INTRODUCCION A LA INGENIERIA QUIMICA BASE DE DATOSConstantes Fundamentales Namero pi . Base del logaritmo neperiano . Constante de Euler . . ‘Aceleracién normal dela gravedad . . . Densidad del mercurio a 0°C y Latm. . p T Cero absoluto de temperatura. ‘Nimero de Avogadro. Constante de Boltzmann Carga del electron Masa del electron Constante de Faraday. . Constante de los gases 1415926536... 7182818285 = 0.5772156649. x e Y 80665 mv/s* 3595.08 ke/m* = -273.150+0.010 °C N_ = (6.022834 0.0022).10% /mol . k = (1.38048+0,00050).10™ julios/Kelvin 1,60199+40.00060).107 culombios(absolutos) 1091.10" kg (9.64853:0,00100).10* cul. (abs. )/equival.-g R= 0.0820567+0.0000034 atm_litro/mol Kelvin = 1,98719+0.00013 cal/mol.Kelvin 0.73 psia.f°/Ib-mol.R e mn 3 Producto PV para el gas ideal a 0°C. . . PV = 22.414640.0004 atm.litro/mol Constante de Planck Velocidad de la luz . Electrén-voltio(absoluto) Constante de Stefan-Boltzman Constante de la ley de Wien Pulgada (definicién). . . Pié (definicién) Libra (definicion) . Galén USA (definicin) Caballo de vapor (definicién) Caloria (térmica) . _h = (6.6242+0,00044).10™ julios.segundo ¢ = (2.99776+0,00008).10* metros/segundo eV =(1.60199+0.00060). 10" julios @ = 4.88.10" kcal/m?K* vo Aga = 2,898.10? mK in =2,54000508 cm ft =12in. 304800610 m . Tb = 0.4535924277 kg, . gal = 231 in? 785412 litros . hp = 350 Ib, ft/s 6.04023447 kg, m/s cal = 4.1840 julios(absolutos) = 4.1833 julios (internacionales) = 0,9993464 cal I.T.(Tablas internacionales del vapor de agua)> eg) ®e) SelSalOalead ) £§/23/ <2] 23] 23] g ) jo “2 Se 8s Siz Fis ° > TNDADES DE LONGITUD s/43/O3|/a3|—3/Ze| ) = ie a mile jn flr Ble Ble Sle 5 7 aaa7 | a2808 | oov0eaTe $ 2 0254 40.0899 | 1586-05 s]OFmsaacacg 0.3048 12 4 0.0001894 jo |S Is 3 "ls > ‘e003 | ease _| 5260 H TRIDADES DE MASA S)/Ze/ OR cslmeims ; — eT Saal Saleete x 7 Te 13. gal(USA) |r To “le “le gis ®le Hs & 1 '0.0005787| 0.004329 | 0.01639 | 1.6395-05, S a1 5 728 + 7481_| 28.32 | 0.02852 25g O3]z3 ; zor] one? | 4 3.785 | 0.003785 is Sle Ele°8 TRIDADES DE PRESION : 33| 231 23 > kPa. ‘aim ‘kgtlom2. sia Abars IO Nm OF ate <3 > 7 —[oro0esss | 0.0102 | a1as08 daim: oidzio%wt (Sls Ble 8 > 701.325 1 7.03923 | 14.696 = 4013 bar SalPalxre > oe.086s | 0567s | 1 “4223. 2 3/o3\23 > 6.8047 | 0.06605 | 0.07031 1 oaleal 7.8047_UNIDADES DE ___ ENERGIA |S E8l=8 J ‘kghm eal Btu kwh Im Sle Sle & 7] onte—|~o.208 | ezooosea) 2.7706-07 Foote ctae z 3066s | 1 23438 | 0.0088 | 2726-06 lu S| 810 3] 3 aia | oase7 [1 | 000807 | 1.16206 ls 8[z Fle = 1054] 1075 | 252 + [0.000289 «|2alocl en > ‘3600000 | 367100 [ 660420 | 3414 1 Seer siarg TNIDADES. DE POTENGI eae fe = aw mp | kgimis | — calla #/S3/Sslzel > 1 1.341 102 239, 3/081 35/33 > one | 1 75 | 172) BS a o.ooges | 0.01316 4 2344 el|> e238) S5 5 ‘.0041e4 | 0.00562 | 0407 * lz S[5 sie | G=OA00GS jad = S2I7A0 R21 bar = 100 KPa = al Sal el Densidad del Hg a O°C = 13.5951 gfems 2/Fa|Nalzg = 0.08208 (atm) itre)/(mobs)(K) is “lg Sle © = 1.987 callimotg)(9) 2/33l>3] 53) 28 5 _|s Sis sie 8[2°8 3 Oe] Fe] Ge) oo] wal oe > s/m8)S8/O8|G8/me/ a8 a j S12 Sle Sls Fle Fs 8 3 “5<| S8lcel Se] esl 33 S5/<3/2e/S3cq > 2 “|F Sle Sis le Sls “LANTHANUM SERIES Cel Pr| Nd" Pm|*Sm|" Eu|" Gd|® Tb |" Dy|"Ho|® Er] Tm|" Yb)" Lu 00.12 |raosorr| 14424 | 145) | 160.98 | 16196 | 157.25 |150.0254] 162350 lreasso4| 16726 |1sas242| 173.06 [174967 Th) Pal U Np» Pul*Am|"Omi" Bk)" Cf" Es Fm" Mdl"™ Nol” Lr sn izsz.oet fest.caso|zsn.osss|za704s| 4a) | aa) | aay | aan | sn | esa | asm | ase) 1259)> > > > > eur vue Base de datos de propiedades fisicas Los compuestos inorgénicos se presentan por orden alfabético del elemento principal de la formula empirica, Los compuestos organicos con el mismo mimero de étomos de carbono se presentan juntos y ordenados atendiendo al nimero de atomos de hidrogeno, con el resto de los &tomos en orden alfabético. NO = Numero de orden en la lista MOLWT Masa molecular TEP ‘Temperatura normal de solidificacién, °C TBP Punto normal de ebullicién, °C Tc Temperatura critica, K PC Presién critica, bar vc Volumen critico, m’/kmol LDEN Densidad del liquido, kg/m? TDEN Temperatura de referencia de la densidad del liquido, °C HVAP = Entalpia de vaporizacion en el punto normal de ebullicién, J/mol VISA, VISB = Constante para el calculo de la viscosidad del liquido, segin la ecuacién: logy n= VISA = S aa pele. THK DELHF = Entalpia estindar de formacién a 298 K, kJ/mol DELGF = Energia libre de Gibbs estandar de formacién a 298 K, kJ/mol CPVAPA, CPVAPB, CPVAPC, CPVAPD = Constantes en la ecuacién para el calculo de la capacidad calorifica del gas ideal: c, = CPVAPA + CPVAPBT + CPVAPC T? + CPVAPD T? e, ll JimolK , TIlK ANTAANTB,ANTC = Constantes de la ecuacién de Antoine para el célculo de presiones de vapor ANTB In p® = ANTA - ———_ . ° \=| mmHg , T \=|K PB T+ ANIC P° |=| mmHg FFI TMN = Temperatura minima para emplear la ecuacién de Antoine, °C TMX = Temperatura maxima para emplear la ecuacién de Antoine, °Cvevvwre PEUGREA AG ay i & i 8. ake oe et San ins “he IR 4 2838: a 5 Fistosrases: i SGhESRUGGESUGRSUNESEDGG FUE 49 gBe38 aeSben ded a eoaed ro $ geszaeesse:BO BESBBEEE, 8855 ee PE DBR ENA ESE BERS: i 28 ¥i aa aaeee i888 fy 3229S SRE RERR EERE Sess yagaeaeed 8 art aa S853 3 3 HH #3 ARRAEERL AbEDD fi ee i SBBEBSES ESS: BB PESSBBeER SAAR EEE SEs: t 4 HE BE aus sus e A § Base. PERL LELLEDS BEBESBBsSU BST REREERE: oF BUBBEBREe ees: Sauk wrasdiexts i t 5 a 5 i 5 i i i 3 00 Sone La penmabune Ba oma Beneweer subbhears aauzesese 3 a E383 SEEISEASEISER ESO RR ERS GEESE: SSSSUREGTEY BUURENRE SE ENESS GESESEESERSERS gayest a BERSSBSE TES SERRESS pey Re ey aot Have duvaessdey vedtavsdeseaaSsy,wuUeEve trmee mtn meat Ko shbebsaede.> = a si tse = 5 en Te > ar gems Siem > a PISS a: om os > 2B. Se BF B > “Bip gee = = 5 3 is a 3 > me = > z B > = =ARARRRRERE> Bo 2i zt 3 , z: : ’ fo zi 8 e mom: aie ; Bigigi ” = 8 > Eiki Hn @ OB > Big: Giie E OE > EEE Bit ii. ms ERS > suet Bt i Ms > 2 3726-07 vuvEEswow [eTRODUCEON A LA INGENTERIA QUDICA ‘ Datos termodindmicos ‘Thermodynamic Data for Elements and Inorganie Compounds * , 7 CC CCE] 021s 1 ‘Carbor 16 ity Carbos (Graphite) ° € Carboa Diouide ~s40s2 9428 6393 10100-3405 Co, Cerboa Disulphide +2755 26352 cs, Carbon Monoxide, 26416 67636 3281 6421836 .-0200 CO Chlorine ° aan 0 1515 24s” 0968, Hydrogen (®) 0 026 -n7 0 6947-020 oat, Hydrogen Chlorides) -2208 3460 -2n 6n2 04s 0370 Ha Hydrogen Fluonde g) 642 800 . Hydcogen Sulphide 41s 4463 -119 ous 57-120 Hs Nisie Aid (1) 41404 1510 Hito, Nie Oxide 42160 322 420719 30 70-03 ©2546 NO. 0 1333 0 4577649 1412-00807 Ny +8041 412390 S747 NO, +1949 39g 4475 2586s tosis 3571 NO. o 1630 ° 4900 © 6095432833 “10171 OF Sulphur Dioside =m 5950 -19 940 T6512 asin Sd, Sulphur Trioxide (g) —9445 9.950 =u ©6128 Go? 537 0687 SO, Sulphur Trioxide (1) —10480 37 wat @ = -57798 917 ~463 45106 7219, 23% 0267 HO. Water Trioxide (1) —68317 =36690 16716 "Thermodynamic Data for Organic Compounds ant AH, aly act Skee « 4 7 ‘Acctaldeiyde(@) 3976600 284983196 THR 08742 CH,CHO ‘Acetic acid (1) Sie 9526 Ta0gss 5380 cHcoo ‘Aectone (1) <92 700 Lar a9 san mT = 15182 (CHY,CC ‘Acetyene (g) #54194 ©4770 310615. +5000 480 262 3M CH, Benzene (e) +1982 7350 von “30989 434-0409 TSM 2649 CHE Benzene Fun 7098 297564130 CH s-butane () =WIS $350 687982 4104124453 EMD = 2224 Hable butane (p) sos Seags42 3320 S28 BM Ec, Carbon wtrachloride -2550 71709201 nes ca, Diethyl Ether 620 65259 <3 87-393 (Cyti,0 Ethane sme 3517 3282-786 suas 224738201 Ethylene +E96 3337 +1622 2452 SO Ethyl Alcohol i360 9220 “00 674 69903974 Ethyl Alcohol () 66356 ee Ethylene onide(g) 12196101 =29 0 atte agas Formaldehyde(g) 277 =1467 22 4a 13983 Formic aid (1) a8 sso 6457 son Methane. Tins 1985-2127) 1a HD 33k BO 450 CH, Methyl Alcohol() 48100430. 17365 3-100 S680 4388242746855 CHSOH Methyl Alcobol()—— —57036 =39750 3030 cHOH Methylamine 67 CHNH, Methyl Chloride ~1958 5150 350 om 731 CHL Propane <4 447 > > > > vue Ecuacién de estado de van der Waals para 1 mol de substancia Standard forms ofthe equation are (P+ al V—b)= RT, a) a (oeE nedrtten on “9 Reduced form: 3 ‘The parameters in terms of critical properties: = 3P.V2 = 27R272/64P,, o b= V./3= RT_/8P., «@ Ro BP /3Te, ° 2.7 0.375. (10) ‘The value of Riven by Eq, 9 is not the same as the true gat constant, 8.314 joules/gmol-K; the true value should be used for evaluation ofthe parameters a and b from Eqs, 7 & 8. Derivation ofthe formulas for a and be Method 1: At the critical condition, the fist and second erivatives with respect to V at constant T are zero. Per- forming these diferetiations, Gr) -- wit i eT ay ap 2RT. 6a av? ) = 6 ve? ay (n+ )ernean as) Eqs, 11-13 are solved simultaneously to obtinthe results of lines 7-9. Method 2: At the ertical point, the three roots of the polynomial, Eq 3, ae equal (= V3 = = 3002+ 3¥2V—V3=0, (14) Comparison of coeficients of like powers of Eqs. 3 and 14 ‘will lea to the same results for the parameters as by method 1 For mixtures, the parameters are expressed in terms ofthe pure component parameters by the combining rules: 8 (EyVvap = Bry, Vara= BLY y0y; (15) b= Eye. 6) Fugacity equations are in tables 3.3 and 3.4. Residual property equations are in Table 11.3. as46 [eTRODUCOON s LA NGENIERLA QUBOCA ica de liquidos Capacidad calorifi 60 ra 3. 2/04 we eoyuon> pepaeseD ue es ro we es 3. um emeeduas (561 “Po "nk "HOA EDON THHMEIDDN "OOgPURH Bau JOjDYD “Aung HT :e1ang ° rt oor a oe we apeiaoy $e pint won \aaanas> > > > > > > VUUYEUs eTRODUCCION A LA NGENIERIA QUICK Capacidad calorifica de disoluciones acuosas a 20°C Sine Sle @Capacidad calorifica media de gases a baja presion C, [=] cal mol" K+, entre 25°C y las temperaturas que figuran en la tabla Temperatura co ch 802 | $03 | ct] cata] cat 2s | 28 | 77 67 #2 9s4/izar| e55| i045 line io | 373 | 213 7,00 824 95/1284) 898 | 1135 | 1396 300 | 493. | 392 102 837 10125 13:78 | 9:62 12'33| 139 300 | 323. | $22 497 48 to2| 1454 | 109] 1365 | 1672 400 | 63 | 352 74 02 | 835, 1094) 1522] 10.97| 14:67 | 18:1 | 500 | 973. 932°|5) 12 | 723738 | 732 | 706 | et 11.22 15382 | 1165 | 15,60 | 1959, i 600 | 873 | 1112 | 7.01 |} 7.23] 7.29 7, 145 | 16.33 | 12.27 | 16.45 | 20.58 700 | 973 | 1292 |7.03 | 730737 7 1166] 1677 | 1250 | 172 | 21-68 300 | 1073 | 1472 | 706 | 739 | 744 z uss] 1717 | 13.48 | 1795 | 3272 900 | 1173 | 1652 | 708 | 7744 [782 7 1201 | 1732 | 1404 | 18.63 | 23.69 000 | 1273 | 1832 |735 | 7st | 739 : 12415 | 1736 | 1456 | 19.93 | 34'se sco | 1373 | 2012 | 7.17] 7.57 | 7.65 1228] 18.17 | 1504] 1981 | 25.40 tooo | 1473 | 3192 [731 | 764 | 371 1239| 1844 | 15.49 |2033 | 2615 1300 | 1593 | 2372 [735 | 69 | 737 1247] 1865 | 1590 |2078 | 3682 1300 | 1673 | 2552 | 135 | 7.94 | 72 1252] 1882 | 1629 2118 | 3743 1500 | 1773 | 2732 |733 | 739 | 787 1285 | 1894 | 16,64 | 21:51 | 3794 1600 | 1873 | 2912 |739| 7-84] 7292 1700 | 1973 | 3002 | 742 | 788 | 736 1800 | 2073 | 3202 | 1:47] 199 | 800 4300 | 2173 | 3452 |7'51| 796 | 803 2000 | 2293 | 3652 | 735 | 799 | 807 2100 | 2373 | 3812 |759| 803 | 8.10 2200 | 2473 | 3993 | 762 | 805 [8.13vuwey ITRODUCION A LA INOENTERUA QUDOCA Capacidad calorifica de s6lidos Ep cal/(mol °C) Intervalo de Compuestos y elementos temperatura| sélidos a ‘Aluminio 48 + 0.00322 T 273931 Cloruro de aluminio 13.25 + 0.028 T [273 — 465 Oxido de aluminio 22.08 + 0.8971 T ~ 522500/T |273—1973 Cloruro de amonio 98 +0,0368 T 273 — 457 Nitrato de ar anio 318 273 — 293 Calcio 5.31 + 0.00333 T 273 — 673 Cloruro de calcio 16.9 + 0.00386 T 273 — 1055 Carbonato de calcio 19.68 + 0.001189 T — 307 600/T*| 273 — 1173 Oxido de calcio 10 + 0.00484 T - 108 000/T? |273 —1173 Sulfato de calcio 18.52 + 0.02197 T ~ 156 800/T |273 —1373 Carbén (grafito) 2.673 + 0.002617 T - 116 900/T| 273 — 1373 Hierro 413° + 0.00638 T 273 —1041 Oxido ferroso 12.62 + 0.001492 T - 7200/7 |273 1173 Oxido férrico 24.72 + 0.016047 - 423 400/T |273 —1 097 Oxido ferroso férrico | 41.17 + 0.01882 T — 979 500/P |273 —1 065 Sulfuro de hierro, piritas | 10.7 + 0.0133 T 273 — 773 Carbonato de magnesio | 16.9 290 Cloruro de magnesio | 17.3 + 0.00377 T 273 991 Sulfato de magnesio | 26.7 296 — 372 Cloruro de potasio 10.93 + 0.00376 T 273 — 1043 Nitrato de potasio 288 401—611 Sulfato de potasio 33.1 287 —371 Carbonato de sodio | 28.9 288 —371 Cloturo de sodio 10.79 + 0.0042 T 273 —1073 Nitrato de sodio 4.56 + 0.058 T 273 — 583 Sulfato de sodio 32.8 289 —371 3.63 + 0.0064 T 273 — 368 438 +0.0044 T 368 — 392 5.25 + 0.0027 T 273 — 692 Cloruro de zine 15.9 +0.008 T 273 — 638 44IETRODUCOON A LA NGENTERIA QUDOCA Calor latente de fusién de sdlidos Punta de | Calor latente Sustancias fusion de fusién °c. cal/g Mercurio 38.87 28 Potasio 63.7 147 Plata 960.5 249 Sodio 97.8 27.05 Estafio 2319 45 Zine 4195 244 Aluminio 660.2, 6 Antimor.io 530.5 383 Cadmio 321 13.2 Oro 1063 14.96 Plomo 327.4 5.89 ‘Agua o 79.5524 [RTRODUCEON A LA NGENERIA QUDICA Constantes del equilibrio de reaccién quimica (actividades de los gases en atm.) 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