO, = 2CaO. 11. hy, Make remaining M into hy, Assign SiO, = M to ky. FIND XS. 12. q. If XS < 0, change the sign, call it g, and go to step 17. 13. by tol. Let of = 2XS, hy = M — ol. Assign SiO, = thy, SiO, = ol/2. £4, ol. If hy < 0, let of = M, hy = 0 and proceed. FIND XS AGAIN. (If XS = 0 go to step 17.) 15. ne. Make ne = XS/4, ab = N — ne. Assign SiO, = de, SiO, = bab. Ifab < Olet ne = N, ab = 0 and proceed. FIND XS AGAIN. (If XS = 0 go to step 17.) 16. Ic. Make le = XS/2, or = K — Ic. Assign SiO, = 4le, SiO, = Gor. XS = 0 + | IF NO ERROR. 17. Mg/Fe TREATMENT. Complete di, Ay, of as follows. di; wo = CaO hy: en = hy(Xu,) ol:fo = OMX yy) en = CaO(Xy,) Ss =hy — en fa =ol -fo fs = CaO —en 18, WEIGHT NORM. Multiply first molecular number for each molecule times the molecular weight/1000 in column HJ. Add up end members. for fsp, di, hy, ol. Add ‘Rest’ at bottom of column IV. Sum should equal analysis sum + 0.5%. Appendix 1A: CIPW Norm Calculation Procedures Selected chemical analyses from Macdonald and Katsura (1964), 14 Is 16 17 18 Spec.no. C4 CIS C16 CIT C18 SiO, 50-22 50-80 49:50 49-70 49-90 TiO, 2-08 1-93 210 2-48 231 Al,O, 15-14 15-25 15-38-1483 14-65 FeO, 3-64 291 451 447 S69 Feo 8:27 723 699-752 GBS. MnO 017 016 86017) O17 O16 MgO 718 827 723° 617 657 CaO 10-07 983 © 10-44 10-34 10-25 Na,O 1-93 2S 2100-213 DAS K,O 0:33 0-28 039 =025 0:26 H,0- 0.55 032 0:36 «0470-50 H,0+ 073° 0-75 (0-88-01 0-82 P,0, 0-25 0-25 0-28 = 0270-26 Total 100-56 100-13 100-33 99-81 100-40 Q 588 45600 468 7147-80 or 1-67 1672-22167 1-67 ab 16-24 17-82 17-82_—17-82_— 17°82 an 369-341 31-4 3002-29-75, wo 684 6507-77 B12 800 di} en 430 4-400 5-40 5405-70 fs 241 1-58 17200 2-11 1-58 ny fen 13-70 16-30 12-70 10-00 10-70 fs 686 6340 4:22 4092-7 fo - — _ — _ ot fie _ _ _ _ _ mt 5 4-18 650 650 B35 it 3-65 395 0 471 441 ap 0-67 0-67 0-67 0-67 GROUP 1. No olivine. 429 Appendix 1 Chemical Calculations Selected chemical analyses from Macdonald and Katsura (continued) 13 i4 15 16 Spec.no. C65 C66 C70 C69 SiO, 43-49 48-72 47-48 45-54 TiO, 3-38 219-263 BBS ALO; 1666 91511 17-421 7-61 Fe,0, 3-69 179-359 3-56 Feo 11-05 950 810 BS MnO 0-18 O17 O18 = OIT MgO 6-74 870 «674 G42 CaO 893 10-69 854 10-82 Na,O 235 185 31274 K,O 0-25 0-28 1-20 0-70 H,O- 1-29 O12 0-22 O10 H,O* 141 072 0-40 O60 PO, 0-33 0-23 0-36 0-34 Total 99-75 100-07 99-98 99-70 Q - _ — = or Vl 1677-23 3-89 ab 19-91 15-72 26-20 23-06 an 34-47 (31-97 30-02 33-92 ne = ~ ~ _— wo 336 B47 4:06 742 di ¢ en 1-90 5-10 2-60 4-70 fs 1-32 290 119224 h en 8-40 16-40 460 0-60 | Sf 5-94 9-50 211 0-26 a1 455 O21 «6727-49 Va 3-37 O10 3-47 3-98 me 5:34 25S 534 534 it 6-38 426 5025-32 ap 0-67 034 LOL «0-67 GROUP 2. Olivine & hypersthene. Appendix 1A: CIPW Norm Calculation Procedures 8 9 10 Spec.no. C22 CB C79 SiO, 4799 $025 49-79 TiO, 262 212251 Al, 19:36 19-03 1837 FeO, $83 4536.03 FeO 347 $50 4-82 \Mn0 021 «0-22 O22 MgO 439° SIL 401 CaO 654 $98 6-68 NaO 458 5300 458 K,O 182-220 2.08 H,O- O17 0-40 0-32 H,O* 0-33 O54 0-24 P,O, 0-63 14 0-56 Total 99-64 100-32 100-21 Q — — _ or 10-56 1279-12-23 ab 361S 4297 37-73 an 26:97 21-68 28-91 ne 142. O85 0-57 wo «OBL 023035 di den 0-60 0-20 0-30 Ss O13 _ =- en = _ _ hy{ fs - —- oF at { # 728 «$32 «6-79 Sa OSI 255 O10 mt 835650882 iu $02 39834 ap 134269134 GROUP 3. Nephetine. z i j Analysis No. Petrographer_ Oxide Wt.% Mol. Wt. Mol. No.* _Subtractions Calculations SiO, _— a M = MgO+FeO after il = ALO; 102 — FeO, ___ 160 ——— Xuq = MgO/M = FO. T2 —_—— N = Na,O = MnO 7 XS = (SiO, used-SiO, initial) MgO ___ 40 — q = [XS

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