VLE data diethyl ketone/ n xexane

P xi yi ln ji ln j2
90.15 0 0 #DIV/0!
91.78 0.063 0.049 2.461533 0.900784
88.01 0.248 0.131 1.603074 0.471923
81.67 0.372 0.182 1.377822 0.320504
78.89 0.443 0.215 1.320258 0.277827
76.82 0.508 0.248 1.293196 0.257116
73.39 0.561 0.268 1.208957 0.189758
66.45 0.64 0.316 1.131369 0.123428
62.95 0.702 0.368 1.137911 0.129194
57.7 0.763 0.412 1.074362 0.071727
50.16 0.834 0.49 1.016224 0.016094
45.7 0.874 0.57 1.027736 0.027358
29 1 1 1 0
tugas 12.1 P2sat
P1sat
P xi yi x2 y2 ɣ1 ɣ2 ln ɣ1 ln ɣ2 GE/RT
19.953 0 0 1 1 1 0 0
39.223 0.1686 0.5714 0.8314 0.4286 1.571984 1.013386 0.452339 0.013297 0.087319
42.984 0.2167 0.6268 0.7833 0.3732 1.470285 1.026389 0.385457 0.026047 0.103931
48.852 0.3039 0.6943 0.6961 0.3057 1.319847 1.075222 0.277516 0.072527 0.134823
52.784 0.3681 0.7345 0.6319 0.2655 1.245527 1.111502 0.219558 0.105712 0.147619
56.652 0.4461 0.7742 0.5539 0.2258 1.162682 1.157443 0.150729 0.146213 0.148228
60.614 0.5282 0.8085 0.4718 0.1915 1.097184 1.233036 0.092747 0.209479 0.147821
63.998 0.6044 0.8383 0.3956 0.1617 1.049702 1.311028 0.048507 0.270811 0.13645
67.924 0.6804 0.8733 0.3196 0.1267 1.030973 1.349537 0.030503 0.299762 0.116558
70.229 0.7255 0.8922 0.2745 0.1078 1.02133 1.382244 0.021106 0.323708 0.10417
72.832 0.7776 0.9141 0.2224 0.0859 1.012475 1.409848 0.012398 0.343482 0.086031
84.562 1 1 0 0 1 0 0
0.7
0.7
f(x) = - 0.2075161757x + 0.6827602795 0.6
0.6 R² = 0.8280031281
0.5
0.5
0.4
0.4
GE/X1X2RT

0.3
0.3 Col umn K
0.2
Li near (Col umn K)
0.2
0.1
0.1
0
0 0.2 0.4
0
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 x, GE/RT
Col umn K
xi

A12 = 0.6828 (intercept)

A21 = -0.2075 (slope) 0.4753
 90

80
GE/(x1x2RT)
70

0.6229350492 60

0.6122922707 50
0.6373254892 40
0.6346412582
30
0.5998827942
0.5931706293 20
0.5706820356 10
0.5360073141 0
0.5230737721 0 0.2 0.4 0.6 0.8 1 1.2
0.4974679734 X,P y,P

0 0.2 0.4 0.6 0.8 1 1.2

x, GE/RT x, LnJ1 x, Ln J2
Col umn K Li near (Col umn K)
1.2
 Eksperimen Grafis Fitting GE Fitting P
P* X1* y1* P X1* Y1 P X1* Y1 P
19.953 0 0 19.953 0 0 19.953 0 0 19.953
39.223 0.1686 0.5714 38.74745 0.1686 0.561883 38.8891 0.1686 0.563061 39.37861
42.984 0.2167 0.6268 42.58164 0.2167 0.618994 42.71209 0.2167 0.619657 43.10376
48.852 0.3039 0.6943 48.55082 0.3039 0.693063 48.64408 0.3039 0.693024 48.80265
52.784 0.3681 0.7345 52.38921 0.3681 0.734083 52.4516 0.3681 0.733711 52.44171
56.652 0.4461 0.7742 56.65602 0.4461 0.775567 56.68456 0.4461 0.774968 56.50691
60.614 0.5282 0.8085 60.86789 0.5282 0.813511 60.86918 0.5282 0.812842 60.57416
63.998 0.6044 0.8383 64.65017 0.6044 0.845788 64.63523 0.6044 0.845174 64.28885
67.924 0.6804 0.8733 68.38468 0.6804 0.876444 68.36198 0.6804 0.875965 68.01617
70.229 0.7255 0.8922 70.60593 0.7255 0.894225 70.58217 0.7255 0.893848 70.25835
72.832 0.7776 0.9141 73.18955 0.7776 0.914546 73.16729 0.7776 0.914294 72.88584
84.562 1 1 84.562 1 1 84.562 1 1 84.562
Fitting P
X1* Y1
0 0
0.1686 0.566932
0.2167 0.621027
0.3039 0.691175 90

0.3681 0.730483 80
0.4461 0.770999
70
0.5282 0.808978
P, X exp
0.6044 0.842007 60
P, y exp
0.6804 0.873844 50 P, x grafis
0.7255 0.892416 P y Grafis
40 P, X Fi tting GE
0.7776 0.913629
P, y Fi tting GE
1 1 30 P, X Fi tting P
P, y Fi tting P
20

10

0
0 0.2 0.4 0.6 0.8 1 1.2
dari grafis, didapat
A12= 0.757736 (intercept)
A21 = 0.434589 (slope)
P* X1* y1* x2* y2* Ln ɣ1 Ln ɣ2 ɣ1 ɣ2 y1
19.953 0 0 1 1 0.757736 0 2.133441 1 0
39.223 0.1686 0.5714 0.8314 0.4286 0.448447 0.027628 1.565879 1.028013 0.566932
42.984 0.2167 0.6268 0.7833 0.3732 0.378986 0.04418 1.460802 1.045171 0.621027
48.852 0.3039 0.6943 0.6961 0.3057 0.271994 0.081686 1.312579 1.085115 0.691175
52.784 0.3681 0.7345 0.6319 0.2655 0.207569 0.114222 1.230683 1.121001 0.730483
56.652 0.4461 0.7742 0.5539 0.2258 0.144022 0.157726 1.154909 1.170845 0.770999
60.614 0.5282 0.8085 0.4718 0.1915 0.092681 0.20632 1.097111 1.229146 0.808978
63.998 0.6044 0.8383 0.3956 0.1617 0.057453 0.252153 1.059136 1.286793 0.842007
67.924 0.6804 0.8733 0.3196 0.1267 0.032482 0.296814 1.033015 1.345565 0.873844
70.229 0.7255 0.8922 0.2745 0.1078 0.021765 0.322125 1.022003 1.380057 0.892416
72.832 0.7776 0.9141 0.2224 0.0859 0.012622 0.349691 1.012702 1.418629 0.913629
84.562 1 1 0 0 0 0.434589 1 1.544329 1

Trial
A12 0.69633
A21 0.47223
P* X1* y1* X2* y2* Ln ɣ1 Ln ɣ2 ɣ1 ɣ2 y
19.953 0 0 1 1 0.69633 0 2.006376 1 0
39.223 0.1686 0.5714 0.8314 0.4286 0.429089 0.024016 1.535857 1.024307 0.563061
42.984 0.2167 0.6268 0.7833 0.3732 0.367649 0.038661 1.444334 1.039418 0.619657
48.852 0.3039 0.6943 0.6961 0.3057 0.271411 0.072427 1.311814 1.075114 0.693024
52.784 0.3681 0.7345 0.6319 0.2655 0.212167 0.102361 1.236354 1.107784 0.733711
56.652 0.4461 0.7742 0.5539 0.2258 0.152295 0.143381 1.164504 1.154169 0.774968
60.614 0.5282 0.8085 0.4718 0.1915 0.102304 0.190746 1.10772 1.210153 0.812842
63.998 0.6044 0.8383 0.3956 0.1617 0.066581 0.237276 1.068848 1.267791 0.845174
67.924 0.6804 0.8733 0.3196 0.1267 0.039977 0.284931 1.040787 1.32967 0.875965
70.229 0.7255 0.8922 0.2745 0.1078 0.027967 0.313317 1.028362 1.367954 0.893848
72.832 0.7776 0.9141 0.2224 0.0859 0.017204 0.345813 1.017352 1.413138 0.914294
84.562 1 1 0 0 0 0.472234 1 1.603572 1

0.8

0.7 90

80
0.6
70
0.5
Ln Y1 60
0.4 Ln Y2 50
GE/RTX1X2
P

0.3 GE/RT 40

0.2 30

20
0.6
70
0.5
Ln Y1 60
0.4 Ln Y2 50
GE/RTX1X2

P
0.3 GE/RT 40

0.2 30

20
0.1
10
0
0 0.2 0.4 0.6 0.8 1 1.2 0
0 0.2 0.4
 P ∆P^2
19.953 0
39.37861 0.02421377
43.10376 0.01434346
48.80265 0.00243577
52.44171 0.11715964
56.50691 0.02105008
60.57416 0.00158758
64.28885 0.08459098
68.01617 0.00849556
70.25835 0.00086127
72.88584 0.00289876
84.562 0
∑ ∆P^2 0.27763686

P GE/X1X2 RT GE/RT GE/RT(grafis) (∆GE/RT)2

19.953 0.69632991 0 0 0
38.8891 0.65854726 0.092311 0.0873193225 2.49191E-05
42.71209 0.64776822 0.109953 0.1039311697 3.62612E-05
48.64408 0.62822702 0.132898 0.1348228868 3.7046E-06
52.4516 0.61384003 0.142781 0.1476190734 2.34103E-05
56.68456 0.59636052 0.147358 0.1482279131 7.57485E-07
60.86918 0.57796221 0.144031 0.1478209443 1.43642E-05
64.63523 0.56088606 0.134108 0.1364504399 0.000005486
68.36198 0.54385474 0.118264 0.1165579207 0.000002912
70.58217 0.53374799 0.106296 0.104170011 4.51889E-06
73.16729 0.52207257 0.090286 0.0860312358 1.81057E-05
84.562 0.47223354 0 0 0
∑ (∆GE/RT)2 0.000134439
0.8

0.7

90 0.6

80 0.5
70
0.4
60
p,x exp 0.3
50 p, y, exp
p,x
P

40 0.2
p,y
30
0.1
20
 0.5
70
0.4
60
p,x exp 0.3
50 p, y, exp
p,x
P

40 0.2
p,y
30
0.1
20
0
10 0 0.2 0.4 0.6 0.8

0
0 0.2 0.4 0.6 0.8 1 1.2
x,y
Ln Y1
Ln Y2
GE/RTX1X2
GE/RT
Ln Y1 exp
Ln Y2 exp
GE/RT exp
GE/RTX1X2 exp
 GE/RTX1X2
GE/RT
Ln Y1 exp
Ln Y2 exp
GE/RT exp
GE/RTX1X2 exp

0.2 0.4 0.6 0.8 1 1.2

 P2 sat
P1sat

P x1 y1 x2 y2 ɣ1 ɣ2 Ln ɣ1 ln ɣ2 GE/RT
19.953 0 0 1 1 #DIV/0! 1 #DIV/0! 0 #DIV/0!
39.223 0.1686 0.5714 0.8314 0.4286 1.571984 0.515516 0.452339 -0.66259 -0.47461
42.984 0.2167 0.6268 0.7833 0.3732 1.470285 0.476446 0.385457 -0.7414 -0.49721
48.852 0.3039 0.6943 0.6961 0.3057 1.319847 0.439161 0.277516 -0.82289 -0.48848
52.784 0.3681 0.7345 0.6319 0.2655 1.245527 0.420161 0.219558 -0.86712 -0.46711
56.652 0.4461 0.7742 0.5539 0.2258 1.162682 0.407655 0.150729 -0.89733 -0.42979
60.614 0.5282 0.8085 0.4718 0.1915 1.097184 0.405892 0.092747 -0.90167 -0.37642
63.998 0.6044 0.8383 0.3956 0.1617 1.049702 0.408746 0.048507 -0.89466 -0.32461
67.924 0.6804 0.8733 0.3196 0.1267 1.030973 0.396433 0.030503 -0.92525 -0.27496
70.229 0.7255 0.8922 0.2745 0.1078 1.02133 0.392714 0.021106 -0.93467 -0.24126
72.832 0.7776 0.9141 0.2224 0.0859 1.012475 0.386241 0.012398 -0.95129 -0.20193
84.562 1 1 0 0 1 #DIV/0! 0 #DIV/0! #DIV/0!
X1X2RT/GE
#DIV/0!
-0.2953454
-0.3413863
-0.4330709
-0.4979592
-0.5749155
-0.6620428
-0.7365772
-0.7908772
-0.8254713
-0.8564397
#DIV/0!