VLE data diethyl ketone/ n xexane

P xi yi ln ji ln j2
90.15 0 0 #DIV/0!
91.78 0.063 0.049 2.461533 0.900784
88.01 0.248 0.131 1.603074 0.471923
81.67 0.372 0.182 1.377822 0.320504
78.89 0.443 0.215 1.320258 0.277827
76.82 0.508 0.248 1.293196 0.257116
73.39 0.561 0.268 1.208957 0.189758
66.45 0.64 0.316 1.131369 0.123428
62.95 0.702 0.368 1.137911 0.129194
57.7 0.763 0.412 1.074362 0.071727
50.16 0.834 0.49 1.016224 0.016094
45.7 0.874 0.57 1.027736 0.027358
29 1 1 1 0
 P2sat
90
P1sat
P xi yi x2 y2 ɣ1 ɣ2 ln ɣ1 ln ɣ2 GE/RT GE/(x1x2RT) 80
19.953 0 0 1 1 1 0 0 70
39.223 0.1686 0.5714 0.8314 0.4286 1.571984 1.013386 0.452339 0.013297 0.087319 0.6229350492
60
42.984 0.2167 0.6268 0.7833 0.3732 1.470285 1.026389 0.385457 0.026047 0.103931 0.6122922707
50
48.852 0.3039 0.6943 0.6961 0.3057 1.319847 1.075222 0.277516 0.072527 0.134823 0.6373254892
52.784 0.3681 0.7345 0.6319 0.2655 1.245527 1.111502 0.219558 0.105712 0.147619 0.6346412582 40
56.652 0.4461 0.7742 0.5539 0.2258 1.162682 1.157443 0.150729 0.146213 0.148228 0.5998827942 30
60.614 0.5282 0.8085 0.4718 0.1915 1.097184 1.233036 0.092747 0.209479 0.147821 0.5931706293
20
63.998 0.6044 0.8383 0.3956 0.1617 1.049702 1.311028 0.048507 0.270811 0.13645 0.5706820356
67.924 0.6804 0.8733 0.3196 0.1267 1.030973 1.349537 0.030503 0.299762 0.116558 0.5360073141 10

70.229 0.7255 0.8922 0.2745 0.1078 1.02133 1.382244 0.021106 0.323708 0.10417 0.5230737721 0
0 0.2 0.4
72.832 0.7776 0.9141 0.2224 0.0859 1.012475 1.409848 0.012398 0.343482 0.086031 0.4974679734
84.562 1 1 0 0 1 0 0

0.7
f(x) = - 0.2075161757x + 0.6827602795 0.7
0.6 R² = 0.8280031281
0.6
0.5
0.5
0.4
GE/X1X2RT

0.4
0.3 Col umn K
0.3
Li near (Col umn K)
0.2
0.2
0.1
0.1
0
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 0
0 0.2
xi x, GE/RT
Col umn

A12 = 0.6828 (intercept)

A21 = -0.2075 (slope) 0.4753
90

80

70

60

50

40

30

20

10

0
0 0.2 0.4 0.6 0.8 1 1.2
X,P y,P

0.7

0.6

0.5

0.4

0.3

0.2

0.1

0
0 0.2 0.4 0.6 0.8 1 1.2
x, GE/RT x, LnJ1 x, Ln J2
Col umn K Li near (Col umn K)
dari grafis, didapat
A12 = 0.6828 (intercept)
A21 = 0.4753 (slope)
P xi yi x2 y2 Ln ɣ1 Ln ɣ2 ɣ1 ɣ2 yibaru pcalc
19.953 0 0 1 1 0.6828 0 1.979412 1 0 19.953
39.223 0.1686 0.5714 0.8314 0.4286 0.423605 0.023319 1.527458 1.023593 0.561883 38.7575
42.984 0.2167 0.6268 0.7833 0.3732 0.36376 0.037584 1.438729 1.0383 0.618994 42.5919
48.852 0.3039 0.6943 0.6961 0.3057 0.269743 0.070576 1.309628 1.073126 0.693063 48.56028
52.784 0.3681 0.7345 0.6319 0.2655 0.211643 0.099935 1.235707 1.105099 0.734083 52.3976
56.652 0.4461 0.7742 0.5539 0.2258 0.152687 0.140332 1.164961 1.150656 0.775567 56.66295
60.614 0.5282 0.8085 0.4718 0.1915 0.103194 0.187233 1.108707 1.205908 0.813511 60.87333
63.998 0.6044 0.8383 0.3956 0.1617 0.067604 0.233599 1.069941 1.263138 0.845788 64.65438
67.924 0.6804 0.8733 0.3196 0.1267 0.040902 0.281439 1.04175 1.325036 0.876444 68.38784
70.229 0.7255 0.8922 0.2745 0.1078 0.028763 0.310135 1.02918 1.363609 0.894225 70.60855
72.832 0.7776 0.9141 0.2224 0.0859 0.017811 0.343204 1.017971 1.409456 0.914546 73.1916
84.562 1 1 0 0 0 0.4753 1 1.608497 1 84.562

90

80

70

60

50
p,x exp
P

40 p, y, exp
30 p,x
p,y
20

10

0
0 0.2 0.4 0.6 0.8 1 1.2
x,y
10

0
0 0.2 0.4 0.6 0.8 1 1.2
x,y