auR-2 CODE (4 PAPER-2 PART |: PHYSICS SECTION — 1 : (One or more options correct Type) US 1: (WH aT afte wel fAaer TET) This section contains 8 multiple choice questions. Each question has four choices A), (B), (C) and (D) out of which ONE or MORE are correct. wa avs F 8 agtoos wea & | yale vet 4 are fewer (A), (8), (C) sik (0) &, RF Rue a aftr wet | 4. Using the expression 2d sin @= A, one calculates the values of d by measuring the corresponding angles 0 in the range 0 to 90°. The wavelength 2 is exactly known and the error in 6 is constant for all values of @. As @ increases from 0°, (A) the absolute error in d remains constant. (8) the absolute error in d increases. c (0) AAG 2d sin O= AT SHAM SI ET FAO PANY Bd! AM VAT aed = | ov AMO a90° } aa FS | aT ef GT a ew Rye: oa fa am 4 gfe, a & wh arte fer wart & 1 SA 0 oA 0° Gaga e aa (A) a4 farter afe Rem vedt & | (8) dF feta afe aedt & | (c), a4 fencer aft Ree edt & 1 (0) d¥ fener gfe vedt & | the fractional error in d remains constant. the fractional error in d decreases. ANSWER: D2. PHYSICS Two non-conducting spheres of radii R, and Ry and carrying uniform volume charge densities +p and -p, respectively, are placed such that they partially overlap, as shown in the figure. At all points in the overlapping region, (A)_ the electrostatic field is zero. (B) the electrostatic potential is constant. ©) (0) the electrostatic field is constant in magnitude. the electrostatic field has same direction. al Haas R, WR, Poa Te Tiel Fl WA: +p F-p WHAM SAGA STAT wa 8 orate fear mae | ga el w faa 4 cate ogee gu ver as ax war 7a 8 fh a sire wo S aftwreag | afttanea aa & ute fag we (A) fer aga da yee | (8) fer aga fara arax & | (c) fer aga aa ar Ram ara & (D) Rew aga aa a fee He z | ANSWER : CDThe figure below shows the variation of specific heat capacity (C) of a solid as a function of temperature (7). The temperature is increased continuously from 0 to 500 K at a constant rate. Ignoring any volume change, the following statement(s) is (are) correct to a reasonable approximation. (A) the rate at which heat is absorbed in the range 0-100 K varies linearly with temperature 7. (8) heat absorbed in increasing the temperature from 0-100 K is less than the heat required for increasing the temperature from 400-500 K. (C) there is no change in the rate of heat absorption in the range 400-500 K. (D) the rate of heat absorption increases in the range 200-300 K. 100 200 300» 400-« S00 T(K) fara 4 fart che af fate Ger enftar (C) or aH (TR Feat a} cefar Tar & | aaa 40 S500 K ae GAM ex B ead Ger et S| aM ae fe arn 4 oRad teria & Pet waert A al ar @ chert ame wet BH 7 (A) 0-100K® aa, saeifta Gon ot ax ATA ox See onan rare | (B) 0-100 K a TIAA BF asi ux sraehfka GIT, 400-500 K TAM & ate TEM Ft GoM Gt gern F waz | (C) saifta Ber a ex 400-500 K aA & ata agRafia & | (D) GT saRisT St Sx 200-300 K AU & ala ag VATE ANSWER : ABCD or BCD The radius of the orbit of an electron in a Hydrogen-like atom is 4.5 ao, where ap is the , 3h Bohr radius. Its orbital angular momentum is 5. It is given that / is Planck constant and R is Rydberg constant. The possible wavelength(s), when the atom de-excites, is (are) Wh QUAM RAN] & eagHA Ge DY AGA 4.5 ay GET ay AR Pron s | ae sega or aay ave wn He | fear & fern cotie Praia aR Reet Praia & | wary & apf eh a woafora faferor & atareef ah eereny & 9 9 9 4 A) 32R 8) Ter () sR (0) 3R ANSWER : ACPHYSICS Two bodies, each of mass M, are kept fixed with a separation 21. A particle of mass ‘mis projected from the midpoint of the line joining their centres, perpendicular to the line. The gravitational constant is G. The correct statement(s) is (are) (A) The minimum initial velocity of the mass m to escape the gravitational field of the two bodies is 4 ae (8) The minimum initial velocity of the mass m to escape the gravitational field of the two bodies is 2 ~\ ae (C) The minimum initial velocity of the mass m to escape the gravitational field of the two bodies is ~\ 2G. (0) The energy of the mass m remains constant. @ fist fre mete or cere, & ata ot Ql of 27 Ree ven Ta es | ST fist & ai a sist arch ter & meq fg Owe m Fe BI OM araae vafta fee orn | yecaeter Paaie Ge | wel weer & (8) (a) 2 fist & qecret as 8 var & fey 22, the magnetic field is non-zero. Wer Bien & shia ae Ghee aerw sort at clas A uw Re oRT/ aE TEAS | Se ter of 2R Broa a oria ofeaferer & ara wre war we | ee uftaferar Fon ade ute gos wag Fe a vw Rex ane | we ese s fay vt ere Or Gl we 8, St aT) THT HATE (A) O2R4, Gaata aa ype es | ANSWER : ADPHYSICS Two vehicles, each moving with speed u on the same horizontal straight road, are approaching each other. Wind blows along the road with velocity w. One of these vehicles blows a whistle of frequency f|. An observer in the other vehicle hears the frequency of the whistle to be 3. The speed of sound in still air is V. The correct statement(s) is (are) (A) Ifthe wind blows from the observer to the source, fs> fi (8) Ifthe wind blows from the source to the observer, fi> fi. (C) Ifthe wind blows from observer to the source, fa fil (c) af arg der 8 cia ot fee A aed e A (C) BR (D) 2BR ANSWER: B 10. The change in the magnetic dipole moment associated with the orbit, at the end of the time interval of the magnetic field change, is fora wera oma Yo qaate as 4 okads et ver @ we one & art 4, omer ar Y ater Yaaita ays amet a aha BOR BOR? (a) ~7BoR @ AE @ AS eo rer ANSWER : BParagraph for Questions 11 and 12 wet 11 sie 12 & fay aq The mass of a nucleus 3 Xs less than the sum of the masses of (4-Z) number of neutrons and Z number of protons in the nucleus. The energy equivalent to the corresponding mass difference is known as the binding energy of the nucleus. A heavy nucleus of mass Mcan break into two light nuclei of masses m, and m only if (m; +m) < M. Also two light nuclei of masses m; and m, can undergo complete fusion and form a heavy nucleus of mass M’ only if (m3 + m,) > M'. The masses of some neutral atoms are given in the table below: we afte 4.x wT OM (4-2) AE wd Zee & gear & ae Bow eer z | Soar HH ott & wager Gol a dea Got wed & | ve Ra MT AN ae m, Va m, FAA & A were aPret A frees et Tear B, ale (m+ m) M' | HS TEATS & ga Ay caer FI was: ‘a | 1007825u [77 [2.014102" [%y [3.016050 | %He | 4.002603 u Sri [6015123 u [727 [7.016004 | MZ_ | 69.925325u | se | 81.916709u | Ga 151.9198030 Pb 205.974455 u Bi 208.980388 u BoPo 209.982876 u (Lu = 932 MeVic") 11. The correct statement is (A) The nucleus $Zi can emit an alpha particle. (B) The nucleus 3,°Po can emit a proton. (C) Deuteron and alpha particle can undergo complete fusion. (D) The nuclei 3)Zn and $4Se can undergo complete fusion. wel weer & (A) aiPre SLi var Yoo oy Grafs SY WHAT F | (B) afar SP var Weis Seaford BY WHAT ze | (C) Sayers aie Vert wor yet teas ax Ted S| (0) =UPra {32m va afta Sse yor Morey SK Wad S | ANSWER : C 12. The kinetic energy (in keV) of the alpha particle, when the nucleus 3,°Po at rest undergoes alpha decay, is oa farmraen 4 anftre 2°Po terres oan &, da tem oo wt ar waif (keV ¥) atch & (A) 5319 (B) 5422 (C) 3707 (0) 5818 ANSWER: AParagraph for Questions 13 and 14 weT 13 oie 14 & fay ores ‘A small block of mass 1 kg is released from rest at the top of a rough track. The track is a circular arc of radius 40 m. The block slides along the track without toppling and a frictional force acts on it in the direction opposite to the instantaneous velocity. The work done in overcoming the friction up to the point Q, as shown in the figure below, is 150 J. (Take the acceleration due to gravity, g = 10 m s~’). We wa WT & Gea gS WH 1 ese & Yew oF ferraen vls1 ora s | ae 1 40 m Broa or Gia ag S| Year oer vey wx fen qs EY USA g | ST yea we yw aio got creas a a faeta feen A aren F | fara A eats ope, fey ove a & fag ator a after oe & fay soy orf oem sa z | (Tees ANT g GT APT = 10 ms cfSTy), 13. The speed of the block when it reaches the point Q is Ua Jeo fg ou wea @, gaat ofa & (A) Sms (B) 10 ms" (C) 10f3ms? (0) 20 mst ANSWER: B 14, The magnitude of the normal reaction that acts on the block at the point Q is FZ OW, Jeo we aM ae afieia ga oT ORATT (A) 7.5 (8) 86N (C) 115N (D) 225N ANSWER: AParagraph for Questions 15 and 16 Wer 15 sie 16 & fare aq A thermal power plant produces electric power of 600 kW at 4000 V, which is to be transported to a place 20 km away from the power plant for consumers’ usage. It can be transported either directly with a cable of large current carrying capacity or by using a combination of step-up and step-down transformers at the two ends. The drawback of the direct transmission is the large energy dissipation. In the method using transformers, the dissipation is much smaller. In this method, a step-up transformer is used at the plant side so that the current is reduced to a smaller value. At the consumers’ end, a step-down transformer is used to supply power to the consumers at the specified lower voltage. It is reasonable to assume that the power cable is purely resistive and the transformers are ideal with a power factor unity. Alll the currents and voltages mentioned are rms values. We anita faea tis 600 KW at erfeet 4000 Ve BRATS, B20 km HT EO unin & soar & fey a ort ort | seer a a Gea aT aera ae ofa 8 Fo oT wear & a at feel we seat a omar geewre or wah fen oT wear & | yeaa der ar che ae & fH gel Gal wr ae aga aiftw ene vate gear & wrath & ate 4 as aga oa alr 8 | ga ae A va sear graerk daa a atk ena oar & fread RT oT A wa a TE | oT & RR 4 agar sear or var fear ora & Pree oral a ve fats oF dee & fage wea & oT ae | ae ArT on wed @ fe Sa Ye ofan & ae RRP sree € a Grer aler qoie va & | vleefea weed neil g deecnsil Br A ms aT AS | 15. If the direct transmission method with a cable of resistance 0.4 Q km! is used, the power dissipation (in %) during transmission is ate Wa Seer wr Soe fsa org frereer of 0.4 Oko! S Ta eet THT BT Rerfe Fo erfter ata (% HF (A) 20 (B) 30 (C) 40 (D) 50 ANSWER : B 46. In the method using the transformers, assume that the ratio of the number of turns in the primary to that in the secondary in the step-up transformer is 1 : 10. If the power to the consumers has to be supplied at 200 /, the ratio of the number of turns in the primary to that in the secondary in the step-down transformer is SraGrR & war fat 4, ae ari fe sear geaerh & mettre a fedtae 4 adel ot ten or agua: 10% | afe fea wea, oortesil ot 200 VR St aT & ct oterA gMBAR A rere g fedtaw & adel a een or aga = (A) 200:1 (B) 150:1 (C) 100:1 (0) 50:1 ANSWER: ASECTION — 3 : (Matching List Type) ws —3: (aor Eh wa) This section contains 4 multiple choice questions. Each question has matching lists. The codes for the lists have choices (A), (B), (C) and (D) out of which ONLY ONE is correct. we ws 4 4 aghtmed ued & | uete oer 4 Gor Ee @ | Ufeal & fer ats & faerer (A), (B), (C) ak (D) & for S daar ya Ae | 17. Match List I with List II and select the correct answer using the codes given below the lists : List 1 Boltzmann constant Coefficient of viscosity Planck constant Thermal conductivity Beppe List If P. Q R s. a8 8 GAS ee gfe A er aa P. deca Pracie Q Ma pie R. wie Pate S. BST aera Codes : (A) (8) (c) (D) RROD Q 1 2 2 1 Neen® woken Beye win (Mer) (ML"T7} [MLT?K*} (Me-T*K") ANSWER : C18. A right angled prism of refractive index ,, is placed in a rectangular block of refractive index 42, which is surrounded by a medium of refractive index 44, as shown in the figure. A ray of light ‘e’ enters the rectangular block at normal incidence. Depending upon the relationships between j1,, 4 and 14, it takes one of the four possible paths ‘ef’, ‘eg’, ‘eh’ or ‘ei’. Ww py, WIE & THT or Py, sada & sacar ware y Tar Tae | wel aren y, sade & are & fers 4 caty ongene feet es S| vere at fern ‘e’ sao aia ux afrciaaa safes el S| yy, wy BR wy AT Ww Prix at eg were at foro ae ta weil ef, ‘eg’, ‘eh’ A ei FU WH AA BI Match the paths in List I with conditions of refractive indices in List II and select the correct preteen the codes given below the lists: aaa fet Ol Eh a saadsie at wel S yAfera afore sie |feat Soak ee ae List 1/ et List 0 / at Pp eof 1 y>V2 wy Q erg 2. fy> My and/T4 py > Ly R. eoh 3. = hh 8. ei 4 ays iy <2 panded py > py Codes : QR s a) 2 3 1 4 ®) 1 2 4 3 (4 1 2 3 ()2 3 4 1 ANSWER : DPHYSICS 19. Match List I of the nuclear processes with List II containing parent nucleus and one of the end products of each process and then select the correct answer using the codes given below the lists : Aa Go arate aires mE SL EAT es aarail Bera ayer a we sifrr aPrata as fey ag F | yfeal & Are fea ae ats wT vad He wal SR BATT List 1 / itt List 11/ at 11 P. Alpha decay 1 PO>PNE A... worry “ 238. 23404 Q Bi decay 2. GPU Gg Tht we Barr Fagen 3. 4g Bia ay P+. freer S. Proton emission 4 Py ota wer sant Codes : P QRs (A) 4 2 1 3 ®) 1 3 2 4 (2 1 4 3 ()4 3 2 1 ANSWER : C20. One mole of a monatomic ideal gas is taken along two cyclic processes ESF+G—E and E-F—+H-—E as shown in the PV diagram. The processes involved are purely isochoric, isobaric, isothermal or adiabatic. We Teanga sneei te a va ata a, faa ¥ aah pv ota & agar a amt wT EF-G—E FEF HE A & oa oe & | Walaa HA Yaa: erode, aad, wraha a wats F | P 32Pp Vo v Match the paths in List I with the magnitudes of the work done in List II and select the correct answer using the codes given below the lists. 14 fed 7a el or yy fed wa orf & oR & eer wafer wry afral & te fea wa ots oT vehT ae we oa a | List 1/ eft List 1/ at P. GoE 1. 160 PpVoIn2 Q GH 2. 36 PoVo R. FoH 3. 24P Vo S. FOG 4. 31 PoVo Codes : P QRS a) 4 3 2 1 ®) 4 3 1 2 (C3 1 2 4 (2) 1 3 2 4 ANSWER: APART Il : CHEMISTRY SECTION - 1 : (One or more options correct Type) Qs 1: (Har flmeu ware) This section contains 8 multiple choice questions. Each question has four choices (A), (B), (C) and (D) out of which ONE or MORE are correct. . . su wes 4 8 aghtacd wer & | uelw wer A are famed (A), (B), (C) ah (0) @, Rr a we a sift wel & | 21. 22, The correct statement(s) about O is(are) (A) 0-0 bond lengths are equal. (B) Thermal decomposition of O, is endothermic. (C)_ O,is diamagnetic in nature. (0) 0, has a bent structure. 0, % Gad F wa gata FH (A) 0-0 are @ cag aeTae & | (8) 0, oT ade fete Gersih F | (C) 0, wfergaaia & | (D) 0, #1 teen afer ett F | ANSWER : ACD In the nuclear transmutation § Be +X ——> {Be +¥ (X, Y) is(are) (A) (7) (B) (p,D) (C) @, dD) (0) (wp) Prfettaa aiPreta acateeer {Be +X ——> ‘Be+y¥ F(X) ee (A) (n) (B) (p,D) (C) (n, D) (D) (p) ANSWER : AB23. 24, CHEMISTRY The carbon-based reduction method is NOT used for the extraction of (A) tin from SnO, (8) iron from Fe,0; (C) aluminium from ALO, (D) magnesium from MgCO, : CaCO, Set & Prin Fo ares sos FAR at er Pry set ae Re 2 (A) Sn0, & fer (B) Fe,0, 8 SRA (C) 41,0, 8 Yaffe (D) MgCO,Caco,& AAR ANSWER : CD The thermal dissociation equilibrium of CaCO,(s) is studied under different conditions. CaCOxs) == Ca0(s)+ CO(g) For this equilibrium, the correct statement(s) is(are) (A) AHis dependent on T (8) Kis independent of the initial amount of CaCO, (C) Kis dependent on the pressure of CO, at a given T (0) AHis independent of the catalyst, if any CaCO, GR) & asia ferer a ween or ser far arent 4 feat 7a | CaCOXs) <= Ca0(s)+ COAg) eH Urea & fer, wel seers & (@) (A) AH TTA Ww Pr aa e | (8) wenn fers (kK) Caco, & RPE oA UK Prk vet xa B | (Cc) K fraa ar We CO, & ara wy fre aa F | (0) av sae Bre a) & ma w Pie et oa z | ANSWER : ABD25. 26. CHEMISTRY The K,, of Ag,CrO, is 1.1 x 10-1? at 298 K. The solubility (in mol/L) of Ag,CrO, in a 0.1 M AgNO, solution is (A) 1.1% 10-1! (B) 1.1 10-10 (C) 1.1 10-2 (D) 1.1% 10° K,, (Ag,CrO,) 1 APT 298 KR 1.1 x 10-? & 10.1 M AgNO, & fae H Ag,CrO, @ facta Areieher Fz (A) 1.1 «107! (B) 11x10! (C) Lax 10-2 — (D) 11 «109 ANSWER: B In the following reaction, the product(s) formed is(are) Pefetad sfiica o seorerscret wr any OH CHCl, OH CH. oH ° oH OH “iy QO Q on CHy Hse! CHCl, Hac! CHo!, CHs P Q R s (A) P (major) (B) Q (minor) (C)_ R (minor) (D) 5 (major) Pe) acim Rte Sq) ANSWER : BD27. The major product(s) of the following reaction is(are) oH aqueous Br, (3.C equivalents) 2 SO3k OH OH OH OH Br. Br Br. Br Be Br Br Br Br Br SO3H Br Br SO3H P Q R Ss (A) P ®) @ (C) R (02) Ss Prafettaa aftfira oa yer sure Be) oH ‘ache Bro(3.0 Gera) 2 SOx OH OH OH OH Br. Br Br. Br ‘Br Br Br ‘Br Br Br SO3H Br er SoH P Q R Ss (A) P ®) @ () Rk ©) s ANSWER : BCHEMISTRY 28. After completion of the reactions (I and Il), the organic compound(s) in the reaction mixtures is(are) Teme sftifrnst (ik 0) We eh & ae werafie fem A oda aire caifral) or ae | a Br (1.0 mol) Reaction 1: Hyc7 cH), ———————— Gir: (1 Omol) aqueous! ory NaH 9 Bra (1.0 mol) Reaction II : nso ScHy a PRT TE: (4.0 mot) CH3COOH 9 9 °O nye? Scyer nyc, ayc7 Bry Ee ORcnen HC P Q R s T u (A) Reaction I: P and Reaction II: P (8) Reaction I: U, acetone and Reaction II : Q, acetone (C) Reaction I: T, U, acetone and Reaction II: P (D) Reaction I: R, acetone and Reaction II : $, acetone (A) afifiear 1: pote oftifirer i: P (8) aftfimari: u, wher atk aftifiear mm: @, Wiel (c) aftfar i: 7, u, wher sik afar i: P (0) afiirar i: Rr, wes six after 1: s, wftels "ONa_ CHBr3 ANSWER : CCHEMISTRY SECTION - 2 : (Paragraph Type) WS — 2: (PGE VSR) This section contains 4 paragraphs each describing theory, experiment, data etc. Eight questions relate to four paragraphs with two questions on each paragraph. Each question of a paragraph has only one correct answer among the four choices Ay (B), (G)and (OD! H Rraidl, Wari shy sitesi ante wl eet act 4 Lary, qs Vata ano ney 2 ior 9 gv ares oy el oe FI Wh agede A ak oer & ay famed (A), (B), (C) she (D) & fSrrt B dact yw wet S| Paragraph for Questions 29 and 30 Wea 29 Ud 30 & fed argewe A fixed mass ‘m' of a gas is subjected to transformation of states from K to L to M to Nand back to K as shown in the figure w Sart ‘mot seen oa KW LS MN oem are K A fers are frag 1g & Pressure aa Volume oqracst 29. The succeeding operations that enable this transformation of states are (A) Heating, cooling, heating, cooling (B) Cooling, heating, cooling, heating (C)_ Heating, cooling, cooling, heating (0) Cooling, heating, heating, cooling Re GY 7 sreren uRadai Y were ae (A) 74, Ser, 1H, Sst OR WR (8) Sor, 74, dsr, TH aR Ww (Cc) Wi, és, os, TH aM we (0) 331, 7H, 1H, Sor oe we ANSWER : C 30. The pair of isochoric processes among the transformation of states is (A) KtoLandLtoM (8) LtoMandNtoK (C) Lto Mand M to N (D) MtoNandNtoK orren uRada at Refeat ¥ wasraattay oar ore (A) KYLAR LAM (8) LUM@RNGK (c) LUM3ieMAN (0D) MaNGR NUK ANSWER :BCHEMISTRY Paragraph for Questions 31 and 32 WET 31 Yd 32 The reactions of Cl, gas with cold-dilute and hot-concentrated NaOH in water give sodium salts of two (different) oxoacids of chlorine, P and Q, respectively. The Cl, gas reacts with SO, gas, in presence of charcoal, to give a product R. R reacts with white phosphorus to give a compound S. On hydrolysis, S' gives an oxoacid of phosphorus, 7. Cl, te wy ott Bix NaOH & ae fae ERI WAT: SS sie ww ore ation ax a (fie) aits & siaed-era & aifsar aa, Pale g az | Cl, (g) Roa BH ake A SO, (g) 8 aififwar ge Gre R Fas | Ras ORERG ant sififrar ox afte s eae | Sa ver-smTes fra ORERE FT we srrdisra Tele | |. Pand Q, respectively, are the sodium salts of (A) hypochlorus and chloric acids (B) hypochlorus and chlorus acids (C)_chloric and perchloric acids (D) chloric and hypochiorus acids Pak o mae: sth Uisaa wag (A) ergdtaciee afi aeiar are (8) egdaeie sik aaa sre (Cc) wiRe sik wae ora (0) Fie sik eetlaciea oat ANSWER: A ._R, Sand T, respectively, are (A) SO,Cl,, PCl, and H;PO, (8) SO,Cl,, PCI, and HPO, (C) SOCl,, PCl, and H,PO, (0) SOCI,, PCI, and H,PO, RS THA: S (A) SO,Cl,, PCI, 3 H,PO, (B) SO,Cl,, PCI, 3 HyPO, (C) SOCI, PCI, 3X HPO, (D) SOCI,, PCI, si HPO, ANSWER: A33. 34, CHEMISTRY Paragraph for Questions 33 and 34 wed 33 Ud 34 & fed ee An aqueous solution of a mixture of two inorganic salts, when treated with dilute HC!, gave a precipitate (P) and a filtrate (Q). The precipitate P was found to dissolve in hot water. The filtrate (Q) remained unchanged, when treated with H,S in a dilute mineral acid medium. However, it gave a precipitate (R) with HS in an ammoniacal medium. The precipitate R gave a coloured solution (S), when treated with H,0, in an aqueous NaOH medium. O serétrr cath & ye Prt or crete freer Ty HC! Sra ERT STAT GT We sae (P) aie ye fege (Q) tm ze | sraeko Pw Ga A gerefta & | firege (Q) ay Gta sreita area 4 H,8 an fatar oe aRafia vem 2, fory waist ser A v5 & wey sadly (R) Sar F | sa RS UT Teta NaOH AE Fa HO, 1 afin GA fara (S) SAF | The precipitate P contains (A) Pb (8) Hg,°* (C) Ag (0) Hg* sada PH safterd & (A) Pb (8) Hg,” (C) Ag (0) He ANSWER: A The coloured solution S contains (A) Fe,(SO,) (8) Cuso, (C) ZnSO, (0) Na,Cro, Or fier s 4 softer & (A) Fe,(SO,); (B) CuSO, (C) ZnSO, (0) Na,CrO, ANSWER : D35. CHEMISTRY Paragraphs for Questions 35 and 36 wer 35 Ud 36 & ford apes P and @Q are isomers of dicarboxylic acid C,H,O,. Both decolorize Br, /H,O. On heating, P forms the cyclic anhydride. Upon treatment with dilute alkaline KMnO,, P as well as Q could produce one or more than one from S, T and U. Pak Ov sepraifrater ara CHO, & a wraedt F | at Br,/H,0 FT we oa & | i ae Ww PU Weg TT | ay aN KMnO, ERT PSR Q ser-srem afta SX va sera va SB ofa aif §, Tarra U aT Wed E | COOH COOH COOH H++oH = HoH ~— HOH H--OH = HO--H HOH COOH COOH COOH Ss T U Compounds formed from P and @ are, respectively (A) Optically active $ and optically active pair (7, U) (B) Optically inactive $ and optically inactive pair (T, U) (C) Optically active pair (7, U) and optically active S (D) Optically inactive pair (7, U) and optically inactive S Pak Qari HF afte wag, & (A) gar whe sud gar yo BPH (7, UV) (8) yan fifi s vd gern fafSea ge (7, U) (C) gam yet a4 (7, L) wd gan le S (D) aur fafa arr (7, U) Td qa Pa S ANSWER : B36. In the following reaction sequences V and W are, respectively Prafatad afiien ogeat 4, vote wara: & HIN a oy CQ. ee, 2. HsPO, ° (A) Ce andiste CO vo we CH,0H ®) and/aie "CH,OH v Ww ; © mm BO vo Ww oY, weer COL ‘CH2OH yotnod W A ANSWER: A CHEMISTRY(CHEMISTRY SECTION - 3 : (Matching List Type) ws —3: qaet Eh ver) This section contains 4 multiple choice questions. Each question has matching lists. The codes for the lists have choices (A), (B), (C) and (D) out of which ONLY ONE is correct. se urs 4 4 agtecr mer é | gee oer Yas ue & | fel @ fee ors & faePea (A), (B), (C) site (0) & fort B act vw BETS | 37. Match the chemical conversions in List I with the appropriate reagents in List IT and select the correct answer using the code given below the lists : aaa at 7a cate eoiet oT atu a fey wa woe afta err gfe Sify ger Yel & Ae faq wy als wr veer Se Tel GER gD List I AGH 1 List ART P. a — = 1. @Hg(OAc),; (ti) NaBH, Q@ one —— oe 2. NaOEt Rr Cr — Oo 3. Ee Br s (Cr — on 4. @ BHy: (ii) H)O,/NaOH “OH = n RENO BRoow -H aan ANSWER: A(chemistry) 38. The unbalanced chemical reactions given in List I show missing reagent or condition (2) which are provided in List I. Match List I with List II and select the correct answer using the code given below the lists : ah 4 fattaa onightta afitrenst 4 smefita aftariooreny etn ¥ et 1s S11 B18 Wiss Hy en Eat oe yw ws wT are wel Gea BP List 1 Ait 1 List IT AR ti 2 P. PbO, + HySO, —> PbSO, + O, + other product ara sere 1. NO 2 Q Na,S,0, + HjO —> NaHSO, + other productara sere Ro NH, > Ny, + other products Sear 3. Warm] S. xeF, 2e xe + other producvarst wane 4. Ch Codes : P QRs @~ 42 3 1 ®3 2 1 4 © 1 4 2 3 03 4 21 ANSWER: DCHEMISTRY, 39, The standard reduction potential data at 25 °C is given below. are arena fart 25°C ux Prefefad & E° (Fe, Fer) = + 0.77 V; E° (Fe, Fe) =-0.44V E°(Cu*, Cu) = + 0.34 V; E°(Cu’, Cu) = + 0.52 V E°[O,(@) + 4H* + 4e~ > 2HO] = +1.23 V; E°[0,(g)+2H,O+ 4e~ > 40H] = + 0.40 V E°(Cr, Cr) =~ 0.74 V; E°(CP*, Cr) =-0.91V Match E° of the redox pair in List I with the values given in List II and select the correct answer using the code given below the lists : wet 14 fed 7a torr FH a En 4 fea 7A aera fra SY Pea wifory den afeet & Ae fed wa ats oT yar ad wel GaN GPA : List AGT 1 List ART P. E°(Fe™, Fe) 1 0.184 Q. E°(4H,0 == 4H" + 40H) 2. -04V R E°(Cu* + Cu >2Cu*) 3. -0.04V S. E°(Cr*, CP) 4. -0.83V Codes : P QRs (A) 4 1 2 3 () 2 3 4 21 (c) 1 2 3 4 (02) 3 4 1 2 ANSWER: DCHEMISTRY | 40. An aqueous solution of X is added slowly to an aqueous solution of Y as shown in List !. The variation in conductivity of these reactions is given in List II. Match List I with List II and select the correct answer using the code given below the lists : List I List 1 P.(C;Hs)N + CHyCOOH 1. Conductivity decreases and then 7 increases Q.KI(0.1M) + AgNO; (0.01M) 2. Conductivity decreases and then _ es does not change much R. CH;COOH + KOH 3. Conductivity increases and then e . does not change much S.NaOH + HI 4. Conductivity does not change much Se and then increases X® vel ers 4 wre: Y or vel ear PA set Gra 8, ORY YAN fear ren & | es aftipasil 8 cert aera at fer Et A dt age | Ga or Et nS GPfera wifey cen |feat w Ae fed wa ars oT yarT Gea wel SAR BP wit win P. (C)Hs);N +CH;COOH 1, Tem ved & sik aoa ast & | x Y Q.KI(0.IM) + AgNO (0.01M) 2. waea vedt & sik ava afte x Y fate ae eh R. CH;COOH + KOH 3. mea ast & ae cea afte x Y uftafea et ett | S.NaOH + HI 4. arerem afte oRafia ae ett site x oY aera ash F | Codes : P QR Ss a3 4 2 1 ®)4 3 21 c)2 3 4 1 (0) 1 4 3 2 ANSWER: ASa UN ten) SECTION — 1 : (One or more options correct Type) ews —1: (tH aT after wel framed aT) This section contains 8 multiple choice questions. Each question has four choices (A), (8), (C) and (D) out of which ONE or MORE are correct. aa ws 4 e aghtoor wea & | ete wer A ae favor (A), (B), (C) sik (0) &, forvt SO Ww ar afte wel & | a4. 42. tet = BEL ana p= fut n= 1, 2,3, ...}. Further H; frec: Rez>3| and Hy= fe € C:Rez<}, where Cis the set of all complex numbers. Ifz, ¢ PO H,, 2, € POH, and O represents the origin, then Zz, Oz, x x 2n Sn A > (8) 6 c) > (2) B +i art f& w= 7 TM P= {win =1,2,3,. see afar A, free: Rez>3} er 1, = frec:Rez<> uel cuPas densi) oT wyea & | aft z, < PAM, 2, ¢ POH, eH O Feterg ves orm z, Ta 2£2,02,= 2x 5x (a) 5 @ = © = 0) = ANSWER : CD If3*=4"", then x= 2 log, 2 2 1 2 og, 3 ) Flog, 2-1 (©) y70g,3 (©) To10g,3 =) Ziog, 3-1 aie = 4, ga x= 2 log, 2 2 1 2 log, 3 ) Fieg,2-1 (8) y7H0g,3 (©) T=T08,3 () Jog, 3-1 ANSWER : ABCMATHEMATICS, 43. Let w be a complex cube root of unity with @ + | and P = [py] be an x n matrix with p,= of. Then P? #0, when n= (A) 57 (B) 55 (C) 58 (D) 56 go OT Yo iis GY o chfer, Get w+ 1 TM P= [p)] VP nxn HS SA, FET p= | aa, Pe 0, Fd n= (A) 57 (B) 55 (C) 58 (D) 56 ANSWER : BCD 44, The function f(x) =2|x|+|x+2|—||x+2|-2 ||| has a local minimum or a local maximum at x = 2 2 (A) 2 8) > (Cc) 2 0) 5 wel f(x) = Bix] [e+ 2] | ]x42[—2 [x 1 Ge RIMa ET aT Ge eI sifteds Rr x & A We, dee 2 2 (A) -2 8) > (c) 2 (0) 5 ANSWER : AB 45. Fora R (the set of all real numbers), a #—1, lim 18+2¢+...+n9 —i no (n+ 1)! [(na + 1) + (nat 2)+...+(na+n)] 60 Then a= -15 =17 (A) 5 (8) 7 () > 2) > ac RAH arate tenet 1 WEA), a 4-1, fay lim 17+ 2%+... nf ai n> (n+ 1)*! [(na + 1) +(na+2)+...+(na+n)] 60 Waa= -1s x17 (A) 5 (B) 7 (Cc) > (0) > ANSWER: B46. 47. 48. MATHEMATICS Circle(s) touching x — axis at a distance 3 from the origin and having an intercept of length 21/7 on y — axis is (are) (A) x2 +y?~6x+ 8y+9=0 (B) P+y-6x+7y+9=0 (C) x +y?-6r-8y+9=0 (D) +y?-6x-7y+9=0 xo BT eg V3 Ge oe weet HA Te (ATA) TM y— oer Oe 2V7 sas FAM TENA) TIF (A) e+ y-6r+ By+9=0 (8) P+y-6xt+ Ty +9=0 (C) 2 +y'-6x~8y+9=0 (0) P+y-6r—7y+9=0 ANSWER : AC Two lines L, :x=5,72— = 2 = 54 are coplanar. Then a can ‘3-a@ 2-4. take value(s) (A) 1 (B) 2 (C) 3 (0) 4 tame £295,575 = Sam Lyx saz 2S wacha & | aa oor AT SO awea @ 1 (@) 2 (Cc) 3 (0) 4 ANSWER : AD In a triangle POR, P is the largest angle and cos P = >. Further the incircle of the triangle touches the sides PQ, OR and RP at N, L and M respectively, such that the lengths of PN, QL and RM are consecutive even integers. Then possible length(s) of the side(s) of the triangle is (are) (A) 16 (8) 18 (C) 24 (0) 22 Bp POR, 4 P ger aro & ae cos P=t Lge afatar Bry or sitar Apnsil PO, OR TM RP BT HA: N, LWA MUX Fe Tee wast Hea & fey PN, OL Ta RM Oca ArT TH DRRENE F | da By a ys AMM) FH waned orang (raga) F (A) 16 (B) 18 (C) 24 (D) 22 ANSWER : BDMATHEMATICS SECTION - 2 : (Paragraph Type) WS — 2: (HPOST VHT) This section contains 4 paragraphs each describing theory, experiment, data etc. Eight questions relate to four paragraphs with two questions on each paragraph. Each question of a paragraph has only one correct answer among the four choices (A), (B), (C) and (0). ga avs 4 ftagidl, vant six siiost anfe o call arel 4 arqede & | ani ayqedal U daftta one wes @, firrt 8 ex orqede oy a) oer & | foe A orqede A ex oer & a fared (A), (8), (C) aR (D)E for O dae yw ewe | Paragraph for Questions 49 and 50 wer 49 Ud 50 & fa awe Let = 8,9 5,0 Sy, where ini<4}, = frec: inf, of ona S,= {2 C:Rez>0}. AM f& S=5, 5,08, Het S,= (ze C:|2/<4}, rec inl AE ob S,={zeC:Rez>0}j. . 49. Area of S: So saya = 10, 202 16, 32. a os e > © 3" ANSWER : B z= 24.8 3-\3 348 ®) 2ea8 (©) ah (0) a8 ANSWER : CMATHEMATICS Paragraph for Questions 51 and 52 wet 51 Ud 52 & feet qe A box B, contains 1 white ball, 3 red balls and 2 black balls. Another box 2, contains 2 white balls, 3 red balls and 4 black balls. A third box B, contains 3 white balls, 4 red balls and 5 black balls. we 8d) B, A 1 wide Ve, 3 ore He cen 2 wreft HE S | aH Gent Vt B, FH 2 ae We, 3 cre He cen 4 wre He S| uw chet Ae wv, A 3 wee Ae, 4 cre Fe cer Soret Fe 1 51. 52. If 1 ball is drawn from each of the boxes B,, B, and B,, the probability that all 3 drawn balls are of the same colour is ufe dfeai 2, B, den B, A wee @ 1 Ae arch ont @, aa Pore ae ait 3 tel & ww Go eM Ht oem zs : 0 & © ay © oe o ANSWER: A If 2 balls are drawn (without replacement) from a randomly selected box and one of the balls is white and the other ball is red, the probability that these 2 balls are drawn from box B, is aft 24% yo agkew gata ta 8 (fen wf & Pract ort & ae ve te ube a gal te ora Reoodt & aa g 2 acl at AS B, a Poe HH wife & 116 126 35 65 A) Ter ®) Tsr () ter (0) igr ANSWER : D53. MATHEMATICS Paragraph for Questions 53 and 54 Wea 53 Wd 54 & ford ogee Let f: {0, 1] + R (the set of all real numbers) be a function. Suppose the function is twice differentiable, f (0) = f(1) = 0 and satisfies f"(x) — 2f'(x) + f(x) 2 e*, x € [0, 1}. ard ff: (0, J oR OR arate eal or ayer vo werd F | aA aifoRy We fA AK saHHAS B, £(0) =f (1) = 0 FM f"(w) - f+ f@) ze x € [0, 1] wl UGe ora F | Which of the following is true for 0se), 00 7 Res | x+a,a>0. 2 Length of chord ?Q is Siar PO a wang F (A) 7a (B) Sa (C) 2a (D) 3a ANSWER: B If chord PQ subtends an angle @at the vertex of y” = dax, then tan 0= ‘af offal PQ, y= 4ax & eff we wer o siafta wedt & aa tan o= a vi Ow ofS 0) FV5 ANSWER : DMATHEMATICS | SECTION -— 3 : (Matching list Type) ws —3: (het Eh va) This section contains 4 multiple choice questions. Each question has matching lists. The codes for the lists have choices (A), (B), (C) and (D) out of which ONLY ONE is correct. wa as 4 4 agftwor wed & | ote oer A yA Ue @ | afer & fag ats fapet (A), (B), (C) te (0) & Brel S dae vw wa | 57. Aline L: y = mx +3 meets y — axis at £(0, 3) and the arc of the parabola y* ~ 16x, 0 (& ( tay cot (si 1 5 nf Q. A cosx+ cos y+ cosz=0=sinxt siny + sinz TA 2 2 cos > wor wetter AFT e 1 R Af oo 4) cos 2x + sin xsi 2x sec x= cos x sin 2x sec x a eof +3) cos 2x TA secx 1 PENI AM S. Af cor (sin ft =x Daas (x/6)).x#0, a aa x or wanted AP Codes : P QR s ay 4 3 1 2 (BR) 4 3 2 1 (3 4 2 1 ()3 4 1 2 ANSWER : BMATHEMATICS +3 ==> and the planes 59. Consider the lines L, : Pi: Tx+y+2z=3, Py: 3x + Sy - 62 = 4, Let ax + by + cz = d be the equation of the plane passing through the point of intersection of lines Z, and L,, and perpendicular to planes P, and P,. Match List ~I with List—II and select the correct answer using the code given below the lists : Pane L,: 253 oon waa P,: Int y+22=3, Py 23x+Sy—62=4 CS | APT fH ax + by + ez=d, TaN L, FL, & Wes ferg O TORY Ten cen Wada P, TP, & Haas, Waa GT wT z | eS ae a ei List It RE TT 1 13 2 3 31 Ss. 4 2 Codes : P QRS a) 3 2 4 1 ®) 1 3 4 2 (3 2 1 4 ()2 4 1 3 ANSWER : AMATHEMATICS 60. Maich List ~I with List —II and select the correct answer using the code given below the lists : List-1 List — 11 P. Volume of parallelepiped determined by vectors @, B and @is2. 1. 100 Then the volume of the parallelepiped determined by vectors 2(@ x b), 3 (B x @) and (é x ais Q Volume of parallelepiped determined by vectors @, b and Zis 5. 2.30 Then the volume of the parallelepiped determined by vectors 3(@ +b), (b + 2) and A(é * d)is R. Area of,a triangle with adjacent sides determined by vectors 3. 24 @ and B is 20. Then the area of the triangle with adjacent sides determined by vectors (24 + 35) and (4 — b)is S. Area of a parallelogram with adjacent sides determined by 4. 60 vectors d and b is 30. Then the area of the parallelogram with adjacent sides determined by vectors (a+ ) and @ is wet -1 ae) yt — 1S BAfera ary aay Geel & Aa fey ay als wT FAT wey WE SAT BA: aati a puree 2, B aen 2 are Pulte waiae sewer or ona 2 1100 & 1 aa ufos 22 « B), 38 x 2) aan (@ « @) ant Patter wa Vesa Gi aI F 2. 30 Ques 2,6 car 2 art Palka waiex sewer oT sae 5B | aa ules 3 (@ +b), (B + 2) wen Ae + @) ERI Praia waar yeas wr aad & R.ve Sym or eotwa, fora vers yout weet Geen Bart 3 24 fruit 8, 20 8 | aa wes dg + 3B) aan (@ - B) art Prafita tert yorsii arel Bryst or eames & SUH wai age oT dare Pra) vers yoy weal Geen 4. 60 b ant Puta € 30 € | aa alee +b) ce a aT feifta wert yoni get wale afar wt aaa F Codes R Ss (A) 4 2 RG () 2 3 1 4 (3 4 1 2 1 4 3 2 ANSWER: C