4.

2 Perhitungan
1. Proses Esterifikasi
a. Minyak jelantah
Volume minyak jelantah = 100 ml
ρ minyak jelantah = 0,0384 gr/ml
BM minyak jelantah = 884 gr/mol
Massa minyak jelantah = V minyak jelantah x ρ minyak jelantah
= 100 ml x 0,0384 gr/ml
= 3,84 gr
𝑚𝑎𝑠𝑠𝑎 𝑚𝑖𝑛𝑦𝑎𝑘 𝑗𝑒𝑙𝑎𝑛𝑡𝑎ℎ
Mol minyak jelantah = 𝐵𝑀 𝑚𝑖𝑛𝑦𝑎𝑘 𝑗𝑒𝑙𝑎𝑛𝑡𝑎
3,84 𝑔𝑟
= 884 𝑔𝑟/𝑚𝑜𝑙

= 0,00434 mol
b. Metanol
mol metanol = 0,039 mol
ρ metanol = 0,032544 gr/ml
BM metanol = 32 gr/mol
Massa metanol = mol metanol x BM metanol
= 0,039 mol x 32 gr/mol
= 1,25 gr x 3
= 3,75 gr
𝑚𝑎𝑠𝑠𝑎 𝑚𝑒𝑡𝑎𝑛𝑜𝑙
Volume metanol = 𝜌 𝑚𝑒𝑡𝑎𝑛𝑜𝑙
3,75 𝑔𝑟
= 0,032544 𝑔𝑟/𝑚𝑙

= 115,24 ml
c. NaoH
Massa NaOH = (massa minyak jelantah + massa metanol) x 0,5 %
= (3,84 gr + 3,75 gr) x 0,5 %
= 0,04 gr
ρ NaOH = 2,2 gr/ml
BM NaOH = 40 gr/mol
𝑚𝑎𝑠𝑠𝑎 𝑁𝑎𝑂𝐻
Volume NaOH = 𝜌 𝑁𝑎𝑂𝐻
 0,04 𝑔𝑟
= 2,2 𝑔𝑟/𝑚𝑙

= 0,018 ml
𝑚 1000
N NaOH = 𝐵𝑀 𝑥 𝑣
0,04 𝑔𝑟 1000
= 40 𝑔𝑟/𝑚𝑜𝑙 𝑥 0,018 𝑚𝑙

= 55,55 N
𝑣 𝑁𝑎𝑂𝐻 𝑥 𝑁 𝑁𝑎𝑂𝐻 𝑥 𝐵𝑀 𝑚𝑖𝑛𝑦𝑎𝑘 𝑗𝑒𝑙𝑎𝑛𝑡𝑎ℎ
% FFA = 𝑥 100%
𝑚𝑎𝑠𝑠𝑎 𝑚𝑖𝑛𝑦𝑎𝑘 𝑗𝑒𝑙𝑎𝑛𝑡𝑎ℎ 𝑥 1000
0,018 𝑚𝑙 𝑥 55,55 𝑁 𝑥 884 𝑔𝑟/𝑚𝑜𝑙
= x 100%
3,84 𝑔𝑟 𝑥 1000

= 23,0185 %
2. Proses Transesterifikasi
a. Metil ester
massa metil ester =(massa metil ester+massa wadah) – (massa wadah)
= 206,8 gr – 115,55 gr
= 91,25 gr
BM metil ester = 298 gr/mol
ρ metil ester = 0,9124 gr/ml
𝑚𝑎𝑠𝑠𝑎 𝑚𝑒𝑡𝑖𝑙 𝑒𝑠𝑡𝑒𝑟
volume metil ester = 𝜌 𝑚𝑒𝑡𝑖𝑙 𝑒𝑠𝑡𝑒𝑟
91,25 𝑔𝑟
= 0,9124 𝑔𝑟/𝑚𝑙

= 100,01 ml
𝑚𝑎𝑠𝑠𝑎 𝑚𝑒𝑡𝑖𝑙 𝑒𝑠𝑡𝑒𝑟
mol metil ester = 𝐵𝑀 𝑚𝑒𝑡𝑖𝑙 𝑒𝑠𝑡𝑒𝑟
91,25 𝑔𝑟
= 298 𝑔𝑟/𝑚𝑜𝑙

= 0,306 mol
b. gliserol
massa gliserol = (massa wadah + gliserol) – (massa wadah)
= 180,61 gr – 127,95 gr
= 52,66 gr
BM gliserol = 92 gr/mol
ρ metil ester = 0,9484 gr/ml
𝑚𝑎𝑠𝑠𝑎 𝑔𝑙𝑖𝑠𝑒𝑟𝑜𝑙
volume gliserol = 𝜌 𝑔𝑙𝑖𝑠𝑒𝑟𝑜𝑙
 52,66 𝑔𝑟
= 0,9484 𝑔𝑟/𝑚𝑙

= 55,52 ml
𝑚𝑎𝑠𝑠𝑎 𝑔𝑙𝑖𝑠𝑒𝑟𝑜𝑙
mol gliserol = 𝐵𝑀 𝑔𝑙𝑖𝑠𝑒𝑟𝑜𝑙
52,66 𝑔𝑟
= 92 𝑔𝑟/𝑚𝑜𝑙

= 0,572 mol
c. metanol
volume metanol = 31 ml
ρ metanol = 0,03254 gr/ml
massa metanol = v metanol x ρ metanol
= 31 ml x 0,03254 gr/ml
= 1,00874 gr
3. Neraca massa
a. Teori
CH2COOR1 NaOH CH2OH
CHCOOR2 + 3 CH3OH 3RCOOCH3 + CHOH
CH2COOR3 CH2OH
Trygliseride Methanol Methyl Ester Glycerol
M : 0,00434 mol 0,039 mol - -
B : 0,0034 mol 0,0102 mol 0,0102 mol 0,0034 mol -
S : - 0,0288 mol 0,0102 mol 0,0034 mol

Tabel 3. Neraca massa teori

No Material Input (gr) Output (gr)
1 Minyak jelantah 3,84
2 Metanol 3,75 0,9216
3 Metil ester 3,0396
4 Gliserol 0,3128
Total 7,59 4,274
b. praktek
CH2COOR1 NaOH CH2OH
CHCOOR2 + 3 CH3OH 3RCOOCH3 + CHOH
CH2COOR3 CH2OH
Trygliseride Methanol Methyl Ester Glycerol
M : 0,00434 mol 0,039 mol - -
B : 0,102 mol 0,306 mol 0,306 mol 0,102 mol -
S : - 0,09766 mol -0,267 mol 0,306 mol 0,102 mol

𝑚𝑜𝑙 𝑚𝑖𝑛𝑦𝑎𝑘 𝑗𝑒𝑙𝑎𝑛𝑡𝑎ℎ 𝑏𝑒𝑟𝑒𝑎𝑘𝑠𝑖

% Konversi = 𝑚𝑜𝑙 𝑚𝑖𝑛𝑦𝑎𝑘 𝑗𝑒𝑙𝑎𝑛𝑡𝑎ℎ 𝑚𝑢𝑙𝑎−𝑚𝑢𝑙𝑎 𝑥 100%
0,0102 𝑚𝑜𝑙
= 0,00343 𝑚𝑜𝑙 𝑥 100%

= 297,376 %
𝑚𝑜𝑙 𝑚𝑒𝑡𝑖𝑙 𝑒𝑠𝑡𝑒𝑟 𝑠𝑒𝑐𝑎𝑟𝑎 𝑝𝑟𝑎𝑘𝑡𝑒𝑘
% Yield = 𝑥 100%
𝑚𝑜𝑙 𝑚𝑒𝑡𝑖𝑙 𝑒𝑠𝑡𝑒𝑟 𝑠𝑒𝑐𝑎𝑟𝑎 𝑡𝑒𝑜𝑟𝑖
0,306 𝑚𝑜𝑙
= 0,0102 𝑚𝑜𝑙 𝑥 100%

= 3000 %
𝑚𝑜𝑙 𝑚𝑒𝑡𝑖𝑙 𝑒𝑠𝑡𝑒𝑟 𝑡𝑒𝑜𝑟𝑖− 𝑚𝑜𝑙 𝑚𝑒𝑡𝑖𝑙 𝑒𝑠𝑡𝑒𝑟 𝑝𝑟𝑎𝑘𝑡𝑒𝑘
% Error == 𝑥 100%
𝑚𝑜𝑙 𝑚𝑒𝑡𝑖𝑙 𝑒𝑠𝑡𝑒𝑟 𝑡𝑒𝑜𝑟𝑖
0,0102 − 0,306 𝑚𝑜𝑙
= 𝑥 100%
0,0102 𝑚𝑜𝑙

= -2900 %