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ı
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M PE K irıe t ic a a n
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t io K in t ic
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łm n s ow naf tio n
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lc u la t e t h e n u c le a t io n a n d
b v io ly n e c e s ea ry to c a
it is
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te s , b u t a n e s t im a n o
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t
b e t a k e n in t o a c c o 1ın
p a r t ic le s
to

tim e t+ A t

f te n d e d h ın ıe T w o
F ig 1 A ıı ilh ıs t r a tio n o f th e co n c e pt o ex v o

n u c le a t e d t o g e th e r d gro w n to a fin it e
p r e c ip it a t e p a r t ic le s h av e a n

d d fo d th e o r ig h ıa l
s iz e in t h e t im e t N e w re g io n s c a n a re rm e as

bu t & b p a r t ic le s o f w h ic h b h a s fo rm e d in
p a r t ic le s g r o w a a re n ew ,
,

h ic h i8 lr e a d y t r a n s fo r m e d
a re g io n w a

T h is i8 d o n e u s in g th e ex te n d e d v o lu m e co n ce p t o f K o lm o go ro v ,
Jo h n so n ,
M eł
ıl

an d A v ra m i R E fe r r in g t o F ig 1, su pp o se t h a t tw o p a r tic le s e x is t a t t iJa ıe t ; a s n ıa ll

in be r v a ıðt la te r , n ew regioï a r lo ĵ
n ı d a ,
b, c & d m e fo r m e d a ssu m in g t h a t t h e y are

a b le to g r o w u n r e s t ń c te d in ex te n d e d s p a c e w h e th e r or n o t th e re g io n in to w h ic h t h e y

gro w r e a d y t r a n s fo
iß a ı rm e d H o w ev er ,
on ly t h o s e co m p o n en ts o f a ,
b, c & d w ric h lie
ł

in p r e v io u s ly u n tr a n s fo r m e d m a t r ix c an co n t r ib u t e t o a ch a n g e in t h e rea l v o lu m e o f

th e p r o d u c t p h a s e (a )
dv °
_ 1
)W ' ı
(1 )
w h e r e it is d th a t th e ic r o s t r u c t u d e v e lo p s
as eu m e m re a t ra n do m T he su b s c r ip t e r e fe r s

to e x te n d e d lu V i8 t h e v o lu m fa
°
v o m e , e o an d V i8 t h e t o t a l v o lu m e M u lt ip ly in g t h e

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ded v o lu m e b y t h e p r o b a b ility f fin d in g tr a n a fo r m e d g io h as
c ln a n g e in ex te n o u n re tH

th e e fĺ e c t o f e x c lu d in g r e g io n a s u c h a s b, w h ic h c le a r ly c a n n o t c o n t r ib u te t o th e re a l

cha n g e h ı v o lm e o f th e p m d u c t F o r a ra n do m d ißb r lb u t io n o f p r e c ip i加 加 d p a r t ic le s ,

t h is e q u a tio n c a n e a s ily b e in te g r a te d to o b 加 加 th e re a l v o lu m e fr a c tio n ,

T he ex te n d e d v o lu ı
ııe W i8 s tr a ig h t fo rw a rd to c a lc u la te u s in g n u c le a t io n d
a ıı

g r o w th n ıo d e ls an d n e g le c t in g co m p le te ly y
a iı im p in g e m en t e fte c te Co n s id e r a e im p】
e

h e r e th e te G d h e r e th e n u c le a t io
case w a g r o ï s ia o t r o p ic a lly a t a c o n s ta n t ra an w n

ra t e p e r rın it vo ı
m e Iv T he v o lu m e o f a p a r tic le n u c le a te d a t tim e t = . (F ig 2 ) i8
,

g iv e n b y
4 3 3
11
.
- rr G (t T )
3

T he c h a n g e h ı e x te n d e d v o lı
ın ıe o v er th e in t e r v a l T d
a iı T + d T i8

4 3
? ? = rr G (t T )3 x Iv x V × dr
3

O n su b s t it u t in B in t o e q ııa t io n 1 an d w r itin g Ę = V -
/V ,
w e ge t

dv °
_ 1
): . G 3
(i T )3 ıW dr

4 3
t
(2 )
8o th a t 1끄 {1 Ę} = ?r G IV (t T )3 dr
3
3 4
an d Ę = 1 ex p { rr G ı
y
t /3 }

F ig 2 : A ıı illu s t r a t io n o f th e in cu b a t io n tim e T fo r ea ch p a r t ic le

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T h is equ a tio n h a s b e e n d e r iv e d fo r t h e e p e c ific a ßa u m p t io n e o f rm d o m n u c le a t io n ,

a co n s ta n t n u cı
ea t io ır a
ı te an d s ta n
a c o ïı t gr o w th ra be T h e re m e d iße r e ııt p a e e ib ilit ie 8

b u l th e y o % en redu ce t o th o g e n e r a l fo rm

Ę= 1 ex p { k. t
"
} (3 )

w h e ıe k A an d Tı c h a r a c t e r la e t h e r e u % io n 88 a flın c t io n o f t im e ,
te ıııp e r a t u re a n d o th e r

ia b le s T he va ı f kA d n can be o b 加 加 e d fr o m ex p e r im m l a l d a t a b y p b t tiııg
w u es o a ıı

f kA d de pen d th e tlır e o f
In ( ln {1 Ę}) v e r s u s In {t} T h e s p e c ific v a lu e s o an n o n n a

C le a r ly , n u c le a t io d g r o w th r a te ı
e a d s to a t iı?
n u c le a t io n a n d g r o w th a c o n s ta n t n an

ll b e g in g r o w t h in s t a n t a n s ly
ex po n en t n - 4 , b u t if it i8 assu m e d th a t t h e p a r tic le s a e o rı

i8 t d e d ) th e 3 w h e iı
fr o m a óx e d u n
n ı b e r d e n s ity o f s it e s (ź e N u c ]e a tio n n o n ee n -

T here th e r s c e n a r io s a n d th e v a lu e s o f th e A r a m i
t h e g r o w th ra te i8 c o n s ta ı
ıt a re o

th a t th e B a r n e p o n en t can
Paramers a re n o t n e c e ssar ily u n am b ig u o u s h ı th e se n se ex

re p r e s e n t tw o d if[e r e n t m ec h a n is m s

T h e fo f e q u a t io 3 is illu s t r a t e d in F ig 3 N o t e th a t t h e e «ec t o f te m p e r »
rm o n

lte r t h e t h e r m dy n ic d r iv in g fo fo r t r a n s fo t io n t o a lt e r d ißh ıs io n
t u r e is t o a o am rce rm a ,

th e r ţ h e r m a J1y ţ iv te d p r o T he e E ec t o f
co e ffic ie n t s , a n d to in flu en ce a n y o ? a c e ss e s

n ese is v ia its in flu en ce on th e s ta b ility o f th e p a r e n t a n d p ro d u ct p has es


m a n ga







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T im e / s

F ig 3 T he c a tc u la t e d in a l\e n ce o f (a ) tr a n B fo r m a t io n t e m p e r a tu r e

a n d (b ) m a n g a n e s e co n ce n tr a tio n o n th e k in e t ic e o f th e b a in ite re a c

p a r t ic u la k in d f lid s ta te p lıa e e
t io n (S in g h 1 9 9 8 )
,
B a lı
ılte i8 & r o ao

tr a n e fo r m a t io n th a t o c c u rs ln s te e le

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