SO GD&DT THUA THIEN-HUE ‘THI THU DAI HOC LAN’ Tee asheahor Mén: HOA v8 TRUONG THPT CHUYEN QUOC BOG HOC ‘Thdi gia lm bai: 90 pit ‘Hp, tén thi sinh: Sé bio danhi, ae Cho biét khdi lugng nguyén wr (theo u) cl cde nguyen 1S Ta: yy P=31:Cl=35,5; Br 27; Cu = 64; $= 32: 0 16; Pb =207: N= 14; Mg = 24: Zn = 65; Cd = 112; Fe 5; F = 19; Na = 23; Ag = 108; Ba = 137; H i 188 gam Cu(NOs)s vi. 29.8 gam KCI (dign eye tro, ming ‘ngin). Sau mt thi gian khdi luong dung dich gidm 17,15 gam so vdi ban dau, thé tich dung dich {a 400ml. Néng do mali eée ehAt trong dung dich sau dign phén A A. Cxci =05M: Cxxos=0,25M 5 Cxou = 0,25M B. Cxcr~ 0.25M 5 Ckwos = 025M 5 Ceon ~ 0,25M €. Cc = 0375M 3 Cxwos = 0,25M ; Ckon = 0,25M D. Cxci = 025M i Cynos =0.5M;” Ckon = 0,25M ‘Cau 2: Cho tirtir 150m! dung dich HCL 1M véo 500ml dung dich A gdm NasCO va KHCOs thi thu duce 1,008 lit khi (dktc) va dung dich Y. Cho dung dich Y tée dung v6i dung dich Ba(OH), der thi thu dirge 29,55g két tia, Nang d6 ctia NazCO va KHCO, trong dung djeh A lain Ture 18 ‘A.0,2 va 0.4M B. 0,18 vi 0.26M €.021 v40,32M D.021 va0,18M Caw 3: Dung dich chia 0,15 mol brom téc dung hét véi axetilen chi thu duge 2 chit M,N la déng phan ofa nhau, trong dé M ¢é khdi Iuigng la 13,392 gam, khéi Iwong cdia N la ‘A.14,508 gam B. 18,6 gam €.13,392 gam D. 26,988 gam (Cau 4: Trdn mét thé tich Hi v6i mdt thé tich anken thu duge hbn hyp X. Ti khdi ca X so vii Hy IA 7,5, Dan X qua Ni nung néng duge hon hyp khi Y c6 ti khéi hoi so véi Hz 1a 9,375, Phan tm khdi lng cia ankan trong Y la 4.20% B.40% 60% D.25% Cu §: Cho cde phan tmg: (a)Zn + HCI (loin) (b) FeO. + H2SO4 (loaine) (@) KCIO; + HCI (dae) (a) Cu + He80, (de) (@) Al +H,80, (loang) (g) FeSO«+ KMnO, + H:80, ‘86 phan img ma H’ ciia axit déng vai tro chit oxi hod 18 AS: B.6. 3 D.2. CAu 6: Thity phan hoan to&n m gam hdn hop X gém sacearozo va mantozo thu duge dung dich Y. Cho Y te dung voi Ivong du dung djch AgNOs/NHS thu duve 0,2 mol Ag. Mat khée, thay phan m gam hén hop X mét thai gian (higu suét thiy phan m3i chit déu [3 8024) thu duge dung dich Z. Cho Z tée dung vi long dur dung dich AgNO, trong NHs thu duge 0,168 mol Ag, Phan tram khdi Jugng cila saccarozo trong hn hyp [a ‘4.60%. B. 55%, €. 40%, D.45%. Cu 7: Cho biét ion M™* 6 cau hinb e & phan Ip ngoai cong fa 3d*, Chon phat biéu dang: ‘A. Bign tich hat nhin ez nguyén tir M 18 30. vacua ion M1 28. B. Dién tich hat nhan cla nguyén tir M a 28 va cia ion M** 1a 26 tich hat nhin eda nguyén tir M va ela ion M’* bing nhau va bing 28 tich hat nhdn ela nguyén tir M va eda ion M2" bing nhau va bing 26 ‘Cau 8: Hda tan 14g hdn hop Cu, Fes0¢ vio dung dich HCI, sau phan img con dur 2,16g hén hgp chat rin va dung dich X. Cho X tée dung, voi AgNO dur thu duoc kh6i litomg, két tia 1 A.47,40 gam. B, 58,88 gam. €. 45,92 gam, D. 12,96 gam, Cau 9: Hn hyp X gbm mg angchit don ehire, mech his va métankin (phan tr ankin o5 cing s8 nguyén tir H hang it hon mot nguyén tir C so vai phan tir andehit), Dét chdy hodn toan 1 mol hn hop X thu direc 2,4 mol CO3 va 1 mol nude. Néu cho | mol hn bp X 14 dung vi dd AgNOs/NHS ci WS ugng ket ta thu dirge 1a A. 308 gam, 1B. 301,2 gam. 1D. 144 gam: ‘Trang 1/4- Ma 8 thi 132‘Cau 10: Phat bigu ndo sau diy 1a dang? : ‘A. Tring hop butae{ 3-dien véi stiren 06 xtie tée Na duuge caosu buna-S. B. Trang hop stiren thu diye poli(phenol fomandehi. C.To Visco la toting hop. 1D. To nilon-6,6 duge diéu ché bing phan img tring hop hexametylen diamin voi axit adipic. Fan 11+ Cho hin hop c6 a mol Zu tée,ctune v6i dung dich chira b mol Cu(NO»)> va c mol ABNOx. Két thie pphan img thu due dung dich X va chit rin Y. Biéta = b + 0,5c, Vay: A. X chira 1 mudi va Y c6 2 kim logi. B, X chia 2 mudi va Y e6 | kim logi. .X chita 2 mudi va Y c6 2 kim logi. —_-D. X chia 3 mudi va ¥ €6 2 kim logi, (Chu 12: Day ghm ede ehdt 06 khi nding phan ting t20 ra polime fa ! A. atilen, buia-1 3-dien, cumen, axit adipie B.1,1,2,2-tetrafloeten, clorofom, propilen, isopren C.stiren, phenol, acrlonitrin, etylen glicol Dinilen, metyl motacrylat, anit eaprois, vinyl axetat (Céu 13: Modi sit 11 im mat miu dung dich KMnO, & méi trudmg axit cho ra ion Fe", cén ion Fe™ vic dung vei F cho [ava Fe. Sap xép ode cht oxi ha Fe", MaOs theo tht €8 magah ting din A.b< MnO. < Fe" B.MnO, < Fe" 2H) 2) HEk) > 12 He (Kit 12 bk) Snihigt db xde djnh, néu Ke eda dn bing (1) bing 64 thi Ke cia edn bing @) la Ad B.0,5.. €.0,25. D.0,125. ‘CA 38: Hoa tan hoan todn 3,75 gam hén hap: 8, FeS, FeS2 trong HNOs di duge 0.48 mol NO; va duny dich X, Cho dung dich Ba(OH); dur vao X, loe két tia nung déa khdi lung kh6ag di thi khéi lugng ehi rin thu duge a A. 17,545 gam B. 18,355 gam 15,145 gem D.2.4 gam Cu 39: Cho cdc chat: BaCly; NaHSOs; NaHCOs; KHS: NH,CI; AICIs; CHsCOONH,, AbOs, Al, ZnO. $6 cht ludmg tinh 1 AS. BAT. C5. D.8. iét rang X chi chia 2 nguyén 16. $6 chat Cu 40: Cho so d3 sau: xenluloza —>X)—> Xr-> Xs-> polime X, ting v6i Xs 1a A? Bl C3 D4 Cau 41: Xa phéng ha hoan toan 100 gam chat béo co chi s6 axit bing 7 cdn a gam dung dich NadH 25%. thu dage 0,13 gam glynerol-va b gam muSi nate. Cid tj eca a, b Ldn huge 18 va 103,37 B, 49,2 va 103,145 .51,2 va 103,37 D. 51,2 va 103,145, tho hn hgp Na, Al, Fe, FeCOs, FeO tée dung véi dung djch NaOH du, Ige lly két tia ri chia lam 2 phan. Phan | dem tie dung vai dung dich HNO ling dur, Phan 2 dem tée dung voi dung dich HCL dur. Sé phin img oxi ha Khir xay 4a la AS. B.6. C.8. D.7. Cau 43: Dung dich X chia 0,01 mol CIM3N-CH;-COOH, 0,02 mo! CHs-CH(NH2)-COOH; 0,05 mol HCOOCH;. Cho dung dick X tic dung vGi 160 ml dung dich KOH 1M dun néng dé phin img xdy ra hodn roan, Cé.can dung dich sau phan img thu durge m gam chat rin khan, Gia tei ctla m 1a A, 8,615 gem B. 14,515 gam C. 12,535 gam D, 16,335 gam Cfu 44: Suat dign dong chun cita pin dign hod Zn-Ag va Fe-Ag [an [uot bang 1,56 V va 1,24 V. Sut dong chudn cia pin dién hos Zn-Fe 1a A.0,64 V. B.1,40¥. €.0,32V D.2,80V. (Cau 45: Cho so dd: Etilen tence x, HO, yy HPOIHe yyy OBB yy, X, 18 L axit cacboxylic don chite, Vay CTCT cia Xyli A CH;CLCOOK D.CIICOOTT E.CH-CHCOON ——_p. C1CLI-CLIcoOLT ‘Cfiu 46; Dét chay hoan toan 54 gam hén hop X gbm axit fomic, anit axetic, axit acrylic, axit oxalic va axit adipic thu duge 392 lit CO» (dktc) va m gam H,0- Mat khdc, khi cho 54 gam hdn hop X phan img hoan toan véi dung dich NaHCO, dur, thu duos 21,28 lit CO, (dkte). Gié tri cita mm Ki ‘A. 46,8gam, B.43,2 gam, €.23,4 gam, D.21,6 gam, (C4u 47: Dung dich axit fomic 0,007 M c6 pH = 3. Két tun ndo sau day khong ding? ‘A. Khi pha lodng 10 lan dung dich trén thi thu duee dung dich c6 pHi = 4. B.D6 dign Ii ofa axit fomic s€ giim khi thém dung dich HCI. €. Khi pha tong dung dich trén thi d3 dign li cha exit fomie ting, D. D6 dign li cca axit fomic trong dung dich tein 18 14,29%, (Cau 48: Chat hitu co éon chisc X mach hi chita C, H, O. Cho X tic dung voi Hy dur e6 m§UNi, dun ndng, thu duge chat hin cor ¥, Bun V véi H2SO, die 6 170°C thu duoe chit hou co Z. Tring hyp Z thu duge poli(isobutilen). X o6 hao nhiéu eau tao théa man? AS B.S C4 b.2 C4u. 49; Lién két trong phan tir nao duge hinh thanh nhé sw xen phi p- p? A, NHS Bch HCL Dit Cau 50: Nhng mt thanh Fe vao dung dich HCl, nhin thay thanh Fe sé tan nhanh néu ta nho thém vao dung dich ands vai gigt A. dung dich K2S0,. B. dung dich Na,SOs. t C, dung dich CuSO,. D. dung dich NaOH. ~ HET ‘Trang 4/4 - Madé thi 132