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Appendix E Tables for Prediction of Transport Properties E.1 intermolecular force parameters and critical properties §E.2 Functions for prediction of transport properties of gases at low densities — ‘et 96 sia tr) @ We TONS cree “HO - 802 ‘002 ote wee | a eee TEBE over SHO. _ ‘eet ISL gor ome | eae gL 80% = THO=HO'HD _ = = — swe | pt oer 900% HOSS'HD e0r oz 8H wer vo | G0 (tee BRE ye HD _ ‘sz ve aos = FzeT) 9 8IT scr 08T “HOH - eet ez gig ewe] Pte FI wo% HOSHO “eet “el £36 gop rier | a St ORE F091 "HO ssuoqres0xps}] =~ — = — ws) us) HRY oe es 5 - - ve wor ows} yes aE 808" 6S ug 06 ocr rag To aie] » use STF $0604 D — — ~ —- -—| wm eve M66 LE 4 9°86 Tue wz su coer] 3 ee (STO 9079 "os Tel cee £96 sie cee] @ Oe (ERE cow ON zs ‘8SZ us 9 ot} ee (ave s09'0€ ON wl ere 116 Bt TwE| » O61 966 owrr ‘oo £98 ‘061 vee sre over] » Ol Oage owe oo €S0L os ay cor PRE] ye ere 666 TE *O. 898 “ost 106 see TIE) 9 866 29 e108 ‘N 06 ‘e6L 98 ze Ptr) > 046 ave #9687 a ase spuroyedjod adung, zor “06F esl oss eae] y crec OOO eclet 2x ¥6r “96e Tt es ret] 7 oO = SVE ores o ol 9 wee osr gon) q@ FUL eRe Sh6 68 Wv ra “ast ew 6% sh |e eee e8ct osroz aN ssove8 91q0N = ve wus ve xe |» eo 9st £00 oH _ Le 099 ostl = eee vy ose S167 9107 ee ssruamayo 1817 (OLX AS-D /]e9) GOL x 8-9/8) | @GIOW-B/z0) CE) —_O)) op ~ w sourysang, y ot A dk | yee we 2 Bem ae[2210 7 _psansadoad yeontr) sreyouresed souof pemuy sarpadoag [eoyTD pue siqaurerey enum (71-9) SsuOf-preuE] TA ATG, 864 @z60) 3G WoBuyseM ‘oy;O uqUHA WaUULEAOD § 1 ‘9Z61 aaydsmLNY Props snot anon eg any sqaadaidpous0prand ay pu Wo seMOU Hem 1D pue suamg ‘{-a mow are Sayssompueo yeusoYs FOND am Jo sone, ‘aOsIeNg Fwy Pu aE NoH YO WHOIg axe Aasoom Te (2961 ‘1961 ‘9g60) woPUeT ‘syPZaMIETING ‘ ‘STA ¥SdOD wi wan se aww Kip Jo uonysedwia> afeiane sy aos Uy {OGL} IGELNL TS" 2 HOHE "UAT "PEARS 'Y | MOH paps}asoue sOUERNANS md AID o) STUEyFUED [ERIE a JO ssaquadard podsuey payeynoye> pur ‘saqnede) oy ‘suayourured souof-preuuaT so s9]qe 24ysu99xa sopLieud yodau s1yy, “ ase saoueysqns soyRO 104 SOAPS ALL souysqns yep Wo wnep Ays0084s HON av PURzUaG JO} SnPeA BYE, (9961) EE-9SC'S SHMDUEpLN OH SMT PY "EORDYS "AM PUL YOION 5 291,'5 71 5 {960 °HOK MON ‘ARM ‘PapPE SOON BHA Sup poseLDD ‘pale meDsHND Je AML LMMER|OW PAE A A BUR SSFAN LD RPRPPSHLO = — si = vee cee | gOS T60ZL “D0 - “vor dt es | FLFR eves. ‘3 - = — 19 ee | 2 9 RTT sav09 $09 - - - os 0h] # EIS ozs "NFO — a [ns 2 eT) west 20 - O we rs es) Ber SOHO — _ — 9 os | 2 86e BL 68 OHO - “Bee “HL s9 eo] 2 ge AS or 05 HD 9s “eat £36 Sor TIGL) @ HSL REE F091 "HD :spunoduios syues0 29110 = “ze ‘wz eres | gue HS wed SUDzUDG — 180 ‘woe Or es | Pee ea 9tyg—— sueXayOPAD - “s92 ‘eo OMT) gee 9zezt peu - “6s wr 8 SHBG ESOL eco St - ws wr Oe Cos | aw RID oz 00 yo - ave oe kez CUS | HET 8198 Myre - — wc || Ke Be) a teases sree "CHD — - moc 8 cee FOR) a wee HIBS sree "HO - ez me tee Ser) gE O'S we HAH — 68% ez MC BOR) 2 Sez HE'S eras Wot Table E2 Collision Integrals for Use with the Lennard-Jones (6-12) Potential for the Prediction of Transport Properties of Gases at Low Densities*** 0, =, 0, =9, KT/e ior viscosity Daan KT/s (for viscosity Qovn or and thermal or or and thermal tor XT/exg conductivity) diffusivity) | &T/e,, conductivity) diffusivity) 030 2.840 2649 27 1.0601 ore, 035 2676 2468, 28 1.0888 0.9682 040 2531 2314 29 1.0882 0.9588, 045 2401 2.182 30 1.0388 0.9500, 030 2.234 2.086 34 1.0300 9.9418 0355 2178 1968 32 10217 0.9340 060 2.088 187 33 1.0189 0.9267 065 1998 1798 34 1.0066 os197 070 1922, 129 35 0.9996 09131 075 1853 667 36 0.9931 0.9068 0.80 1270 1612 37 0.9868 0.9008 O85 1734 1562 38 0.9809 0.89852 098 1682 1517 39 0.9783 0.8897 0.95 11.636 1477 40 0.9699 0.8845 1.00 4.893 540 4a 0.9647 0.8796 185 1554 1.406 42 0.9598 2.8748 19 1518 1375 43 0.9551 08703 15 185 13 44 0.9506 0.8559, 120 1458 1320 45 0.9462 0.8617 125 127 1296 46 0.9420 0.8576 130 1401 Lava a 0.9380 0.8537, 1.35 1377 1258 43 09341 0.8999 140 1358 1234 49 0.9308 0.8168 145 1304 1216 50. 2.9268 0.8828 150 1318 1.199 60 0.8962 0.8123 155 1287 1.183 70 08727 0.7808 1.60 1.280 168 80 0.8538 om 165 bs 154 90 0.8380 0.7555 170 1249 wat 30.0 one 07422 175 1.235 1.128 120 08018 07202 180 127 17 140 0.7836 0.7005 138 1.208 0s 260 0.7083, 0.6878 1.90 1198 41.085 180 o7552 6751 198 1.186 1088 200 0.7136 0.6640 2.00 1176 1975 230 o7198 oon 240 1156 1.058 500 0.70 06235 220 1138 1042 350 0.6854 0.6088 290 iz Lom 400 06723 05968 240 41.107 1.013 00 06510 05763 2.50 19938 ‘L006 750 06140 O5H5 2.60 sun807 0.9860 1000 0.5887 05180 "The values inthis table, applicablo forthe Lennar ones (6-12) potential. are interpolated from te rsuls of L.Monchick and B.A. Mason, f. Chom. Py, 35, 1876-1697 (1961. Tha Monehick-Mason tables believed to bostighuly better than the caries table by J.O, Hirschfelder, KB. Bie and E. L. Spaz, f. Cher. Phys, 16, 968-981 (1948). This table has been extended to lowes temperatures by C.F. Cutis, Chem. Phys 9, 7679-7686 (1992). Curtiss showed that at low temperatuces, the Boltzmann eRuation ied fo be todd to take into accnunt “orbiting pairs” ‘sf enolacals, Only oy making this modcaton e3t possible to get smooth trnsin from spuantm to cassia] ‘behavior. The deviations are appreciable below dimensionless temperaturs of O30, ©The collision intopvals have bean curve-ited by P.D. Neufeld, A.R Janson, and R.A. Ariz, Cis. Pigs, 57, 1190-1202 972, 08 follows: sors, 052487 21678 penn” GRarmOT | SPORTS ea) 09300 sess, 176r4 22) SOATEST)” WEEE) * ApS 2 where KT Ye Appendix F Constants and Conversion Factors §F.1 Mathematical constants §E.2 Physical constants §F.3. Conversion factors §F.1 MATHEMATICAL CONSTANTS 14159. e = 2.71821 In 10 = 2.30259... §F.2. PHYSICAL CONSTANTS" Gas law constant (R) 8.31451 J/g-mol+K 8.31451 x 10° kg+m?/s?- kg-mol + K 8.31451 x 10 gem?/s?- gmol+K 1.98721 cal/'g-mol+K 82.0578 cm’ atm/g-mol-K 4.9686 x 10% by ft/s! Tb-mnol +R 1.5443 x 10° ft-Tb,/Ib-mol-R ‘Standard acceleration 9.80665 m/s? of gravily (go) 980.665 m/s? 32.1740 ft/s? Joule’s constant (f,) 4.1840, J/eal mechanical equivalent of heat) 4.184) x 107 erg/cal 778.16 ft Tby/Ber Avogadro’s number () 6.02214 x 10° molecules/g-mol Boltzmann's constant 1.38066 10> /K {k= R/N) 1.38066 X10" = erg/K Faraday’s constant (F) 961853 C/grequivalent Planck's constant (i) 6.62608 X10 Jes 6.62608 X 10°" ergs Stefan-Boltzmann 5.67051 x 10 * Wim? Ke constant (7) 1.3553 x 10-1* cal/s-cm’K* 17124 x 10% Btu/hr: f?R* Electron charge (e) 1.60218 x 10" Cc ‘Speed of light ina 2.99792 x 10" m/s vacuum () E.R. Cohen and B.N. Taylor, Physies Taday (August 1996), pp. BG9-BGI3; R.A. Nelson, Physios Fodey (August 1998), pp. BGIS-BGI6. 867 868 Appendix F Constants and Conversion Factors §F.3. CONVERSION FACTORS In the tables that follow, to convert any physical quantity from one set of units to an- other, multiply it by the appropriate table entry. For example, suppose that p is given as 1Wb/in2, and we wish to have p in poundals/f. From Table F.3-2 the result is p= (10)(4.6330 x 10°) = 4.6330 * 10" poundals/it? ‘The entries in the shaded rows and columns are those that are needed for converting from and to SL units. In addition to the tables, we give a few of the commonly used conversion factors here: Given a quantity in these units: Multiply by: To get quantity in these units: Pounds 459,59 Grams Kilograms 2.2046 Pounds Inches 2.5400 Centimeters Meters 39.370 Inches Gallons (US) 3.7853 Liters Gallons (US) 231.00 Cubicinches Gallons (US) 0.13368 Cubic feet Cubic feet 28.316 Liters Kelvins 1.800000 ‘Degrees Rankine Degrees Rankine 0555556 Kelvins Table F.3-1 Conversion Factors for Quantities Having Dimensions of F or ML/P Givena Multiply by Geos ecsy os quantityin —ablevalue : these units to convert to grem/s Ib, ft/s? (dynes) (poundals) By t these units 1.3826 10" 3.4081 x 10° 4.4482 x 10° 32.1740 1 “¥990001 Aa aa 1. pampaiggy souoe> argu, ays wuoNeUrO;U wt possuce sonuEnb yanua> of 's9}ge >nUEUSpONLOYE [eRUYD aMUDS Posts, ey poseaatage IN SH ¢ sy 07 L OlFET OLX TIPE — OLX THOOR OLX ZIT OLX 6FE'R 4,01 X ODOT mow WeMOPEY (OLX 09% L OLX SHST OLX THLFI OLX O86 L OLX SIED OL x SHBOT sinoy 1omodasi0y] s-OLX 20867 OL x TOBE t OUXOIZET URAL OT X 9GDET OLX OSD" sun yeurayy sng OLX Z2OEL OLX 9REFT OL x £5968 L O90E OLX 48066 OLX OFS SeHo|e> jeoarMpouarp OLX ZOLE OLX SOS — OLX IATL OL x goRT'E L OPLTTE OLX $9881 ‘aly POL OMIT ¢ OX R69TT — OLX ThOEE OLX ZZOOL OLX IS0TE 0} eatto> 0} syn asayy soe ayqey ut Arpurenb Aq Sdn Baars) (anbio 0m “AB.9u) 1/720 7 Jo suOTSUALUIC] SUIAEH] SOANUEND 10; SIOPEG UOTSIOAWOD ELA AIFEL -peoR6'0 49 Stdnnur ‘soraydsoune 01 sseq wos; yaa%t09 09 pie 1 eq dru ‘gosta oy oq MO yoAtCD 012, s10q, Ut poyrodax 61 omssaad ays SUNADHUOS ‘unsse ‘Suryosaid ayy suutus aunssaud agmosqe st aunsseud oer (@208 yout oxenbs 1od spun) su, 20 aynronqe your asenbs sad spunod) ,usd, poyernougge AERIAL L OOPS OLX IZHE OLX OTIS OLX LZd0L LX OLTT OLX FREE Sy ur 2 OLX 0Le6E L SOX SGLEL OI LRG L — SrRLT (OLX 88968 OLX ZeET 8p war Iz66z 092 L 9691 OLX 291Z OLX £8089 OL x CELT une 980% OLX SLES; OLX 94089 L FL OLX OREO OL L1689 "ay aa 2 OLX GEIRL | OLX EL6SE 401 & BSE -u/"al = 38/s1epuned OLX SHOE ¢-OLX TITLE 5 OLX 289F'T OLX BEES 1 Gs-u/“aD zu/sjepunod — jwuo/eusp — sum asamp O10 0} sIpM esau anes age) ur Arquenb fq Atdninyy Pani (xny UTyUAUIOW ‘ainssaud) -17/ WW 40 7/7 JO SuosUAUN uae S9MHUEND 405 SLOPEY UORIAATOD T-A IGEL 869 1 OLX SLD OLXSITT — GED OLX ZOELT = E Ay ayo WL S210 1 OLX 9627'S OL x TSH LOL x OFEL'Y OE ON 2. 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