VI.

PERHITUNGAN

6.1 Ion Exchange Kation

6.1.1 Konsentrasi Sampel CaCO3

1000 𝑚𝑔 𝐶𝑎𝐶𝑂3
[𝐶𝑎𝐶𝑂3 ] = = 500 𝑝𝑝𝑚
2𝐿
6.1.2 Standardisasi Larutan Baku EDTA

𝑚𝑔 𝐶𝑎𝐶𝑂3
= 𝑉𝐸𝐷𝑇𝐴 𝑥 𝑁𝐸𝐷𝑇𝐴
𝐵𝐸 𝐶𝑎𝐶𝑂3

200 𝑚𝑔 𝐶𝑎𝐶𝑂3
= 57,1666 𝑚𝐿 𝑥 𝑁𝐸𝐷𝑇𝐴
100
𝑚𝑔/𝑚𝑒𝑘
2
𝑁𝐸𝐷𝑇𝐴 = 0,06997 𝑁

6.1.3 Penentuan Kesadahan

𝑚𝑔 𝐶𝑎𝐶𝑂3 = 𝑉𝐸𝐷𝑇𝐴 𝑥 𝑁𝐸𝐷𝑇𝐴 𝑥 𝐵𝐸 𝐶𝑎𝐶𝑂3

𝑚𝑔
𝑚𝑔 𝐶𝑎𝐶𝑂3 = 4,2233 𝑚𝐿 𝑥 0,06997 𝑁 𝑥 50
𝑚𝑒𝑘
𝑚𝑔 𝐶𝑎𝐶𝑂3 = 14,1752 𝑚𝑔

𝑚𝐿
14,1752 𝑚𝑔 𝑥 1000 𝐿
𝑝𝑝𝑚 𝐶𝑎𝐶𝑂3 =
50 𝑚𝐿
𝑝𝑝𝑚 𝐶𝑎𝐶𝑂3 = 283,504 𝑝𝑝𝑚

∆𝑝𝑝𝑚 𝐶𝑎𝐶𝑂3 = 𝑝𝑝𝑚 𝑎𝑤𝑎𝑙 − 𝑝𝑝𝑚 𝑎𝑘ℎ𝑖𝑟

∆𝑝𝑝𝑚 𝐶𝑎𝐶𝑂3 = 500 𝑝𝑝𝑚 − 283,504 𝑝𝑝𝑝𝑚

∆𝑝𝑝𝑚 𝐶𝑎𝐶𝑂3 = 216,496 𝑝𝑝𝑚

6.2 Ion Exchange Anion

6.2.1 Konsentrasi Sampel NaCl

1000 𝑚𝑔 𝑁𝑎𝐶𝐿
[𝑁𝑎𝐶𝑙] = = 500 𝑝𝑝𝑚
2𝐿
6.2.2 Standardisasi Larutan Baku AgNO3

𝑚𝑔 𝑁𝑎𝐶𝑙
= 𝑉𝐴𝑔𝑁𝑂3 𝑥 𝑁𝐴𝑔𝑁𝑂3
𝐵𝐸𝑁𝑎𝐶𝑙
200 𝑚𝑔 𝐶𝑎𝐶𝑂3
= 48,7666 𝑚𝐿 𝑥 𝑁𝐴𝑔𝑁𝑂3
58,5 𝑚𝑔/𝑚𝑒𝑘

𝑁𝐴𝑔𝑁𝑂3 = 0,0701 𝑁

6.2.3 Penentuan Klorida

𝑚𝑔 𝑁𝑎𝐶𝑙 = 𝑉𝐴𝑔𝑁𝑂3 𝑥 𝑁𝐴𝑔𝑁𝑂3 𝑥 𝐵𝐸 𝑁𝑎𝐶𝑙

𝑚𝑔
𝑚𝑔 𝐶𝑎𝐶𝑂3 = 2,1333 𝑚𝐿 𝑥 0,0701 𝑁 𝑥 58,5
𝑚𝑒𝑘
𝑚𝑔 𝐶𝑎𝐶𝑂3 = 8,7483 𝑚𝑔

𝑚𝐿
8,7483 𝑚𝑔𝑥 1000 𝐿
𝑝𝑝𝑚 𝐶𝑎𝐶𝑂3 =
50 𝑚𝐿
𝑝𝑝𝑚 𝐶𝑎𝐶𝑂3 = 174,966 𝑝𝑝𝑚

∆𝑝𝑝𝑚 𝑁𝑎𝐶𝑙 = 𝑝𝑝𝑚 𝑎𝑤𝑎𝑙 − 𝑝𝑝𝑚 𝑎𝑘ℎ𝑖𝑟

∆𝑝𝑝𝑚 𝑁𝑎𝐶𝑙 = 500 𝑝𝑝𝑚 − 174,966 𝑝𝑝𝑝𝑚

∆𝑝𝑝𝑚 𝑁𝑎𝐶𝑙 = 325,034 𝑝𝑝𝑚