Test - 4 (Paper-I) (Answers & Hints) All India Aakash Test Series for JEE (Main)-2014

TEST - 4 (Paper-I)

ANSWERS
PHYSICS CHEMISTRY MATHEMATICS
1. (4) 31. (1) 61. (2)
2. (3) 32. (4) 62. (1)
3. (1) 33. (1) 63. (3)
4. (1) 34. (3) 64. (2)
5. (2) 35. (4) 65. (2)
6. (4) 36. (2) 66. (1)
7. (3) 37. (3) 67. (1)
8. (3) 38. (2) 68. (2)
9. (1) 39. (1) 69. (4)
10. (3) 40. (1) 70. (3)
11. (2) 41. (2) 71. (2)
12. (3) 42. (1) 72. (2)
13. (3) 43. (2) 73. (4)
14. (3) 44. (1) 74. (3)
15. (3) 45. (3) 75. (3)
16. (4) 46. (3) 76. (2)
17. (3) 47. (3) 77. (4)
18. (4) 48. (4) 78. (3)
19. (3) 49. (3) 79. (2)
20. (1) 50. (1) 80. (2)
21. (3) 51. (1) 81. (2)
22. (3) 52. (3) 82. (2)
23. (3) 53. (2) 83. (2)
24. (4) 54. (3) 84. (1)
25. (4) 55. (4) 85. (1)
26. (3) 56. (2) 86. (4)
27. (3) 57. (4) 87. (4)
28. (4) 58. (4) 88. (3)
29. (4) 59. (1) 89. (2)
30. (3) 60. (1) 90. (3)

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All India Aakash Test Series for JEE (Main)-2014 Test - 4 (Paper-I) (Answers & Hints)

PART - A (PHYSICS)
1. Answer (4) For pure rolling,
m 0
R
( 3 1)mg R v t ...(iii)
Spring force : kx = R ( 3 1) 3f
R
1 2
= 2mg Now, s at
2
Total force along centre of circle 2 2
R
∴ s 0
= 2mg cos 30° + mg cos 30° 18 g
3 3mg 6. Answer (4)
=
2 A
= NB

90
C

°–
2. Answer (3) v2

θ
v
G 45° θ
Rˆ 2R
ap aiˆ i ( jˆ) O v1 B
2 2
OC
3 ˆ v2 BC
ai ( jˆ) sin 2
2 2R
OC
3. Answer (1) AC
cos 2
2
l Ml OC 1 1
mu ...(i) BC AC ...(i)
4 12 2 sin cos
l /2 l /2 2 v1
2 M
F dF dm x x dx ...(ii) Also, cot ...(ii)
l v2
0 0

9m 2u 2 Also, BC AC AB t v12 v 22 ...(iii)

∴ F
8M l Solving equations (i), (ii) and (iii), we get
4. Answer (1) v1v 2 2
v
Let point P moves with velocity v and its direction v1 v 2
makes angle θ with l1. 7. Answer (3)
Now, v sin θ = v1 ...(i) G G G
mu mv1 mv 2 ...(i)
and v sin(α – θ) = v2 ...(ii) 1 1 1
mu 2 mv12 mv 22 ...(ii)
Solving (i) and (ii), we get 2 2 2
From equations (i) and (ii), we get
v12 v 22 2v1v 2 cos
v u2 = v12 + v22 = v12 + v22 + 2v1v2 cos 90° ...(iii)
sin G G
Thus, v1 v 2 0
5. Answer (2)
8. Answer (3)
f ft Velocity of BALL w.r.t. ground (after collision)
a v at ...(i)
m m = (v – u) + v = 2v – u
2
mR 2f ⇒ ΔK = Kf – Ki
f R
2 mR 1 m 2
= m[(2v u )2 ] u
2ft 2 2
⇒ t ...(ii)
0 0
mR = 2mv(v – u)

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Test - 4 (Paper-I) (Answers & Hints) All India Aakash Test Series for JEE (Main)-2014

9. Answer (1) 13. Answer (3)

The impact should be inelastic. WE theorem,
JG JG
2 work done = K F d
2u 0 3v v u
3
14. Answer (3)
1 2
⇒ KE = (2 1) v F – 30 = μ1(m1 + m2)g
2
1 F – 30 = 0.5 × 15 × 10
= 3 v2
2 ⇒ F = 105 N
=3 Here, friction (limiting and kinetic) between 10 kg
2 and horizontal surface is 30 N.
v 2
⇒ 1 v 2
2 15. Answer (3)
4 2 3 1 1 2
⇒ v 2 v ms mgh mv
9 2 W 2
P =
10. Answer (3) t t
2
mxrel = (m + M)x m v
= gh
t 2
m
⇒ x xrel
m M 2
m 1 V
m d 1 2 = gh
A v 2 ms t 2 A
m M dt rel 3
2
200 1 V
⇒ F MA N = V P gh
3 2 A
11. Answer (2)
1 2
m1y1 m2 y 2 3 1 1 10
yCM = = 10 10 10 10 2
m1 m2 2 10

2R 4R = 15 kW
m m
3
= 16. Answer (4)
m m
a
5R m [m m][ x ]
= 2
3
12. Answer (3) a
⇒ x
4
The block leaves the surface at t = 5 s.
a a 13a
dv 20t 100 Hence, d 3a
Now, a 2 4 4
dt 10
17. Answer (3)
v t
20t 100
⇒ dv dt Forward journey :
0 5
10
10 2 1
⇒ v = 25 + t 2 – 10t t 5 t s
2 2
dh 2
⇒ 25 t 10t 10 2 1 1 1 15
dt y 10 m
2 2 2 4 4
125
⇒ h m vx = 10 ms–1, vy = 5 ms–1
3

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All India Aakash Test Series for JEE (Main)-2014 Test - 4 (Paper-I) (Answers & Hints)

Backward journey : 20. Answer (1)

15 1 2 3
5 t 10 t t s
4 2 2 v
v ω=
R
e × vx × t = 5
3 1 t=ts
⇒ e 10 5 e
2 3 α
18. Answer (4)
t=0
v 2v0
v
3 ω0 = 0
l 3
ω0 R f
r N1 N2
C G 2v 0 f
v t ...(i)
mg 3 m
2
mR
f1 f2 f R ...(ii)
2
For no skidding :
2
2f
mv ...(iii)
mg v max rg ...(i) mR
s s
r
ω = –ω0 + αt ...(iv)
Here, v max is the maximum safe speed for no
skidding. ∴ ωR = –ω0R + αRt ...(v)

For no overturning : 2f
R 0
R t ...(vi)
N1 + N2 = mg ...(ii) m
For pure rolling,
l l
N1 f h N2 ...(iii)
2 2 2v 0 ft 2ft
v R 0
R
From (ii) and (iii), 3 m m
1 2fh 2v 0 3ft 2v 0 3ft
N1 mg ⇒ 0
R v0
2 l 3 m 3 m
⇒ l = 2a ⇒ N1 = 0 5 mv 0 5v 0
⇒ t t
fh mv
2 3 3f 9 g
When mg mg h
a r a 21. Answer (3)
mg – T = mA ...(i) αI
gra T A′ =
⇒ v max ...(iv) 2
h 2
I mI
v max is the maximum safe speed for no toppling. T ...(ii) a
2 6
gra a Now, at a A A
If v max v max , then s
rg
h h
19. Answer (3) A I
A ...(iii) mg
2 2
3v v
2mv mv m v v Solving A = 6 ms–2
2 4
3v 7v 22. Answer (3)
2mv mv m v v
2 4 α×I–2=5 ⇒ α×R=7

v 7v v 4L 7
⇒ x ⇒ rad/s2
4 4 3v 3v 3

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Test - 4 (Paper-I) (Answers & Hints) All India Aakash Test Series for JEE (Main)-2014
23. Answer (3) Component of (2iˆ jˆ) along ( iˆ 2 jˆ) , is
KE about P = T KE about P + R KE about P
4 ˆ 4
T KE about point P = 0, because point P translates [ i 2 jˆ]
5 5
with VCM
4
1 2 Speed of approach =
R KE about point P = I 5
2 P
2 Component of (iˆ ˆj ) along ( iˆ 2 jˆ) , is
1 mR 2
= I
2 CM 16 1 ˆ 1
[ i 2 jˆ]
2 2
5 5
1 mR mR 2
= 1 1
2 2 16 Speed of separation = e
5 4
9 2
= mv 26. Answer (3)
32
Nett work done by friction is non-zero.
24. Answer (4)
27. Answer (3)
2
I1 mR 2 Limiting friction is insufficient for rolling of disc and
5
2
ring.
3R 83 2
I1 ICM m ICM mR 28. Answer (4)
8 320
2
Force of friction becomes the internal force for the
3R 13 2 system of truck and earth.
I3 ICM m R mR
8 20 29. Answer (4)
2 2
⇒ I1 mR 1 m1m2 G G 2
5 K (v1 v 2 )(1 e )
2 (m1 m2 )
25. Answer (4)
G 30. Answer (3)
pball m[ iˆ jˆ] m[2iˆ jˆ] m[ iˆ 2 jˆ] Ns
G 1 2
psurface (iˆ 2 jˆ) Ns Total work done upon spring is kx .
2

PART - B (CHEMISTRY)
31. Answer (1) 32. Answer (4)
According to Bent's rule, more electronegative atom YS has least value of Ksp. Precipitation occurs when
prefers to occupy axial position so as to have ionic product > solubility product.
minimum repulsion. 33. Answer (1)
F F 3
KE per mole = RT
Cl Cl 2
I. Cl P II. F P 3
= 2 300
Cl Cl 2
F F = 900 cal
μ =0 μ≠0 34. Answer (3)
CF3 CF3 Entropy is a state function
CH3 CH3
ΔS(X → P) = ΔS(X – Y) + ΔS(Y – Z)
III. CH3 P IV. CH3 P
+ ΔS(Z → + ΔS(Q → P)
CH3 CH3 Q)

CF3 CF3 = 20 e.u. + 40 e.u. + (–30 e.u.) + 10 e.u.

μ =0 μ≠0 = 40 e.u.

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All India Aakash Test Series for JEE (Main)-2014 Test - 4 (Paper-I) (Answers & Hints)

35. Answer (4) 40. Answer (1)

Spin quantum number is not derived from solution of
0 6 12
Schrodinger wave equation. Cr(Z = 24)
On increasing temperature, water dissociates more
and hence value of K w increases from 10–14 to 1
Total spin = × number of unpaired e–
10–12. Thus, pH scale now becomes smaller and 2
neutral pH is 6.
1
Also, pH + pOH = 12 = ×6
2
So, pOH also becomes 6. =3
But, water will still remain neutral. Orbital angular momentum of an e– in 5s
36. Answer (2) = l(l 1)
He gas shows positive deviation only.
= 0(0 1)
At high temperature and low pressure, a real gas
behaves like an ideal gas. For other gases at =0
moderate pressure range, attractive forces dominate. 41. Answer (2)
37. Answer (3) S = 1.65 × 10–4 mol/L
E = φ + KE Ksp = 4S3 = 4 × (1.65 × 10–4)3 = 1.8 × 10–11
hc hc 1 pOH = 14 – 9 = 5
mv 2
0
2
[OH–] = 10–5
1 1 [Mg2+][OH–]2 = Ksp
mv 2 2hc
0
11
1.8 10
[Mg2+] = = 1.8 × 10–1 = 0.18
2hc 0 (10 5 )2
v
m 0 42. Answer (1)
38. Answer (2) When CH3OH is added, equilibrium shifts backward
and a new equilibrium state is established.
n + p = 45
Addition of catalyst or inert gas at constant volume
n = 1.14p
will have no effect.
On solving, p = 21 and n = 24.
43. Answer (2)
So, atomic number of atom is 21.
HA ZZZ
X
H2O YZZ
Z H3 O A
Electronic configuration of ion (21 – 3)
C1 1 1 2 1

= 1s22s22p63s23p6
HB ZZZ
X
H2O YZZ
Z H3 O B
So, outermost shell of ion has 8 electrons. C2 2 1
2 2

39. Answer (1) Since α1 and α2 are very small, so

F Cl C1 – α1 ≈ C1 and C2 – α2 ≈ C2

1
( 1 2
)
Xe I K a (HA)
C1

F Cl 2
( 1 2
)
K a (HB)
Both are linear molecules. C2

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Test - 4 (Paper-I) (Answers & Hints) All India Aakash Test Series for JEE (Main)-2014

Divide, 51. Answer (1)

C2 6 a
1 4 10 P (V b) RT
2
C1 6 10 6 V2

If 'a' is negligible, then

[A ] 1 2 0.2 1
P(V – b) = RT
[B ] 2
3 0.4 3
PV = RT + Pb
44. Answer (1) 52. Answer (3)
In solid form, XeF6 exist as XeF5+F–.

F
F F
Xe
F F

3d z2 has two nodal cones.

Hybridisation state is sp3d 2. 53. Answer (2)

45. Answer (3) 54. Answer (3)

Cl Cl Cl 55. Answer (4)

I I
Cl Cl Cl CaCO3 CaO CO2 (X)
X is CO2
8 I – Cl bonds are present.
46. Answer (3) Na2CO3 + H2O + CO2 ⎯→ 2NaHCO3

At boiling point, temperature remain constant. So, 10

the total energy remain same for them. Moles of CaCO3 = = moles of CO2
100
47. Answer (3)
Moles of Na2CO3 = 1 mole
Since Kp depends only on temperature, if the volume Number of moles of NaHCO3 formed is 0.2 mole
is doubled, equilibrium is disturbed and more because CO2 is limiting reagent.
products would be formed. So, α will change while
Kp will not change. 56. Answer (2)

48. Answer (4) It is the drawback of first law of thermodynamics

that it fails to predict the direction of reaction taking
Pure element has zero standard enthalpy of place.
formation in its standard stable state.
57. Answer (4)
49. Answer (3)
3
Molar heat capacity is intensive property. KE per molecule = kT, where 'k' is Boltzman's
2
50. Answer (1) constant.
58. Answer (4)
ZZZ
X
H2O(s) YZZ
Z H2O(l )
Dipole moment of CH3Cl > CH3F.
273 K is melting point of water and the process is
59. Answer (1)
at equilibrium, so ΔG = 0 while ΔS = +ve, since
solid is changed to liquid phase. 60. Answer (1)

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All India Aakash Test Series for JEE (Main)-2014 Test - 4 (Paper-I) (Answers & Hints)

PART - C (MATHEMATICS)
61. Answer (2) 66. Answer (1)
0 ≤ cos2x ≤ 1 As, (a + b) cos C + (b + c) cos A + (c + a) cos B
= a+b+c (Using projection formulae)
⇒ 0 cos2 x
4 4 67. Answer (1)
⇒ 0 tan cos x 2
1 1
4 Period of cos 2π{2x} =
2
62. Answer (1)
1
sin x sin y sin x sin y Period of sin 2π{2x} =
2
a b a b
Also, sin 3x cos[3x] – cos 3x sin[3x] = sin(3x – [3x])
(a b ) sin x (a b ) sin y
∴ a ,b = sin{3x}
sin x sin y sin x sin y
(a b )(cos x cos y ) 1
⇒ a cot x + b cot y = Its period =
sin x sin y 3
x y 1 1 1
= (a b ) cot So, required period = LCM of , , =1
2 2 2 3
63. Answer (3)
68. Answer (2)
a
tan α + β = –5, αβ = –5
b
1 1
2a tan b b tan2
⇒ a sin 2θ + b cos 2θ = ( 1) 3
( 1)3
1 tan2
a a2 ( 1)3 ( 1)3
2a b b
b b2 [( 1)( 1)]3
=
a2 3 3 2 2
1 3( ) 3( ) 2
b2 3
(1 )
(2a2 b2 a2 )
= b ( )3 3 ( ) 3( )2 6( ) 3( ) 2
(a 2 b2 )
3
(1 ( ) )
(a 2 b2 )
= b
(a 2 b2 ) 125 15( 5) 3( 5)2 6( 5) 3( 5) 2
= b 3
(1 5 5)
64. Answer (2) 125 75 75 30 15 2
(2 tan θ – 2)2 = sec2θ ( 9)3
⇒ 3 tan2θ – 8 tan θ + 3 = 0 108
3 9 9 9
⇒ tan 1 tan 2 1
3 4
65. Answer (2) 27
–13 ≤ 12 sin x – 5 cos x ≤ 13 69. Answer (4)
∴ max(12 sin x – 5 cos x) = 13 1 sin x cos x
(sin x cos x ) 7
⇒ –14 < –13 – {2x} ≤ – 13 sin x cos x sin x cos x
⇒ max(–13 – {2x}) = –13 1 1
∴ (sin x cos x ) 1 7
⇒ max(13, –13) is 13 sin x cos x sin x cos x

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Test - 4 (Paper-I) (Answers & Hints) All India Aakash Test Series for JEE (Main)-2014

2 2 73. Answer (4)

2 2
⇒ (1 sin 2 x ) 1 7 Simplifying the equation becomes,
sin 2 x sin 2 x
(2a + b)x 2 – (a – b)x – (a + 2b) = 0
⇒ (1 + t)(t + 2)2 = (7t – 2)2, where t = sin 2x
The sum of the coefficients = 0.
⇒ t 3 – 44t 2 + 36t = 0
∴ x = 1 = α is a root.
⇒ t 2 – 44t + 36 = 0 (sin 2x ≠ 0)
(a 2b)
∴ Product of the roots = αβ =
⇒ t 22 8 7 2a b
(a 2b)
∴ sin 2 x 22 8 7 ∴ β=
2a b
| a | = 22, b = 8 74. Answer (3)
a = ±22, b = 8 sec2(a + 2)x – 1 + a2 = 0

70. Answer (3) ⇒ tan2(a + 2)x + a 2 = 0

⇒ tan(a + 2)x = 0 and a2 = 0 ⇒ a=0
n(A × A × B × B) = n(A) × n(A) × n(B) × n(B)
= (4 × 3)2 ⇒ tan 2x = 0 ⇒ x 0, ,
2 2
= 144
∴ (0, 0), 0, , 0, are the ordered pairs
71. Answer (2) 2 2
x 6 + y 6 + 3x 4y 2 + 3x 2y4 = x 6 + y6 + 2x 3y 3 satisfying the equation.

⇒ 3(x 4y2 + x 2y4) = 2x 3y3 75. Answer (3)

Let the 7-digit number is
⇒ 3x 2y 2(x 2 + y 2) = 2x 3y3
abcdefg
⇒ 3(x 2 + y2) = 2xy
9 10 10 10 1 1 1
x2 y2 2 b, c and d can be selected in 10 ways.
⇒
xy 3
a in 9 ways.
x y 2 Now, when a, b, c and d are fixed, e, f and g will
⇒
y x 3 themselves be fixed and can be selected in 1 way
only.
72. Answer (2)
Number of 7-digit numbers = 9 × 103.
sin3θ + sin2θ + sin θ – 2 sin2θ cos θ – sin 2θ –
2 cos θ = 0 76. Answer (2)
Required divisors are 1, 5, 32, 3 × 7, 72, 32 × 5,
⇒ (sin3θ – 2 sin2θ cos θ) + (sin2θ – 2 sin θ cos θ)
3 × 7 × 5, 5 × 72, 32 × 72, 32 × 5 × 72.
+ (sin θ – 2 cos θ) = 0
77. Answer (4)
⇒ (sin2θ + sin θ + 1)(sin θ – 2 cos θ) = 0
z z
Since sin2θ + sin θ + 1 ≠ 0 is a purely imaginary number.
1 zz
∴ sin θ – 2 cos θ = 0 ⇒ tan θ = 2 ∴ arg
z z
is or
1 zz 2 2
From figure, the number of solution is 1.
5
y Now, arg z is .
y=2 9
z lies in second quadrant.
0
–π π x Im(z) is positive.
2 2 z z
⇒ arg
1 zz 2

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All India Aakash Test Series for JEE (Main)-2014 Test - 4 (Paper-I) (Answers & Hints)

78. Answer (3) 82. Answer (2)

cos45° + icos135° – cos(180 + 45°) – icos315° + 1 10! 10! 10! 10! 10!
...... + cos(3645°)
10! 1! 9! 3! 7! 5! 5! 7! 3! 9! 1!
1 1
= ...... 21 terms 1 10 10 10 10 10
2 2 = [ C1 C3 C5 C7 C9 ]
10!
1 1
i ...... 20 terms 29
2 2 =
10!
21 20
= i ∴ m = 9, n = 10
2 2
1 5m + n = 45 + 10 = 55
= (21 20i )
2 83. Answer (2)
2 A B C
= (21 20i ) As, r 4R sin sin sin
2 2 2 2
79. Answer (2)
2R A B C
a2 = b 2 + c2 – 2bc cos A ⇒ 4R sin sin sin
9 2 2 2
= (b – c)2 – 2bc cos A + 2bc
C A B A B 1
⇒ sin cos cos
2A 2 2 2 2 9
= (b c ) 2 2bc sin
2
C A B C 1
A A ⇒ sin cos sin
= (b c )2 4k 2 sin2 4k 2 sin2 2 2 2 9
2 2
A 2
i.e., a 2k sin C 1 C 1
2 ⇒ sin 0 sin
2 3 2 3
80. Answer (2)
C 1 7
⇒ cos C 1 2 sin2 1 2
2 9 9
s s a s b s c
84. Answer (1)
1 1 1 1
⇒
s s a s b s c ( x 1)( x 3) x2 4x 3
Let a = x 2 + 2, b 2 2
c b (s b )(s c ) x x
⇒
a s(s a ) 2
x 4x 3
A c b a + b = x2 2
⇒ tan 2
x2
2 a
1 A x4 3x 2 4x 3
As, A A tan 2
1 = 2
3 3 2 3 2 x
c b 1 i.e., | a + b | = | a | + | b |
∴ ,1
a 3 So, ab ≥ 0
81. Answer (2)
(x2 2)( x 1)( x 3)
i(1 – 3 + 5 – 7 – ...... – 47) ∴ 2
0 (x ≠ 0)
+ (–2 + 4 – 6 + 8 – ...... + 48) = x + iy x
⇒ x ∈ (–∞, 0) ∪ (0, 1] ∪ [3, ∞)
x = –2 + 4 – 6 + 8 – ...... – 46 + 48
y = 1 – 3 + 5 – ...... – 47 85. Answer (1)

x = (2 + 2 + 2 + ...... + 2) = 2 × 12 = 24 We are given 2m – 2n = 120

y = [(–2) + (–2) + ...... + (–2)] = –24 By trail, m = 7, n = 3
⇒ 3x + 2y = 3(24) – 2(24) = 24 ∴ 3m – 7n = 21 – 21 = 0

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Test - 4 (Paper-I) (Answers & Hints) All India Aakash Test Series for JEE (Main)-2014

86. Answer (4) 88. Answer (3)

a Total number of functions = nm.
Vertex of f(x) will be at x =
2
∴ Statement-1 is correct and statement-2 is false.
Case 1 : a > 2, then minimum value of f(x) is at
x = 1. 89. Answer (2)

∴ f(1) = 5 ⇒ a2 + a – 2 = 0
⇒ a = –2 or 1 which is not possible. cos(sin x ) cos cos x
2
Case 2 : a < 0, then the minimum value is f(0).
⇒ f(0) = 5 ⇒ a 2 + 2a – 3 = 0 1
⇒ sin x cos x 2n ,n ∈I
2
⇒ a = –3 or 1
⇒ a = –3 is possible 2
1
⇒ 1 sin 2 x 2n 2
a 2
Now, if 0 < a < 2, then the minimum value is f
2
2
a 1 2
⇒ f 5 3a 2
8a 12 0 ⇒ |sin 2 x | 2n 1
2 2
4 2 13 4 2 13 ⇒ RHS > 2 for all n ∈ I
⇒ a or a
3 3
∴ The equation does not possess real roots.
4 2 13
⇒ a is possible Statement-1 is true, statement-2 is true but it is not
3
the correct explanation of statement-1.
2 13 4 2 3 13
Sum of values of a = 3 = . 90. Answer (3)
3 3
87. Answer (4) || z – z1 | – | z – z2 || = k is
Statement-2 is correct as period of sin x is 2π and (a) Hyperbola if k < | z1 – z2 |
2
hence period of sin(πx) is = 2. (b) Two rays if k = | z1 – z2 |

Similarly, period of cos x is 2π and hence period of (c) Empty set if k > | z1 – z2 |
2
cos( 2 x ) is 2. Here, | z1 z2 | 2, k 1
2
Hence, statement-1 is not true as LCM of 2 and ∴ Statement-1 represents a branch of hyperbola
2 does not exist. statement-2 is false.

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