real vs imaginary boundary

pure substance
gibbs energy
0th law
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t=ap+b---temp measurement bfr 1954
t=273(p/pt)---after 1954
w=+ve(done by sys),-ve(done on sys)
w=pdv--applied only when system is(closed,reversible)
w@cv=0;w@cp=p(v2-v1);w@ct=p1v1ln(v2/v1);w@adiabatic=pv^gamma=c=(p1v1-p2v2)/gamma-
1(for polytropic replace gamma by n)
k=0@cp;k=1@ct;k=n@poly;k=gamma@adiabatic;k=infinite@cv
inc in p=heat supply;dec in p=heat rejn
t2/t1=(p2/p1)^(gamma-1/gamma)=ideal gas eqn@adiabatic
slope of isothermal=-p/v
slope of adiabatic=gamma(-p/v)==>slope of adia>isothermal
c=q/mt(kj/kg.k)
cp>cv=gamma=cp/cv>1;cv=only internal energy;cp=internl+external energy
first law=>Q(net heat transfer)=W(net work done)=>closed system,cycle
dq=de+dw(closed sys,rev/irrev)=>Q=E+PDV=>closed system,rev process,
dE=DKE+dPE+dU=>KE=PE=0;dE=dU=>U=internal energy=rep as spc internal
enrgy=U/M(kjkg)=>int prop
isolated system-no mass,energy transfer
meyers equation=cp-cv=R=>cp=1.005,cv=0.718,R=0.287,gamma=1.4=>air
isothermal=>t=0;u=f(t)=0=>dQ=dW=>ideal gas;Adiabatic process Q=0