UNIVERSITI KUALA LUMPUR . MALAYSIAN INSTITUTE OF Sey CHEMICAL & BIOENGINEERING TECHNOLOGY = MICET APPENDIX FINAL EXAMINATION PHYSICAL PROPERTY TABLES CHEMICAL PROCESS PRINCIPLES THIS TABLES IS NOT TO BE TAKEN OUT OF THE EXAMINATION HALL.‘Table B.t Selected Physical Property Data’ SG AAT. Compound Formula Mol, Wi. _(20"i4°) TyCCy —_kWfmol TAK Patatmye Acetaldehyde CHsCHO 44.05 0783!" 202 0 AAG = 166.2(8) 1192.48) 871.6901) Acelicacid — CHs;COOH 60.05. 1.089 1182-2439 SMB STL Acetone H.O 58.08 0.791 560-302 50RD aD Acetylene GH 2604 — = — -815 176 = 39S GI ‘Ammonia NH; 03 “78 5653-3343 23351 3113 Ammonium NH,OH 303 = = = - —- = = hydroxide Ammonium NH.NO; 80.05 1725" 169.654 Decomposes at 210°C - nitrate Ammonium — (NH)SO, 132.14 1.769 513 - Decomposes sulfate after me! Aniline GoHN 93.2 63 — ieee — 24 - Benzaldehyde C,HsCHO 26.0 ee ee —88.83() —3520.0(1) ) — Benzene Cats 7s11 0879 553 9837 $010 O.765 562.6486 1212 1266!" 122.2 — m8 — ee — 108.13 1.045 “154 — 95.2 = = = 7 15983 3.119 4108 386030 SA 102 0) 1,2-Butadiene 5409-1365 - 101 — 446 = = 3-Butadiene 5409 1094 — 46 — a a7 = S812 — 133.4661 062.305 HS:1T B47 S82 1596 4.540. 7 21292 4081360 Cis 3610 — 1853 3.8480 6.252.916 397 HIKE) acy 64.10 2.22" 2300 — = = = = 62.7640) Caleium CaCO, 100.09 293 Decomposes at 825°C = 1206.9(0) = Cac, mo99 2150" 782 2337 16m — = =794,96¢€) - axipusddy $zoPhysical Property Tables 629 (pamnuc9) CE? Anu Jou-qymi © H94409 OF gy Aq ange UDA Spa OWNED OEY DAUOD Cy tang on ouypeUD; 4 pe onpord v ae (8) HEM ZF ayeIRATED OL, BIEN pee “{BENOH “BIOS “(OAH “AOD 28 IMPOR 0 SSI “aN IND poowayseg "my i 1 worssasod 4g powdepy “rg pue TC SIGN, HL6LO “som Pag BaD San song moO Vc ON Ye DONE Timeess DFS SmHROIORD - or vee S96 - sp Sap OCS. = To pet poe sore sor oto Gy to @osee— Nezse— osr ¥98s em WE 6 get west O =a aprrouow @ooz8e- sve oeer Oo SeI- uwde age , oat) 9 Or SpYINsiP sunt ose ess ep #19 9 wwoaies = spaoip = ad 8 995- tp t00 oat, feuds’) (istse— - - = oxy he sez) cro 2 ant) (aunsais) = — = scot er) tet sTtet_ OFHZ-OS*D ~~ ~~ ~ ~ _ — te 967 SLUEL "OSE - - - = — wr OSE gz ero oIseO une aivydsoud cc @s- BR eeI- i %- S180 EOE 0% ap yspreMOT puns = = - = esr rer cous so snowed - — 7 7 = cS SIL ay epkxo snoeg ‘2.0961 18 sosodaiovoq, Zs 06ST = FOE apIND ILO roskis = 69s | TL6r eit er~ wr = OH ay SOs Ver © pSET «ESOT see z69t- sosz, HO sunt ‘suxeu vor ice gst ~ 7 uo we HD wns ows ce TEL zee EREI- ADO EPP DEHED. apHONYD Faun, si9 = ose = Fott- O9PT 86301 HESHED epauorg (Ay, oie eo SSE HET TG FO tgs 9190T RED auazuag (Au ‘(qouena) ow eis aoe SRL 120s oPI- 60 L8Y HOH gis res OL = sea- Toso ores O*H'D Tee PSOE WPL ORR SBT eel- Loe HD ames, ose ieee KE ore, EOLI- —8OLO TPL OFSHED) tame pStpetcT soc 6 ELT = eer- ceo seert FHM auoagw sso STIS rez oh HH ve6~ sreo TOL os sueyaodojaiy ror vess Oe eos ee £9 oieo ors SPD attaxYOIKD ‘sueyins 2.0119 < sesodwov2cr 16st *08n9. audn3 - ore = Sse WEL eso cd "9 aaddoy ors o9es 019 a Le- sell © 1H moyOTOND, eenerd OPE oP OIL oure IEE TAO wIsuGET —_punodiso> OD'EY oe ye (penned) Ta 9108,Physical Property Tables 631 (ang09) - @uww- oss ror a «vos (stot Boe-oweL we 69 a @ovi- Oto (eee (ose ose orets sete HHO (Osest- ren aro E90 ves — 6x ges 808 @ocos— — Bewre- SSF © LOST. LTS SIN HO Sew HOT = on = = eos ESE Ore EL 1900 2px0 = @s- coe rue id se ceo OW unsaLie sprvounsy - - ose v ssodin029q, YE fess MHO)B —wnsocte 2pUONS + @)e Tro _ _ S9Er ‘SIFT ver ble STET ETS. 43 uinsouseyy - eo - = si om oso et ete Sq wnsea5eyy 7 = = fe whet oe $6 Wee = OMe POPE = = 66LTOSLT OFS EEE lL IE LOE a peat a = = orse ose sest “Less, ag ou] a bad O98 = erst oad eer for «SESE 1 SUIpO] pains @os295— Cs nT sore str waters = epuong - = res 0 - ee owe IH uaFornsyy aptued - = % 7 I> sole NOH vatoupiiy 2puoly> a a a arse 1H wadoupsty ‘piuoig - e- = oe- 2608 sa uafoupiiy a s107 tH uodouphey eee SHS SUSE LBD UT. eS 659] LOR MHP uo oe COSTE erRS UT SOK HR] OOMT HED aude632 Appendix B @o Q)gLT- _ _ O.StL yas ETTS wre 065 ore — OBELL (orn - “bojysizt— | - @rmi- — = — Orzo; ech ghBT O86 MOSH = Gre (S)SE90E— so 1769 ~ vist rT se sh 0T HOSH'D @ecise- @woe- weet a rs mH @eeese- Boze - (Wszoce— Weretl— Sze OO'T9F al cee Tost- sree. @)roese— @)rorl— Weeose— Woreti— eee OF 69F Use LOE e6e8 90 SPR uRpUa = 10 cor Phst| 9 coz HO SL8IZ- We u38K80 (e1se- @RRE- Saat 1 sxodiuos9q ost 1006 pe 2080 @)zziss~ @rgoc— WMeours— (Weere— see s'R05 — ssel OLs- 0 PIT Bois (sre- — Wez- ose SS ses sIkoseset - Beis ove = Swe BR V16— ay 922TH - @rss 0s =r S6- HT 06 - - - -— w# O49 ew BOT _ (@ec06+ oso OT GLE Bee sisi- TET seat 7 oor - @yeer ow «ote cece vo oF — Go see Ov9TT Less e6T— oor ms w'st 2608 = = gor ss col VEC] NFOAH?D. ouszvagoniy (boyusene— - Deel = OES Rev T= aT. OED FON Prov otnin “ si 0eee— siseo r 3 tox 09 spixouoN woare o0si-0 tL 1 38 10% "09 apacrp oat eLeT-tez LX 1687— Zz 9 loz 2 oat eLLeLe OLX 28F— 73 a9 on cue-Oe T 2 or = © {HO} se0i-£z 1 X £8L— Z 2 sor = fO8J_—_atwuoqueD uM! Oce-36¢ 01 X 98— 2 2 ore =e) eplgneo utaTe=) ooer-o Oss zu- 1 8 ores D ‘vanngos} o0cT-0 86FE arst- tr 8 zee HD aueing- oozt-0 RF test 1 3 wes WD averngost wzi-0 | Sk oese- 14 ws Bor we ow auszu9dd sze-siz T 3 STZET FOS*CHN) Ins wmmyGouruy wozi-o— 9899- Tero 1 8 wut ‘HN uommry oosi-ez S96 T- oour0 1 3 0st S96T— tole0 1 8 o6e av oor Oe ee0's— 1 8 poo "HO auaysiooy ooi-o LYE aczr- a 0-08 1 8088 HDOO"HO 200129y Cy OtxP IX? Wun Woy AIS WW PIMOS punoduoy situn) dw, 10 sey olP oho + 49 + = [OKI “dd oy seis jo uoRenbo seB jeop! 91) 10} OUD Moy saanssand ve epquanidde Dost p asoye ig ove sowed 16) SPLTULIO] DHL PION (40) satduuose senpedey WHT TH ONL,‘Table B2 (Continued) Range Mol (Units Compound Formula Wt State Form ex ex ax t0® ofr) Camene 019g 1 13925376 —39.79 1205 0-1200 (sopropyl benzene) Cyciohexane M6 ke 4962 —21.90 8063-1200 Gyelopentane WI ge 1 3028 25.54 68660-1200 Ethane wor g 1 BR “S816 72800-1200 yl alcohol wor ot 1 o Poe 100 e <6) 1572-8749 19830-4200 Ethylene 28053 < 1147 ~6891 17650-1200 Ferrie oxide 15970 K 6m -17 x10" — "ar tgp Formaldehyde 3003 g ac 4268 0.0000 86940-1200 Hetiura 40g 1% 41201 wir tte 20-100 e 1 408s 2392 57.66 “01200 Hydrogen 206 § 1c 000% 6.3088 0.8698 01500 Hydrogen b m2 gs 1 0.0227 0.9887 48580-1200 Hydrogen el 347g tC ~O.4 4971s 43350-1200 Hydrogen ¢ m3 g 1 8e 298 1.092 0.1200 Hyérogen sul MOS og LC 147 03012 32920-1300 Magnesiu ch 923 © 1 K 158 213-991 Magnesium oxide = MgO 4032 eK 05008-8732 10% 273-2073 Methane cH, Woe 1 546903561 1.00 0-1200 ei «K SOL 1.268 =1100 273.4500 mo oT 1 1683 65 gs o1 °C 93 S301 187 8030-700 818g 1 C3 5653-3772 1008 01200 MIG et CORRS ass? Ode BS OL 62 1 1 "C100 25 3001 gt 28508188 —02925 03682 “0-8500 axpuaddy 9¢9m0 gg 1 °C 2900 2199 S723 2871 4eol og 1 °C 360T397 = 2.88 787 mo g 1 © 7 WSs 3 402g LG 376s] 2.604 3200 g of C2910 1158 0.6076 131 RIS 1 LC 15s4 4368 et C48 3409 42.26 Propane GH 409g tC 8B2 DSO 371 Propylene GH, 4208 gt 59580 17.71, 2460 Sodium carbonate Na,CO; 10599 © 91 9 Kol Sodium carbonate NaxCOs 28615 c¢ 1 -K 5856 decahydrate 10,0 Sulfur s w07 ce LK S268 (Rhombic) © 1 K 183 184 (Monoclinic) HSO, 9808 11°C 1311559 0 07g 1 ROL 3904 3.104 8.606 S03 so07 gt °C ABS 9.188 8.540 3240 Toluene GHs 9213 1 LC BB 3d e 1 °C 9418 3800 ~2786 033 Water HO wow 1 1) 8 784 2 1 C3346 0.6880 0.7608 3.593 tg9 sojoe, Auodoag yeasskua638 Appendix B ‘Table B3 Vapor Pressure of Water” pe(ram Hg) versus TC) Example: Tho vapor pressure of guid water at 43°C is 6250 mm Hg Tec) 00 01 0203S TOD “14 1361 LMS 13361241312 1300 12881276 1253 <13 1a) a7 La64 14501437 Lame Lat 1309 1303 Teo 121622617602 1S88 1S 5591546 1.532 1508 11 178517691753 1937722 LTOT Leal 1.676 L6t6 10 1950 19341916 1.899 18831856 L8AY 1883 1800 -9 2131 2122 -2.093 2.075 Das? 2039-2021 2.008 1.968 “8 2326 2306 2.285 2266 ©2245 «2226 «2.207 2187 218 -1 258 2518 2493 2472 2450 2499-2408 2.387, 2346 —6 2765 2712 278 2605 2672 2649-20626 2.008 2599 <5 3013 2987 2.962 2937 2912 2887 2.862 2.858, 2.750 4 3280 3252 3.225 3198 3171314317 3.01 3.039 -3 3568 3539 3509 348034513472 3303 3.368, 3308 2 3880 3BIS 3816 3785 3. 3722 3691 3.660) 3.599 <1 4217 48240474113 4.079 4088 4.012 3.979, 3913 <0 4579 454824504 4467 44S 4398 4.359 4308, 4.252 | 0 4579 4613 4607 46SL 47154750 4.785 4.820 4890 1 4926 4962 4.998 S03 S07) S107 S144 S481 Liquid 2«-5:284-5382 S370 540K S447 S486 5.525 5.565, 585 water 356855725 5.765 S807 5.848 S889 S931 5.973 6.058 4 G10l G18 6.187 6290 6274-6318 6.363 6.408 6.408 5 6583 6589 66356681 6:78 GIS 68226869 6.965 6 7013 7062 7.1L 7.160 7.209 7.259 7.309 7.360 7402 7 7513 7565 7617 7.669 7.722775 7.828 7.882 7.980 8 845 S100 SIS 8211 $267 83238380 EAT BSS 9 8609 8658 8727 8785 S845 RODS 89G5 9025 94a? 10 9.209 9.27) 93339395 9.458 9.521 9.585 9.64 om LL 9844 9.919 9.976 10042 10.109 10.176 10244 10312 10449 12 10518 10588 10658 10.728 10.799 10.870 10941 11.013 138 131123111305 11.379 11453 11.528 11.604 11.680 11.756 11910 1 UL987 12065 12444 12223 12.302 12.982 12462 12.543 12.706 15 12788 12870 12953 13037 13.421 13.205 13290 13.375 13517 ¥6 136M 13721 12809 13.898 13.987 14.076 14.166 14.256 14.838, 17 14580 14622 14715 14.809 14903 14.997 15,092 15.188 15.380 18 15477 15575 15673 18772 ISSTl 15.971 167A 1617 16374 19 16477 16581 16685 16.789 16804 . 16.909 17105 17.212 Irazt 20 17535 17644 17783 17.863 17974 18085 18.197 18.309 1842218536 21 18650 18.765 ISASO 18996 19.113 19.231 19.3949 19-468 19.587 19.707 22 19827 19.948 20.070 20,193 20316 20.440 20565 20.690 20815 20941 23 21068 21.196 21.324 21.453 21583 21.714 21845 21977 22.110 22243, 2420377 22.512 2264S 22.785 22.972 23060 7319825337 24762616 From RH. Perey and CH. Chilton, Eds, Chemical Engineers’ Handbook, ‘Tales 33 and 3-5, Reprinted hy permission of McGraw-Hill Book Co. th Edition, MeGraw-Hil, New York, 1973, (continued)Physical Property Tables 639 Table B.3 (Continued) TCO) 08 Ol 023d 25 23.756 23897 24039 25.182 24326 24471 24617 24,768 24912 25.060 26 25.209 25.389 25.509 25.660 25812 25.964 26.117 26.271 26.426 26.582 27 26730 26897 27085 27.214 27374 27535 27.606 27.858 28021 28.185 28 28349 28514 28680 28847 29015 29.184 29.354 29525 29.697 29.870 29 30043 30.217 30392 30568 30.745 30923 31.102 31.281 31.461 31.642 30 S824 32,007 32191 32.376 32561 32.747 32934 33.122 33312 33.503 BL 33695 33.883 34082 M276 MATL 34667 34864 35.062 35.261 25.462 32 35663 35.865 360068 36.272 36477 36.683 36891 37.099 37.308 37.518 33 37729 37,042 38155 38369 33584 38801 38018 39.237 39.457 39.677 3d 30898 40.121 40.344 40.569 40.796 41.023 41.251 41.480 41.710 41.942 35 d2N7S 42.409 42,644 42.880 43.117 43355 43595 43.896 44.078 44.320 36 ddS63 44808 45.054 45.301 45.549 45.799 46050 46.302 46.556 46.811 37 47.067 47.324 47582 47.841 48.102 48364 48627 48891 49.157 49.424 38 49.692 49961 50.231 50502 50.774 SLOMS $1323 $1,600 51.879 52.160 39 52442 52.725 $3009 53204 53.580 53867 54.156 54446 54.737 55.030, 40 $5324 S561 5591 5621 S6SL_ S681 STAN S741 57.72. 5803, 4L 5834 5865 5896 5927 5958 59.90 60.22 60.54 6.85 61.18, 42 6150 6182 2.14 62AT_— «GLAD BIB BAH 63.7 LID GAG 4B G48 65:14 6548 65.82 66.16 HST 68H 67.21 6756 G79 44 6826 6861 68.97 69.33. 69.49 7008 TAL «7077 -TL14 TSI 45 7188 7225 7262 7299 7336 7374 74127450 TARR 75:26 46 a7 48 7565 7604 7683 7682 77.21 7780 7800 7840 7880 79.20 79.60 80.00 8041 8082 81.23 S164 8205 8245 MIST 83.29 B71 8413 8456-499 BS42_—BHBS—8H.IS_ BHT BT 87.58 49 8802 8846 88.90 8934 89.79 90.24 90.69 TIA 91.59 92.05, reo) 0 1 2 3 4 5 6 7 8 9 50 9251 97.20 10209 10720 11251 11804 12380 12982 13608 142.60 60 14938 15643 16377 17138 17931 187.54 19609 20496 21417 203.73 70 2337 24392546 © 265.7 2772-3014 ANA] 327.3 341.0, 80 3551 3697 3849 4006 41GB 433.6 4509 468748715061 Tec) 00 0102 3 04 05 06 07 —O8 a9 90 525.76 527.76 529.77 SB1LI8 533.80 53582 53786 539.90 SHL95 544.00 91 54505 S4B.TL SSDI8 55225 554.35 $5644 S5KSA S006 362.75 SHAT 92 $6699 $69.12 57126 573.40 $7555 57771 STOS7 582.04 584.22 586.41 93 588.60 59080 593.00 59521 59743 509.66 601.89 604.13 606.38 GORGE 94 61090 GI317 615.44 617.72 62001 622.31 624.61 62592 679.24 63157 95 633.90 636.24 938.59 GANOF 643.20 645.67 GAROS 650.43 652.82 655.22 96 GS7H2 GOD03 662.45 66488 667.31 669.75 67220 674.66 GTT.12 679.69 97 68207 684.55 687.04 68954 692.05 694.57 697.10 69963 70217 704.71 98 70727 70983 71240 71498 71756 72015 7227S 72536 72798 73061 73588 73853 TALIS 74385 74652 749.20 75189 75458 757.29 6272 76545 76819 71093 77368 77644 77922 782.00 78478 79037 793.18 79600 79882 801.66 $0450 807.35 810.21 813.08640 Appendix B ‘able Ba Antoine Equation Constants" logia p* A a - ~pee Pinmm Hg, Tin’c Example: The vapor pressure of acetaldehyde at 25°C is determined as follows: 1600.017 og40 Peyno@SO) = BOOSS2 ~ ae ar aa => Peno(25°C) = 10°" Compound Acetaldehyde ‘Acetic acid Acetic ucid® ‘Acetic anhydride Acetone Acrylic acid ‘Ammonia Aniline Benzene Butane 1-Butene Butyric acid Carbon disulfide (Carbon tetrachloride Chlorobenzene Chlorobenzene* Chlorobenzene® Chloroform Chloroform? Cyelohexane Cyetohexanol r-Decane 1-Decene L-Dichloroethane 12-Dichloroethane Dichloromethane Diethyl ether Diethyl ketone Diethylene glycol Dimethyl ether Dimethylamine NN-Dimethylformamide 14-Dioxane Ethanol Ethanolemine Ethyl acetate Ethyl acetate" Ethyl chloride Ethylbenzene Formula CHO CHO: GH; CAHOs H,0 CHO; Nits CHEN CoH neCy i-CAHio CH CAH 90 Cis Cis: cs cc CHCl CoHsCl GHsCl cH, CHC, CoH CHO n-CioHn CHa HCl, HCI CHsCle CoH C5H 0 CoH: CHO 29551 = 902 mm Hig Range CQ) A B 0210344 8.00552 1600.017 298t0 1265 738782 1533313, D036 718807 1416.7 62800 1394 714948 1444.718 1290553 TANT4 1210595 20010700 5.65204 648.629 83 10.60 7.55466 1002.71 102.60 185.2 7.32010 1731515 14510809 6892721203531 “7801003 682485 943.453. -85.Lto 11.6 6.78866 89.617 B92t0 1257 7.36366 1305.198 7asto 107.1 7.20131 1157.00 } squmia = coer’ x BUPL:20N Saeynus supads = pu7*s9E9 ‘agpods = tunjon aypods = -8561 “Jopur said Sissouran BRAID "HA OHPR 1S ipo, OONSEEL i WK og reir sone 6th e191 oot ¥si9z suv veose FLIP 769'T 966, eee sur yrose | FILP uet 86 609 sor suse SOF 6981 196, 999 o36€ sous, = SR6E zest 86 9992 Lee vase | S16E 1307 see ose sve Lose PRE ae sod S16 v9 s94e vous ee gentoo 06 9597 99 S99 ee send 88 esoz eos ese ee es 098, worse suse rose 967 a ce ogre score sore a ott £18 ct vee secs ase 82 cst 69690 bate out 66 & ese seer e408 EOE scr si bu wsz07 08d yee 8 cs a ro eur cat some Lee ses Teorg0 Sa9 ois este rio Ste 36S veiavo «6's 919 ze9 reo C80 sro sior000 ri seIoe ose yosre Tose ove siora0 = 779 6092 sist ose S18 sot cio T08 6109 + gore wsske | $9Ne ws crown 08S 63092 ore ees Ot sre 000 SES sane 698 etre 69 95 91097 grec gosre TEE ese 66st o9ez acd ors‘Table B6 (Continued) Pon's) (kites) Hi(klike) Water Water Steam __Water_Evaporation Steam 28725002 4288 2679.6 43925121 4394 2683.4 401 25149 449.2 2687.0 4583-25172 4584 2603 aero 5 4671 2693.4 47525217 4154 2606.2 430 25237 4832 2699.0 4s 25256 4907 2s 491 25275 4978 27040 20 Sos 25202 5047 27063, Sita 25324 5176 2706 25354 5296 24s, 2538.1 S409 27182 25406 5514 2715 opni07 25430 S14 247 o.001076 25452 5709 27216 78 25472 5799 27303, 2549.2 5885 27329 25510 5968 27353 40 25527 27376 42 2554.4 27388 44 25559 6196 27419 46 2557.4 6267 27439 48, 25588 6335 2745.7 50 25602 640.1 27415 55 25633 6558 27517 60 o.001101 25662 e104 27555 65 o.o0r10s 25687 684 27589 70 o.onr 108 2514 oni 27620 axpucddy 993 1136 0.001139 dooraL pois o.oou49 gongs, ogo1s9 001193, o.o01197 001201 .001205 .on1209 0.001213 0.001216 0.2554 02403 0.2268 02148 02040 25890 25908 23024 25088 2595.1 25963 2597.3 25982 25989 25996 2600.2 26007 2601.2 26015 26018 2642.1 2602.3 2602.4 2602.5 2602.2 2601.9 20555 20465 20379 20295 2021.4 20136 2008.9 19985 bo sora Auodoag jo1sdya5 Alkiteg) (bar) Steam Evaporation Steam 40 26013 17129 28003 2 26007 1697.8 77994 “4 25099 16829 27983 46 2599.1 1668.3 2074 48 2598.1 16539 2798.97 0 2597.0 1639.7 27942 52 2595.9 1625.7 27926 4 2594.6 16119 27908 56 25933 15982 2789.0 58 0.001312, 25919 15847 2787.0 60 0.001319 25904 27850 e ‘0.001325 25888 27829 64 0.001332, 25872 27806 66 0.001338 25885 27783 68 0.001345 25837 27159 ” 001351 25818 27135 n 0.001358 2579.9 27109 4 0.001368 25780 7768.3 76 0.001371 25159 2765.5 8 0.001378 25738 27628 80 0013s 2571.7 27599 2 0.001391 25695 27570 se 0.001398 2367.2 27540 86 2564.9 27509 38 2362.6 20478 90 2360.1 2146 2 o.001425 2557.7 mal 94 0.001432 2555.2 27380 axipusddy gpg0.001439 o.001436, o.001453 0.001470, o.001.489 0.001507 0.001527 001547 9.001567 0.001588 ooo16n o.001634 o.001658 .001683 ooai710 0.001739 00170 o.oo .001840 0.001881 0.001926 o.oo1977 00208 00211 00220 0.00234 o.n0267 0.00317 0.01213 o.otiso 0.01030 o.o1034 0.00981 0.00931, 0.00883 0.00837 o.oo7es a.00750 o.0070s 0.00668 0.00628 0058s .00546 2552.6 2580.0 25473 25404 2533.2 2525.7 25178 2500.4 2500.6 2491.3 24814 2471.0 24599 24482 24360 2423.1 24093 2394.6 23789 2362.1 2343.8 23236 23008 244 2242.1 2198.1 2a 2038 27347 27312 2077 2187 2093 26995 2680.2 26784 2667.0 2655.0 2642.4 2629.1 26150 2600.3 25849 25688 25516 25333 25139 2498.1 2406 2486.0 24184 23864 2347.6 22982 2196 2408 6r9 sora Auodoag porssug650 Appendix B ‘Table B7 Properties of Supesheated Steam" reba Sara Sard] Temperate ()—> Wace Steam | "30 8 to i050 wasn eo =) BRS Ooo) oso a7 g = 5 | tie pat asr7 smo ase ask 280 ol ins as | 298 sess eT sD tig asta | sas atte awh esl 2G 2D P oom 7 | tas too mts SRT os Mos asin [2935138] asa ams ery as aewen | 3210 | asia asked) amt P oom 324 | coo —oomos | 34 3a) 3S ams Sa) ts jo fais aorsa | a3 go | aes ams aeons ad att6 wo 0 4s 1 | a2 sig | sma desert RTO P oonis “169 | onion —onmos |_to iu 217 32s 2 so soi zs | a7 143. aig aaa) aes mS He ais) 0 es sz | 292 Sages te | 6882 ¥ nm ‘03% | nani — coins oooies capton | ows dae sO ms mma | ror sar aig7 aes | omer sas am) 9 vas 32 | mot ay ais? ia | ecto Naa ® omits 039 | coro —onoies note ats |_o206 ass Ga58 ae 20 me ama | mie = iss 0s 31s] masa eng 0 oz ass2 | do Sissons | 27 bre 282 ¥ copii mss | oom —enoier—oomi0} auto ameits | O1n as. wo tora omons | 227 ata aad toms] amas es 0 ima mais | mms sna amotio | aezta P awiras ooi975 | odoin: —ogoicz owas union omnis non12s | cases Sess sof tur mmso | ated sia? ans sas | mes sas (se) 8 rms wos | 283 oe Stand 0mm3 | 2s 2 P oon dos | ccoio — amin ours avo1ge aamils gaoies | casei onze of ima a | net amass axes ss t0858 | 2m” 2080 95m 8 ten asn7 | amr 33g? aka rss | 29952350 ¥ om129 ams | color — aura —apaios —ogoite amis coni2e | oats ons iw tss0 2m | 278 my aass RLS IGE] 206 ono oasis oases | asa Siero turna fazed | ono P aoiés ois | ocoior am —avotns —cxaion omnis cooias aaitan | ae 1 ft setio asso | 221 50 ass aks ase e308 | 2405 Gey 8 aso 249 | oom oat? asst tet sive | 2503 % nonies 003 | enpie — canter —o.onds gatos omits ganas aoniss [otis am wags anise | 2264 sass tas ming 867 HST (057) 0 s7as7 © amos | an63 op? ig2g29a)ome2 aunt 6t37 P oorms ogase7s | outa —cooie2 —oumias — vomias anti anoize aaol36 ooviet gia) 208 2108 | 282 TST ISR HLT SR SS Gini) 0 urs 2078 | 200 a2 RG 0600 31600 ¥ ooost7 —ooosi7 |_coiey —_uonine _oonig> _eving _naotI4 _apoi22 ondtss ooo 2 8 = maT a0 as aan) aos TL 1050 O 8 5 fms yep fata tesa ao7s ses % = = econ aamior —onotes conios notts eooize amiss dooIK0 so mS S669 tos aT KD © § = = xo any os “oa? 887 tse P= = acooss90 onto Gouics cooler unit oeizl am0133 nts sm} st a5? ass stars 6ST asTAD © @ = = ws oa ass oa? toad 93 Ise PF = = eowmssi1 anton naie2 —o0pi06 gett agony a0t3 conte im 2 ap 351 sss a8 ae 503 8 5 ies es7 Stings ws tony tatoa P= = _ coms oxeosis2 enon nome cooias pools utt3 oni “Adapted from RW. Haywood, Thermodynamic Tables in SI (Mente) Units, Cambridge University Pees, London, 1968. ‘Water isa liquid in the eneiosed region between 50°C and 350°C. Hl = specific enthalpy (Kiikg), 0 = specific internal energy Gihiy), P = speitc volume (mfg). Noe: kik 0.4303 = Bub. (continued)Physical Property Tables 651 Table B7 (Continued) Tee) Temperate Pe)— (anh oo so wos 00 oan ae seals re) BBG DL , = = oo = so” bl masa SIG cs 2 bee mrs 30TH voR x3 mo 3 eT Cy ee ee iy 832k een sor mah ROG MO lo REHM aEa oy be) eka Sas P3338 3s) aa AAD sof em sme 00 (sry 0 aS 8D P cs ee QI a758 OR ORT wf mt MSS TH omy Gm aN eS TST 0 amy aa «O33 OTT cam azk ts Pe ee ee ee ed wit) 0 ome uns mie 9 gist Gis OS aug aOOS me SMS or st cms) 0 a Hoge meas eats P core Gir» kos cons cmos aT ® a 3% 3m Mom) SM 3m se 0 ts OL Som Ste ass ST Gis ats D qorrs — Gas2k oases ou uns es 873 NTT 8 eR odd) 0 (osm) oye Sous ses MT oma ome Os? opis GES sis dose nse ne Gin 0 east S88 ts cover ome I2R GAS aos tt ORS ODE. ee ee ee ee cay 0 ma bes me soar 807 cols nga idm dung amie - omer ee ee ee ee ee F oomos —noiz7 ood ames ats ST Oat mms Aoxm won| aa) 8a SS aS Guinn) 0 Bs moss P apesist oollo amis © an47 nig = ouIr6 ative mo fsa 368 TR OG Ose ms amas) Sass P anowois oui oll aula anist OOS ates OTS ow RST MBH an SD Ob fon Sees aikmaL % vammo carers omen note ULI izs aI nis so Rte mM RIT a 9 ooatras onaio1 oauskse aos? ommsti2 ocovieg mm2a nOUkEIS re ee ee (0 tess mek 3a psoas om P ooordss qinieas oimises —ooma4s —odmases oust oamss6 acest652 Appendix B ‘Table B. Specific Enthalpies of Selected Gases: ST Units = Fi(ks/mol) Reference state: Gas, Pu Air 0; Nh CO COO. atm, Tigg = 25°C 7 0-072 -073 -073 -072 -073 092-84 25° 000 0.0) © 9.00 0.00000 10 2.19 224219 24629290 2.54 20 545531513505) 56708) 30 R17) R47 BIZ 79H— BITS 937 400 11241172 1.5 108911251635 13.23, 500 1437 1503 14241383 4382170 600 1755 18411739 I6l_ TST 26532091 7m 20802185 2059 1981-2082 31882492 800 2410 2535-2386 228524133736 29.05, 900 2746-2889 2719-2593 2749 4294 33.32, 10003086 3247 3056-904 BOT 485D 37.69 1100 343136073399 3219 M37 S433 418 12003781 «30.70 3746-3539 F787 OLE 46.78 1300 41M 43.38 409738624140 65.98 S147 1400448947007 4451 4190957189 56.25 180048455077 48.06 45.22 48.51 77.84 61.09 ‘Table BY Specific Enthalpics of Sclected Gases: American Engineering Units A(Biwlb-mole) Reference state: Gas, Pug = Latm, Ta = 77°F Air O2 co CO; 0 32-82 315 312-394 361 1 0 0 0 0 6 0 160 B62 160206 18S 200, 858875. 300. 1563 1602 400 20752342 500 2993 Od 859 1132986 13642108188 2276 31292652 2004 41923499 3720 52934359 M454 6295233 S195 75996122 5043 870-7025, 6702100157948 746711263 RRO $239 125339831 soz 1382010799 9309 1512211783 10606 1643612783, 1409177313798 12220 1911914831 13036-21469 15877 13858 21840 16941 1468823211 18019 mo 44514633, 800-5192 S18 900 5940 6212 oo 66957015, 110074597825 1200-8230 6AS 1300 90109471 1400979710304 1s00 1059011142 1600 1139211988, 4700 12200 12836 180013016 13691 190013837 14551 2000 1466315415Physical Property Tables 653 Table B.0 Atomic Heat Capacities for Kopp’s Rule* Cubdig-atom"O)] Element Solids __Liquids c 18 2 H 96 18 B ui 20 si 16 mM oO 7 25 Fr a 2» Pp ZB 31 s 26 31 AllOthes 26 33 "D.M. Himmelbiau, Baste Principles and Calculations Ohermical Engineering. 3rd Edition, Prentice-Hall, Englewood Clit, NU, 1974, p.270 ‘Table BIL Intcgral Heats of Solution and Mixing at 25°C (AA nc — Bao) (ab sog r{molH:Oimol solute) _klmol HC]__kifmol NaOH _kdfimol HsSOs os = = 1573 1 =2622 — 2307 1s - — 6.90) 2 41.92 3 4899 4 54.06 3 5803 10 -67.03 20 _ 2 -72.390 30 7 0 = 50 1334 100 =197 200 — 30K -16.3 1000 -7857 2000 * — 5000 8443 10.00 87.07 50000 — 100000 - -93.64 00000 = — =9531 e 7514 = 12.89 =96.19 “Tom, C. Whitwell nd R. K. Toner, Conservation of Mass and Energy, pp. 334-246. Copyrigit © 1969 by MeGraw-Hil, In, Used with permission of Mera HilATOMIC WEIGHTS AND NUMBERS Atomic weights apply to naturally occurring isotopic comp: of "C= 2 Atomic Atomic Atomic Atomic Element __Symbol_Number Weight Element Symbol Number Weight Actinium Ac 9 — Iridium Ir 22 Aluminum AL 13 26.9815 Iron Fe 26 S887 Americiom Am 95 = Krypton Kr 36-8380 Antimony Sb Sl 1275 Lanthanum La 3713891 Argon AD 18 39.948 Lawrencium == Lr 103 — Arsenic As 33749216 Lead Pb 2 20719 Astatine At 85 — Lithium Li 3 6939 Barium Ba 3613734 Latetium La m1 17497 Berkelium BK. 7 — Magnesium Mg 24312 Beryllium Be 490122 Manganese Ma 25 54.9380 Bisrauth Bi %3 208980 Mendelevium = Md 101 = Boron B 5 10811 Mereury He, 80 20059 Bromine Br 35 79.904 Molybdenum = Mo 2 95.94 Cadmium Cd 48 11240 Neodymium Nd 60 14424 Calcium Ca 20 40.08 Neon Ne 1020183, Californium CE 98 — __Neptunium Np 93 — Carbon c 6 120111 Nickel Ni 28 S71 Cerium Ce 58 40.12. Niobium Nb 41 92.906 Cesium ce 35 132905 Nitrogen N 7 140067 Chlorine a 1735453 Nobelium No 102 = Chromium Cr 24 S196 Osmium Os 15 1902 Cobalt Co 27 589332 Oxygen ° 8 159994 Copper cu 29 63546 Palladium Pd 46 106.4 Curium Cm 96 — Phosphorus P 18309738 Dysprosium Dy 66 16250 Platinum Pt 78 19509 Einsteinium Es 9 — Plutonium Pu 4 = Exbium Er 68 16726 —_—Polonium Po a — Europium = Eu 63 151.96 Potassium K 19 39.102 Fermium Fm 100 — —Praseodymium Pr 59 140.907 Fluorine F 9 189984 Promethium = Pm 61 a Francium Fr 7 ——Protactinium Pa 91 = Gadolinium Ga 4 18725 Radium Ra 88 = Gallium Ga 31 69.72—-Radon Rn 86 = Germanium Ge 327259 —-Rhenium Re 15 1862 Gold Au 79 196.967 Rhodium Rh 45° 102.905 Hafnium HE 17849 Rubidium Rb 378457 Helium He 2 4.0026 Rutheniutn Ru 44° 101.07 Holmium = Ho 67 164.930 Samarium Sm 62 15035 Hydrogen 1 1.00797 Seandium Se m 44.956 Indium In 4911482 Selenium Se 347896 Iodine I 53 126.9044 Silicon Si 14 28086‘Atomic weights apply to naturally occurring isotopic compositions and are based on an atomic mass of 9C = 12 ‘Atomic Atomic Atomic Atomic Element Symbol Number Weight__Element Symbol _ Number Weight Silver Ag 47 107868 Tin Sn 50 11869 Sodium Na 1 229898 Titanium Th 2 47.90 ‘Strontium Sr 38-8762 Tungsten W Ta 183.85 Sulfur s 16 32.004 Uranium =U 92 238.08 Tantalum Ta 73 180948 Vanadium 23 $0942 Technetium Te 8 — — Xenon Xe 54 131.30 ‘Tellurium = Te. 52 127.60 Yiterbium Yb 0 173.08 ‘Terbium Th 6 158924 Yttrium ¥ 39 88.905 Thallium = Tl 81 20437 Zine Za 306537 ‘Thorium Th 90 282.038 Zirconium Ze 40 9122 Tm 168.934 THE GAS CONSTANT 8314 m*-Pai(mol-K) (0.08314 L-barl(mol-K) (0.08206 Leatm/{mol-K) 62.36 L-mm Hg/(molK) (0.7302 £t-atm/(Ib-mole*R) 10.73 £¢-psia/(ib-mole-"R) 8314 JI(mol-K) 1.987 eal(mol-K) 1,987 Buu/Ib-mole-*R)Table $.3-1 Pitzer Acentric Factors Compound Ammonia Argon Carbon dioxide Carbon monoxide Chiorine Ethane Hydrogen sulfide Methane Methanol Nitrogen Onygen Propane Sulfur dioxide Water ‘Acentric Factor, 0) 0.250 0.004 01225 0.049 0.073 0,098 0.100 0.008 0559 0.00 0.021 sz 0251 0.344 SOURCE: B.C, Reld, JM. Prousaitz, and BE. Poling, The Properties of Gases and Liquid, th Ei FACTORS FOR UNIT CONVERSIONS Quantity | Equivalent Values Mass kg. = 1000 p = 0001 metre ton = 2.20462 Ibq, = 35.2739 07 Llbq = 16 02 = $104 ton = 453.593 g = 0.453593 ke Length 1m = 100.cm = 1000 mm = 106 microns (um) = 10! angstroms (A) 3937 in. = 32808 ft — 1.0956 yd ~ 0.0006214 mite 12in. = 1/3 yd = 0.3048 m = 30.48 cm Volume 1000 L = 10 em? = 106 mL = 220.83 imperial gallons = 264.17 gat 7.4805 gal = 0.028317 m? = 28.317 L Foree LN = Lkg-m/s? = 10° dynes = 10° gcm/s? = 0.22481 Iby Llby = 32.174 bg fe = 4.8889 N = 482 x 10° dynes Pressure | Latm = 1.01325 x 10° Nim? (Pa) = 101.325 kPa = 1.01325 bar 1.01325 x 108 dynesiem? = 760 mm Hg at @*C (torr) = 10.333 m H,0 at &C 14,696 lby/in2 (psi) = 33.9 ft HO at 4 29.921 in. Hg at PC Energy LJ = 1N-m = 107 ergs = 10 dyne-em 2.778 x 10°? kW-h = 0.23901 cal 0.7376 ft-by = 9.486 x 10-* Btu Power 1 W = 1 J/s = 0.23901 calls = 0.7376 ft-Iby!s = 9.486 x 10°4 Btu/s = 1341x107? hp Example: The factor to convert grams to Ib, (2.20462 Ib, 1000GENERALIZED COMPRESSIBILITY CHART 15 1 | | Geneilized compressibiliy factors (z= 0.27) 13 12 factor, 2 Compress or 02 030405 10 20 304050 10 20 30 Reduced pressure, P, Figure 5.4-1 (Reprinted with permission from Chemical Process Principles Charts, 2nd Edition, by O. A. Hougen, K. M. Watson, and R. A. Ragatz, John Wiley & Sons, New York, 1960.)080 Our ono 079 050 Reduce pressure, Fy, Figue £42 Generalized compressibility chart, low pressures, (From D. M. Himmelblau, Basic Principles andl Calculations in Chemical Engineering, 3rd Edition, copyright © 1974, p. 175. Reprinted by permission of Premtice Hall, Ine., Englewood Cliffs, Ni.) 06-05 10 iS 20 25 30 35 #0 45 50 55 60 G5 70 75 80 Figure 5.43 Goncralized compressibility chart, medium pressures. (From D. M. Himmelblau, Ba- sc Principles and Caleulauions in Chemical Engineering, 3rd Edition, copyright © 1974, p. 176. Reprinted by permission of Prentice Hall, Inc, Englewood Cliff NI) [From Figure 54-6, the intersection of 7, = 2and Vi!" = 0.161 occurs at ap From Equation 54-2a, we can now ealeulatea0} : : 29 al 0 Reduoed ress, Figure $44 Generalized compressibility chart, high pressures. (From D. M. Himmelblau, Basie Principles and Calculations ix Chemical Engineering, 3rd Ecition, copyright © 1974, p. 177. Reprinted. by permission of Prentice Hall, Inc., Englewood Ciiffs, NI.)