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FIITJEE JEE (Main)-2014
ANSWERS, HINTS & SOLUTIONS
FULL TEST –I
(Main)
S. No. PHYSICS CHEMISTRY MATHEMATICS
ALL INDIA TEST SERIES

1. A C C
2. B A B
3. D B B
4. B D C
5. C C C
6. C B A
7. A D A
8. C B C
9. B C B
10. C D A
11. B D C
12. D A D
13. C C C
14. B D B
15. B C D
16. D C B
17. C D A
18. D B B
19. D D B
20. D C D
21. D A C
22. B A A
23. A D C
24. A D B
25. A C B
26. A C B
27. D A B
28. B A B
29. D B B
30. B B D

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AITS-FT-I-PCM(Sol)-JEE(Main)/14

Physics PART – I

SECTION – A

M 2
1. For full square about an axis passing through ‘O’ =
6
3  M2  M 2
by symmetry for remaining portion it must be  
4 6  8

2. apply work-energy theorem


2 2
 1  mg  1  mg  
mgz   K   z  K     Fz  0
 2  K  2  K  
 z = 2F/K.

3. a = 2 + |t – 2|
for t  2
a=2–t+2
a=4–t
dv = (4 – t)dt
v = 4t – t2/2
at t = 2, v = 6 m/s.
for t > 2
a=2+t–2=t
v t

 dv   tdv
6 2
t
v – 6 =  t 2 / 2  2
t2
v= 4
2
at t = 4, v = 12 m/s.
    
10. (a  b)  [a  (a  b)] . Dot product is zero.

11. Say speed of boat is v w.r.t. water and speed of river is C. Then, distance travelled in ground
frame
1 1
= (c + v)  hour + (v c)  hour = v  1 hour
2 2
= distance travelled by boat w.r.t. river.

12. In the shown frame the particle appears to be at rest. 


P
 Net force on it must be zero. Therefore pseudo force must be m
equal and opposite to the tension.’ O L

13. Successive frequencies will differ by an amount v/2L

14. Linear magnification = v2/u2

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AITS-FT-I-PCM(Sol)-JEE(Main)/14

Q+x x
1  2 
15. Electric field between the capacitor plates = 
20 2 0 C

Qx x 1
E=   Q  2x 
2A0 2A0 2A0 

d
 Potential different Ed = Q  2x   
2A 0
Q  2x
 
2C
Q
 x =  C
2

16. conservation of momentum


M 2gh  m 2gh =MV1 + mV2 (1)
V1  V2
1  (2)
2 2gh
V2  3 2gh
V22
h'   9h
2g

1 1 1
17.  
C C1 C2
x a b  x  A
=  C= 0
0 A 0 A ab

18. FBD of ‘B’ and ‘C’


T T

B a C a

2g 3g
 T – 2g = 2a . . . (i)
and 3g – T = 3a . . . (ii)
12g
T=
5
for A
T=2T

A a

mg
 T = mg
12g
2 = mg  m = 4.8 kg.
5

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AITS-FT-I-PCM(Sol)-JEE(Main)/14

/2
mgR
19. W =  f.Rd  = 1 joule.
0 2

20. Coulombic force between them remains same.

21. Let us assume cylinder is no moving then


T + fs = mg sin 
T. R  fs R = 0
mg 3
 fs = .
4
but (fs)max = N = mg cos 
1 mg
= 0.4 . mg  
2 5
 (f s) < (fs)max, our assumption is wrong. So, friction existing must be kinetic
1 mg
fk = mg cos  = 0.4  mg  =
2 5

22. Circuit is forming a wheatstone bridge Req = 2R R R


For maximum power transfer 2R = r.
R R

R 4R

 r

3 2
23. = B
4
d 3 2 dB
=  
dt 4 dt
 32
i= 
R 4R

x dx
RT 5RT
24. C= 
M0 3M0
A B
5R   TL  T0  
dx = C. dt = T0    x  dt T0 TL
3M0   L   L

2L 3M
t
( TL  T0 ) 5R

E
25. = E – ir
2
E
 i= . . . (i)
2r
2E = i(3 + r) . . . (ii)
r=1

26. dQ = dU + dW

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AITS-FT-I-PCM(Sol)-JEE(Main)/14

PdV
C = Cv + …(i)
ndT
Differentiating TV 2  cons tan t
dV V
 …(ii)
dT 2T
PV = nRT …(iii)
solving eq. (i), (ii) and (iii)
R
C=
2

27. Equivalent circuit is 2RT


V RT
90  V 20 0
  V = 50 C
2R T RT
P (900C) 0
RT R (30 C)

Chemistry PART – II

SECTION – A
2. 2B atoms (ions are missing from every unit cell).

3. Only KI produces I ions in aq. solution.

n3
6. Time period 
z3
T1 n13  z 23
 ; z1 = z2 for same element.
T2 n32  z13
T1 13 1
Hence,  
T2 33 27

7. From Keq value; % of -D-glucose is 64.3.

O
9. Leaving group is at  position to anion stabilizing group (i.e. group.)
C

11. OH OH OH

H  / Methyl

 
Shift

O OH OH

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AITS-FT-I-PCM(Sol)-JEE(Main)/14

12. All others are used for this purpose and they form cyclic acetal or cyclic thioacetals at C O

group.

17. Bauxite is (Al2O3.2H2O)


Magnetite is (Fe3O4)
Bornite is (Cu3FeS3)
Cerussite is (PbCO3)

21. HN Ac HN Ac HN Ac NH2
NO2 NO2
X= Y= Z= Product P =

SO3H SO3H

22. NiCl4 2  dsp2, square planer and diamagnetic


2
Cu  NH3  
 4
 dsp2, square planer and paramagnetic
Ni  CO    is sp3, tetrahedral but diamagnetic
 4

25. CaF2  CaF2 (solution) - H2O


= 4.05  10–3 S/m

Conc   2.025  104 mol / dm3
m
K sp  4C3  3.32  10 11M3

27. Heat supplied at constant pressure in the range of temperature, T is H and change in internal
U 1 1
energy is U hence    0.71 approx 
H  1.4

28. (A) 2KClO3 + I2  2KIO3 + Cl2


(B) 5NaBr + NaBrO3 + 6HCl  6NaCl + 3Br2 + 3H2O

(C) CaOCl2 + 2NaI + 2HCl  I2 + CaCl2+ H2O + NaCl

(D) NaCl + H2SO4  NaHSO4 + HCl

29. A and C possesses plane of symmetry. While D possesses centre of symmetry.

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AITS-FT-I-PCM(Sol)-JEE(Main)/14

Mathematics PART – III

SECTION – A
n n
1. C3  C2  n = 5

PA  PB 1/ 2
2.   PA  PB 
2
|PA| + |PB| > 2|PT| = 2 3
Maximum length occurs when PAB passes through centre
i.e. |PA| + |PB| = 4 (Maximum)
So, range is 2 3, 4 
2
3. Length of tangent is = z1  i  4
2
= 3  2i  4  9  4  4  3

7!
4. Required number of sentences =  6 C0  6
C1  6C2  
2!

5. The given line can be written as y = x


Hence reflection is 3 + 2i

1 1 1 1
6.   
an1 an  an  1 an an  1
1 1 1 1
 S   .....  
a1 a2 a100 a101
1 1 1
=  2
a1 a101 a101
Since, a101 > 1  [S] = 1

5
7. Height of the cone =
3
2
5 8
Radius of cone = 92     11
3 3
2
8  5 3520
Volume =   11    = 
3  3 27

8. 4! = 24
5! = 24 × 5
6! = 24 × 5 × 6
1! + 2! + 3! = 9
So, 1! + 2! + 3! + ….. 100! = 9 + 24p
=9

9. |z| = O × O – I × I = –I2
2
det(|z|) = |–I | = (–1)

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AITS-FT-I-PCM(Sol)-JEE(Main)/14

 1  2 2
10. f x  f    ….. (1)
 1 x  x 1 x
1  1   1  1 2
Now replace x by we get f    f 1    2 1  x   2  1    2x  ….. (2)
1 x  1 x   x  x x
1  1 2x
Replace x by 1  we get f  1    f  x    2x ….. (3)
x  x x 1
From equation (1) – (2), we get
 1 2
Now, f  x   f  1    2x  ….. (4)
 x 1 x
From equation (3) + (4), we get

2x 2
Again, 2f  x   
x  1 1 x
x 1
f x  which is a one–one function
x 1

11. x = –a is the only asymptote to the given curve N


a
A  2 ydx  3a2

a (–a, 0)B (a, 0)

12. M = ey, N = x · ey + 2y
dM
Now, (keeping x constant) = ey
dy
dN
= (keeping y constant)
dx
Hence, the given equation is exact
Now, f  e y dx  g  y   x  e y  g  y 

dg
Differentiating w.r.t y we get, x  e y   N  x  e y  2y
dy
dg
i.e.  2y
dy
Integrating g(y) = y2 + c1
y 2
 f = x·e + y + c1
So, desired solution is x·ey + y2 = 0

13. b  v  b  b  c
4v   b  v  b  b  c
vb  c
 v b sin   c
2 v sin   3
3
sin  
2

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AITS-FT-I-PCM(Sol)-JEE(Main)/14

1
cos  
2
 1
 4v   2  1  b  b  c
 2
1
v  b  b  c 
4

1
 dx  2
 1  x at point (, 1 – 2) tangent is
2
14. Area under curve and axis =
3
0
2
[y – (1 –  )] = –2(x – )
 2  1 
 2x + y = 2 + 1  P   2
, 0  , Q  (0,  + 1)
 2 
Hence, Q   2, 1  4x1  x12 
 A  1  2x1  x12   1  4x1  x12    1  3x1  x12
dA 3
 3  2x1  x1  
dx1 2

   
15.   , 0  lies on directrix and centre be (x1, 0). Equation of one of the tangent is x  y   0
 4  4

and chord is x   0 , centre is (x1, 0)
4
 
x1  x1  2 2
4  4  x 2    x = 2x 2    x
1 1
2 1 16 2 8
3x 2 3  3 
x12    0  x1  x 2   Midpoint   , 0
2 16 2  4 

16. 2x + y – 1 is the axis and (1, –1) is the point of intersection with the tangent at the vertex, length
of latus rectum is 5
So, coordinates can be (h, k)
 5  1  1 3 5
h  1   
 4     1 4  4 , 4
5
 5  2  1 1 3
k  1     1    , 
 4   5  2 2 2
3 1 5 3
 ,   and  ,   are required points
4 2 4 2

17. For the common tangent m 2 sin2  + cos2  = m2 + 1


m2 (sin2  – 1) = 1 – cos2 
1  cos2  cos 2 
 m2  2
=  2
  cot 2 
sin   1 sin 
 
Clearly no such m is possible (when      )
4 2

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AITS-FT-I-PCM(Sol)-JEE(Main)/14

h  h 
18. Let midpoint is (h, k) then chord is y   x  2h and if it is a tangent then x 2  4   x  2h 
k  k 
D=0
h
 k 2   (Parabola)
2

19. 11  22  12  12 12  22


 11   22  1

n2  n1
20. g n   
0
 x / 2
e 
x  
2
d x

1
=  n2  n  1 e 
0
x / 2
 x
2
dx

1
x
=  n2  n  1 e x / 2   dx

0
2
= n2 + n + 1[4 – 2e1/2]
So, minimum value is 12  6 e

21. f(0) < f(1) now if suppose


 f(n – 1) < f(n)
 f  n  1  6  f n   6
 f(n) < f(n + 1)
Also, f(0) < 3, let f(n) < 3
 f n  6  3  6
 f(n + 1) < 3
So, f(n) is bounded above 3

1 
22. Any plane containing the line is p1  p2  0 . It’s distance (d) from origin  .
  a  a'2
 2  2  1
Let d2    where A  2
 a ' , B  2 aa ' and C   a 2
.
A 2  B  C
  A  1  2  B  2     C  1  0 . As   R , D  0
4  A  C  B p p
 0   2
 . So, dmax  .
4AC  B q q

1 1
23. We have f(x + a)  and so f(x)   x  R.
2 2
1
Lets set, g(x) = f(x) – we have g(x)  0  x  R
2
1 2
 g x  a   g x 
4
1 1
 g2  x  a    g2  x  = g  x  2a    g2  x  a 
4 4

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 g2  x  2a   g2  x 
 g(x + 2a) = g(x)
 f(x + 2a) = f(x)

24. ( In) Adj( In) = | In| I


 Adj( In) = n – 1 In
n(n – 1)
 |Adj( In)| = 
3 13
25. B = A1 + 3(A2) + ….. + 13(A7)
T 3 13
B = –[A1 + 3(A2) + ….. + 13(A7) ] = –B

m 1
 a  q  a  q 2 m 1
a q 
26. f  a  p 1     .....  ap 
 a  p  a  p    
pm  t  qm  t
Now coefficient of at is m
Ct
pq

27. Point of intersection of L and x = –2 is the required point

ln 2
2x
28.
e f "  x  dx
0
ln 2
ln 2
=  e 2x f '  x  0  2 2x
f '  x  dx
e
0
ln 2
1 
=  f '  ln2   3   2  e2x f  x   2 e2x f  x  dx 
 = 13
4   0

30. |a – b| < c
|b – c| < a
|c – a| < b
 a  b 2  c 2 

2 2 2 2
  b  c   a 2   a  b    b  c    c  a   a2  b 2  c 2

 c  a 2  b2 
 a2 + b2 + c2 < 2ab + 2bc + 2ca
 a2 + b2 + c2 + 2ab + 2bc + 2ca < 4(ab + bc + ca)
2
 4(ab + bc + ca) – (a + b + c) > 0
a –a
Also, 2 + 2  2
Hence, for all values of a, b, c the above z is defined.

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