van der Walls

n-heptane
T 350 Tc 540.2
P 10 Pc 27.4

𝑇�= 𝑇/𝑇� �= ∩𝑃�/𝑇� β= 0.0704118874

�=(� �(��) " " )/(∩𝑇�)

P�= 𝑃/𝑃� q= 5.2081453714

Fase Uap
�=1+�−�� ((�−�))/█((�+𝜖�)(�+𝜎�)@)

Iterasi
Z= 1 Z= 0.729518
Z= 0.729518 Z= 0.828708
Z= 0.828708 Z= 0.792333
Z= 0.792333 Z= 0.805672
Z= 0.805672 Z= 0.800781
Z= 0.800781 Z= 0.802574
Z= 0.802574 Z= 0.801917
Z= 0.801917 Z= 0.802158

PR

Pr 0.365
�=[1+(0.37464+1.54226ω−0.26992𝜔^2)(1-
Tr 0.648 〖𝑇�〗 ^(1/2))]^2
1+√2
σ
�^2= 0.1225
ϵ 1-√2 1.54226 X ω= 0.539791
 ψ 0.45724 0.26992 X �^2= 0.033065
α(Tr) 1.373271 〖𝑇�〗^(1/2)= 0.805
Ω 0.0778
R 83.14 α(Tr) = 1.171866 1.3732707 1
ꙍ 0.35 1

q= 12.45682

�= ∩𝑃�/𝑇� b= 0.043824

iterasi

fase uap

�=1+�−�� ((�−�))/█((�+𝜖�)(�+𝜎�)@)

Z= 1 Z= 0.455938 ΔZ = 0.5440617553
Z= 0.455938 Z= 0.211085 ΔZ = 0.2448529505
Z= 0.211085 Z= 0.104937 ΔZ = 0.1061487752
Z= 0.104937 Z= 0.067749 ΔZ = 0.0371877399
Z= 0.067749 Z= 0.065871 ΔZ = 0.0018775927
Z= 0.065871 Z= 0.066397 ΔZ = -0.0005255693
Z= 0.066397 Z= 0.0662 ΔZ = 0.00016
Z= 0.0662 Z= 0.0662 ΔZ = 0.00000
 Pr 0.365 Vv vdW, SRK, PR
Tr 0.648 Vl
σ 0
ϵ 0
𝑉�=�𝑅𝑇/𝑃
ψ 0.4218 Vv = 2334.199
α(Tr) 1
Ω 0.125
𝑉�=�𝑅𝑇/𝑃
R 83.14 Vl = 273.1888
ꙍ 0.35

Fase Liquid
�= �+(Z+𝜖�)(�+𝜎�)((1+�−�)/��)

ΔZ = 0.270482 Z= 0.070412 Z= 0.0839 ΔZ =

ΔZ = -0.09919 Z= 0.0839 Z= 0.0894 ΔZ =
ΔZ = 0.036375 Z= 0.0894 Z= 0.0918 ΔZ =
ΔZ = -0.01334 Z= 0.0918 Z= 0.0929 ΔZ =
ΔZ = 0.005 Z= 0.0929 Z= 0.0934 ΔZ =
ΔZ = -0.002 Z= 0.0934 Z= 0.0937 ΔZ =
ΔZ = 0.001 Z= 0.0937 Z= 0.0938 ΔZ =
ΔZ = 0.000 Z= 0.0938 Z= 0.0938 ΔZ =
Z= 0.0938 Z= 0.0939 ΔZ =
Z= 0.0939 Z= 0.0939 ΔZ =
Z= 0.0939 Z= 0.0939 ΔZ =
Z= 0.0939 Z= 0.0939 ΔZ =
Z= 0.0939 Z= 0.0939 ΔZ =
Z= 0.0939 Z= 0.0939 ΔZ =
Z= 0.0939 Z= 0.0939 ΔZ =
Z= 0.0939 Z= 0.0939 ΔZ =
Z= 0.094 Z= 0.094 ΔZ =

0.37464
1-〖𝑇�〗^(1/2)= 0.195

- 1.4142 -0.4142
+ 1.4142 2.4142

fase liquid

�= �+(Z+𝜖�)(�+𝜎�)((1+�−�)/𝑞�)

Z= 0.043824 Z= 0.082674 ΔZ = -0.03885

Z= 0.082674 Z= 0.120474 ΔZ = -0.0378
Z= 0.120474 Z= 0.157352 ΔZ = -0.03688
Z= 0.157352 Z= 0.193419 ΔZ = -0.03607
Z= 0.193419 Z= 0.228783 ΔZ = -0.03536
Z= 0.228783 Z= 0.26354 ΔZ = -0.03476
 SRK

1.574 ω = 0.5509 Pr 0.365

0.176 �^2 = 0.02156 Tr 0.648
〖𝑇�〗^(1/2) = 0.805 σ 1
0.48 ϵ 0
ψ 0.42748
α(Tr) 1.432381
1 1.00934 0.195 Ω 0.08664
0.196821 R 83.14
1.196821 1.432381 ꙍ 0.35

�=[1+(0.480+1.574ω−0.176𝜔^2)(1- 𝑉�=�𝑅𝑇/𝑃
〖𝑇�〗 ^(1/2))]^2
alfa = 1.432381
𝑉�=�𝑅𝑇/𝑃
q= 10.90793
-0.0135
-0.00543
-0.00241 �= ∩𝑃�/𝑇� b= 0.048804
-0.00111
-0.00052
-0.00025 Fase Uap
-0.00012
�=1+�−�� ((�−�))/█((�+𝜖�)(�+𝜎�)@)
-5.57E-05
-2.65E-05
-1.26E-05
-6E-06 iterasi
-2.86E-06
-1.36E-06 Z= 1 Z= 0.517722 ΔZ = 0.482278
-6.47E-07 Z= 0.517722 Z= 0.775644 ΔZ = -0.25792
-3.08E-07 Z= 0.775644 Z= 0.637525 ΔZ = 0.138119
-1.47E-07 Z= 0.637525 Z= 0.711407 ΔZ = -0.07388
0.000 Z= 0.711407 Z= 0.672 ΔZ = 0.040
Z= 0.672 Z= 0.693 ΔZ = -0.021
Z= 0.693 Z= 0.682 ΔZ = 0.011
Z= 0.682 Z= 0.688 ΔZ = -0.006
Z= 0.688 Z= 0.685 ΔZ = 0.003
Z= 0.685 Z= 0.686 ΔZ = -0.002

Z= 0.686 Z= 0.685 ΔZ = 0.001

Z= 0.685 Z= 0.686 ΔZ = 0.000
Z= 0.043824 Z= 0.082674 ΔZ = -0.03885

0
n-heptane
T 350 Tc 540.2
P 10 Pc 27.4

Vv= 1995.672

Vl= 178.5259

fase liquid

�= �+(Z+𝜖�)(�+𝜎�)((1+�−�)/𝑞�)

iterasi

Z= 0.048804 Z= 0.3923 ΔZ = -0.3435

Z= 0.3923 Z= 0.2622 ΔZ = 0.1301
Z= 0.2622 Z= 0.1693 ΔZ = 0.0929
Z= 0.1693 Z= 0.1098 ΔZ = 0.0595
Z= 0.1098 Z= 0.0795 ΔZ = 0.0303
Z= 0.0795 Z= 0.0674 ΔZ = 0.0121
Z= 0.0674 Z= 0.0632 ΔZ = 0.0041
Z= 0.0632 Z= 0.0619 ΔZ = 0.0013
Z= 0.0619 Z= 0.0615 ΔZ = 0.0004

Z= 0.0615 Z= 0.0614 ΔZ = 0.0001

Z= 0.0614 Z= 0.0614 ΔZ = 0.0000