ow ae ©- Cag Val 20 29190-10198 ted at an. goad Pu sosee-sorsi) coozt-1 S884 #8188 ¢8.00'+ 90 ‘THERMODYNAMIC EVALUATION OF Fe-Sn PHASE DIAGRAM Hr Raa, ols a Delay ‘Bguronn a ete Oven owen “te Cran? ot ann BELGIUM (Prod CALEHAD 00, Mao, USA ne 1986) [ABSTRACT The thermody depts fr lhe ble pases in the Fen system ae obtained tye lstequeeepinzton othe Utmost and the pase ogra ct om ltr: Te et resend of expen forbs energies of pre en re {in The cles pw dip and termechemial properties are comped wih he xperientldta snzopucTon “Tan ison undestedsement in steel hoses grenboundary enbithment ae tar dtr ‘ncchcal popitne of se With he eve inceing demand for myalng of sap in he sel {nny the chars having on nn sel ata ces b oer totale hi pb is Import kow the phe dag ad themodyeamic properties af ti Fes system Te purpose of the work is to stn dhemodyramie dserptor for al able phases of the Fen Som Oy ‘pti hernacomal nd pase apa data fo he erate [xperimeal dla forthe Fon est ware ily eval by several authors (an, ‘ta 82s 900k 97h [Nas] ced at he heey modeling snd the cleultion of the pise ding, vilsng experimental dats fm erat Gb nary xpi for eres ‘ed by [9 Nisa amy considered fob cuca ph Fo ar Sy ep 5 Sle by (aN ae ow beloved to be metble: Moreover te sable compound Fes, Was Pot [rcded inthe escent f(s) Sc the work of Ns] mone experi dts hav come {vale Hence new maceusmertf he hemedyami decption is Waraned TWeRMOOYNAMIC MODELS ‘ne ultra passin he Fen tem ate: Lig, BCC, FCG, BCT, and four inet compound analy Fay Fe Fe and Fen, ‘rial veson reseed on nny 1995, vise Yen on 2 Fea 1996uo 6 HARI KUMAR ‘he lg, AC, and FOC pees ae male a random sions. The negra! lar Ge ergy (6) cepa cane expres ab Eat ergata atte whee "0 the Gi ergy oF eS inthe scr tte (= Liu BCC oF and a Ua tha ‘The conics “a obtained by the leastsqure optimisation of the expeimasal (thermochemical and phe dram dt The emperatr pendence Ui, mesprened a “thes en. “Te Gb ergy cottons das to the magale warlon of BCC ant FOC phases a ecried ung he Herat model (AE), Amin © tie mode the bbe ene of mage ‘nding, oh, given Mets armas og, Whee is the average mgtic monet per aa eprsed in Ra mags, 8 a polo Fenton of and itr 727 blog the etal weopertze othe mae erst Ba and 72 may bcocentaton depend. ‘The slubilyof Fen the BCT phase i nelly ow. This allows us Yo ttt as BCS. Al ‘etemete pause mele atc cmon, ace hae am no experectal dt her omopenely anges ‘Gis ENERGIES OF PURE ELEMENTS aes enemy expres for BEC, FCC, Laue, BCTSR, BCC, and Liga Sa ae ‘akan fom 91Din Tse we ot ede hare nore sae Spc. erry expression fr he _etutable FCC So tan an the wok IN, ec ago = 45510-8467 J ‘Ts expression compares rate wel with the experiment enalpy and entopy foe BCT-ACC ‘raeormaton pres pet Fea. COPTNRSATION OF MODEL PARAMETERS _Expsimonal data forte FS tema rahe sparse due wo severe epaimatal dials in ending ths sytem For camp, vlsle natu oan approxima sane deny frig Fe se ag Sn preven ele detriton of teh mit gp wing weno metsEVALUATION OF Fo-Sn PHASE DIAGRAM [TRULEY Seminary af apeinental Themen Data forthe Fea Sem Tefzess —[-—_Eepemenal einige Und Messen Sm | pore aint sh — [ip pee ‘sigs re tga Tava nd io ay of ig ‘ie ibs nes of san of Fed FS, [rss ag mu re Ep fgg Tiki — [Tasers aa od, ea. Enya gS Bian — [ive weno a Bo on an [Mas spectamary sd, iil nya ag oT Ea [Can ay of ig ga zat] bs rps of farses of Fee ane, use [esa py mig af gd Ne [Na gene ain “ABLE 2 Sumy of fxprinetal Fase Diagram Data ore Sa Sem iia [Themal anaes meabgghy — [aga Fh as, tan Tikde— [Weal Sabi esp ont ar] BoBC wes=) “tae | henselae agaphy [Soul iy Sat — [emia aay reSastaqidvagd ‘tae | Key, deren CONE FS) ‘ints | Mesa Macy “iba — [Outed Da] Monae ‘aw | Qo in orb sb ‘tba —| Quad ORB) Sc ie ‘sta noon ‘kr — [en Seat ie ‘shi [au Ms spe [any Heep gfe Mach ina a “ie [ay RCCHBCCY Fe) Fk fen COREE Resa) al — [Di cng ay BPA Si, COC Fey "etn [Bison Sil ng of oppo ion [Resins erm Sercheoecte a Mee igs; [gation A Fe iq i — ives — [Dian opt, FPA Sts, BCCABCCHne Fee) ‘sin [x Sabi of empeae Nes |i sr sig gp Sls [A Fe ie1 6 HARI KUMAR o {or the lntsquate opinion hetyramic an phase dara data ae dos rm he titrate: Tenet sma in ber and 2 Cota evalantons of KG, 9001, S103] were ‘snsieed while cing the pe gra dt forth opiisation Expos othe concentration pens 72 an I ape baie tot a aay of tho enpeinena dts dc te [the Th Cure grate of BCC x dere igh by the ‘etn Sn f2Ne nda ay experienal ata regan egret popes PCC Pee see a 1 oD ao rr asin epg pp npeimental stad sugges minciy gap he gl phe, Unforterely ‘he daw scattered tht aes tiation a potion of te mca yp very ie. [00a 210k place ies pur ote mst papa 0. X, 778K) based nthe expeinen) leo (tana, HPN, However [ODka) pai ot eat (BCL Liu igldas Word Sppens fo sugges as even ler tegen. Tare the seed clity gap 8 Vry meaty ‘nea ity be nt Har "GE could be deeb BY Xk found at Crartocsulte de misty gap suggested by 1Oke| ove rogue an Ui, of 26H 2SIET Ha Mong evap fru alloys wee etd sing alorinetry by 2 rumba of esis (rate, it Lc} Fathers, (20g, SOs, Sam calculated ebay of mig for bey fom earned acves Th clone mesma by eS, Bet ar st sonable Spconent withthe rns of Krusoneal ave spear tes by [Siam 0° FA ‘peed ees thn at aw tt nny ing an erp by XX, 884 “Te activity of Fe and/o Si alge were ao Meaney Pay twetipons employing rious wetvuqes and at several teers Kon, Man, OSM, 7k, 72g, 77d, Aho, ‘t¥ami, Nan} In ode to male compacta of he oot af thse uc al he aly da ae [alcultel fo 16? sing vant Hol Serve. Camron shows tat slit data ported by fern stay ee] am i rmeuble oper, se Figs 7 and 3) Stamens weighed ogni of sled yl expel eyo ning (Lat ¥en] and act data {ern f2¥omt, koe} ater Unt "G2" can be anatoly nerd by NX Q1857 29707, ool Tas epson cpl wih he psa exprenin ng Taka ml (ST, 9H] (ba288 IT However wth tar expen impose opr the misty {sp suggested by 510k Sc slr may be wed as det cartons in experimental at ‘ie tre wpored hermodyeanie da seen agree wi one ate ha he asc fp ‘nu it nave ly tht former sale. Tht ws eno eordenstion wle weighting te ‘epinetl dnt fr oponatinsThe starting vale fo Ly, wae tha coven a 257-2577. “Anappovimae value fo °LES, i aed rm nays of th Ligd/BCC atloope pase boundary an the acy data due [SLAG Te storing valu for “Ui dined om he rays oF Liga/ FC alle pawe ondary For compound appoint values for Ue moa paras Sree sti fm theosyama dla (7 SZab) and magus odie of Ue hase ‘Sli iwaling tone compound 10a ‘he fia optimisation was permed wing PARROT move of he Thomo-Cale data stem [Sun Aliogter 290 pases of dat were In optniston. Approimae alice of ote parce ctsined a explained sve nerd a pan sting vac fore tons. eal ‘Seana c del perietes that minse hs tal sum aque eran, eit ine[EVALUATION OF Fen PHASE DAGRAM rn Discussion 1 Fig 1h cult ewtaiy of mining Higa phases compa with experimen at “Te cakulte eueate pou apne wh he sul of Ea], spc ne Hecho 2nyeement wih the dat de [Le and [8] ae ao rntonble Enh of ming ts Imported by (72Aep Mar devise siglo ef TY, SDSS Beth 7g ant [SoMa] coined prs oud ity get tpertor fh tes (110 Kan 17K respect) Ltr satis by (81ar2] and [7a] showed ut Os regions wel above the tlemisng eon Caloric data pred by (Pet ao show 4 ferent tnd Caney ce hn (72 ng, 78 tha) werent considered in fhe opis “Th ctv Fe Sin the gid oid 1979, a compat wth experimental at in Riga 2 and'3-mapectiely. Tw olcuated Feats compre well wih experimental als of (cekon, Nun. The agement 9 the clase Sn actin with experimental ets of (1, {PNanlis ao resonable Sacer oben by vpoutpresueteanaennts I, MS, 7, "red deviate conser frm the est. The prec spears to be tet for Fe acts tan Sh ‘cto nig actviy of Sn BCC aloy ae compared wih i epenraldatau (S.AT Jn “leased it ep formain of en and Fen ae compre wih experimen at. 1 ig Ste clei pce dg compar with experenta dt rm the rae Except fr testy gupta with te epee dita The cele ‘ie porto the mii gap i 1X lower a ot ep by (and, TN, shows he ‘Sanju tien the ete plop an experimental data. Calli cooranates of sant ‘ett ty compan wih eae values ACeNOWEDCEMENTS “The inci upp ere the Depstnent MM fhe Kalk Univer Leven byte mish Minny of es snd by te Rewach Coe o Kahle Universit Leute, the ftameworkof COA-Adt Conta 92/964, pally acknowledged (sy Etonic and Tammana, Zong Cham, 5, 281-2719. SIEAwe CA. Edward an A, Pec Stl st, Lando, 124-6089 SANE Ned, Aen Phys, 18 (850, {9B WR Bet ae AF Wetge, J Am Chen, Sc, 8 19923510909) Red) O.Redich ed AT Ke, Id ng Chem 34534096) ‘cam: ALN. Campbal JH, Wood, nd Gi Sint, Am. Char So: 7, 172-7358), 1A Kaho a. Akad Nak SSSR, Ot Tei Nok, (1), 46511957. kak Stine M Hansen, Consens McCraw Hook Company Ie, New Yck,pp.718- ra (tax C Juma PL aA Mil CR. Sans Ad SS, 27, 1905197186. (ue Kail and, Twrdogany Tar. Metal So AIME, 24 120212380969), (6Der: TRA Davey nd JM. ay Proc Australas est Min Met, 218, 14196)owes PA. Weght Rance Meaty CT evi, Amsterdam (186) (Darts TRA. Davey, tt. Mining Met, Tas, SC, 76,C274C28i967. ‘THA Dave, rt Maing Met, Tras, Se C76 C6695, Mil. Wada ane. Wad, ron Se st, London, 205, 544-8117, or (Kor: Z Kanak, ¥ hidahura,E Sugnoto,N Watarbe an} Moriyama, Nippon Kogyo Kai, Sines she Sy Shh and HH Hal sk Mining Mt, Tas, Sct, 77,CIOUCHL Mor: J. Moriyama and Z Kens, Men Fae. Bg, Kolo Un, 3, 88857095). (Yar A.Yazaes and K Kathe, Nippon Kogye Kash, 650, 3942096) ‘7M SY. Sarah and HL elt Mig Met Ter, Set C7, CLAO-CIZANO) ‘ibs VN fromenb, GM Lather, an V1 Pat lv. Akad, Nauk SSR, Met, (0), entre ‘Pipe: A Splgh Mel SI, 6 57-0072). ‘iow: T-Heumane an Ft Wotan Z Meta 68 323400972). ‘Wag: § Mapper and GR Sere Met Tens, 3, 257325780972) ‘la K Hulten PD. Des DT Hawks, M. Ges, end KK Kelly Sa Valustihe ‘arn Sooty fo Meas Meas ark Go, possess. 7st % Peel and M, Fb Mtl ars, 2482390979, AN: M. Nagesnasis, Ch Manon, and H Harman, Mtl Trane, §,1061-108057 7Utrt: D-teeeus D.Dag an Gaal Mee 5 Re. Met, 71, 2882581978) 24tra D. Trees P Guilin Se Metal, 8,5 340978) 75Con:_ J. Conny sn LV- Mel Ata Mel, 23120-1214097) 18h: VN Enema, MEM. Chur and LE. Pacentovaay, ev. Akad. Nauk SSSR Mat soso, {ifed: AN Federer nd VG Hrovkn Sb. Nau Te: Gos. Prsktn Naw se ns Gipret0)} 8940977. ene Mert and Mot Capa 227280579, ‘abet MS Perwtersi, Yo. Ein VM, Bp, an PV. Ca, Re. Meta, (0), 6-970, {Nise HLD. Nise, 0. Yon Goch, and). Spon, Capa 3192489). Mar _N. Maruyama and Hay, Nippon Klgok Gola 4, 14221581880, LAs: M. Arts, M. Ohya, KS. Got and M SomenoZ. Meal, 722425015) SIN: TL NgslandV.A, Chang Cp § 257276058) S1Yam: M Yamiots, 5. Mod an E Kato Testo Fagan 7, 15298), Yana Yamamoto, Takashing a Khia, Nipper Kao Gata 5, 565-9006). ‘Kb: 0. Kutachewsi mia ae Diagrams Spring erg, Rein pp 1142980. ‘Yam M.Yanimots, Morn Kato Trane. kon Stel nt pa 23, 56-4185). BRE Gl stain, VS Sudatoe, an VP. Kura Abad Naa SSSR Met, (0, 5010980), 12a Zaye, stay, Ach Hat, 2827-28418. LGR Lick and Pre Z Mela, 75, 684-8485.sun sake san: 1 Sunde, Jason a ]-0, Andes, Cpa 9 15190085 [M SinghandS. an J Miter St Lat, 5, 735755058) '5.Nunoue and Kal Testo Hagan, SGH75(987. 1. Foh MX Zhrg..A. Gang, and JL Fespesk, Metal Tran A 204, 795 002989), 1. Okamoto oar Alloy Phase Dag Second Fon Vol, B78, Mass, ASM. Tniematana Matera atk ONo pp. 774777050) AT Die, Cala 183172809). Ils. Tana, T. Yul Tia and Mot Tete Hagan, 77, 2423009, Okamoto, Fe don), iy Has Diagrams Sec Beta 95), ‘C Ha Kumar, P. Wallets and Delay, Program nd Abstracts, CALPHAD XXD, (Cte Spin ay 1621 (08) "Tina, NA. Gost 21 Mot and id, 2 Metal, 418219098) [ ARLES Opie Vals of Mac Poem Tor Soaton ‘Phanesindhe Fea St Tiga GaiFatee ts tga e204 is ip, = 6417 rug 2074 CC. (imate ofsons) pg, = eaeaaa v.seor ugg aeaaa = s1048x, +018 Xf) BP 12.00%" 658 5X. a Behe magtos) FCC. nmol sors) 53, = 928610 201.0%) Lore a5 Hi Te OH TET) ose 61,028 Fo, time ota5r) or PH TM HA GST) 01270 51.008 FS: amie 5h) GH EY Cc) 48072 94.9047 Fi aT fF Hs BE) NO TR) 781867 8067 “TABI Comparison of Calclaiod Gita Engin aT le ow] af Fon aed Fs with Experinentl Daa oat erate sien Sis PeBce, Se uqus Prase ‘lad apermanal | Soace esa | Bois sat —| ae 0a [si sn, SEs RT — | — 27816 +2868 — | — hz Fs a ud 30507 | eteKC. HARI KUMAR ora "TABLES Compara of Cleland Teva Equip wih trate Valo Racin —| Conpaitin al ise Xa Eee = Bg: 3900-098 0-797 ea BH OOS SIE aT obs 2: 180. 0-07, st 39-38, 8.085, kab oa one 0 aoe oar REGRET 8 oe TOIT Cees ha. en TSO 510 Ege [OSs eae wae Gist con TITS OaeT Ose 310m ERROR [OTS 0.0522 0-0 Gated FSO o-aT Oks Higa] 0: 008-941, 0-500 Gated Risa seus Toe OTST asoe 9s] woh ERR |e to 0-7 0-500] 580| Cate Tae =7s—[ sb Saga] S00 wes C667 | Teo | eat 76 [ata TSO E TE ECT] 06st SST | Oa OH 8 [Se Ses eee oan SHS | — acon[etoronce states Felon setuid row /r ‘oun fo 09H Mole Fraction Sn FIG. 1, Enthalpy of Mixing of Liquid Fe-Sn Alloys Fotorence Site [pega Mole Fraction Sn FIG. 2, Activity of Fe in Ligid Fe-Sn Alloys at 1873 Keteronce Sate 2 ohh ok ak Mole Fraction Sn FIG. 4. Activity of Sn in Liquid Fe-Sn Alloys at 1873 K otronce Sate : [stig F |S o« 68 ts l> 6 Soe FIG. 4, Activity of Sn in BCC Fe-Sn AlloysMole Fraction Sn FIG. 5, Computed Fe-Sn Phase Diagram Compared with Experimental Data fom Literature