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wide distribution of barrier heights ⌬E and hence of relax- We now make the basic assumption that during sliding the
ation times , and the transition from the rubbery region to whole rubber interfacial surface area moves forwards accord-
the glassy region is very wide, typically extending over three ing to ⫺r(t), i.e., we assume that no Schallamach wave
orders of magnitude in frequency. propagation or local interfacial stick-slip motion 共where dif-
ferent interfacial areas slip at different times兲 occurs 共see
II. SLIDING FRICTION Ref. 20兲. At this point it is convenient to introduce a coordi-
nate system with the xy plane fixed in the 共undeformed兲
This section is based on the formalism developed in Ref. bottom surface of the rubber block, and consider the sub-
5. Using the theory of elasticity 共assuming an isotropic elas- strate as moving with the velocity ṙ(t). We first assume that
tic medium for simplicity兲, one can calculate the displace- the rubber block is in complete contact with the substrate
ment field u i on the surface z⫽0 in response to the surface during sliding. Thus, the rubber block surface displacement
stress distributions i ⫽ 3i . Let us define the Fourier trans- field induced by the substrate roughness is
forms
冕
1 u共 x,t 兲 ⫽u关 x⫺r共 t 兲兴 ,
u i 共 q, 兲 ⫽ d 2 x dt u i 共 x,t 兲 e ⫺i(q•x⫺ t) ,
共 2 兲3
where r(t)⫽x(t)x̂ and
u i 共 x,t 兲 ⫽ 冕 d 2 qd u i 共 q, 兲 e i(q•x⫺ t) ,
u共 q, 兲 ⫽
1
共 2 兲3
冕 d 2 xdt u关 x⫺r共 t 兲兴 e ⫺i(q•x⫺ t)
and similar for i (q, ). Here x⫽(x,y) and q⫽(q x ,q y ) are
two-dimensional vectors. We have5
⫽
1
共 2 兲3
冕 d 2 xdt u共 x兲 e ⫺i 兵 q•[x⫹r(t)]⫺ t 其
u i 共 q, 兲 ⫽M i j 共 q, 兲 j 共 q, 兲
⫽u共 q兲 f 共 q, 兲 , 共3兲
or, in matrix form,
where
u共 q, 兲 ⫽M 共 q, 兲 共 q, 兲 ,
where the matrix M is given in Ref. 5.
We now assume that the surface stress (q, ) only acts
u共 q兲 ⫽
1
共 2 兲2
冕 d 2 x u共 x兲 e ⫺iq•x
in the z direction 共see below兲 so that
and
u z 共 q, 兲 ⫽M zz 共 q, 兲 z 共 q, 兲 . 共1兲
Since ⬃ v q 共where v is a typical sliding velocity兲 we get
/c T q⬃ v /c T Ⰶ1 in most cases of practical interest. Thus,
f 共 q, 兲 ⫽
1
2
冕 dt e ⫺i[q•r(t)⫺ t] . 共4兲
冕 冓 冔
are obtained independently of whether one assumes that the
interfacial stress or displacement vector are perpendicular to 1
the nominal contact surface. In reality, neither of these two f 共 t 兲 ⫽⫺ d 2x u共 x,t 兲 • 共 x,t 兲 . 共7兲
A0 x
assumptions holds strictly, but the result above indicates that
the theory is not sensitive to this approximation. Using Eqs. 共1兲 and 共7兲 gives
134106-2
THEORY OF RUBBER FRICTION: NONSTATIONARY SLIDING PHYSICAL REVIEW B 65 134106
f 共 t 兲⫽
共 2 兲2
A0
冕 d 2 qd d ⬘ 共 ⫺iq x 兲 e ⫺i( ⫹ ⬘ )t 冕 d ⬘ f 共 ⫺q, ⬘ 兲
E共 ⬘兲
2 共 1⫺ 2 兲
e ⫺i ⬘ t
⫻ 具 u共 q, 兲 • 共 ⫺q,⫺ ⬘ 兲 典
⬇
共 2 兲2
冕 d qd d ⬘ 共 ⫺iq x 兲 e
2 ⫺i( ⫹ ⬘ )t
⫽
1
2
冕 dt ⬘ e iq•r(t ⬘ )
E 共 t⫺t ⬘ 兲
2 共 1⫺ 2 兲
. 共15兲
A0
Using these equations, Eq. 共13兲 gives
⫻ 共 M zz 兲 ⫺1 共 ⫺q, ⬘ 兲 具 u z 共 q, 兲 u z 共 ⫺q,⫺ ⬘ 兲 典 .
共8兲 f 共 t 兲⫽
1
2
冕 d 2 q q 2 cos C 共 q 兲
Substituting Eqs. 共3兲 in 共8兲 gives
f 共 t 兲⫽
共 2 兲2
冕 d qd d ⬘ 共 ⫺iq x 兲 e
2 ⫺i( ⫹ ⬘ )t
⫻ 冕 dt ⬘ e ⫺iq•[r(t)⫺r(t ⬘ )]
iE 共 t⫺t ⬘ 兲
2 共 1⫺ 2 兲
. 共16兲
A0
If we define
⫻共 M zz 兲⫺1 共⫺q, ⬘ 兲 f 共 q, 兲 f 共 ⫺q, ⬘ 兲 具 u z 共 q兲 u z 共 ⫺q兲 典 .
冕
follow the substrate surface profile and that 兩 ⵜh(x) 兩 Ⰶ1. 1
Thus we can approximate u z ⬇h(x). Using Eq. 共9兲 gives f 共 t 兲⫽ 0 d 2 q q 2 cos C 共 q 兲 Im F 共 q,t 兲 . 共18兲
2
f 共 t 兲⫽
共 2 兲2
A0
冕 d 2 qd d ⬘ 共 ⫺iq x 兲 e ⫺i( ⫹ ⬘ )t The friction coefficient can be obtained by dividing the
frictional shear stress 共18兲 with the pressure 0 :
⫻ 共 M zz 兲 ⫺1 共 ⫺q, ⬘ 兲 f 共 q, 兲 f 共 ⫺q, ⬘ 兲 具 h 共 q兲 h 共 ⫺q兲 典 ,
具 h 共 q兲 h 共 ⫺q兲 典 ⫽
A0
共 2 兲4
冕 d 2 x 具 h 共 x兲 h 共 0兲 典 e ⫺iq•x
In Eq. 共19兲 we have introduced an additional factor P(q,t),
defined as the fraction of the original macrocontact area
where contact remains when we study the contact area on the
A0 length scale ⫽2 /q 共see below兲. In principle, depends
⬅ C共 q 兲, 共11兲 on frequency but the factor 1/(1⫺ 2 ) varies from 4/3
共 2 兲2
⬇1.33 for ⫽0.5 共rubbery region兲 to ⬇1.19 for ⫽0.4
since 具 h(x)h(x⬘ ) 典 depends only on the difference x⫺x⬘ . The 共glassy region兲 and we can neglect the weak dependence on
spectral density C(q) is defined by frequency.
Since C(q) and P(q,t) only depend on the magnitude of
C共 q 兲⫽
1
共 2 兲2
冕 d 2 x 具 h 共 x兲 h 共 0兲 典 e ⫺iq•x. 共12兲
q, from Eq. 共19兲,
f 共 t 兲⫽ 冕 d 2 q q 2 cos C 共 q 兲 冕 d d ⬘ e ⫺i( ⫹ ⬘ )t f 共 q, 兲
Note that the factor cos in the integrand vanishes when
共20兲
134106-3
B. N. J. PERSSON AND A. I. VOLOKITIN PHYSICAL REVIEW B 65 134106
具 z2 共 t 兲 典 ⫽
共 2 兲2
A0
冕 d 2 qd d ⬘ e ⫺i( ⫹ ⬘ )t 具 z 共 q, 兲 z 共 ⫺q, ⬘ 兲 典
⫽ 冕 d 2 qd d ⬘ e ⫺i( ⫹ ⬘ )t M zz
⫺1 ⫺1
共 q, 兲 M zz 共 ⫺q, ⬘ 兲 C 共 q 兲 f 共 q, 兲 f 共 ⫺q, ⬘ 兲
⫽
1
4
冕 d 2 qd d ⬘ q 2 e ⫺i( ⫹ ⬘ )t
E共 兲 E共 ⬘兲
1⫺ 2 1⫺ 2
C 共 q 兲 f 共 q, 兲 f 共 ⫺q, ⬘ 兲
冕 冏 冕 冏
2
1 1 E 共 t⫺t ⬘ 兲
⫽ d 2q q 2C共 q 兲 dt ⬘ e iq•r(t ⬘ )
4 2 1⫺ 2
1
⫽ 20
4
冕 dq q 3 C 共 q 兲 冕 d 兩 F 共 q,t 兲 兩 2 . 共23兲
G 共 q,t 兲 ⫽
1
冕 q
dq q 3 C 共 q 兲 冕 d 兩 F 共 q,t 兲 兩 2 . 共24兲
so that
冕
8 qL 1 E 共 t⫺t ⬘ 兲
F 共 q,t 兲 ⫽⫺ dt ⬘ e ⫺iq•ṙ(t)(t⫺t ⬘ ) . 共30兲
2 0 共 1⫺ 2 兲
Let us summarize the basic results obtained above. The
friction coefficient (t) for a flat rubber surface sliding on a Substituting this in Eqs. 共25兲–共27兲 gives (t)⫽ k 关 ẋ(t) 兴 ,
nominally flat substrate in the most general case is given by i.e., the friction coefficient depends only on the instantaneous
sliding velocity. The necessary condition for the validity of
共 t 兲⫽
1
2
冕 dq q 3 C 共 q 兲 P 共 q,t 兲 冕 d cos Im F 共 q,t 兲 ,
the expansion 共29兲 in Eq. 共28兲 is that
q 兩 ẍ 共 t 兲 兩 共 * 兲 2 Ⰶ1, 共31兲
共25兲
where * is the memory time of the kernel E(t) 关see Eq.
where the 共normalized兲 area of contact A()/A 0 , on the 共38a兲兴.
length scale ⫽2 /q, is given by We consider now the limit 0 ⰆE( ⫽0), which is satis-
fied in most applications. In this case, for most q values of
P 共 q,t 兲 ⫽
2
冕 0
⬁
dx
sin x
x
exp关 ⫺x 2 G 共 q,t 兲兴 , 共26兲
interest, G(q,t)Ⰷ1, so that only xⰆ1 will contribute to the
integral in Eq. 共26兲, we can approximate sin x⬇x, and
G 共 q,t 兲 ⫽
1
冕 q
dq q C 共 q 兲
3
冕 d 兩 F 共 q,t 兲 兩 .
2
共27兲
P 共 q,t 兲 ⬇
2
冕
0
⬁
dx exp关 ⫺x 2 G 共 q,t 兲兴 ⫽ 关 G 共 q,t 兲兴 ⫺1/2.
8 qL 共32兲
In the equations above Thus, within this approximation, using Eqs. 共27兲 and 共32兲 we
get P(q,t)⬀ 0 so that is independent of the nominal
冕
1 E 共 t⫺t ⬘ 兲 stress 0 . Similarly, note that if we scale E( )→ ␣ E( ),
F 共 q,t 兲 ⫽⫺ dt ⬘ e ⫺iq•[r(t)⫺r(t ⬘ )] . 共28兲 then from Eqs. 共27兲 and 共32兲, P(q,t)⬀1/␣ , so that de-
2 0 共 1⫺ 2 兲 pends only on the frequency variation of the complex elastic
modulus, but not on its magnitude. For tires, the condition
Note that if E(t) changes slowly with t, then in Eq. 共28兲 we 0 ⰆE( ⫽0) is usually satisfied. Consequently, on a dry
can expand road track one expects the same friction for wide and narrow
134106-4
THEORY OF RUBBER FRICTION: NONSTATIONARY SLIDING PHYSICAL REVIEW B 65 134106
共 t 兲⫽
H
共 q h 兲2
4 0 0
冕 1
q 1 /q 0
d 1⫺2H P 共 ,t 兲
G 共 q,t 兲 ⫽
H
共 q h 兲2
16 0 0
冕 1
q 1 /q 0
d 1⫺2H 冕 d 兩 F 共 q,t 兲 兩 2 .
共36兲
Note that since, to a good approximation, P(q,t)
FIG. 1. 共a兲 Rheological model corresponding to Eq. 共37兲. 共b兲
⬃ 关 G(q,t) 兴 ⫺1/2, it follows that P⬃1/q 0 h 0 , and thus The complex elastic modulus E( ) as a function of frequency. The
⬃q 0 h 0 . logarithm has 10 as the basis. E 1 ⫽109 N/m2 and a⫽1000.
冕
III. NUMERICAL RESULTS 1
dt ⬘ E 共 t⫺t ⬘ 兲 e ⫺iq x [x(t)⫺x(t ⬘ )]
2
As an example, assume that E is given by the model
shown in Fig. 1共a兲. This model is, in fact, not a good descrip-
tion of real rubbers, since the transition with increasing fre-
quency from the rubbery region to the glassy region is too
⫽E 1 1⫺ 冋 冕 a
t
⫺⬁
册
dt ⬘ e ⫺(1⫹a)(t⫺t ⬘ )/ e ⫺iq x [x(t)⫺x(t ⬘ )] .
冉
E(0)⫽E 1 /(1⫹a) so that E(⬁)/E(0)⫽1⫹a. Since typi-
cally E(⬁)/E(0)⬇1000 we take a⫽1000 in all numerical a 1 共 ⫺t 兲
F⫽⫺ E 1 1⫹ ⫺
calculations presented below. We assume E 1 Ⰷ 0 , in which 1⫹a a 1⫹iq x v 0
冋 册冊
case (t) is independent of E 1 and 0 . Note that
e ⫺t⫺iq x v 1 t 1⫺e ⫺t⫺iq x v 1 t
E共 t 兲⫽ 冕 d e ⫺i t
冋 a
E 共 兲 ⫽2 E 1 ␦ 共 t 兲 ⫺ 共 t 兲 e⫺(1⫹a)t/
册 ⫺共 t 兲
1⫹iq x v 0
⫹
1⫹iq x v 1
where t is measured in units of * ⫽ /(1⫹a), v in units of
, 共39兲
共38a兲
1/(q 0 * ), and q is measured in units of q 0 . 共ii兲 Stop and
so that start:
134106-5
B. N. J. PERSSON AND A. I. VOLOKITIN PHYSICAL REVIEW B 65 134106
x共 t 兲⫽ v 0t for t⬍0,
x 共 t 兲 ⫽0 for 0⬍t⬍T,
F⫽⫺
a
1⫹a
1
冉
E 1 1⫹ ⫺
共 ⫺t 兲
a 1⫹iq x v 0
⫺ 共 t 兲 共 T⫺t 兲 冋 e ⫺t
1⫹iq x v 0
⫹1⫺e ⫺t 册
⫺ 共 t⫺T 兲 冋 e ⫺t⫺iq x v 1 (t⫺T)
1⫹iq x v 0
⫹e ⫺(t⫺T)⫺iq x v 1 (t⫺T)
⫺e ⫺t⫺iq x v 1 (t⫺T) ⫹
1⫺e ⫺(t⫺T)⫺iq x v 1 (t⫺T)
1⫹iq x v 1 册冊 , 共40兲
134106-6
THEORY OF RUBBER FRICTION: NONSTATIONARY SLIDING PHYSICAL REVIEW B 65 134106
134106-7
B. N. J. PERSSON AND A. I. VOLOKITIN PHYSICAL REVIEW B 65 134106
FIG. 5. 共a兲 Friction coefficient (t), and 共b兲 relative area of FIG. 6. 共a兲 Friction coefficient (t), and 共b兲 relative area
contact P⫽A( )/A(1), as a function of time when the sliding ve- of contact P⫽A( )/A(1), as a function of time when the sliding
locity changes abruptly from 10⫺4 to 0.1 at t⫽0. The relative area velocity changes abruptly, reducing from v 0 ⫽10⫺3 to 0 at t⫽0 and
of contact is shown at two different magnifications, ⫽3 and then returning to v 0 at t⫽5. The relative area of contact is shown
⫽100. The time and the sliding velocity are in natural units, * and at two different magnifications, ⫽3 and ⫽100. The time and
1/(q 0 * ), respectively 共see text兲. H⫽0.8, q 0 h 0 ⫽1, a 0 /E 1 the sliding velocity are in natural units, * and 1/(q 0 * ), respec-
⫽0.03, a⫽1000, and max⫽100. tively 共see text兲. H⫽0.8, q 0 h 0 ⫽1, a 0 /E 1 ⫽0.03, a⫽1000, and
max⫽100.
the height ⌬ of the stiction spikes shows that ⌬ (T) in-
creases logarithmically with stop time T 关see Fig. 9共a兲兴 as
long as the height of the stiction spike is much smaller than time. Figure 9共b兲 shows ⌬ as a function of ⌬A(T)/A 0 for
the limiting 共saturation兲 level, ⌬ (⬁)⬇2.8, observed for ⫽3, as obtained from Fig. 8.
large stopping time. Thus the results in Fig. 8 for T⬍3 are
well described by
IV. DISCUSSION
冉
⌬ ⫽ max⫺ k 共 v 0 兲 ⬇ 共 ⌬ 兲 0 ln 1⫹
T
3*冊, 共42兲
The theory developed above can be used to estimate the
friction coefficient for nonsteady sliding of rubber on a
rough, hard substrate. The input for the calculation, namely
where (⌬ ) 0 ⬇4. This curve is given by the solid line in Fig. the complex elastic modulus E( ) and information about the
9共a兲 while the circles are the data from Fig. 8. This type of substrate roughness 关spectral function C(q)] can be obtained
logarithmic time dependence of ⌬ on T is often observed in directly from relatively simple experiments.
experiments,22 but the origin of the effect for nonrubber ma- The theory relates the friction force to the coordinate x(t)
terials is likely to be different from the present case 共see Sec. of the bottom surface of the rubber block. However, the ex-
IV兲. One contribution to the increase in the height ⌬ (T) ternal driving force does not act directly on the bottom sur-
with increasing stopping time T results from a corresponding face of the block, but usually on the top surface or at some
increase in the contact area ⌬A(T). If the average 共over the other distant area. When studying the motion of the rubber
contact area兲 shear stress that is needed to start sliding block it is, in general, necessary to include the elastic defor-
would be independent of the stopping time, then one expects mation of the rubber between the bottom surface of the block
⌬ (T)⬃⌬A(T). This formula is often assumed to hold, but and the area where the external forces act. Consider, for ex-
Fig. 9共b兲 shows that this relation does not hold accurately in ample, a rectangular elastic block. Assume that the upper
the present case; thus, also will depend on the stopping surface of the block is ‘‘glued’’ to a thin rigid sheet as indi-
134106-8
THEORY OF RUBBER FRICTION: NONSTATIONARY SLIDING PHYSICAL REVIEW B 65 134106
FIG. 7. 共a兲 Friction coefficient (t), and 共b兲 relative area of FIG. 8. 共a兲 Friction coefficient (t), and 共b兲 relative area of
contact P⫽A( )/A(1), as a function of time when the sliding ve- contact P⫽A( )/A(1), as a function of time when the sliding ve-
locity changes abruptly, reducing from v 0 ⫽0.1 to 0 at t⫽0 and locity changes abruptly reducing from v 0 ⫽0.1 to 0 at t⫽0 and then
then returning to v 0 at t⫽5. The relative area of contact is shown at returning to v 0 at t⫽T⫽0.1, 0.3, 0.5, 1, 2, 3, 5, and 10. The relative
two different magnifications, ⫽3 and ⫽100. The time and the area of contact is shown at two different magnifications, ⫽3 and
sliding velocity are in natural units, * and 1/(q 0 * ), respect- ⫽100. The time and the sliding velocity are in natural units, *
ively 共see text兲. H⫽0.8, q 0 h 0 ⫽1, a 0 /E 1 ⫽0.03, a⫽1000, and 1/(q 0 * ), respectively 共see text兲. H⫽0.8, q 0 h 0 ⫽1, a 0 /E 1
and max⫽100. ⫽0.03, a⫽1000, and max⫽100.
cated in Fig. 10. If a parallel force is applied to the rigid to both the static and kinetic friction forces. Finally, since
sheet, either directly, or, as is typical in many applications, most real surfaces are contaminated with a few monolayers
via an external spring 共spring constant k s ), then the block of physisorbed organic molecules, the contamination layer
will deform elastically as indicated in the figure. This elastic will also contribute the friction force as discussed in detail in
coupling between the sliding interface, where the friction many recent publications.21,7 All these additional contribu-
force is generated, and the point or area where the driving tions to the rubber friction give a contribution to the friction
force acts must be taken into account when studying sliding coefficient which is typically of order ⬃0.2.
dynamics of the block, and is particularly important for ma- Let us comment on the concept of the static friction force.
terials with a low elastic modulus such as rubber. We will If there would be no interfacial pinning processes of the type
study this problem in another publication. described above, then, strictly speaking, the static friction
Let us point out that in addition to the contribution to force would vanish. However, assume that the E( ) function
rubber friction from the internal friction of the rubber studied has the form shown in Fig. 11共a兲, giving rise to a kinetic
above, there will in general be other contributions arising friction coefficient k ( v ) of the form shown in Fig. 11共b兲.
from pinning effects at the interface. Thus, for a clean rubber Assume now that we start to pull the block with some speed
surface 共if that ever exists兲 in contact with a hard substrate, v 1 indicated in Fig. 11共b兲. In this case we would observe a
the rubber molecules at the interface will rearrange them- stiction spike 共or static friction coefficient兲 of height
selves to bind as strongly as possible to the substrate surface. ⬃ k ( v a ), see Fig. 11共c兲. Thus, if there are very low-
Because of the lateral corrugation of the substrate potential frequency 共long-time兲 relaxation processes in the solid 关cor-
this will in general give rise to an energy barrier towards responding to the low-frequency peak in Fig. 11共a兲兴, they
sliding. If the rubber is in contact with another polymer sur- may show up as a static friction force under most normal
face, e.g., rubber in contact with rubber, chain interdiffusion sliding friction experiments. However, if the sliding velocity
may also occur at the interface which will give a contribution is extremely small ( v ⬍ v a ) there would be no stiction spike,
134106-9
B. N. J. PERSSON AND A. I. VOLOKITIN PHYSICAL REVIEW B 65 134106
134106-10
THEORY OF RUBBER FRICTION: NONSTATIONARY SLIDING PHYSICAL REVIEW B 65 134106
friction, but rather by interfacial processes as described has been developed for arbitrary E( ), e.g., the experimen-
above. tally measured E( ) can be directly used as an input. The
theory relates the friction force to the coordinate of the bot-
V. SUMMARY AND CONCLUSION tom surface of the rubber block. In most practical applica-
tions the external driving force acts some distance away from
There is at present a strong drive by tire companies to the sliding interface, and it is then necessary to include in the
design new rubber compounds with lower rolling resistance, equations of motion the elastic coupling between the bottom
higher sliding friction, and reduced wear. At present these surface of the rubber block and the area where the external
attempts are mainly based on a few empirical rules and on driving force acts.
very costly trial-and-error procedures. We believe that a fun-
damental understanding of rubber friction and wear may help
in the design of new rubber compounds for tires and other ACKNOWLEDGMENTS
rubber applications, e.g., wiper blades or products for the
cosmetic industry. This work has been supported by a research and develop-
In this paper we have presented a general theory of the ment grant from Pirelli Pneumatici. We thank O. Albohr,
hysteretic contribution to rubber friction for nonstationary G. Heinrich, M. Klüppel, U. Kuhlmann, G. Luengo, and
sliding. The theory has been developed for rubber sliding on V. Peveri for useful discussions. B.P. also thanks BMBF for
a hard self-affine fractal surface, e.g., a tire on a road surface. a grant related to the German-Israeli Project Cooperation,
Numerical results were presented for a simple rheological ‘‘Novel Tribological Strategies from the Nano to
model of the complex elastic modulus E( ), but the theory Meso-Scales.’’
1
D.F. Moore, The Friction and Lubrication of Elastomer 共Perga- 13
J.F. Archard, Proc. R. Soc. London, Ser. A 243, 190 共1957兲.
14
mon Press, Oxford, 1972兲; M. Barquins, Mater. Sci. Eng. 73, 45 J.A. Greenwood, in Fundamentals of Friction, Macroscopic and
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