Resonance JEE ADVANCED TEST-3 (JAT-3) TARGET : JEE (MAIN+ADVANCED) 2014 DATE : 29-12-2013 COURSE : VIJETA (JP) REVISION TEST HINTS & SOLUTIONS PAPER-1 PART; (MATHEMATICS) wee | ey aah 5 1} ew OT Jing) de = ener «3 soy 22° sindeosdd0 ; Lt | reno Jisinoayde = srfe=t sol. (¢) = -6(c08%)|} =-6(ost ~ 1) = 6(t ~ cost) 2.11.2 satisties the equation 22° — 222 — 18 iz + 271= 0. af 2 ethane 223 — 3c? ~ 18 ie + 27 =O 1 eat so. a) (238 (Arn bound by te une y= A me yom ih Osnee = late Seiziss sot.) 2 y= x= 17 2.11 ean aptay constant then ue ce eo aS at Be paz eo A ol. (0) % aoe) = = 11a + x= 11 soto) = 9048-1) 2B Rated Area xx-1)P de 2g = (Dae ee 7. A conic passing through the point A(t. 2) roe eas rapa Fy A, 2) 8 ge Be Tore & So. (8) Equation of normal at P(x, 9) ls ov + [eed =ee+ ner +6 Poe. 9) me a Fe & ax = yoer1+ ce Yovs— gy 9 Ae H2N08+ y+ 29 = c+ 2y 4 42) WR Mee peer aye ey Ht meets Xans at @ (xv. ° Sol. (8) We pezee wy (he Ba A ay 2) thas ay dap 0 we xa aia [x+y 2, 0) mane Sy 2eF + a= ay? (ae xan waxy or, 0] Yee ayy rayne mid point of PQ is vee / a yty om Pom mer fry xy.zerenGP. ee a HB) since tes on y-axis 1 ‘eae ya ie Pera i ax & he ond 1, een) on yw) “2 a “PM Resonance Sogy Y Ox 2 ie ax =~ yay Since it passes through (1, 2) eeunga awh s Mase ie 2 2 eas) ats 2 3 1 Hence 08 J 8. I(2,,2,) and (2,2, ) ae two pairs of non 2er0 “af (2.2) Ae (2,2, oR TH Sol. (a) 2; 1 Bn (z | say (22 ] (222) (224) ag |Z. | +39 a9 29 25) 789 (24 )° 9 (2524) °%9 (2529) 9. Let C denote the set ofall complex numbers set C ah tay een ar Bape 8 ay AER B Sol. (A) Ar B isthe set of complex numbers represented by the shaded region in the figure where QC || OX and CP yo makes an angle of vith the postive x-axis 23 say 3% an "Zn lim tan tan 10, {tan Sol. 2 [entanyat 2 Fenieottyat 2inp= 2 fen(tant) +en(oottydt nz ° 2 fenttantoottydt 9 2 11. For a postive integer n, let a(n) ea eras tas 2b PY ARP ao) = Sol. (A) eee d (100) < 100 12, If fae the rots of the equation x2 + 2x + 3= 0 aft THE Ie + e+ 3207 A af Sol. (A) Musing (), (i) 8 7 = ab + (ap)? (a+ B+ BP te [xt-4 : V ans.4 t [e—4 9200 tant t 2tan6 = | eee? 208 ano y sin?6, =} cos0 do. [ (eco -cosa)do = tn(eec0 + tano)f- (sino)p”? 8 -nbs.9)-% 1 44, Ifthe real pat of is equal to > then the be j Pewee D 2 ate eee wi aRatae a ‘amen 2z+i 2 ans. 7 Sol. et 2=x+ iy 244 (x+4)ely 224i 2x +if2y+t) (x+4)+iy |, [2x-i(2y +4], = |axsiay+) ese | (zis) Meeterere 1 Relazsi) "4x? +Qy +1? 228 + x + 28 + y) = dee + Hye +1 + By S toes 2y=t ay > 2y= 16-1 hich represents equation of straight ne 46, If a,b and ¢ are real numbers euch that af% apse aratie weMy ans.7 Sol. 22+ b?+2+ Ga + do + 2b=—14 (a+3P+ (e+ tye e(e+2P=0 9 Resonance SSOLIPVATSO91219 -2 mm46. Find the number of real values ofk for which (x? = (k -2)x +2) io areas ars A weer eI A GP — 2+). Ans.t Sol. Case-t Both equations have both roots common 2s ez = ap oars 1-2) = ket 1 2k=1 « Case-2 Each equation have equal roots citer when Te (= 2)? = 42 = Dand K?— 42k — 1) = 0 kee 17. IG, and G, are two geometric means and Ais the ‘fg 6, aan G, 2 he me & we A Ans.2 rey"? Sol. r= le oe? ic: + 2and f food we 2m Jroodx tn 4te4 3(1-t) axvd 25 9" 3G) 2. 8 "3° 3(x-1) 2,8 Jtooax int) +6 48. Iz, 2, 2, ae the vetoes ofan equster! rangle 2A yay 3G lat SEE AT PH ba ans. 2 At =f}, aan, of fata 13558))° 08 +AD=28 (rape tye ( equate of the area = 3 20, The sum of the areas of n squares isn? gel & Arch a a a? ae asl & dmc at 21. 11109 = [ eostcos(x — tat, and to» foostcos(e it ant sos. S01. 116) = feostsinie—at Jena 22. If singular solution of p + cospx siy = sinox cosy 2p + cospx siny = singx cosy 21 FRA Ee Ans.2 Sol. p = sinfpx—y) => pemy= sin"p oon...) Cifferentate wet.» putin equaton 23. 1116) = + sin then ft AE fo) =x a ns.3 Sob Letx= Ht) = ax= at = [Peper = fer cnat = UFC ee - freee (4x? 22). frenat 2 » 1 foo + sind = Fone 1 fonsax es x — J ftydt + | sinxdx = 32? | (10¢)—sin xx 2 2 2 Mgnt at 291? [ude = 35? 304 ) =3 2 24, If the area of the region In first af Astro Bes i a, Sea gate Ans.s 9 Resonance SSOLIPATSO91219 -3 mmate ott met ifs efearafteanes of sem = Rat (4) a ora 0g = Te a ora (.-0 Haft oot a Gy —0) BE eI AGT er ok Rete a ene foResPn é a 28. 1C wo gamaay aati rat # Sol (A) frees 17 3e, = « dloagss « 920 Mev + £,=05113 Mev 25, Experimental measurement 29, ucius with ‘afore ae a ahh ret Rew ea Sol. (A) Redaton force on one miror Sol. (@) 2A (Q=AB)Y _ (65-0216 _ ww ai ye fare aa = r Ye 216+4 40 Mev. 30. A resistor has Torque ofthis foree about center ae 2IAL Sol. () ra Rote of heat produced un seurry af a dav ve v2 “dt “RO” Rot ¥a(T=0)) ~ Rota) dQ dt angen = 28. I represents at qr aT Sol. (0) : "8 gt ~ Ro(irat) Oo us 2h L Vv (14+ 0T)dT = dt qv v ‘ Fenk gy = ap ealy J cms ce o oP Vv uv TD” * Roms From) ©, Om Ae Roms qT? abo ree 27. factory produces, 31, 9 spheres A, Band © ee tha Prag ay, sata A.B ae C Sol. (C) Sol. (8) Between t=121=1+ ; No. of radionuclide formed = Rat Weis law fe amr Fra Ant =b ( 1) Stefar's law ere wT Frm P= GeAT* Wf aveage te == 5, = wil decay for time intent — Then setty ater tme (y=!) Wl become cam aR ‘Fae ule, a a 0;>0,>0, (. 1 = Reg eRe) 9 Resonance SOLIPYATS291215 -432, A large open 36. Sol. (©) Sol oy -A f at 7 2207 39, A metalic wire dorm wwe Sol. (A) a. 21 coed [ar sol Vig 34, Radius of a nucleus safes 3 Prom Sol. (©) From the conservation ofthe energy KE at infny=PE at the surface of the nuceus 1 ___ klzoje 2" ROAM? we ** | DregmReAT> ) we wim sot SFr KE Rw gS OE PE 1 Keele 3m Ral 12 wey ** | DregmRGAT® | 26. A containers 8, weap we sol. 0) sot for pot A tom tp sutace P, = and rom dat val, etl wae BAG AG fy eye pg men eA oe BP, ro eel 4, fend so A point mass mass or T,c0830° + T,cos60° Tising0® = T,sin60" Solving these equations we get, Fa vithoenh at se ea TR ore SIT 8 1,2 om 2 stress in wire -1 ‘stress in wire -2 B ngs a an-1asttaa TA, 2 Moxv3 aR-2 Fata TA,” m9 . 2 Ang of rac. pas & aad & @ 40 : Bin = dimer 0/2 ‘wo diferent vertical 3 See estar 6 2Teos45* he tpg a ea) W2* tpg MH = cos Ina photostectc. sore ep oo 0 morte Mosley po fork, hoax Pree 0 Af s0@-b) = ape = 2521 av oope = SIO oy 095 «1015+ 10" @O-b) > vet IW Resonance SOLIPUATSOS1219 -5 mma Sol Sol a. Sol ‘Minimum energy Her sa “ (ae c(t te" sass ‘aoe eo) ) oexsxsxis=7> = Ss ‘An ideal gas ew areal Ae oy For process A> B >, aU = From 1 fa of thermodynamics O=W. 400k 02 FT A+ B30 faaU=o = sn fA a gem Pee a-w 400k «02 Nucleus a ses A, = 801, 00k! L@ Energy released = incease in BE = 85 « 120 +70 ~ 80-6 = 203 = 122 MeV. wreftia Gf = 86 # gf = 65» 120+ 70+ 60-6» 203 La Since fF W=0, AU=Q=25Cal oo fgomeett sitestort a ¥2Km FD spatonsmtt or afta Gai WH 81 |A simple open we wa Gh o Pressure at A that is at interface of water and mercury and B is ‘same as both are at same horizontal level in same liquid, Thus Ace omg Toh aA arate wag an TW wen BO aT seer eben eh ich me ma a A ee 8 | eo Pot 222" 10% = 100010 Py x 1380 10 Height to which mercury has risen ore grat wr arg 48. Ice at oc falta are Sol. (8) Heat capac of flask sere oft or ener = © (6(70 = 40) + 200 (70 = 40) «1 ‘SOL + 50> 1 « 40-0) (0(40 ~ 10) + 280(40 - 10) = 1 = 80L + 801 « (10-0) L= 90 calm, PARTAll : (CHEMISTRY) 49. Which ofthe folowing Fra a a ata ota Sol. (0) ‘They wil react to form NaHCO, 3 ipa NaHCO, wat 81 Na,CO, + H,C0, ——>2NaHCO, 50. soliton of @ metal em ng es ar Sol. (@) Ht + 21 —> Hal, | (scat red) Hal, +21 (excess) ——> Hal, (eouble complex) Hg + Go(SCN), ——> ColHg(SCN),] + (deep bive) We Hg + 2 —> Hol, J get are Fer) Hal, + aT cates) —> (Hal (Rae igs) HP + Co(ScN), ——> colHitscn,) 4 cree Ata 151, Which ofthe flowing ‘hea 3 ae a Sol.) Easy NO- > NO > —NO* ond lengthy Bond order 20° «258 Hy > Hy > He Gand eneroy) Bond order 1° 0 08 (move antibonding) NO > NO, > NOz(bond lengthy Bond angle 180" 133" 118 Ose oieton (Garamagnelic moment No.ofunpaiede- 0 «0 m No- > NO > NO* Gia aM Bio je Hee HY > He, Gia ara wm 1 08 os (cits zach) No,’ > NO, > NosGia aT daa tert or> of > O, orggertta srerhy safiae®@ eno 02 52. Kn, in noua sentrrgta art, S01. (6) 5Win0;- + 38,0, + HO —+ BMnO, + 650,> + 20H- 153. Match Columns wth sam fag me ae Sol (A) (8) Ho (aq) + 21 (29) —> Hat, (re (©) Cure)» fFe(Cmnge (2g) —> Cu, [Fe{CN), | Grown) {6} Mg (2g) * NH,aq) + HPO,*(aq) > Ma(NH)PO, 4 (ie) {0} PO (ag) + C10,> (aq) ——> PHCIO, L yelon) SOLIPYAT291215BA (8) Ho" (aq) + 21 (6c) —> Hol, $ (Te) (6) Cu*(aq) + [Fe(CN} a (aq) —> Cu, [Fe(CN)J ¥ C5 (©) Mg (eq) + NH,(aq) + HPO,*(aq) > MaiNHJPO, + (em) (0) PE (aq + C10," faq) —> PocrO, +(e) 54, Which ofthe folowing coordination Fret & aren svecechfh Sol. () [Co(en),No, cher and cae) {Co(en).NO,8r Cl ~ lnsation isomerism (sree SATE [Co(en),NO,chBr and (em) {Cofen),ONOCI) Br = Linkage isomerism. (Fa ATE) 55. The sum of the oxidation ‘afte aa Sol. (8) afion of Zeise's sat ‘oxidation number of Pt: x=3+0=—1 eae EAN = 78-2462 64 ‘Sum ofthe oxidation number + EAN = 2 + 84 = 86, ‘ae am 1 EO Pear statiaem ai: x-3+0 peer) FAN=78~2+6=64 itd oie + EAN a1 ai = 2+ 84 = 86. 156. Choose the incorrect aa fren 1 Sol. (0) (A) cycle silcate [810.4 3 (62) +x (3) x=2 (®) In C.F, carbon carit expand ts octet. NO, isan odd electron specie in which seven electrons are present valance shel of W som VAN o (A). aftr feFeTE [840 34 (2) #xx (93) 1220 xe? ©) Of ,8 orks aot seen wenfta af we aoe ty NO, fam stair eh & roe Newey eee ara i ara aa geage wafer 8 \ we P o"\Ty £ (0) air are ow age oes 8, aery Ae Hew so HB ae eter crix BObvam aR Sol. (8) Lal act, MX > crc, (ay > s I H WYN He: HA, N aos Td 4" HoT Sy cu, @) I i 1 We ity gn fra att og ‘Sol. (C) (i) 60" has 3a” configuration; SON is weak fed igand So ihe comple paramagnentc with thee unpared eecons (i) Cu has 5° conigutation, complexe paramagnete wth ne unpated dlecuon (i) gho® has 54 configuration; all electrons are paired so ‘lamagnentc (0) Pull) wr fare Se? 8, we geragIA afta 2, ore: TE Sirgen #1 (i) CoP a7 frre ut, SON-os Gia da Fre 8, oat Fige d wana wags & oe TTT # (i) Curt a Rare Boh, age wo BPP SARI eT Sgpere| (Ww) hgh ar Fore sa, ent gaagia gftra @, a: Sg Siegen 8 59. A mature of bauxite ‘Serr 180050 a ee Sol. (0) Ajo,aH0+36-+N, 18D, aaN + 360+ 240 Resonance SSOLIPATSO91219 -7 mm2AIN + 3H, ——> AIOH), + NH, (0) Reaction involed In ostvald’s process. Cote pet 0) Punta NHC) + 50,(9) —Saim, e806” 4NO{o) + 6H,019) NO + 1120, —>NO, ;3NO, + H,0 —>2HNO, + No. om 120° AL,0,2H,0 + 3¢ +N, > 2AIN+3¢0 + 24,0 2AIN + 3H,0 —> AKOH), + NH, (whe pty (re sera) (x) (©) steares mern a FH Se PE Punctayst ANH) + 50,(9) —Saim,ss010 > 4NO{@) + 6H,09) NO + 1/20, —>NO, ;3NO, + H,0 ——>2HNO, + NO. a Etngham diagram Tecj—> Which of the foloning aweds fe am sol. (C) G(s) + 0,(g) —+ 60,49) [Same volume of ges so ite changes in entopy] fren a rer er, een TET ae a PH ‘i 18) + 50:19) —> cow 2 ume doubles wo greter entropy change] ary GT, Ta CTH es I 61. Mn es, Sol. (0) nin + 58,07 + 84,0 > 20, + 1080+ 16H ‘Mn ~ [Ar 36" No unpaired electron so ‘spin only magnetic a ‘moment of compound Moov) tar aor are scare gees a | ae: hs vapor ae gee se A (O)S 62. How many of the Fea # a) a iP, XeOF, a cior, ii c 7"! ap we Ly “sei 664, Among the following metals frm orgs Hg, Zn, Sal. (8) 2HgS +30, —> 2Hg0 + 280, ‘2Hg0 + Hos ——> Hg + $0, cus +30, —> 2¢u,0+250,; 20,0 + Cu,8 —> 6Cu +80; 2PbS +30, —> 290 + 250, 2°00 + PbS ——> 3Pb+ 80, 65. NH, can be neatly fs 8 ahaa PR Sol. () Ca(OH), + 2NH,cl > 2NH,t + CaCl, + 2H,0 Na,CO,+ NH,Cl "> NaliCo, + Naci + Nyt Na,po,+ NH,CI "> a,HPO, + NaCl + Nit 66. How many of the Fs oral sol. (4) Haematte 5; Limonte : Fe,0,3H,0 ; Syvine: KCL Magnesite _MgCO, :Cupile :Cu,0;" ” Sidette : Feco, sal. (3) Geruste POO, Sonate: 2ng 3° Znce: ZnO Ale 3Hcl—> lh, +32 HA» NaOH + 0 Seer re eee Tracts eer —+ Navlo, + 3271.7 hate 6 BH, + 6HCI_—-> 3BCI, + 6H, 7, B.H, + 64,0. mIAIRE | MGCO, ; TEE: Cu,0 Fasere * Feco, ie Rereenge :PoCO,; WEE :2n8; RANE :2n0 MOF, 4,20, +041 Nanny + AHCI Nal A, 4H, Naa, a ha any of he oH sree Bm sat MO Nao, fo + 4H + 24,0 sot. ater al odo so. 90 63. tn how many of il Fret 2 fier ronftri, HO—S—S—OH Sol. (5) I 80) INResonance souuarszeiats° 6 % 2 i Ho $0 OS—oH ° Yo ° 0 ROA (HS.0,) oy A Ng (803, i ° 9 Bj HOE-O~S—OH Ho Ib YoH il il oo cao (80) 1 oy o oe (80) Hou many of he flowing Fret a fa arenes Sol.) {)) 0, is amphetee and dsohes in very strong NaOH and ‘ery song ocd forming VO,” and VO fons tespectiely Gr, ls anphota and iesches nace and concerted at orming [1(,0)* and CxO. ine respect 20 amphoteric and disses n NaOH and ds fring [ZnOF),F one and eae respecte (i) fimo, 1 acide ode and ges Hn, when essohes in wate GO, is acc onde and ges H,0r0, and H,Cr,0, when Gisetives mor (i) V0, 6x0, FeO and Cu,0 ae bac oes nd dso in seis forming sats V0, rae Ber be a a NAOH, a ABR 2 game ae vo" ae Vo, area a Fn ah 1 cx, seth at 8 ae aes a Pa ees HG Pe [EMHO)P mH Cros wT Pet 200 seat fen oH NaOH a anh A RTA oe [2o(OHF ee a Poin ae ( Wo,0, sre & ta aH ARE HMNO, kar 1 CxO, Sra segs & we TH YEAH, CHO, wATH,CO, aad (i) V0, 610, FeO wen Cu,0 enter aes Bo aH gee a a Fn aH 81 69, dng which of he fer a Pr “Pra Sol. (6) Sho, +2H,0— 2KOH + H,0, + 0,4 PHI +O —*> PH « HOried) + F am) 2K + 2H-OH—> 2KOH » Ht KH, + HO —2> 2KOH + NHL Beh,» 2,0 —> Be(OH), 24,7 Berd + HO —> 2be(0H), «EL 70. Heating with aqueous Frere Ps et Sol. () 1 Be can iberate H, with NaOH, P iberates PH, Cy and Fe fall to react 8, Al, Be aa NaOH & re H, Ae Rt wT Py PH A ‘Bel 81 Cy tat Fela El we oT EH 71. Fluoroapatte ‘reietteree. Sol. (5) H,PO,, Ca(H,PO,),, CaHPO, HF, CaSO, can be obtained, not athers, IM Resonance H,PO,, Ca(H,PO,)s, CaHPO, HF, C280, aist &t wl 8, aH a 72. How many of the fs a @ Per Sal. (6) () 8KBr + K,Cr,0, * 7H,S0, —> Br, (eddsh-broun) +20" + 8K" + 7802+ THO (Nos +H* —> HNO, SHNO, —> HNO, +No t+ #,0 2NOt+0,t —> NO, f (bru) (i) 3r-+2H,80, —> lyf (ket) +80} +2H,0+ 80, (uw) KS +H,S0, —> HT (coloutess) + K,S0, (W) Cr+ H,S0, —> He! * (colourless) + #50, (ui) 2KBe + MnO, + 2H,S0, —> Br, P (redeish-brown) + 2K" + Min + 280" + 24,0 (il) 4NO, + 24,80,» Br, F redash-brown) + 2K* + Mie" + 250, + 24,0 (ui) KCI + MnO(OH), + 2H,S0, + 2c —> Mn®* # Cl 7 (yellowish green) + 250, + 3H,0 (o) $0.4 2H" —> 80, 7 (coloutess) + H,0 Sol. ()) 6KBr+K,Cr,0, + 7H,S0, —» 381, t (Ts ae ED +200" + 9K" +750," + 71,0 (i) Nos+Ht —> HNO, HNO, —+ HNO, +NO 1+ H,0 2NO t+ 0,t —+ NO, 7) () 3h + 24,80, —> Ip t ty + S024 24,0 + $0, (w) KS+HS0, —> 4,87 cma + K50, () cr +H,80, —> HoIT eng) + HS, (Wi) 2KBe+ MnO, + 24,80, —> Br, t (TR Te) +2K" + Mn + 280, + 24,0 (wi) 4NO> + 24,50, + r,t TERI TS AED +2K" + Ma + 280.2 + 2H,0 (ui) KCI# MnOOH), + 24,80, + 2 —> Moe + ol (fiat ean + 2802+ 3H,0 (o) $0,-+ 24" —+ 80, t (em) + H,0 PAPER-2 PART-1 : (MATHEMATICS) 1. Consider the graph of quadratic polynomial fer agra y "ax? sxc Sol. (48¢) SOLIPYATS291215 -8yraeroere from graph 15 & Letz, 2, betwo complex numbers represented 25 0 Jconcaty upvards ] rat 2, 2,2) aia Se I feet @<0 110) <0) Sol. (ABC) Since 2, and ze on l= 1 and fel= if 2, she 2p a)= 1 HEN al = 20% aa & then (= fand 2 =2 waist gz, 42) < 22) + e)=21+2 <4 mek [22 +2 2) — 2) Ie ~ #112] a,b 8b .e <0 1 at2 tppt eet ae 2b +4e<0 bola #20 + 4e) <0 2. Caine es aeny Sol. [ xsin® xcos* x dx agute sol. (RaD) Prine xe08x , J (@x=x)sIn® xe0s* x ax ’ ain | on? eos de ate al Sn x00" sin? xcoe! x : _( Seeno-9 Gx3DBx) 3x7 4 0x8x6x42)" 2 * 128 1 6. Atne vais ofa, for wtih bath the ate, fer" deat a wih mn firm fq wre 1-0 2 sol (ABC) Sol. (ac) ‘Accotang te condton 1. ~ 1 os isi the rats of he equation a we Gana)x =o nO jeve BR & OTA 4, —1 WAT w+ (Qa) x 268-08 nm Rea & fy <0 1439-9303 <0 (tae) Gat ty>o feed 1-334 9'-38<0 sorter 2e-5 (+t) Ga-1)>0 Belo) @ From () > (9 & acts) y= fotee—nac-etee-0f -fotax =2- ae C1190) (ay a1, == 1-22 1 3ae-9) tae eae ate 65 Resonance SOLIPOATSIE1213 -10frrh a ata peer Sol. (ABC) wet * (z m ® 1 ae 4 orm pe . 2 128 *'"4 xe xet Als correct 8 & 4 11 Sol. (0) Now sm <——— «> in(t, e) ae 1 : 3 “fmx+2 “2 wie 4 | poe atete fica nears f ; Peto [SEP a = fomeraee Sm Hences <3<0- 5 12 ce 2ein2<1<> 8 Sein2<1< 12 sincel>3ein2 ws [oe But itis given that |= 4 m2 — Dis incorect | Jeane 8. Foran neresing AP.a, 2,9, a8, + - Sol. (AO) ere: btatae-12 a +1) seat adear ad sat (0) Bie eg eee eo Leet cr) (4-20) (4+ 29 : Since AP i increasing, 80d foc caer tty safe wr Fah ier 8 ae d= +3 ,a=—10, a yet pote (cee rent-3 etde—t = Pca" Nia 8. IT mye Ren the ordered pa of (xy) pevens te s AR ayy eR AR TH xy) ET sect 3 frye Linge — a Sol. (80) ve 998 = 4 =O and en 2k— 3+ 5=0 : A) (8 ctak > (8 8\G8 +1) =0and Bn 24-37 +5=0 emeeeaa azine) (a) (-21 a A = «n=@9 0-23] 1-30 = 10. Let a,b,c be the three sides of @ triangle and Pere raf abe Go a a at poe & wen 278 Sol. (AC Boles ot a9? = ret 14, Point L D= (ota abe) +e! 38+ 2bo) ans.) D=( Pale ee] D=(-c+ayo-c-a}04c+a\o+e~9) 18. Pont N is oven D=4arbaojera—bibrc-ajbrora) id side of 8) -ns.(C) =< 0 and paraboa is upward Hence st: F070 VER IW Resonance SOLIPUATS2=I215 -11 mm Which of the following416. i218 of pint Mt then weave J = VRE “fe 2, ry Mar Biter 8 aa us a ‘ans.(c) Wak Sot 14.18,16) sorafe |-Kivie—a[ aerate ae So, al the rots have modus 4 BAL a3 ef ih et or wor 1B B6L= 5-28 1 ye pene | ae craton 5 ans. (A)-> (9, (B)-» (), (C)-» (@),_ 0)» (@) Beem ae Sol. (a) I hae ¢ 6a = 28, 224 Fevers nate = Be using fren ox fcavb-» a] 4 ay? giant am ding () and fy we get = JX Oo. ot ex?! te I sinx? dx Sin? + sin (x14)? (14-x)? de sinx? +sin (x -14)* “ ‘ Saar remota? 3 OAC = 5-8 Rotation abun & Rar “ame 2-24 Bate oR [using fen ax— fied) ax ) Dividing AT eA ‘ ung) and pve gat al= [Ox te. T= wore uta os king (9 and i) we get 20 J I angeinende PHS. Zo Z4Kee=Za) * anBsine @u-2P gen ose @stet we 2 GB-BaNee ZH) * snanc « fo vo tet Interchangng 8.6 1 © Te ae 417. ab.c are complex numbers and all rocts of ape sitim wom & an 2 +az*+b2 +070 Ans. (Aq), (B 1), (C1), (D-#) Sol Lette tos + aa be + © Obe af then Jrox+ fadx+ [aac+.+ fredx HIRD 2+ a2! +be+e=0% YS ashy 4 7 1 ota tee Jog URN 428-2) 934-3) oo 21912 2 eres ree = lal= belo = ay 2634. 41g = 156 Alsowe fa = kx +P + 71 < lol + Ip # Hels Put, al= 2+ 1 Hw when TAF kt 0) 1+ f ensin 2x aeeE ira “Thus i 2° + fala +(e + fl 0 24 Qk4 e+ Oke te @+@+2e+1) 1 (nin 2 £5 J insnar an} Ithas roots 1 & x ya singe, RSI, we. ate ga eg BR Ee est IW Resonance SOLSPUATS29I219 -12PART-II: (PHYSICS) Es 48. Some unknown 40°C aT TR (4), (0) Sol Sol 20. Light of intensity Sol wat wi oF Sol. (A), (@). (0) 21, An isolated ve frat Sol. (8). (C) p a. Sol 22, Iipis the fe p TORT @.@) ‘The siess is max atthe uppermost point and is equal to he weight ofthe rod divided bythe aea At the highest point stess eaking sitess = = Weight of rodlarea of cress section of ‘ALpg =u a The fs Bad oO fg we aftram o aT we a a agra wre $ aqaa Fv sm) Gea fg we see ort afte =o = UR AT MTG RE are eT = ALeg A the ro = 0 2, Pg ‘The stress decreases lneaty to zero at the lowest end site Sera a Pere fry oe AT aw wee | 23, A hyckogen ag sraen @.¢) “Transition that should occur is n Sam Gh et Wom ta=1an=4 SE, = E,—E,= (085+ 136) eV = ‘maximum 3 diferent lines can be emited in emission spectrum 3 shown ae cgay wets wag trae far nt eerie Sol tone 1275 ev nt 24, One mole of wit ew Sol. (8), (C) (0) (250 KPa) (19 = P, 4)" 250kPa pe pn = 3125 KPe IW Resonance Ut ina internal af aretha (©), (0) (One mole of ee are ww 0) THB = constant FIAT PUA = constant, plyropic process with 1 = ole 4 3 molar spectic heat Ate fe ST Cee ee sneen =i u-i 2712 Werk done by gas fret ret ftpat ara ar ART, —-T) 413-7) w=-3RT, Pyle = Pramas, age Ba y= An ideal atomic Se aree SRMTS (@yeNtC) Internal energy artes rat since 9 UT, and een PV = constant Pec oyrope process with AETErT nam 1 | (7) SU (=) 100%( 2-1 a9 z-1) } 1 77) \ 2) 2 vented A tnemaly inate 0.) v, eh co Pr, TP Let compartment PV mR Tae Right compartment 2P2V_m,R T OM nea Right comartement has 4 mole and left has 1 mole pv PV Let p’ be the final pressure fort —~ = —— e a Pay 2Tx2V_ P’@V-V) T T 3PV-PV ev for right ave SPV SOLIPIATS2OI219-13 mmSol 30. sol 34 22, 3 fy ves for volume of ight et W-VEWV- Beg vine 20,1, 2° aida PV _ mR TM sama rat pad @ Ray 2Tx2V_ P'@V-V) 1 i aid & Fag 8 & ore fee av-veav- BY WEN eS What is the. seats, 0) What is the, seattia p, M, © Total energy son a) Total energy released from Au'™ —> Hg" in ground state My) 197'8682 - 197.9662) (990) 86 MeV Energy released from Hg in first excited state > Hg in ground state ($1.8) ~ (-2) MeV 4 Mev = Energy released from Ag’ —> Hig! second excited state 86 ~ 0.4 = 1.48 MeV = max. KE, of f, particle AuSed orattia Ea Tat Hols scree Am,,) © 19778682 ~ 197.9862) (930) 86 MeV "Hg amt ae sea seen weet ES a sree #iHg (1.6) ~ (-2) MeV Mev = Aga sonia sat > Hol Rs sae srreen 86-04 = 1.46 MeV = py ae seme RI Sh ‘Similarly mayimum kinetic energy of 6, paticle = 1.86 — Be re pT a rrr af oH = 1.88 = 0.88 Mev choose the uave IW Resonance Sol 33. Sol 34, Sol 35. Sol “ a tt ® as, ta ) pronat ee +10 F005) = on [3] (35 2 ot 0 0 RTA 5 (5) vee oe Sar «(5) av-vy u=(3} «ne Hence (A) is correct sft: (A) 881 8) Cote mom rus 2 oe p= 4 Tive2dhex & fig siftoam 8 of p=—v+4 2442 2am p ave (72g) «1m prs oRT Toe = 400K Ans. (8) Hence, Si Usa = AC, Ty 5R won (Jen = 1000. Ans. In Column, certain atom, ae wrest (A) 1B)=s:(6)-4: ©)-P ° (ay 2 = BE = 12820 gta eV ~ 30000 h 826.10 ‘ a 86:10 ©) Tak” Te810724 6.10 [aR © ye=ae-w=/FPa-9 leaeeeaar [2.09107 g, V4 220198 SOLIPIATS2I219-14 mmNhe ot 10" 6.6.10 «310° 57 36. In Colurnn I cata Li Poh Re Sol. (A) =p :(8)~ a: (C)~p: (0) (A) Applying Bemoulls equation between A and 8 Amen BS Hey wea eh STA P= 2h (8) Applying Bemouls equaton between A and & Ae Ba non aeaeh ethare STA Oe Pat+Spa+hpg y,? Pa+SpG_ v,? P 2° p ° 2 vinyi = 29h Also em exhtn 69, v = 24, er sracaen 8 2gh “3 (©) (A) Applying Bernoul’s equation between A and 8 Ae Ba Mon aeaTeh hore STA Oe = 2h PARTAI ; (CHEMISTRY) 37. Which of the follwing creftram Asem, Sol. (ABC) (0) Gites prussan blue precipitate of Fe(Fe(CN),, wih Fe (0) me Fem ae garg 1 SAN FesFe(CN),, a & 38, Cl, when lola oa Sol. (ACD) Cl * NaOH —> Nac + Naot aNao! —2> anal» Nalo, 38, Select the comect, are Saat Sol. (AD) In [Niémg),. NP* and dmg are present Hybricisation -» dsp, square planar Neatoms are donor atoms in cg” IW Resonance {Nirmg).) NE Tea degree 8 1 Be dp oH TT dmg Neve erm TY & 40. AKOH), feta fee ‘ans.(B0) 44. Which ofthe fling fara 8 aioe Sol, (BCD) XeF, f dstres octahedron or capped octahedron Ker, a agra, EH aMeTOa erat TAT SNeTETT & 42, Which ofthe following Prey werd Sol. (ACD) (A) Nitrogen is more electronegative than phosphors, Ne? phe x aso Kl SH, 25-04, aus cH, So, cole moment of trimethylamine is greater than trimethy phosphine © nsiio ) — SIH, In tre the the lone pai of electron an oxigen atom ie less easly avaiable fr donation because of pred delccalsaton due to presence of the vacant debtal win i. Ths however nat possible vith carbon in CH,~ © ~ CH, due othe absence of d- Eta making & mare baste (©) Bond order of C, and 0, are same ie, 2 In C, molecules both bonds are s-bonds whereas, hee Is ene c and ane r-bond in molecule Che i3t pm; 0,= 121 pm SiMe), © |<—sp'(trigonal planar) (Me) si7” “si ave), F be-op'tuigonal planar) FOF Te, (A) Tag, eae oh gor A sty Fags 8 Newey beat Satu 28K 25—> cll cn, 2564, IS vo a gator, ro ap ot rs wh west 8) ® Hi Son, +> HSi= 0 —SiH, mths er tear eo oe pred Perse, Seer & coral ger ara we fee a ea A SET Er gear arensine Rema. A auf 21 ae CHO HCH Horde ane ae ee aE & a, me or 24 §, get eR as anda (©) ©, me110, ae ams (ae 2.8) Ca] A Re A wae 18) TA 0, oy HT o AEM UO xa Ren & C,= 131 pm 0, = 121 pm. SOLIPIATS2OI219-15 mmSite), (0) UN<— 9p (Prati wre) (Me)si7 “si (Me), F hesp'(Pretvha sree) FF 43, In hich ofthe following arrangements, Frafefeaa arent Sol. (cD) ‘omic radius Fst lonization energy_(ks/mole) cgay Pasar gem To a (Kata sc 144A 631 Yo 182A 618 la 1894 541 44, dently the incorrect ee, Sol. (ABD) (A) Zine fs highly reactive meta, I may nat be possible to Feplace it from a soluton of ZnSO, so easly, (co (©) Feo + si0, ——> Fesio, (0) Graphte rad acts as anode and ion tank as cathode, (a) fore orate Brana arg 8, $4 ZnSO, Pear He sare afene 8h Pra SPAT 8 (eco (©) Feo + slo, (Oto meat 81 sol > Fesio, 45, On boiing wth NaH,PO, = Sol. (cD) NaH,PO, diepropertonate on boing NaHPO, sare ne fergie Ee 81 2NaH,PO, + NaOH —> No,PO, + PH? +H. 46. Nizogen (1) oxide srgetord () stregs Sol. (AD) (aynnino, 95 no +240 ()2NaNO, + (NHiy, SO, —> 2NH,NO, + Na,SO, ;NH.NO, 4s nero (©) 4HNO, + P,0,, —> 2N,0, + 4HPO, (0) 4zn + 10HINO, (a) (A) —+ 4Zn (NO,),+N,0 + SH,0 47. (A) and (8) (a) a), Ans.(0) 48, (0) is. (Fe Ans.(C) 49. (6 © Pm Ans.(A) 50. (A) may (8) @ seat Ans.(0) ers gers ae ee els TA a 51. Heating (), eas Ans.(B) 82. [Bis @) Sol. (A) BH,—>B0, + HO Le, (6) cle, lio! 80, + H. © ©) 3, Math the scons mannan Sol Ao pa BoaN Ce ons): 0-99 re om ay a Mino} ae — 280g + Wo, +2H0 (@)2cu sar —> cul, t+ (0)2610% +2" —> c,0% +0 (Dares Fetowge —> FesPeC, 54. (8) forme (a) aR, Ans.(A) ~q, 5: (8) ~@, 5: (C)~P. :(O)—p, 5 IW Resonance SOLIPUATS201215 -16