Grafica ELV

Construir un diagrama P-xy para el ciclohexano(1) - feno(2) a 130°C

Datos:
�^�/𝑅𝑇⁡⁡=−2.1�_1⁡
�_2
Hallar y
�_1^° �_2^°
ln⁡〖� _1^��� (���) 〗 =15,0886−4093,3/
(𝑇(𝐶°)+236,12)

ln 〖
〖�_2^��� (���)= 〗
14,413−3490,885/(𝑇(𝐶°)+174,569)

𝑇(𝐶°)= 130 〖�_𝑖^𝑠𝑎𝑡⁡ 〗

ln⁡〖 �_𝑖^°
Ciclohexanona 3.9084 49.8185
Fenol 2.9513 19.1304

Hallar 〗 y _2⁡ 〗
ln⁡〖� _1⁡ln⁡〖� con el modelo indicado
ln�_1=𝐵�_2^2 𝑙��_2⁡⁡=𝐵�_1^2

�_1 ln⁡〖� _1=𝐵�_ ln⁡〖� _2=𝐵�_

0 2^2⁡ 〗 1^2⁡ 〗
-2.1000 0.0000
0.1 -1.7010 -0.0210
0.2 -1.3440 -0.0840
0.3 -1.0290 -0.1890
0.4 -0.7560 -0.3360
0.5 -0.5250 -0.5250
0.6 -0.3360 -0.7560
0.7 -0.1890 -1.0290
0.8 -0.0840 -1.3440
0.9 -0.0210 -1.7010
1 0.0000 -2.1000

�_1 �_1 �_2 � �

0 0.1225 1.0000 19.1304 0.0000
0.1 0.1825 0.9792 17.7688 0.0512
0.2 0.2608 0.9194 16.6698 0.1559
0.3 0.3574 0.8278 16.4261 0.3252
0.4 0.4695 0.7146 17.5593 0.5329
0.5 0.5916 0.5916 20.3935 0.7225
0.6 0.7146 0.4695 24.9539 0.8560
0.7 0.8278 0.3574 30.9183 0.9337
0.8 0.9194 0.2608 37.6416 0.9735
0.9 0.9792 0.1825 44.2540 0.9921
 1 1.0000 0.1225 49.8185 1.0000

60

50

40

30 P-x1
P-y1

20

10

0
0 0.2 0.4 0.6 0.8 1