Neraca Massa Masuk Reaktor

Masuk
Komponen BM xi ρi, kg/l
kg/jam kmol/jam
CH3OH 32 2170.37 67.82 0.2897 0.7541
H2 O 18 138.24 7.68 0.0185 0.9950
C6H4(CO)2O 148 5018.99 33.91 0.6699 1.2711
C6H4(COOCH3)2 194 63.13 0.33 0.0084 1.1563
H2SO4 98 101.39 1.03 0.0135 1.7019
Total 7492.13 110.78 1

M 7492.13 kg/jam
Fo = =
ρ 1.1211 kg/L

Cco = 0.0051 Konsentrasi awal C6H4(CO)2O

Cao = 0.0101 Konsentrasi awal CH3OH
M = 2.0000
T = 60 C = 333
P = 4 atm

C = 2
B = 67.82
k = 0.007662518 l/mol.mnt
459.7510724 l/kmol.jam

Neraca Energi
To 130 403
Komponen Mol Cp
CH3OH 67.82 40,152 + 3,1046.10-1 T – 1,0291.10-3 T2 + 1,4598.10-6
H2 O 7.68 92,053 – 3,9953.10-2 T – 2,1103.10-4 T2 + 5,3469.10-7
 C6H4(CO)2O 33.91 -105,627 + 1,984 T – 3,8847.10-3 T2 + 2,8513.10-6 T3
C6H4(COOCH3)2 0.33 116,404 + 1,1694 T – 2,5655.10-3 T2 + 2,4033.10-6 T3
H2SO4 1.03 26,004 + 7,0037.10-1 T – 1,3856.10-3 T2 + 1,0342.10-6 T

T, oC T, K CH3OH H2 O C6H4(CO)2O C6H4(COOCH3)2

80 353 85.7214 75.1728 236.0765 315.2317
85 358 86.3827 75.2364 237.5917 316.5144
90 363 87.0709 75.3182 239.0658 317.7978
100 373 88.5324 75.5379 241.8991 320.3743
110 383 90.1148 75.8351 244.5937 322.9755
120 393 91.8269 76.2130 247.1665 325.6159
130 403 93.6774 76.6747 249.6347 328.3099
140 413 95.6750 77.2235 252.0154 331.0719
150 423 97.8286 77.8626 254.3258 333.9163
160 433 100.1468 78.5951 256.5828 336.8576
170 443 102.6385 79.4244 258.8037 339.9102
180 453 105.3123 80.3536 261.0055 343.0885
190 463 108.1771 81.3860 263.2054 346.4069
200 473 111.2417 82.5246 265.4204 349.8798
210 483 114.5147 83.7728 267.6677 353.5217
220 493 118.0049 85.1338 269.9643 357.3470
230 503 121.7211 86.6107 272.3274 361.3700
240 513 125.6721 88.2068 274.7741 365.6053

dHR 13331038.3 kJ/jam

To 80 353
T
Xc dT
C K
0 80 353 0
0.111363553 90 363 10
0.225709161 100 373 20
0.343127888 110 383 30
0.463747101 120 393 40
0.587730472 130 403 50
0.715277975 140 413 60
0.846625886 150 423 70
 To

Wa Q Xc

0 0
1881.6105 118168.9035 0.2
3699.9168 232362.1726 0.4
5452.9856 342458.4014 0.6
7138.1132 448287.7849 0.8
7876.6426 494668.9075 0.9
8574.8968 538520.6685 1

To
Wa Q Xc
16982.725 1066549.105 0.8
16210.785 1018069.711 0.875
15356.862 964441.6234 0.949120109
14096.938 885315.8726
 ρi.xi, kg/l

0.2184 0.6123 T
0.0184 0.0693 30 303
0.8515 0.3061 40 313
0.0097 0.0029 50 323
0.0230 0.0093 60 333
1.1211 1 70 343
80 353
90 363
= 6682.961 L/jam
100 373
110 383
120 393
130 403
140 413
K 150 423
160 433
170 443
180 453
190 463
200 473
210 483
220 493
230 503

Cp
1 T – 1,0291.10-3 T2 + 1,4598.10-6 T3
2 T – 2,1103.10-4 T2 + 5,3469.10-7 T3
 T – 3,8847.10-3 T2 + 2,8513.10-6 T3
T – 2,5655.10-3 T2 + 2,4033.10-6 T3
0-1 T – 1,3856.10-3 T2 + 1,0342.10-6 T3

H2SO4
146.0677
146.6043
147.1272
148.1348
149.0967
150.0192
150.9084
151.7706
152.6119
153.4386 Xc v T
154.2569 1.2
155.0729
155.8929
1
156.7231
157.5697
158.4388 0.8

159.3368
160.2697 0.6
Xc

0.4

0.2

0
30 50 70 90 110 130 150

1333186

Konversi v waktu reaksi

Perhitungan reaktor
 80 353
T
dT
C K
80 353 0
90 363 10
100 373 20
110 383 30
120 393 40 618261.319814
125 398 45
130 403 50

80 353
T
dT
C K
80 353 0
90 363 10
100 373 20
110 383 30
k Xc
-79.8149063009 0.999952
-28.6307795308 0.999927
109.4815399559 0.999887
459.7510723976 0.999822
1299.2754160583 0.999713
3210.191605698 0.99953 Xc v T
7358.8667033548 0.999211 1.2
15983.003648695 0.998645 1
33208.143683184 0.997614
0.8
66366.971927117 0.995689
128060.32333543 0.992007 0.6

239278.36680498 0.984809 Xc 0.4

433993.75016237 0.970542
0.2
765744.13936262 0.942352
1316837.1491496 0.888516 0
30 80 130 180 230
2210932.7038239 0.7935
T
3629882.0833347 0.646201
5835824.3442568 0.455889
9199654.1107046 0.263575
14237074.467483 0.12124
21653529.626825 0.047196

Xc T
0.1 -28264
0.2
 0.3
0.4
0.5
0.6
0.7
mol T= 0.8
CH3OH 67.82 To = 353 0.9
H2 O 7.68 Tref = 298 0.91
C6H4(CO)2O 33.91 dH 298 = -99.33 0.92
C6H4(COOCH3)2 0.33 Cp dT = 715979 0.93
H2SO4 1.03 dHR = -715879 0.94
∑f.Cpi = -86.9808 0.95
0.96
0.97
0.98
0.99
1

110 130 150 170

148468 0
148468
0.111364
Kebutuhan air pendingin (Wa)
Sifat-sifat fisis air pada 30 oC
Cp = 1 kkal/kg.oC
dengan: = 4.1868 kJ/kg.oC

dT = beda suhu pendingin, 15 oC

T

180 230 280

T
kkal/kg.oC
k 459.7511
Cao 0.005074
M 2

Xc t, jam
0.1 0.026459
0.2 0.066975 t, jam
0.3 0.131216 1
0.4 0.238133 0.9
0.5 0.428639 0.8
0.6 0.803698 0.7
0.7 1.666929 0.6
0.8 4.286388 0.5
0.9 19.28875 0.4
0.91 24.07786 0.3
0.92 30.80841
0.2
0.93 40.67695
0.1
0.94 55.96118
0
0.95 81.44137 0 10 20 30 40 50 60 70 80 90
60 70 80 90
Volume reaktor

XA1 0.95
Cao 0.0051 kmol/l
M 2
k 459.7510724 l/kmol.jam
Fv 6682.960681 l/jam
V 544269.4774 l

Volume reaktor seri

2 reaktor
Dari persamaan neraca massa

untuk 2 reaktor dengan volume sama, maka V1 = V2

Dengan menggunakan goal seek maka XA1 didapat:

XA0 0 0
XA1 0.85229886 0.852285
XA2 0.95 0.95
V 55974.47192 l 55982.35

3 reaktor

untuk 3 reaktor dengan volume sama, maka V1 = V2 = V3

Dengan menggunakan goal seek maka XA1 didapat:
XA0 0
XA1 0.779586201
XA2 0.909885863
XA3 0.95
V 22982.00012 l