- 1 WW. Trl Sopurtin of Adi T 4-0 Cy of dbmenia ab 25° @ Maly 2 | as rei mt tr on npn 5 9.1 ex ly. fe ma” A in of Ms ene) | 7m, (3K’) A : fat ly Tempera vi, of an dyes To disouss fot tapi of maisriah, usd TK" Rg" (apse Lect gael) TK" ont" (ondlar hast capaci) fut diva Af Nj=6.080 07 ols Sipe, om tondtn of mane mets ‘winie Cp or by ( -snogaiun Cp yoni of ali ts Amal ‘ ‘piel, only, few parce1-9 Yc sinpare some char proper uf, cnn of asd, Ae an be Ame |074 seven! + Thee ust be dome imple, plavation, em 25K ml aloments : Au, Mylo " Mar heat capacty ("mot of 50 100 180 200 250300 Temporance 0) chips ta sero sempre decree 1400 pe © 195-535 3K nol! op Hy argh (ALO) 1200 F "reper ) tw to drop to jér0 as tempat, derems ‘t ‘200 400 600 800 1000 1200 1-@ "Wy, te slo ths 7 25 J 1 on pe * Wy ts Cp chop wth femprodt, and tnd to gem? B, Knowing, harmon oynminatn, bt gua och Element : Loom per primitive cll > BN dams of Sli tv ne ma Havmonit spins (Wg pte a) > afr inking ‘normal, des, IN sindependos osellalors C weal the egeniegeia form 3 acoustic branches For & clowtital, farmonie oscillatnr: 4- £ 4 a ib B at Dye A vais 1 nk $A ter th ‘h aye eneyyo- amy T “Egipattin of ney"Sor 30 sila ft ily (hy al 10 diye ws!) ¢ U = Bagi sd intemal enemy U= BNx(axder) + U, tos etch asellalyr tam Gy = (ras An ib Cv , wh Cp) = 3Nb Molar by > N= Ng Cy (molar) = SNR = 3R) = 3x $3) TK nd! = 448 TK mt C Notes Solis’ oxpansviy ds stall (0 105 4D, ard ‘tus the volume change fw a ch hh femperab th ainall, > 6 imine fmm» fag Thus , Cpe bv, If the sumption dot wb Id then ue awit Cp >Cv] n@ Cylrmlor)= 38% Cp (milan) fr moe dan of the clmerts + comes from claatical Heahnert f farinonl osilatns » Satter vibrato, dominate the contributions to Cp at 10mm temperatore (tine even ir metic elements! Why? Abowd He dechow alse contabute?) * harman, apparition > why, nly om stow of gltrian posts cand Winding mechantoms doy nar! ‘tus nay sane behavior fora olémayts! Aw C= 5R saat i called fh Law of Sule, Hou about AbsOs? 5 dom in a primis cl > SAN dps of don > SAN rma, mos & WN independent tvsU- © yah + “22 (+, 3p Vind = 3oNKT + Uy Cy= 3h Nk Colima) = p 3R, Uh Abels : 45 > Ll mlan)= 162 Bub, fr clauical, escillabys a 1H) hah tts "Nb terrain sande >C¢ dal i dp a T drys! ind guontom tnustment_or phonons to 6) a aps wath ebwuremoyt | A 1-0 O. Teating wirs_gurhow mada y After thing, normal, males, we have e348 Aihis 34 nase “Thee are tndependert oslators + Tor ond osilabr of agar Hegucy last GM ays th, energy, 2ychum fr thio male hg Ay, gett ( tees 63 fhm " Fn far ine ” ile jh in he moe (GB) ti, Clic stmt nica te dees, or Trt) T=0 + esilalr in G5 > 0 phon TH» howd ny, phon are, there?ut ne dam_o spain fo TO te pb du okt 0 Using, the phn pickin, te "male of iain (5,4) EY can on by Os ord, ory ovd, » pls °F 6 Mt " ra cays an one ws) given tuk w te odebd to 7 i, At fen. the thera suena oF ‘nla weber an) oe mH w(t) Hf phonons in fe tale lel) be (ge 8 4 ——— — B-Enthin m oP dababuin oh iti pots ie 4 te 4 , bi ‘bla = Haat) + half th phon munker (ont, atony An the bai) (2d basi) ree Re ne = internal ener, at fomp.T? ey hy ill ly tag | oe a U= pe t XL “ef zy P ey AIT 4 or 33 d6parsion oa Tost (gz Cad) li‘eanvereg, the clauieal, Litt: *O if ky hub) tr al ws) (and Te me) at * a = i “ Us Us+ oy H = Ut 3k C= 3pNb or Cylimla) = 3% Physice & clear naw! Ay Aone T, eT > ual) far 2ome, ares (cobs) iy< tug) for dame odes > cabs last st@) Fe bz, 3p vances wth 3 act rane ‘pb atoms pining cell alwod ts + Fate) in standad andra Abita 4ochania. course, + thon yi om, or ately amas, Labelled wap ‘the cpullatr co tobe 0 eneng O,1,2,000 * Ground shale nora, Mag =O for als and} (ll ms) Ealy odilalar condriuts its gew-pant onc “GS enenty Up “2d, he) sum cner all, moses Us does nd daptad on Hmptratue T > Us plas ‘m0 wl tv adealating CyKoy, wuts in Staite, menanie gts b x pocsibl, cia fnh U=-2 tne = ap ° Gea The sys of Sp oilers fos possibh etry, f te nts 2} (ng p+ zag) waitin eachs ‘Msg =0, 4, ote BE of sy ey Shap uly Tago “Wy 2 2 etilg 4 Abul) ~ “~~ Sy tance prt rep pin fi . lf) “4 I-@ ~ phil 4 ie qe a hed = x 4 pha) + bap U = ik = Ws Hen peer >]U= WY ‘ a A J er iy, serpent «Hiv ed Wor ‘has om avenge wom tarde ff < " mary deel ort 20 “thew Cy= all ae pon som-@ E, the Einstoum Motel «A inp ‘ppininadion : gon, dll on vation! * Assume, al wirmal, mies carry, hy ms fog lid, We ) = We — (aom-digerie) CNet This do obvinutly, a von era Ayaan ‘err omliatd g)] Syatoo lysomes clacton of ide ola Conmicer NI unit cls wtth 4 atoms in the bas, eave 3N mma mde oe U= Uy + SN_ The efit _4 Heat Copsel, due tie vibmins wtakinskin eli Grit = = fh, " ( lal 4 ree - Einoin =e EO” tt ae we Gjenertiing, ta pal in th cna vm: Cy Loalay) = 3p (is) € “sr Ly (ea i” =3 ph (SJ hdl We fee Hie & ib wd wa Enh teomperalue a ops it un? 30 Cy mor" Ky 0 300 7000 7300 rw ‘The heat capacity of diamond compared to Einstein's theory (1907). The experimental yalues shown are those of Weber (1875) which were used by Einstein when be compared his theory to experiment. C beomes deen Trt, theo that 40, C->0' as T->0!L@ + High T behaviour — kT >>fule Cy > 3K game os clauizal, elt) ( uly, and Poth aw) * LowT behaviour — rec fede o> 3a ou chili 0 abT>0 with @ ™ pehavine (sone physite a jn ‘ane’ Wath boy, ratio, Pribln! em) cf digs tw et at, us , when compe (oth data! ‘Temporanre 09 Moy? Need Arter vrata ues Cie dapusio) Flue nl, ond, dom vibrates fata at siaturbanu! ode ea val! arn