physical chemstyict- Adobe Acrobat Reader DC Edit View Window Help cal chemistry... ®8HQ 0 Nuweivcal Puivsical Chewastity > Problem 23, Te density of KCL is 1.9893 got ade legth fase wit ell 1629082 Aas dtemired by Xa dilation. Calculate the vale ol Avogul's number > Problem 24, cc slement (atomic ms itsdonsty? > Problem 25, Pots Mucride (KF) has NaCl structure hs density is 248g en and is molar mas is $8 g mo! Compute de disance between K” and Fins 9 KF > Problem 26, Atom eper, sodium exystlizes in aby cette cab latice with 4=424A. Calevlaie teocetical density of sodium (ALL of Na=23), > Problem 27, Use the following dato calelate Avogaito's aur (N), Density NaCl= 2.165 gu. Disance between Nat and Cin NCI = 281 pn > Problem 28. An clement crysilies into a siecue ich may be described by 2 cubic typeof unit cell having cream on each cores fhe cube sn two ates on one of is diagonals. Ie volume of his unit cell is 24% 10cm} and dersiy of elemen. is 72 gen", Calculate the ‘umber f atoms prestatin 200g of elemeet > Problem 29. The density of slid arpa is L65 lnk. a ~233°C, Ihe argon stom {is assumed tobe sphere of odus 1.54310 em. what personage of sohd argon is appurenly empty spe? (AL wt of r=). > Problem 30. In a compound AB, the ers rai A” aed Bre 88 pn and 200 pm tesgectvly, Wha! isthe co-edinazon number ofA"? > Problem 31. Cale the concertion of cson vacancies if NACL i doped with 107 mole of SC, > Problem 32, Inde cutis of SC1(d=3.97 gem") heighcorer recep! by CO with a C5" atthe cee ard vie-vers, Calcul the distance beiweet the neighbouring Cs" and Tons. Whats the radi rato of the two ions? (AL. wt of C5= 15292 aed C= 38.5) > Problem 33, Caulae the waveergh of Kays which paces a dilaton angle 2Bequal wo 1640 foracytel Assume firs order ifracton with nse parle cistnce in crystal of 2 nm. > Problem 34, The angle of ciracion 20 fra fist order rature was fed to be PV using rays of mavelengh 229 A Caculae the distance beween two dfs plns, has a cal edge of 0p. Wha isTE shysical chemisnyed-Adbe Acrobat ReaderDC Fie Edit View Window Help Preble 2. > Probl 13. > Prefer 14 > Problem 15. > Problem 16. > Problem 19 > Problem 0 ‘As ees A" Herpes aby cemed cable stucure. The sone betwen exon sion in th ice is 338 pm Cael he ge eg of te unt ‘heed leagh of ably caved cae nicl 390 pe. he ras ft cain i 50 pn, whats ted of hao? ‘Theedgeleagh ofa fie ceed cubic tcl s OB pn. Ifthe ais lth shin ie 4p, wt ie ral of cao? ‘The ant cell cube nth fr LiCl (NCI struct) 14 A. Asumiog rion coe the oni ai or elie fon ‘The leah fhe tel edge of by entre atc metal ets 382 pm. Clee he rads ofa tm of te metal Body diagcal AA. Cea oie rains in te ai ste sit ls Cs" jon at the body centre and a Brion at each corner: ts density is 4.44 ‘8m Determine the lest ofthe unit cell edge. Cafalite he weo Apa ne fm einem dct Of cen sn NCL 22a an te ety of li AC 217x108 ig. Al cms 4 ema wits (ahs a aed tear which cnt vive ghee xing 4 of hl cane the esi fit 193 gs, Case te apes ns of godin inte si. Liu binds ina orktoic gem ith & alse pr ant cell The ait cll dinensow ae a= 08A 02444 andc=7.2A. If the molar mass is 21,76, calculate dei of ey LA clemcat cys as body cened cab aie Hs desy 7.12 y anh gh of side oe wit clit 288 A. CleTD physical chemistry pdf - Adobe Acrobat Reader DC File Edit View Window Help PC eee > Problem 1 > Problem 2 > Problem 3, > Problem 4 > Problem 5, > Problem & > Problem 7. > Problem 8, > Problem 9, > Problem 10, > Problem 11, (Caeuat the ruber (of ates consid with (@) cubic el, () a body-cemed cubic ee, (© a fae eenved cubic el ‘A body cent eabie latices composed of aniont Q ard cations P, Where ont occupy the corners ands Pca he cee (i) What ete formula of he compound? i) Whats te coverinaton number of Pend 7 ‘compound formed by cloments A and Berylizs i ebie ste ‘whore A stom asa he comer of eo and atoms zee the face coir, What ithe fomla ofthe composed? Calculate the coordintion aember of a acm ‘@)A primitive cubic unit cll (@)A body-entred cubis nit oll (i) A face cence cubic nit cll Inaclse packed suueure ofan ion: compound anions 8 fom theese backed lati a the cations A occupy cetodal voids. Predict Ue fox ofthe coupound. Incomundum,oxie ion are aanged in hep_aray andthe aluminium fon ootupy toed of ootbedal Yds) What te fol corm? ‘Acid betnoen A and Bas the following erangement of ators: (Alors A are arranged in cep. amy, (i Atos F ocanpy al the cesbedal voids at half he teak ‘eis, What the formula of the compan? Ina cote packed structure of mixed ender, the letice is compas of snd fre; one eighth of ieeuhedd vids are cocupied by divaleet Cations hile coe ba of octahedral voide are ozeupied by tvalent Cetins, What ite formu of he oxi? Jn & crystal of a ionic compound, te anions B form «close packed lui an te cations A occupy one hl of de tevabodral voids. What inthe formula ofthe cemmpound? Ina asta ofa onc compound die ions 8 Frm te clos packed Wace aa tie ors A ozapy all the abode voids, What ste forma of the compound? ‘Acosed packed srutre of uferm spheres has the cel ed mun, Calcite te rains of molecule hs (a simple cutie lace, (b) bee. tie, (© bec alee‘physical chemistry.pd - Adobe Acrobet Reader DC File Edit View Window Help Home Tools Nenu? oo) > Problem 1S, If ae raivs of the oct > Profilem 46, thf onde dilactio CINSIA.OGIAIHY 19 vol ral radius ofthe atoms in ion between and close packing i, esiv 3 X-raysliom acerain set ofl panes If the planes 20.281 nm ons atananghe of. fom th pl apart, wa isthe wavelength of X-rays? © Pubes 17, Under what cntons, the Bags equation wl il dete engi ‘ ‘Answers: 1 wil 2 4: 2 Ah; 102, 4 184A & Wis; 6 lascioten; 7 X97 phew! 8 6.06% 10; NT a NP =a; 16, 225 «10? uniteell Hh. 040% as 12, Cabiccell; 19. 215510 1366 pms 4; HS repaiter 16 C1M9pmD physical chemistry pt Adobe Acrobat Reader DC File Edt View Window Help Car Ree ae as *®8HQ OO Problem 1. Calculate the number (7) of atoms censined win (a) cubic cell, (B)abody centred eubie cell, () a face cere cubic ell > Problem2. compound fornedby ements Aand Bersales incubeestucure where atoms ae atthe comers fa cube and atoms area the face centre: Wht she formula of the compound? > Problem 3. Attoom temperature sodium crsalizesina body ertredeabi tice with @= 424 A. Calelats theoretical density of sodium (AL wt. of Na=23) Sodium metal rysslzesina body centred cuie lates wi the cll edgea = 4.29 A. What isthe radius of ediam atom? > Problem§. Silver crysalies in fee. atice. I edge length of the cll is 407 « 10 cmand density is 10.5 gem, calculate the atic mass of sive > Problem 6, Nictiumcrysllzesinbody centred ebie structure. density is 8 $5 ‘bom aka tonic ads nibium wsingis atomic mass 9290 > Problem 7. Copper erysallizes into a fe. latice with edge lenth 361 « 10°" «en. Show tathecalulsteddersiy is napreerent wits measured value of 892 em > Problem 8, Formulas of Nel is $8.45 gel and density ofits preforms 2.167 g om”. The average distance between adjeceat odin and ‘ord iors in th expt is 2814 «10° on, Calle Avogato cersrt > Problem 9, Analysis shows that nickel oxide has formula Wij, ye What fractions ofthe nickel enst as Ni and Ni™ ions? > Problem 10, Aluminium crystallize inacubic close-packed structure. ts metallic radusis 125 po (2) Whats the length ofthe side ofthe unit cot? {o)How my unit cel’ are ther in 1.00 cm? of aluminium? > Problem {1. Gold (atomic radi = 0.144 nm) crystallizes ina face centred unit «ell What she length of sd ofthe cll? > Problem 12. Thallium chloride, TIC crysallizesin ether simple cube letizeo7 4 face centred eubie late of CT iors with I ions in-be holes. If te density ofthe soi is 900 gen? and edge of he unt cel is 4385 lon, what she uit cell geometry? > Problem 13, & solid 4B has the NaCl structure. Ifthe radius ofthe cation is (pn, whats the rai of the sion 52 > Prablem 14. The radius ofS" on in 140 pm wil the radius of CI"onis 181 pm Sugyest te eosonraton of cesium in CC > Prablem 4.