BEARY Cotronarion SAFETY DATA SHEET eyed Ae P esha it-1e} Identification of the substance/preparation and of the company/undertaking 1.2 Identification of the substance or preparation: Productname POLYKEN 1027 LIQUID ADHESIVE - 1s0 Synonyms POLYKEN 927PN LIQUID ADHESIVE ~ EU N PRIMER 927 PN = EU PRIMER 927PN = BU cas No NA £0 index wo. Nix: NFPA code EINECS No ‘ Molecular weight RIES No. x Formula of the substance/preparation: cating Company/undertaking identification: Serty Plsseres SvBR Nijvbchetdsstrast 10-11 5-260 westerlo Fel: 3214 712°25 00 Fax: 332 14 72 28 70 eomail address: opgedberryplastics.com Emergency telephone bere ts CTE) Brandveerinformatecentrun voor, Gevagrligke Stoffen (B16) mische Schoolstraat 43 Ay Br2440 Geel 2. Hazards identification Highly flammable 2 Hadneta “by tahalacion = Terieacing to skin = flarmful: may cause and in contact with skin du owed danage if swal Very toxic to aquatic organisms, may cause long-term adverse effects in the Bquacie environaent printing date ‘-may-2010 yhPOLYKEN 1027 LIQUID ADHESIVE - ISO cure cae) Tazardous ingrediente eas wo. Zones) | tawards | manana | erwecs/ELINCS No. | syabql feriene, intave of feomere ta30-20-7 pane [reas wm | ® | Jethylibe 7 00 4 0. 11-20 a [Fx 2 bance is Gm oulen wecarg Ce conics sta 4.1. After inhalation: Mimenove the victim int Respiratory problems = Take vickin’eo a doctor if irritatie resh air sult a doctor/medical finee with plenty of water Bo'not. apply neutralizing agents = Bake wideln’eOvan ophthalmologist if irrit tion persists ingestion: Touth with wate: induce vonitin = FE you feelunwell: consult a doctor/medical serv: Printing date 6-5-2010 aiaPOLYKEN 1027 LIQUID ADHESIVE - ISO 5.1 5.5 Suitable extinguishing media: Water spray Polyvalent foam BC ponder rbon dioxide Unsuitable extinguishing media: No data available Special exposure hazards Cas/vapour spreads at’ floor level: ignition hazard = May build up electrostatic charges: risk of ignition jpon combustion CO and CO2 are formed Instructions ool tanks/drums with water spray/remove them into safety = Fake account of environmentally hazardous fire-fighting water Use fire-fighting water moderately and contain it = Dovnot move the load if exposed to heat Special protective equipment for firefighters Weat/ Five exposuret self-contained breathing a Protective clothing ee eed Personal precautions See heading 8-2 Environmental precautions Prevent sold and water. poll = Prevent spreading in sewers = Contain released substance, pump over in suitable containers Plug the leak, cut-off the’ supply Dan'up the liquid. spilt Ty be Eeduce levaporation See heading Methods for cleaning up {nto a non combustible material e.g-: sand/earth tance in closing drums = Carefully colle Jieftovers Danaged/eooled be empti = povnot use compressed air for pumping over spills Clean contaminated surface lexcess of water Take collected spill to ma /eompetent authority eu U cet Handling: SMObserve normal hygiene standards Use spark-/explos ionproo: Yances and lighting sys Take precautions agacnst electrostatic charges Handle uneleaned empty containers as full ones = po"not discharge the waste into the drain 7.2. storage seep, container tightly closed Ventilation at floor level = Provide to collect spills Keep away from: heat sources, ignition sources, oxidizing agen ting date e-5-2010 vePOLYKEN 1027 LIQUID ADHESIVE - ISO Seren tee pecnaciog : to avo: no data available 7.3 Specitic use(s! SPSee informetion supplied by the manu acturer for the identified use(s) 8.1 Exposure limit values: 8.1.1 Occupational exposure: xylene, mixture of isomers Tuv-T¥a : g/m) 100 ppm Lv-SteL : mg/m 150 Ppa wen-ureL g/m 50, Ppa WeL-SreL mg/m 100 Ppa sTRGs 900 g/m? 100 ppm ag/? 100 Ppa 210 ie) 442 21 ppm 442 Pen 2 pea aaa Pen : a2 ppm EC-STEL 2 i Ppa ethylbenzene muv-mwa, 90) Ppa TuV-sTeL 125) Ppa wen-urEt 100 ppm WEL-STEL 25 Ppa ‘FRGs 900 100 ppm wsutro0 8» : g/m’ (wettelijk) Gweni—tes 1s'min, 130 mg/m yMe-3 2 88, g/m) 20 Ppa VEE-15 min. a mg/m 00 Epa cune-8 h 4 ng/m 100 Ppa Gueei5 min 2 85 maf? 125 Ppa 442 g/m’ 100 pee a4 mg/m 200 Ppa Printing date 010 ansPOLYKEN 1027 LIQUID methanol TLV-TWA TLV-STEL WEL-LTEL WEL-STEL RGS 900 aK GwWBNL-76G 8h GWKNE-76G 15 min. vMe-8 VuB-15 min. b min. owns. Gm: Ee C-sTEL cyclohexane TLV TLv-STEL WeL-LreL WEL-STEL ‘TRGS 900 heptane [and isomers] ‘TRGS 900 methylcyclohexane ‘TLV-TWA ‘TLV-STEL ‘mcs 900 Max GWENL-7GG 8h vMe-3 ‘VLE-15 min, cwap-2 GHK-15 min. 810 e10 1600 600 1633 jm ad n/m =e mg/m? g/m? mg/m g/m jo ae g/m? g/m g/m? mg/m? ag/e 100 100 300, ean (wetteligk 100 400 200 200 (indicatiet) Tih HR pm ¥ ppm PPR i Pa Ppa Ppa Pen i HA TTR oyPOLYKEN 1027 LIQUID ADHESIVE - ISO hexane TLy-TWA, mg/m, 50 Ppa TLv-STEL mg/m? Ppa WEL-LTEL R mg/m 20 Ppa ‘WEL-STEL mg/m Ppa ‘7RGS 900 : 180 mg/m? 50 Ppa Max : 180 mg/m? 50 Ppo Gwewt-T6s 8h mg/m} (wettelijk) SRNREE fain, ss Wis ain, oy ae m S88 Ban 1 me? E Eaoren Ee ws 2 i octane and isomers TLV-THA, 300 ppm TLv-STEL Ppa vue-8 bh + 1450 300 ppm 8.1.2 Sampling methods = Xylene (Hydrocarbons, aromatic) Xylene (0%, m=, & prisoners) Xylene (Volatile Organic compounds) = xylene Methyl Alcohol (Methanol) Methyl Alcohol = Methanol {organic and inorganic gases by Exractive FTIR) NIOSH Methanol (Volatile Organic compounds) NIOSH = Methyl Alcono: OSHA. yelohexane (Hydrocarbons, BP36 to 126C) NIOSH ‘yelohexane OSHA. = Cyelohexane OSHA = Ghelohexane Nrosa htHeptane (Hydrocarbons, BP 26 to 126 C) NrOSH = n-Heptane OSHA. Hexane (isomers other than n-Hexane) OSHA = Methyl Cyelohexane (Hydrocarbons, BP36 to 126C) NrosH = Methyl Cyclohexane OSHA. Methylcyelohexane OSHA = Methyleyelohexane NrosH hiltexane. (ilydrocarbons, BP36 to 126C) NIOSH = n-Hexane OSHA’ = feHlexane (organic and inorganic gases by Exractive FTIR) NIOSH = ncHexane (Volatile Organic compounds) NIOSH Hexane (n-Hexane) OSHA. 2 hellexane Nrost 8.2 Exposure controls: 8.2.1 Occupational exposure controis: ScePacure the Concentration in che air regularly Week under local exhaust /vent lation Personal protective equipment: 4) Respiratory protection: Gastmask with Fiver type A at co a date 6-5-2010 oriPOLYKEN 1027 LIQUID ADHESIVE - ISO b) Hand protection “suitable material = Breakthr ough time: ND. ) Eye protection: Protective dogg 4) Skin protection: Head/neck protection = Protective clothing Suitable material Nite PVA 8.2.2 Rnvironmental exposure controls: see headings 6.2, 6.3 and 13 Gene) Ce ee 9.1 General information Appearance (at 20°C) pid odour } Petroleun-1ike Colour : Black 9.2 Important health, ‘ety and environmental information: pH value (at 4) Boiling point /boiling range Tashpoint /flanmability Explosion limits (explosive properties) ec °c volt (°c) Oxidising properties Vapour pressure (at 20°C) bea Vapour pressure (at 50°C) bpa Relative density (at 20°C) Water solubility Tasoluble Relative vapour density :> Viscosity (at °C) PN Partition coefficient n-octanol/water : N Evaporation rate ratio o butyl acetate Ni ratio to ether N 9.3 Other information Melting point /melting range N °c Auto-ignition point N oe. Saturation concentration Nip. g/t? Specific conductivity Nib. S/n 10. Stability and reactivity 10.1 Conditions to avoid: Sho data availa 10.2 Materials to avoid Keep away from: he jurces, ignition sources, oxidizing agents 10.3 Hazazdous decomposition products: Upon combustion Co and coz are formed Printing date 65-20 1"POLYKEN 1027 LIQUID ADHESIVE - ISO 11.1 Acute toxicity: , mixture of isomer okal rat methano ED50 oral rat +: >,$000 LDS0 dermal rabbit 13800 1050 inhalation rat: 85 L680 inhalation rat: 64000 clohexane B50 oral rat > 12705 DSO dermal rabbit > 18000 £c50 inhalation rat methyl cyclohexane 1D50' dermal rabbit 2D50 oral rat 1D50 dermal rabbit 150 inhalation rat 11.2 Chronic toxicity: xylene, mixture of isome: Carcinogenicity (TLV): Ad Teratogenicity (MAK): > TARC classification =: 3 Teratogenicity (MAK) c cyclohexane ‘Teratogenicity (MAK) D methylcyclohexane Teratogenicity (MAK): D n-hexane Ec'repr. cat Teratogenicity (MAK) 11.3 Routes of exposure ingestion, ng/kg ng/kg oe ng/i/4 bh ppn/4vn nays ng/ife nh o/kg ea/kg fe BH Bal, inhalation, eye and skin onePOLYKEN 1027 LIQUID ADHESIVE - ISO 11.4 Acute effects/symptons = AFTER INHALATION = EXPOSURE TO HIGH CONCENTRATIONS: CNS depression = Headache = Nausea Dizziness = Disturbances of consciousness = AFTER INGESTION = Gastrointestinal complaints Risk of aspiration pneunonia = AFTER SKIN CONTACT I Tingling/irritation - APTER EYE CONTACT < Tititation of the eye tissue 11.5 Chronic effects = Contains a substance which is (possibly) teratogenic (methan = Contains a substance which (pos: isomers) Pare) 12.1 Ecotoxicity ol) Sibly) impairs fertility (xylene, mixture of xylene, mixture of isoner: Uce0 (96 h) 3.77 mg/l (SALMO GATRONERI/ ONCORKYNCHUS MYKISS) = EC50 (48 fh) 724 mg/i (DAPHNIA MAGNA) = ECBO (72h)? 10'mg/1 (SKELETONEMA COSTATUM) methano! BMILCSO (96 h) : 10800 mg/l (SALMO GAIRDNERI/ ONCORHYNCHUS MYKISS) = ECBO (48 h) : 24500 mg/1_ (DAPHNIA MAGNA) EC50 (72 h) ? 8000 mg/l (ALGAE) cyclohexane SYUC5O (96h) : 4.53 mg/1_ (PIMEPHALES PROMELAS) CSO (48 h) ? 0.9 mg/l. (DAPHNIA MAGNA) methylcyelohexane 150 (96 hp (SALMO GATRDNERT/ ONCORHYNCHUS MYKISS) = ECS0 (48 hy (DAPHNIA MAGNA) = EC50 (3h): (ALGAE! 113 mg/l (TILAPIA MOSAMBICA) 2.1 mg/l (DAPRNIA MAGNA) Tid mg/L (CRLOROPAYTAD Effect on waste water purification no da 12.2 Mobility: Volatile organic compounds (voc): < 22% Ingoluble in water For other physicochemical properties see heading 9 Printing date 65-20 ondai 1027 LIQUID ADHESIVE - ISO 12.3 Persistence and degradability: = biodegradation BOD; D top water N.D. ~ soil TM: ND. days 12.4 Bioaccumulative potential ~ Log Pow ND. ace Nib: 12.5 Regults of PBT assessment Sehot applicable, on she basis of the ava able data. 12.6 Other adverse effect: woK ies (Classification based on the components in compliance with Verwaltungsvorschrift wassergefanrdender Stoffe wwS) of 27 July 2005 (Anhang 4)) Effect on the ozone layer ? Not dangerous for the ozone layer (1999/48/EC) effect No data available Greenhous 13. Di SR, os 13.1 Provisions relating to waste: Macca material code, (91/689/EEC, Council Decision 2001/118/EC, 0,J. 147 of Meee obb1y 08 OL 11" (waste paint and varnish containing organic solvents or other dangerous substances) Lick (ehe Necheriands): KGA category 03 (17683 /BEC) Seeordance with local and/or national regulations horized plant for the destruction, neutralization an fon of hazardous wast not discharge into surface water 13.3 Packaging: Seay PT terial code packaging (91/689/EEC, Council Decision 2001/118/EC G7 of 16/2/2001) 12-01 10* (packaging containing residues of o: ‘éaminated by dangerous substances) 6-8-20 onsPOLYKEN 1027 LIQUID ADHESIVE - ISO 14.1 Classification of the substance in compliance with UN Recommendations ON-number 1139 CLASS. 3 ‘SUB. RISKS PACKING GROUP ieeat 14.2 ADR (transport by road) Ciass fe PACKING GROUP 1 CLASSIFICATION CODE 1 DANGER LABEL TANKS DANGER LABEL PACKAGES PROPER SHIPPING NAME €oating solution, Special provision 640 14,3 RID (transport by rail) Lass. 13 PACKING GROUP oir CLASSIFICATION CODE FL DANGER LABEL TANKS 3 DANGER LABEL PACKAGES 3 PROPER SHIPPING NAME i Coating solution, Special provision 640D 14.4 ADNR (transport by inland waterways) Ctass 13 BACKING GROUP CLASSIFICATION CODE DANGER LABEL TANKS DANGER LABEL PACKAGES 14.5 IMDG (maritime transport) Guass 23 ‘SUB _RISKS : PACKING GROUP por MAG EMS. FE, S-2 MARINE POLLUTANT P PROPER SHIPPING NAME Coating solution, Special provision 640D (heptane and isomers: octane and SSomers) MARINE POLLUTANT 14.6 ICAO (air transport) ctass ‘SUB RISKS =, PACKING GROUP. IT PACKING INSTRUCTIONS PASSENGER AIRCRAFT 305/¥305 PACKING INSTRUCTIONS CARGO AIRCRAFT #307 14.7 Special precautions none 14.8 Limited quantities (19) When substances and their packaging meet the conditions established by RDR/RID/ADNA in chapter 3.4, only the following prescriptions shall be ‘omplied with? each package shall display a diamond-shaped figure with the inseripeion on Ti38" or, in the case of different goods with different identif within @ single package wMthe Letters "LO" fon _nunbe Printing date o-8-2010 wisPOLYKEN 1027 LIQUID ADHESIVE - ISO Pee eC Cn 15.1 EU Legislation Labelling in accordance with EC directives 67/548/EEC, 1999/45/EC and 2006/8/¢ 8) heptane and Aighly flammable Harmful by inhal rritating to skin effects in the aquatic envir R6S jarmful: may cause lung dama: 36/3 : Stable protective clothing and glove S60 i This material and its container must be dis fas hazardous waste 61 Sease to the environment. Refer to specia Thstructions/safety data sheets 15.2 National provisions the Netherlands Waterbezwaarlijkheid: 4 Germany: wake of) c based on the components (WeVwS) July 2005 (Anhang 4)) POMC 2nade Noyenne ’Exposition ~ Kortstondige bloctatelling ~ Belgi os: fibre fa: (tibee) we & /Olnebe! (oil mist) ccnronte toxicity * Tat Sf the carcinogenic substances and processes uli text of any Rcphranes referred £0 under headings 2 and 3 Highly. €lanpable with akin and if swallowed Mamntuls danger of serious damage to health by prolonged exposure through inhalation Printing date 6-5-2010 ana