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MB = ppm

Cat = gr
H2O2 = mL

Tanggal Co
t (MENIT) A C A C
10 0.519
20 0.418
30 0.402
40 0.389
50 0.365
60
90
120

MB = 10.3 ppm
Cat = 0.05 gr
H2O2 = 5 mL

10 PPM Co = 2.575
t (MENIT) A C Degradasi (%) MB tersisa (%)
10 0.423 2.54819277 1.0410574336 99.151469692
20 0.418 2.51807229 2.2107848871 97.9794665041
30 0.402 2.42168675 5.9539127383 94.229056303
40 0.389 2.34337349 8.9952041174 91.1818480146
50 0.365 2.19879518 14.6098958943 85.556232713
60 0.289 1.74096386 32.3897531875 67.7417842577
90 0.223 1.34337349 47.8301555738 52.2713421781
120 0.196 1.18072289 54.1466838227 45.9425249637

MB = 44.3 ppm
Cat = 0.05 gr
H2O2 = 5 mL

50 ppm Co = 11.7 PPM


t (MENIT) A C Degradasi (%) MB tersisa (%)
10 0.354 10.6626506 8.8662341674 91.1337658326
20 0.298 8.97590361 23.2828750901 76.7171249099
30 0.262 7.89156627 32.5507156832 67.4492843168
40 0.198 5.96385542 49.0268767377 50.9731232623
50 0.247 7.43975904 36.4123159304 63.5876840696
60 0.212 6.38554217 45.4227165071 54.5772834929
90 0.168 5.06024096 56.750077232 43.249922768
120 0.194 5.84337349 50.0566368036 49.9433631964

MB = 118.8 ppm
Cat = 0.05 gr
H2O2 = 5 mL

100 ppm Co = 29.7


t (MENIT) A C Degradasi (%) MB tersisa (%)
10 0.237 7.13855422 75.9644639163 24.0355360837
20 0.145 4.36746988 85.2947142104 14.7052857896
30 0.376 2.26506024 92.3735345422 7.6264654578
40 0.362 2.18072289 92.6574986816 7.3425013184
50 0.324 1.95180723 93.4282584885 6.5717415115
60 0.318 1.91566265 93.5499574054 6.4500425946
90 0.333 2.0060241 93.2457101132 6.7542898868
120 0.332 2 93.265993266 6.734006734
𝐷𝐸𝐺𝑅𝐴𝐷𝐴𝑆�= 𝑀𝐵 𝑡𝑒𝑟𝑠𝑖𝑠�= 𝐶_𝑡/𝐶_𝑂 X
(𝐶_𝑂−𝐶_𝑡)/𝐶_𝑂 X 100 % 100 %
A C C rata-rata Degradasi (%) MB tersisa (%)
=(C1+C2+C3)/3
Orde nol Orde kesatu
0 mL 5 mL 10 mL 15 mL 0 mL
10 22.9879 19.6481 21.4402 20.2835 10 3.1350
20 22.4014 17.6768 20.2346 19.7621 20 3.1091
30 22.1245 17.2043 17.6279 19.3874 30 3.0967
60 21.6683 14.6953 16.0313 17.0740 60 3.0759
90 21.3750 13.0661 15.8847 16.5200 90 3.0622
120 21.2447 12.0723 15.3307 16.0639 120 3.0561

25.0 3.2
f(x) = - 0.00065304
f(x) = - 0.014357754x + 22.7566431373 3.0
20.0 R²
f(x)==0.8766077691
0.00226348
- 0.00286973

f(x)==0.8693400151
- 0.0514546524x
0.0407906417x + 20.5882392157
20.4253019608 f(x)
f(x)==0.7713820388
- 0.0660396257x + 19.3593294118 R² ==0.7962983989
- 0.00431756
0.9319523434
R² 0.9237027695 2.8 R² = 0.9744214029
15.0 R² = 0.9513946034

ln [MB]
[MB]

2.6
10.0
0 mL 2.4
Linear (0 mL)
5.0 2.2
5 mL
Linear (5 mL)
0.0 10 mL 2.0
0 20 40 60 80 100 120 0 20 40 60
Linear (10
t (menit) mL) t (menit
15 mL

orde nol
Variasi
k
0 0.0144
5 0.0660
10 0.0515
15 0.0408
Orde kedua
5 mL 10 mL 15 mL 0 mL 5 mL 10 mL
2.9780 3.0653 3.0098 10 0.0435 0.0509 0.0466
2.8723 3.0074 2.9838 20 0.0446 0.0566 0.0494
2.8452 2.8695 2.9646 30 0.0452 0.0581 0.0567
2.6875 2.7745 2.8376 60 0.0462 0.0680 0.0624
2.5700 2.7654 2.8046 90 0.0468 0.0765 0.0630
2.4909 2.7299 2.7766 120 0.0471 0.0828 0.0652

3.2 0.10
f(x) = - 0.0006530496x + 3.1250772054
3.0 R²
f(x)==0.8766077691
0.0022634868x + 3.0206418095
- 0.0028697316x 3.0264854623 0.08 f(x) = 0.0002866032x + 0.0497383228
f(x)
R² ==0.7962983989
- 0.0043175626x + 2.9781085127
0.9319523434 R² = 0.9895604935
2.8 R² = 0.9744214029
0.06 f(x) = 0.0001613207x + 0.0483523836
f(x)
R² ==0.8203857018
0.0001260653x + 0.0485390095

1/[MB]
2.6 R² = 0.9398470825
0.04 f(x) = 2.97157638867923E-05x + 0.0439
0 mL
2.4 R² = 0.8836689276
Linear (0 mL)
5 mL 0.02
2.2
Linear (5 mL)
2.0 10 mL 0.00
0 20 40 60 80 100 120 Linear (10 mL) 0 20 40 60 80 100 120
t (menit) 15 mL t (menit)
Linear (15 mL)

orde nol orde satu orde dua


R 2
k R 2
k R2
0.8693 0.0007 0.8766 0.00003 0.8837
0.9514 0.0043 0.9744 0.0003 0.9896
0.7714 0.0029 0.7963 0.0002 0.8204
0.9237 0.0023 0.9320 0.0001 0.9398
15 mL
0.0493
0.0506
0.0516
0.0586
0.0605
0.0623

866032x + 0.0497383228
604935
613207x + 0.0483523836
260653x + 0.0485390095
857018
470825
7638867923E-05x + 0.0439230549
0 mL
689276
Linear (0 mL)
5 mL
Linear (5 mL)
10 mL
Linear (10
60 80 100 120 mL)
15 mL
menit) Linear (15
mL)
CONTOH
DEGRADASI MB (%) MB tersisa (%)

t (MENIT) 0 gr 0,025 gr 0,05 gr 0,1 gr 0,2 gr t (menit) 0g


0 0 0 0 0 0 0 100
10 1.6358 24.7773 54.7255 84.818 95.2619 10 98.36
20 2.5101 32.2318 65.3661 85.334 95.4585 20 97.49
30 3.3782 34.0485 72.6754 85.9659 95.6039 30 96.62
60 3.5099 43.6517 77.2101 86.4148 95.6335 60 96.49
90 4.3194 50.0177 78.1225 86.7849 95.6574 90 95.68
120 4.3862 53.7447 78.6712 87.2371 95.6689 120 95.61

100 100

80 80
MB terdegradasi (%)

[MB} tersisa (%)


60 60
0 gr
0,025 gr
40 0,05 gr 40
0,1 gr
20 0,2 gr 20

0 0
0 20 40 60 80 100 120 0 20 40 60
waktu (menit) waktu (m
0,025 g 0,05 g 0,1 g 0,2 g
100 100 100 100
75.22 45.27 15.18 4.74
67.77 34.63 14.67 4.54
65.95 27.32 14.03 4.4
56.35 22.79 13.59 4.37
49.98 21.88 13.22 4.34
46.26 21.33 12.76 4.33

00

80

60
0g
0,025 g
40 0,05 g
0,1 g
20 0,2 g

0
0 20 40 60 80 100 120
waktu (menit)

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