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p
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ln ξ = dπ 67
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fi◦,L (T, p◦i (T )) = fi◦,V (T, p◦i (T )) = ϕ◦,V


i (T, p◦i (T )) p◦i (T )
 
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p
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ln P ≡
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fiL (T, p, x) ≈ γi (T, x) xi ϕ◦,V


i (T, p◦i (T )) p◦i (T ) P 6!7


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fiL ≈ γi xi ϕ◦i p◦i P 6!7
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p − p◦∀j Vi∞
ln fiL (p) ≈ ln xi + ln Hi (T ) +
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i
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2 2 xA + xB ABA xB + xA AAB
 
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ln γB = − xB ln (xB + xA AAB ) + xA −
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= 
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RT i j

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= 
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j
Λkj xj
k
j

  
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Λij ≡ exp −
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j

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k




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j
+
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Gkj xk G kj xk
k k k

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comb G + ∆res G

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E
∆comb G = RT xi ln + qi xi ln
i
xi 2 i θi
⎡ ⎛ ⎞⎤
∆GE
res
=− ⎣qi xi ln ⎝ τji θj ⎠⎦
RT i j

ln γi = ln γicomb + ln γires
 
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ln γicomb
=1− + ln − qi 1 − + ln
xi xi 2 θi θi
⎡ ⎛ ⎞ ⎤


ki k ⎥
τ θ
ln γires = qi ⎣− ln ⎝ τji θj ⎠ + 1 − ⎦
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j

  
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i

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k

 
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2
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n
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wm Qm
Θm =

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n

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