Professional Documents
Culture Documents
CBSE Class 12th Chemistry Theory Set 1
CBSE Class 12th Chemistry Theory Set 1
com
Q5)s ~ . :iIii1
tR~~1
i i
. Please check that this question paper contains 12 printed pages. ! ';)
",'
. Code number given on the right hand side of the question paper should be t
written on the title page of the answer-book by the candidate.
. Please check that this question paper contains 30 questions.
. Please write down the Serial Number of the question before
attempting it.
. 15 minutes time has been allotted to read this question paper. The
. ~m~~~~~~~,~~~~~1
~ ~ ~ ~ ~ ~-~~ -q'{ ~ ~ ~ ~ I
CHEMISTRY (Theory)
56/1 1 P. T .0.
...'
"
.,
Downloaded From:http://www.cbseportal.com
General Instructions:
(i) All questions are compulsory.
(ii) Marks for each question are indicated against it.
H/~/-<I ~ :
.'3i~~ q;1~''qj)
~ ~ I
2. What is meant by 'shape selective catalysis' ?
, ~ 3Tr'i:"frf{ff ( ~ -~~ fCfC:q ) ~' CiiT ~ 31'4 mm ~ ?
~~~~~-q:3tw~~ I
56/1 2
Downloaded From:http://www.cbseportal.com --cc,~
'I
CH2 = CHCH2Br
CH2 = CHCH2Br
4-q.<:"J1\1~;?:-1-2-:ift;r ~ ~ 3:r~ ~ I
if you know its mass density and the dimensions of unit cell of its
*
~-~
crystal.
31N ~
(~)
~
~
~ "q)"T ~CX.j~I-i
m m ~
~
~
~
~CX.j~I-1
~ ~
i1:r ~
~ ~
~?
~
CX.j1~1
~
2
~I
10. Calculate the packing efficiency of a metal crystal for a simple cubic
lattice. 2
~ ~-1lcfJl( ~ (~ ~ ~) ~ fu{{ ~ ~ ~ ~ ~ ~
yRcfJl(.1d ~ I
Rk1I(.1I~d "q)"T"qj~ ~ :
(i) ~{10!4-1'i# ~I~I~ ~~ ~ # ~ "q)"T ~ I
(ii) f4~ # ~ ~ ~ ~ ~ ~~ # ~ "q)"T ~ I
56/1 3 P.T.D.
- -
III_IIIII=
Downloaded From:http://www.cbseportal.com
--
12. What do you understand by the rate law and rate constant of a
reaction? Identify the order of a reaction if the units of its rate
constant are : ~
31fq~3l~~~~~~~~~~~ ?~~~
1r1~I(.1I~(1 ~ ~ 3:{fi:{~ ~ W ~ ~ ~ :
c o. ) 11 L mo 1-1-1 s
Cii) ~~I~.s ~ ~ ~ ~ m ~ ~
56/1 4
\
Downloaded From:http://www.cbseportal.com
serIes.
~I~~ ~ "q)RUT ~ ~ ~ :
(ii)
-a:qT.\11.fq;jm-cn
~ ~31T
~I ~ M 9)uft #, -m ~ d~ ~ # ~:q~~ ~~ ~
~ -qR"rT ~, ~ 9)uft $ ~ # ~ ~ ~ I
(i) MnO
-
4 (aq) + 82°3
2- (aq) + H2O (l) -t
,
(i) Cu (I) ion is not stable in an aqueous solution.
(ii) Unlike Cr3+, Mn2+, Fe3+ and the subsequent other M2+ ions of
the 3d series of elements, the 4d and the 5d series metals
\ (1)
. Mn?
-
4 (aq) + 82°3
2- (aq) + H2O (l) -t
,
:
31~
$ "q)RUT ~ :
~I
~I~~
56/1 5 P.T.D.
...
"'
---
Downloaded From:http://www.cbseportal.com ~i~~" 1 8-.
...
-'..,...
, ~f';~ '
(i) ~~ ~
18. Write the main structural difference between DNA and RNA. Of the
four bases, name those which are common to both DNA and RNA. 2
~~~~.q'Qr(!:~~ I
molar mass.
~~~I-1
20. Classify colloids where the dispersion medium is water. State their
OR
~-~ ~<:.I~(UI ~ I
3t~
~I~I ~ fCfi ~ mm ~ ~
(ii) ~~~m~~M~.q~~~~~
56/1 6
Ei\ii;
Downloaded From:http://www.cbseportal.com
, ,,'
~
",;~,:
c...'~;~
,
1. How
(i)
would
H2S is
YOU
more
account
acidic
for
than
the
H2O.
following: 3 ~W ,,\
"i
(iii) Both 02 and F 2 stabilize high oxidation states but the ability of
oxygen to stabilize the higher oxidation state exceeds that of
fluorine.
~~fctft9""(1: ~ ~ ~ ~ :
(iii) 02 ~ F 2 ~ m ~ ~ 31"CfT!lJ.T311 ~ ~~ ~ ~ ~ ~
22. Explain the following terms giving a suitable example in each case: 3
~~~~~~~~I
~~~~f;{~~~~~~~:
(ii) ~ ~ ~ (Denticity)
compounds ~ ~ ~
of each of the ~
(ii) l-Bromo-3-methYlbutane,2-Bromo-2-methYlbutane,
3-Bromo-2-methylbutane
\ (iii) l-Bromobutane,
l-Bromo-2-methylbu~ane
l-Bromo-2,2-dimethylpropane~
.
t;
;. (i)
~~~~~~~~SN2~~~~~~~:
2-~-2-il~~~~' 1-~~~' 2-~~~
56/1 7 p.T.G.
Downloaded From:http://www.cbseportal.com
- ~
.
24. How would you obtain the following: 3
31fq" R~I~I{gd ~ ~ ~ :
(i) ~ ~ ~~II~-1I-1
(iii) ~ ~ ~-2-~
(i) pKb value for aniline is more than that for methylamine.
water. . ,
I
(iii) Primary amines have higher boiling points than tertiary amines. ~
1-1~I~I{gd ~ q:jT\UT ~ :
(i) Polythene
(ii) PVC j
(iii) Teflon 11
R~I~I{gd ~~~~~~"CfIT
~~ ~ : I
(i) ~\!ft';:r
(ii) PVC
(iii) ~
56/1 8
Downloaded From:http://www.cbseportal.com of f
--~-- ~
---
27. What are the following substances? Give one example of each. 3
(i) "&ro ~
28. (a) What type of a battery is lead storage battery? Write the anode
and cathode reactions and the overall cell reaction occurring in
the operation of a lead storage battery.
(b) Calculate the potential for half-cell containing
0.10 M ~Cr207 (aq), 0.20 M Cr3+ (aq) and 1.0 x 10-4 M H+ (aq)
OR
reaction that occurs when the cell generates an electric current.. : f_:
2+/ =- 0 ~
.
(Given: E 1.66 V)
N .
1
N
1 AI AI 5 .
f'~'. '. .
, ~\;:
~ ~ i~Fi_,. I :_~~ft:c
Q, I\,I~~ . :;;;e:'
(b) 0.10 M ~Cr207 (aq), 0.20 M Cr3+ (aq) ~ 1.0 x 10-4 M H+ (aq) ':i,
"'-~.;:
4.
.,
ql~ ~~-~~ "q)T
~~
Ig~g
..~_.
'11\q)I~(l
F;;,~ ~
'f)11"l~ I .;r
~;, "~
31tf-~ ~~ ~ "SI"q:jR
~ ~ ~ '."
3:r~
56/1 9 P.T.D.
.
~ ~
Downloaded From:http://www.cbseportal.com
-~J~I. !
\
i
.I
-, (a) 3 ~ ~ 'f(;nr; 2.00 A ~ ~ ~ ~ ~ * 1.0 M Hg(N03)2'~
"
~ 'q:jT ~ - 31f:ff1G;;r ~ '\jffifT ~ m ~ ~ ~ W 'q:jT d ~ I c:: wi W1T ?
~~~~~~mm~~~'q:jT~~~ I
(i) (HP03'3
(ii) BrF3
OR
(ii) Why does fluori:ne not play the role of a central atom in
interhalogen compounds?
(iii) Why do noble gases have very low boiling points? 5
!
56/1 10
Downloaded From:http://www.cbseportal.com
'-
--
..
-~ .~IIIIIIII
~ ,",",", c",- ~.
(i) (HP03)3
(ii) BrFs
a:r~
(a) 'q:<:rT ~ ~~
(i ) Na oH ~ ~ 1T{!:I" ~ # "CR'!l-U-;:r
~ ~ ~?
i:fi1\3fT"ffi
(b) R~I~I(gd ~ ~ ~ :
(i) H3P03 i:fi1 ~ (basicity) ~~ ~ ?
'q:<:rT
~ ?
(iii) ~ (~) ~ ~ ~~rjictl~ ~ ~ ~ ~ ,?
',.c~,;;
30. (a) Illustrate the following name reactions:
OR
56/1 11 P.T.D.
Downloaded From:http://www.cbseportal.com
""':-
(b) Complete
eachsynthesis
by giving missing reagents or products
in the following:
(i)
(( I
COOH SOCl2
~ COOH heat
H2NCONHNH2
(ii) C6H5CHO ~
(i) tmro ~ ~
(i) ~ ~ ~-2-~
(ii) ~~ ~ ~~~ ~
(iii) ~1~~~~I-1 ~ ~~ ~
3t~
(i) ~~~~~~~
~~ -qj) 1uf ~ :
(( COOH SOCl2
(i) I ~
~ COOH ~
H NCONHNH
(ii) C6H5CHO 2 2 ~
Downloaded From:http://www.cbseportal.com