باكلوريا الجزائر 2008 مع التصحيح

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2
3
4
5
6
(*)

: 2008

@@@@
@@
l‹Í¾a@J@óï÷bîïÑÜa@ãíÝÉÜa@ójnÙà@Œb−g

‫ا
ل ا
ت ا
و ا ا‬ ‫ إز‬
(#‫ی‬%
‫م
(' & ا
ت ا‬% *+‫ ا‬,‫ا‬-‫ة ا‬/01 ‫رة‬3 ) !
‫ا‬
‫ א
א‬
: ‫אאא
א‬ (1
CH 3COOH ( aq ) + H 2O( l ) CH 3COO( aq ) − + H 3O + ( aq )
..
./1,2'34H+(' !(‫*)א‬+,-.
./01/: !"#$
‫א‬% &'(11
:16‫א‬1,2‫א‬7(/ ‫(א‬89‫(א‬21
+
. H 3O H 2 O CH 3COOH CH 3 COO −
::!#‫א‬.
.;‫(>!אא=(<א‬31
[H O ] .[CH COO ]
3
+
3
−
K = éq éq
[CH 3COOH ] éq
: ?‫@א‬A ‫א‬B1,2'&.CD (2
J,3,7
.)‫&<א‬pHI.-C = 2,7.10-3mol.L-1G9./ '
‫אא‬EHAV = 100mLE4F
.25°C
:NJ‫א‬O ..K‫א‬LM9./ '(12
[H O ]3
+
f
= 10 −3, 7 = 2.10 −4 mol.L−1 :QJA H 3 O + [ ] f
= 10 − pH :P&
:26‫א‬R‫(א‬22
1,2‫&א‬A CH 3COOH ( aq ) + H 2O( l ) CH 3COO( aq ) − + H 3O + ( aq )
‫א‬ (X)O)‫א‬ (mol)S‫א‬.
/ (mol)S‫א‬.
/
.C‫א‬ X=0 n 0=C.V T* 0 0
1,2‫א‬34 X C.V - X T* X X
7
.NJ‫א‬ C.V – Xf T* Xf Xf
UV)‫א‬ C.V – Xmax T* Xmax Xmax

(32
nf xf
[H O ]
3
+
V f
V
= = ⇒ x f = H 3 O + f .V [ ]
:JXfW#$ •
⇒ x f = 0,1 × 2.10 = 2.10 −5 mol
−4
C.V – Xmax = 0 Xmax = C.V = 2,7.10-3.0,1 = 2,7.10-4 mol :xmaxW#$ •

:NJ‫א‬O)‫א‬C# •
xf 2.10 −5
τ = = −4
= 0,07 = 7 0 0
x max 2,7.10
/TXY1,2'?‫@א‬A ‫א‬B1,2'(MZJ#
.Q)*‫א א‬S,)‫א
א‬A1/9./ 'W#$(42
−M
n f (CH 3COO − ) = x f = CH 3 COO − f .V [ ]
2.10 −5 xf :26‫א‬R‫א‬A
[
⇒ CH 3 COO f =
V
= −
]
0,1
= 2.10 −4 mol.l −1
C = [CH 3COOH ] f + CH 3COO − f [ ]

⇒ [CH 3COOH ] f = C − CH 3COO
−
[ ] f :S‫\א‬2]‫ א‬
[CH 3 COOH ] f = 2,7.10 −3
− 2.10 −4
= 2,5.10 mol.l −3 −1
:pKA^J‫ –א‬W

[CH COO ]
3
−
f
pH = pK A + log
[CH 3COOH ] f
[CH COO ] 3
−
f
⇒ pK A = pH − log
[CH 3COOH ] f :J
−4
2.10
pK A = 3,7 − log = 4,8
2,5.10 −3
8
P&

J
pH 〈 pK A − 1
.
‫א‬H(b /‫)א‬J
.N‫_א‬.V‫*`(א‬ :QJA
(J‫?א‬9.2‫ א
א)א‬
(1
.J.&‫א‬U,%Vc2A=3‫א‬.JA9‫א‬S‫א‬،%VJ‫
א‬,
#t1/2 :%VJ‫
א‬,% &'−M

:C.CA%VJ‫
א‬,e.&'−W

,!N., *‫)א‬.>‫א‬-O&‫ א‬g:\fA)
N.,1V‫
א‬.)‫א‬hiW -‫א‬R‫א‬hiW -‫
א‬.)‫א‬
(t1/2 = 2240s (`*+JfJ‫א‬A

(2
λ A9‫>!א‬j!%VJ‫
א‬,TC&'−M
N = N 0 e − λt
t → t1 / 2
N → N0 / 2
N
= e −λt1 / 2 ⇒ log 2 = λt1 / 2
N0
log 2
t1 / 2 =
λ
log 2 0,96

λ= = = 3,1.10 − 4 s −1 :)!#‫א‬-3&‫א‬A ZA X SJλW#$– W
t1 / 2 2240

9
38 A
17 Cl :HSJ‫(א‬MZJ# Z X SJ:%VJ‫
א‬,A-3<‫(א‬3
bJ‫א‬f‫&א‬A(4
35
17 Cl +3 01 n→1738 Cl
(J)R‫א‬:W ( k*(l;i_.‫)א‬Mev :Wk! ‫א‬-D– M(5
:k! ‫א‬-D:% &'
[
El = ∆m.C 2 = Zm p +( A − Z )mn − m(1738 Cl ) C 2 ]
El = [17 × (1,00728) + (38 − 17) × 1,00886 − 37,96011]1,66.10 × (3.10 )
− 27 8 2
El = 5,22.10 −11 J ⇔ E l = 326,25.10 6 eV = 326,25MeV

El 326,25
ξ= = = 8,58Mev / nucléon :1;k! ‫א‬-D–W
A 38
( .;.‫)א‬:m‫ א
א‬
:#‫&א‬A (1
،'.J‫"א)(א‬#$
:";?‫א‬K‫א‬T>F'1
NJMn
r r r
∑ Fext = P = ma

r
(o; j ) ‫א‬+,o)‫א‬ •
Voy = V0 .sin α
y 0 = h0 a y = − g = C STE
ay = −g L.<&‫א‬A 1 2
⇒ y (t ) = a y t + Voy t + y0 → (1)
−g 2 2
y (t ) = t + (V0 .sin α )t + y 0
2
r
(o; i ) +,o)‫• א‬
10
ax = 0
x(t ) = V0 x t + x0
x0 = 0
x(t ) = (V0 . cos α )t → (2)
A9‫?א‬V-`!:#‫&א‬A •
 −g  2
y =  2
.x + x. tan α + h0
 t =
x
2 (2)7p& :ZJ#(2)A
 2.V0 . cos α  V0 cos α

q.+JfJ‫!(א‬8‫א‬GEH7N.,1V‫א&א‬L).C<‫א‬:*‫'א‬j- ):+JfJ‫
א‬,! (2
(.(fA3u ‫א‬v.fV‫א‬7HwA@A)A-!P.)‫א‬r;st‫א‬SR!
9.
@x‫אא‬EHJ,+JfJ‫א‬x = 12mJ,8",3‫א‬:Q2Mvx‫א‬1; ‫א‬A-3<‫ –א‬M
(!! N2)‫) (א‬QMy* zG ;‫*`(א‬1,80mQD",3‫(א‬Mny =3m : W
h2 = 1,20mW

V0S ;",3‫א‬N.<&t‫א‬.C‫א‬, #‫ –א‬W

:#‫&א‬A7p&yp = 0 Xp = 18 m y0 = h0 = 2m :M )+JfJ‫א‬A
:";:
&‫א‬L.<&‫@א‬A
11
 − 10  2

yp = 0 =  .18 + 18.0,4663 + 2
2 2 
 2.V0 .0,9063 

⇒ V0 = 13,7m.s −1

.N-, #‫
א‬.-P>t = 1,17s gf‫א‬J,M<)J‫@א‬xA– ^
* x(t ) = (V0 . cos α )t
x(t ) = (13,7 × 0,9063)t
M<)J‫א‬L.>‫א‬$i]A9‫א‬p& x(t ) = 12,4t :.JA9‫א‬Lj&‫א‬A
* y (t ) = −5t 5 + 5,8t + 2
. YM ≈ h0 = 2m W'M K XMV*‫א‬L‫)<{א‬J‫א‬+JfJ‫א‬AXM = 14,5m

t = 1,17s gf‫א‬J,, #‫^א‬J‫;א‬s

./ ‫א‬-<‫א‬JH|A
r
1
2
(
2 2
)
m VM − V0 = WO →M ( P ) = mg.h = mg.( y0 − y M )
VM = V0 + 2 g ( y0 − y. ) = V0
2 2
= V0
VM = 13,7ms −1
r
:J ( 0, i ) ‫א‬+,.JA9‫א&א‬A–
XP 18
tP = =
V0 . cos α 13,7 × 0,9063
≈ 1,45s
@!‫ א
א א‬
S‫אא‬1
&' ∆t = 15s &!–1
m.$،P‫אא‬OgJ‫א‬:*
Uc = E ⇔ i = 0
τ = RC (MP&−2
:&!‫&א‬AA
12
[V ][I ][T ] = [T ]
RC =
[I ][V ]
@A}‫אא‬16MJ,I
‫@א‬D)') DJ
&‫א‬G3,M1; ‫א‬7 τ = RC ≈ 2,4 s +JfJ‫א‬A
.(Uc(τ)=0,63E1!)‫ )א}א‬D
&‫;א‬s
/)W)‫א‬k~‫א‬
:%;‫
&א‬.-^J‫א‬
τ 2,4

C= = = 240µF
R 10 4
– 4
dq
i = S‫אא‬7‫א‬gf‫ !א‬N;‫א‬.‫א‬S−M
dt
q
UC =
C :%;‫א‬7 De!! N;‫א' א‬−W
U C(t) N))rt‫א‬.x2‫^ –א&א‬
UC +UR − E = 0
U C + Ri = E
dq
UC + R =E
dt
dU C
U C + RC =E
dt
:.x2‫א&א‬71‫א‬p&−5
 −t

U ( t ) = E 1 − e A 
C   :1‫א‬p&
 
dU C E −At
= e •
dt A
 −t
  E −At 
E 1 − e A  + RC  e  = E
 A 
   
−t
 RC  A
E + E − 1e = E
JfCA=3‫א‬.JA9‫א‬S‫א‬HA9‫{א>!א‬iA1z  A  •
RC
⇒ − 1 = 0 ⇔ A = RC
A
.UV)‫א‬N
.-A63°/°%;‫א‬
13
(?.
./) w‫ א
א‬
(1
1,2‫&א‬A + O2 ( g )
2 H 2 O2 ( aq ) 2 H 2 O( l )
‫א‬ (X)O)‫א‬ (mol)S‫א‬.
/ (mol)S‫א‬.
/
-2
.C‫א‬ X=0 n 0=C.V=4.10 S *! 0
1,2‫א‬34 X 4.10-2 - 2X S *! X
.NJ‫א‬ Xf 4.10-2 - 2Xf S *! Xf
t gf‫א‬J, .w.#/‫א?א‬SA.

/(2
nt ( H 2O2 ) = n0 − nrea = [H 2O2 ]0 .v S − 2 x

2x
[ ]
⇒ H 2 O2 = [H 2O2 ]0 −
vS
V (O 2 )
n (O 2 ) =
VM
[H 2O2 ] = [H 2O2 ]0 − 2V (O2 )

v S .VM
:R‫א‬Ozi(3
:‫א‬R‫א‬9./l‫א‬W#)!#‫א‬-3&‫
א‬,!
t(min) 0 4 8 12 16 20 24 28 32 36 40
V(O2) mL 0 60 114 162 204 234 253 276 288 294 300

8,0 7,0 6,1 5,3 4,6 4,1 3,7 3,4 3,2 3,1 3,1
[H 2 O2 ](10 −2 mol.l −1 )
– W

:1,2.
w‫א‬, #‫^ –א‬
1 dx
Vvol =
vS dt
egf‫א‬J,1,2‫א‬, –
14
24min 16min
:1,2‫א‬,
dx
V =
R
= vS .Vvol
dt

Vvol ( H 2 O2 )
.
w‫א‬, #‫א‬1,2‫א‬, e!-3&‫א‬ZJ#QJA Vvol = :1,2‫&א‬AA
2
A9‫א‬34 H 2 O2 ( aq ) ?24j
1
V
+Jf
JI
Q8‫א‬1A&‫א‬1z vol ( H O ) V
2 2 @A R
= Vvol ( H 2O2 ).vS :QJA
2
+JfJ‫א‬A.egf‫א‬J,
.v1 = 3,6.10-4 mol/min:m.$t1 = 16 min gf‫א‬J,I
Q8‫א‬1A&‫ ]א‬.1
v2 = 2,66.10 -4 mol/min:m.$t2 = 24 min gf‫א‬J,, #‫א< )]א‬q2J! .2
:*‫'א‬AH)L3,2‫א‬9./‫' א‬-J'hi@8‫{ א‬A9‫א‬34-J', #‫(א‬M$3
.(..
./,
<'e‫א‬-
:bMUV)‫א‬Q
.-%VJ#AxO)‫א‬.*vCVbE‫א‬A9‫א‬H1,2‫א‬%VA=– G
xmax
(.C‫א‬A xt1 / 2 =
2

15
−4

elghzizal@live.fr:|,V'j‫א‬8 ‫א‬:.&'Mg$3A1;
W _‫*א‬.9.2‫א‬O&‫א‬C;A:hi08 ‫א‬M
16

باكلوريا الجزائر 2008 مع التصحيح

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باكلوريا الجزائر 2008 مع التصحيح

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1,2‫א‬34 X C.V - X T* X X

.NJ‫א‬ C.V – Xf T* Xf Xf

UV)‫א‬ C.V – Xmax T* Xmax Xmax

C.V – Xmax = 0 Xmax = C.V = 2,7.10-3.0,1 = 2,7.10-4 mol :xmaxW#$ •

C = [CH 3COOH ] f + CH 3COO − f [ ]

:pKA^J‫ –א‬W

El = 5,22.10 −11 J ⇔ E l = 326,25.10 6 eV = 326,25MeV

V0S ;",3‫א‬N.<&t‫א‬.C‫א‬, #‫ –א‬W

t = 1,17s gf‫א‬J,, #‫^א‬J‫;א‬s

1,2‫א‬34 X 4.10-2 - 2X S *! X

.NJ‫א‬ Xf 4.10-2 - 2Xf S *! Xf

t gf‫א‬J, .w.#/‫א?א‬SA.

nt ( H 2O2 ) = n0 − nrea = [H 2O2 ]0 .v S − 2 x

[H 2O2 ] = [H 2O2 ]0 − 2V (O2 )

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باكلوريا الجزائر 2008 مع التصحيح

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باكلوريا الجزائر 2008 مع التصحيح

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@@www.bibliophy.sup.

 1,2 ‫א‬34  X  C.V - X  T*   X  X

 .NJ‫א‬   C.V – Xf  T*   Xf  Xf

 UV)‫א‬   C.V – Xmax  T*   Xmax  Xmax

 C.V – Xmax = 0 Xmax = C.V = 2,7.10-3.0,1 = 2,7.10-4 mol :xmaxW#$ •

C = [CH 3COOH ] f + CH 3COO − f [ ]

 :pKA^ J ‫ –א‬W

El = 5,22.10 −11 J ⇔ E l = 326,25.10 6 eV = 326,25MeV

  V0S ;",3‫א‬N.<&t‫א‬.C‫א‬, #‫ –א‬W

 t = 1,17s gf‫א‬J,, #‫ ^א‬J ‫;א‬s

 1,2 ‫א‬34  X  4.10-2 - 2X   S *!  X

 .NJ‫א‬ Xf  4.10-2 - 2Xf  S *!  Xf

 t gf‫א‬J, .w.#/‫א?א‬SA.

nt ( H 2O2 ) = n0 − nrea = [H 2O2 ]0 .v S − 2 x

[H 2O2 ] = [H 2O2 ]0 − 2V (O2 )

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1,2‫א‬34 X C.V - X T* X X

.NJ‫א‬ C.V – Xf T* Xf Xf

UV)‫א‬ C.V – Xmax T* Xmax Xmax

C.V – Xmax = 0 Xmax = C.V = 2,7.10-3.0,1 = 2,7.10-4 mol :xmaxW#$ •

:pKA^J‫ –א‬W

V0S ;",3‫א‬N.<&t‫א‬.C‫א‬, #‫ –א‬W

t = 1,17s gf‫א‬J,, #‫^א‬J‫;א‬s

1,2‫א‬34 X 4.10-2 - 2X S *! X

.NJ‫א‬ Xf 4.10-2 - 2Xf S *! Xf

t gf‫א‬J, .w.#/‫א?א‬SA.