PART A — PHYSICS ALL THE GRAPHS/DIAGRAMS GIVEN ARE SCHEMATIC AND NOT DRAWN TO SCALE. 1. The density of a material in the shape of a cube is determined by measuring three sides of the cube and its mass. If the relative erross in measuring the mass and 1.5% and 1'%, the maximum error in determining thediensity length are respective a @) 35% Br 45% (4) 6% 2. All the graphs below are intended to represent the same motion. One of them dows i incorrectly. Pick it up velocity ty) renin i distance Ae 5 @ e+ time e aa. Cy FS stime velocity 4 cH | time N Two masses m,=5 kg and m,=10 kg, connected by an inextensible string over a frictionless pulley, are moving as shown in the figure. The coefficient of friction of horizontal surface is 0.15. The minimum weight m that should be put on top of my to stop the motion is : flor my Tv 7 ¥mg Q) 183 kg BW kg @B) 433 kg (4) 103 kg A particle is moving in a circular path of radius a under the action of an attractive potential U=— a Its total energy is A/Page 2 SPACE FOR ROUGH WORK5. Ina collinear collision, a particle with an initial speed 0, strikes a stationary particle of the same mass. If the final total kinetic energy is 50% greater than the original kinetic energy, the magnitude of the relative velocity between the two particles, after collision. is, a) 1 . QQ) Vin, (3) © % 6. Seven identical circular pianar disks, each of mass M and radius R are welded symmetrically as shown. The moment of inertia of the arrangement about the axis normal to the plane and passing through the point P is: 8. From a uniform circular disc of radius R R and mass 9 M, a small disc of radius > is The moment of inertia of the remaining disc removed as shown in the figure. about an axis perpendicular to the plane of the disc and passing through centre of disciss (A) a s > ‘te * Say, o/ 7 / aya Me Ay 9 Ny 2 Or? Yt ) (3) 10 MR? A particle is mowing with a uniform speed in a circular orbit of radius R in a central force inversely proportional to the ntl Power of R. If the period of rotation of the particle is T, then : (2) T2R*/? for any n, @ Tart © TxRMene (4) TxRe/? SPACE FOR ROUGH WORK9. A solid sphere of radius r made of a soft material of bulk modulus K is surrounded by a liquid in a cylindrical container. A massless piston of area a floats on the surface of the liquid, covering entire cross section of cylindrical container, When a mass m is placed on the surface of the piston to compress the liquid, the fractional decrement in the radius of the sphere, (*) is: (Fh ka One Ka @ img @ 7s w 2 10. Two moles of an ideal monoatomic gas occupies a volume V at 27°C. The gas expands adiabatically to a volume 2 V. Caloulate (a) the final temperature of the ges and (b) change in its internal energy. @) WOK &) 27K @) (@) WK ) -27k @) (a) 189K (b) 2.7 ky @ @ 195K &) 27H 1. 12. 13, The mass of a hydrogen molecule is 3.32x10727 kg. If 102 hydrogen molecules strike, per second, a fixed wall of area 2 cm? at an angle of 45° to the normal, and rebound elastically with a speed of 10° m/s, then the pressure on the wall is nearly (1) 235x108 N/m? (2) 4.70% 10? N/m? (3) 2.3510? N/m? (4) 4.70102 N/m? A silver atom in a solid oscillates in simple harmonic motion in some direction with a frequency of 10!2/sec, What is the force constant of the bonds connecting one atom with the other ? (Mole wt. of silver = 108 and Avagadro number ~6.02 10 gm mole~}) Q) 64.N/m Q) 7a N/m @) 22N/m (4) 55.N/m A granite rod of 60 cm length is clamped at its middle point and is set into longitudinal vibrations. The density of granite is 2.7 x 10 ky/m? and its Young’s modulus is 9.27% 10! Pa, What will be the fundamental frequency of the longitudinal vibrations ? (1) SkHe (2) 25 kHz @) 10K (4) 75 KHz SPACE FOR ROUGH WORK14, Three concentric metal shells A, B and C of respective radii a, b and ¢ (a ‘A/Page 8 SPACE FOR ROUGH WORKWhich of the following lines correctly show the temperature dependence of equilibrium constant, K, for an exothermic reaction ? @) Band @) Cand D 7A and D “The combustion of benzene (1) gives CO,(@) and H,0(1). Given that heat of combustion of benzene at constant volume is 3263.9 kJ mol 1 at 25° C; heat of combustion (in kJ mol”) of benzene at constant pressure will be : 314 TK>! mol) 4152.6 (2) - 452.46 8) 3260 (3267.6 A/Page 9 For 1 molal aqueous solution of the following compounds, which one will show the highest freezing point ? @) [Co(H1,0),]Cly (2) [Co(H,O).CIC],.H;O 8) [Co(H,O),CL,|C1. 24,0 {D> [Co0,0),C1,].311,0 An aqueous solution contains 0.10 MHS and 0.20 M HCl. If the equilibrium, constants for the formation of HS~ from. HS is 1.01077 and that of S2~ from HS~ ions is 1.210713 then the concentration of $?~ ions in aqueous solution is : (@) 5x 10-8 (2) 319720 (3) 6x 1072 () 5x10-"% An aqueous solution contains an unknown, concentration of Ba?*. When 50 ml. of a 1 M solution of NajSO, is added, BaSO, just begins to precipitate. The final volume 1s 500 mL. The solubility product of BaSO,, is 110-12, What is the original concentration of Ba?* ? () 5x10-°M @ 2x10-°M @) 11x1078 M (4) 10%10-19 M SPACE FOR ROUGH WORK39, At518° C, the rate of decomposition of a } sample of gaseous acetaldehyde, initially was 1.00 Torr 5-1 when 3% had reacted and 05 Torr s~1 when 33% had reacted. ‘The order of the reaction is : at a pressure of 363° Torr, a) 2 ye) 3 ome 2 “oo . “A 40. How long (approximate) should water be electrolysed by passing through 100 amperes current so that the oxygen released can completely burn 27.66 g of diborane ? (Atomic weight of B=108 u) Y 64 hours 2) 08 hours (@) 32 hours (1.6 hours 41. The recommended concentration of fluoride ion in drinking water is up to 1 ppm as fluoride ion is required to make teeth enamel harder by converting [3Ca,(PO,).*Ca(OH),] to = @) (Cak,] @) (CaF) Ca(OH] @) BCaPO)eCaFy] (2) [BICa(OH),)-CaF,] 42. Which of the following compounds contain(s) no covalent bond(s) ? KCL, PHy, 02, BsHy H3S0, Q) KCL BH, PHy Q) KCL H.SO, @) KCl (KCL BH, 43. Which of the following are Lewis acids ? (1) PH, and BCL, @) AICL, and Sil, PH, and SiC [G97 PH and sict, @) BC), and AICI, 44, Total number of lone pair of electrons in Ig tonis : am 3 @ 6 @ 9 (4) 12 45. Which of the following salts is the most basic in aqueous solution ? () ANCN); (@) CHYCOOK @) FeCly (4) Pb(CH,COO), A/Page 10 SPACE FOR ROUGH WORK46. Hydrogen peroxide oxidises [Fe(CN),]*~ to [Fe(CN),[°~ in acidic medium but reduces [Fo(CN),J>~ to [Fe(CN)g*7 in alkaline medium. The other products formed are, respectively : (1) (H,0+0,) and H,0 2) (H,O+0,) and (H,O+OH (3) HO and (11,0+0,) HO and (H,O+OH~) 47. The oxidation states of Cr in [Cr(H,O),]Cly, [Cr(CgH,) 9], and Ka{Cr(CN),(O)4(02)(NH)] respectively are : wT, +4, and +6 +3, +2and +4 @) +3, 0, and +6 @ +3,0,and 14 48. The compound that does not produce nitrogen gas by the thermal decomposition is (1) Ba(Ny)o Q@) (NHy)Cr,0, (3) NH,NO, (4) (NH,),S0, A/Page 11 49. When metal 'M’ is treated with NaOH, a white gelatinous precipitate 'X’ is obtained, which is soluble in excess of NaOH. Compound ’X’ when heated strongly gives an oxide which is used in chromatography as an adsorbent, ‘The metal ‘M! is : Q) Zn 2) Ca @) Al _ or Fe 30. Consider the following reaction and statements [Co(NE) Brg} + Br-—[Co(NH,),Bry] + NH () Two isomers are produced if the reactant complex ion isa cis-isomer. (Il) Two isomers are produced if the reactant complex ton is a frans- isomer. (11) Only one isomer is produced if the a truns- reactant complex ion is isomer (IY) Only one isomer is produced if the reactant complex ion is a cis-isomer. ‘The correct statements are : @) Mandan (2) @ and (itl) (2) dl) ana avy (3) and ayy SPACE FOR ROUGH WORK51. Glucose on prolonged heating with HI gives (U7 n-Hexane (2) -Hexene @) Hexanoic acid ® 6-iodohexanal 52. The trans-alkenes are formed by the reduction of alkynes with (1) Hy PA/C, BaSO, 2) NaBH, @)Na/lig. Ny of s-ncl 53. Which of the following compounds will be suitable for Kjeldahl’s method for nitrogen estimation ? a CO 2) ~ No, NH Phenol on treatment with CO, in the presence of NaOH followed by acidification produces compound X as the major product. X on treatment with (CH,CO},0 in the presence of catalytic amount of H,SO, produces "o 2) CO On_ABs x ® On Gone w LO ‘CoH ON CEs T oO A/Page 12 SPACE FOR ROUGH WORK55. An alkali is titrated against an acid with methyl orange as indicator, which of the following is a correct combination ? Base Acid_—_End point Colourless to pink () Weak — Strong, (2) Strong, Strong Pinkish fed to yellow (3) Weak Strong Yellow to pinkish red (4) Strong Strong Pink to colourless 56. The predominant form of histamine present in human blood is (PKy, Histidine ~ 6.0) ‘ . a N e Ne @ ies ne ni ul re) @) be SNH ni “ Va ‘A/ Page 13 57. 58. Phenol reacts with methyl chloroformate in the presence of NaOH to form product A, A reacts with Br, to form product B. ‘Aand B are respectively Lon BL a a ore gs © ‘ ° Ne o CJ c a re TE oanen oc wo SAY AN v re The increasing order of basicity of the following compounds is (a) Aw oO NAN o NH @ “Snir WM @ Vand 2) vx —3|+ Vx (Vz —6)+6=0}. Then S (1) isanempty set (2) contains exactly one element (3) contains exactly two elements. (4) contains exactly four clements. 63. Ifa, fe C are the distinct roots, of the equation x2=x+1=0, then al? +B1"? is equal to : ont 2 0 Qt wm 2 fra 2x2 64. LE) 2x x4 2x] =(A+ Bx) — Ay’, 2x 2x ad then the ordered pair (A, B) is equal to : () (4-5) Q (-43) (-49) a 5) 65. If the system of linear equations xtky+32=0 Brtky-22=0 2rtay—32=0 has a non-zero solution (x, y, 2), then 7 is equal to: a) -10 2) 10 (3) —30 «30 66. From 6 different novels and 3 different dictionaries, 4 novels and 1 dictionary are to be selected and arranged in a row ona shelf so that the dictionary is always in the middle, The number of such arrangements is = (1) at least 1000 (2) toss than 500) (3) _at least 500 but less than 750 is} least 750 but less than 1000 67. The sum of the co-efficients of all oda degree terms in the expansion of (x Vea) + (e-V8 =a) is: qao-t Q 0 QB 4 (4) 2 A/Page 15 SPACE FOR ROUGH WORK75. Thevatucot f° ax i t+ @ ¢ @ F a 3) ) @ 5 76. Let glx)=cos x2, f(xy= VF, and B (@ < B) be the roots of the quadratic equation 18x2—9nx+n2—0, Then the area (in sq, units) bounded by the curve y= (gof)() and the lines y=«, x= and m ia~1) 2 @) S(v2~4) 78. 79. Let y-y(x) be the solution of the differential equation sinc 4 yooer er ce (0). 0, then yf =) is equal to: 6) @ dpe @ ® (4) A straight line through a fixed point (2, 3) intersects the covrdinate axes at distinct Points P and Q. If © is the origin and the rectangle OPRQ is completed, then the locus of Ris : () art2y=6 @Q) av+3y=ay (G) Sx 42y=xy (4) 3x 42y=6xy Let the orthocentre and centroid of a triangle be A(=3, 5) and BG, 3) respectively, If C is the circumcentre of this triangle, then the radius of the circle having line segment AC as diameter, is : ay vio @ wid - 3) (a) A/Page 17 SPACE FOR ROUGH WORK -68. Let ay, ay ay... ayy be in ALP. such that a2 D aie S416 and ag tayy=66. TF af + ad +... 02, < 140m, then mis equal to () 66 2) 68 72 If the curves y?=6x, 922+ by2=1 intersect each other at right angles, the: the value of b is : @ 6 Zz @ 3 @ 4 69. Let A be the sum of the first 20 terms and | 73, B be the sum of the first 40 terms of the series xeR-(~1,0, 1}. 1 h(x) = £2), then th 142274324242 45242624... BQ) If B-24 = 100d, then A is equal to local painimum value of h(2) is : (1) 232 we 248 2) -=3 G8) 464 @) -2y5 ) 496 @ a2 70. Foreach te R, let [t] be the greatest integer Jess than or equal to t. Then 74. The integral 17 rs} in? cos? Jinn af) 2] 4/274 - 1/8) fk sin cos" dx roe Na) * Le bx (sin’x+cos*r sin? 14 sin xcos"x+ cos x)? (2) is equal to 0, is equal to : 2) is equal to 15, () is equal to 120. a (4) does not exist (in R). FAL Let S={te R: Fee)=[x—n}-(@"—1) sini @ is not differentiable at t}. Then the set Sis equal to @ (2) 6 (anempty set) @) (0) @ sc moth @) tr) T 4 cot ) 0, a) (where C is a constant of integration) A/Page 16 SPACE FOR ROUGH WORKgo, If the tangent at (1, 7) to the curve | 83. TfL p sthe}ime of intersection of the planes ye=y-6 touches the circle dy -2y+32-2=0, roytz+1=0 and 24 y+ ox + 12y+c=0 then the value of {pis Ue line of intersection of the planes cis ae2y—2-3=0, 3x-yt 2210, then a 198 the distance of the origin from the plane, containing the lines Ly and Ly is (@ 185 6) 85 “ «95 2) °) 81, Tangent and normal are drawn at P(16, 16) on the parabola y= 16x, which w intersect the axis of the parabola at A and B, respectively If C is the centre of he | gq. The length of the projection of the Hint Gacle through the points P, A and B and : Bo aa then g value of tn 8 is segment joining the points 6, 1, 4) and " (4, -1,3) om the plane, x+y t2=7 18: 1 2 Ms oO ow 2) 2 2 ‘ QF @ 3 : @ 4 4 @ F fz @ 82, Tangents are drawn to the hyperbola ~ : 85, Let y bea vector coplanar with the vert 4,2 yP=3o at the points Pand Q If these ae ae span “ee we tangents intersect al the point 7(0, 3) then geatsaj-fandb=j+k. wu the area (in sq. units) of APTQ is = 40 “t is perpendicular to @ and wb — 24 () 45N5 2 5 tren? equal: @) sN3 @) 396 (@) 603 @ 3 (@) 256 (@) 365 @ 84 ‘A/Page 18 SPACE FOR ROUGH WORK86. A bag contains 4 red and 6 black balls. A ball is drawn at random from the bag, its colour is observed and this ball along with two additional balls of the same colour are returned to the bag. If now a ball is drawn at random from the bag, then the probability that this drawn ball is red, is : 1 (3) 5 3 wf ° ° 87. If 0, -5)=9 and Dea, ~ 5)? =45, a a then the standard deviation of the 9 items 88. If sum of all the solutions of the equation "9 in [0, n] is kz, then k is equal to: eons | cos) F + x}cos(Z a 3 a 2 @ ¢ w 2 89. a triangular park with 00 m. A TY. tower stands at the mid-point of QR. If the angles of elevation of the top of the tower at P,Q and R are respectively 45°, 30° and 30°, then the height of the tower (in m) is : (100 @) 50 3) 1003 @) s0y2 A ta wy is 90. The Boolean expression ay 6 ~PYQ¥ ~ pag) is equivalent to: () =p 2) 4 2) p ara @) 2 bo m3 -o0o- SPACE FOR ROUGH WORK Sos A A/Page 19 - a