Tagitador 21.

4 C factor termop+agit
Ttermopar 21.3 C

g
g
g

Replica ud I II III
m calorimetro g 834 834 833
m calorimetro + 250mL(F) g 1087 1085 1085
m calorimetro + 250mL(F) + 250mL(C) g 1339 1337 1338
mf (agua) g 253 251 252
mc (agua) g 252 252 253
Tinicial (solo agua fria) ºC 20.6 20.3 20.4
Tagua caliente ºC 51 50 51.4
Tfinal (mezcla) ºC 36.2 35.7 35.7
∆t-fria ºC 15.6 15.4 15.3
∆t-caliente ºC -14.8 -14.3 -15.7
∆t-calorimetro ºC 15.6 15.4 15.3
c-w J/(gK) 4.181 4.181 5.181
Ccalorimetro J/(gK) 0.070 0.085 -0.047
c gande J/K 58.212 71.077 -39.450
gr agua 13.923 17.000 -7.614
-58.212 -71.077 39.450
 0.1

Replica ud I II III
m calorimetro g 833 833 832
m calorimetro + 250mL(F) g 982 982 984
C calorimetro J/K 64.6446923 64.6446923 64.6446923
mf (agua) g 149 149 152
m_aluminio g 121.26 121.26 121.26
Tinicial (solo agua fria) ºC 21.4 22.5 21.2
Taluminio ºC 97.3 97.3 97.3
Tfinal ºC 30.5 31.9 30.2
∆t-fria ºC 9.1 9.4 9
∆t-aluminio ºC -66.8 -65.4 -67.1
∆t-calorimetro ºC 9.1 9.4 9
promedios
0.036 0.072505494 J/(gK) 0.77248825 0.8150365 0.77445764
64.645 9.0966567758
7.770 13.4114200383
-29.946 60.4423944047
 Réplica
ud I II III
m calorimetro g 833 833 832
m calorimetro + 250mL(F) g 982 982 984
C calorimetro J/K 41.381638 41.381638 41.381638

Réplica
ud I II III
mf (agua) g 149 149 152
mAl g 121.26 121.26 121.26

Réplica
ud I II III
Tinicial (solo agua fria) ºC 21.4 22.5 21.2
Taluminio ºC 97.3 97.3 97.3
Tfinal ºC 30.5 31.9 30.2

Réplica
ud I II III Media Desv. Std
CAl J/(mol*K) 20.137 21.246 20.201 20.528 0.623
CAl J/(gK) 0.746 0.787 0.749 0.761 0.023
 Réplica
ud I II III
m calorimetro g 833 833 832
m calorimetro + 150mL(F) g 982 982 984

mAl g 121.26

Réplica
ud I II III
mf (agua) g 149 149 152
mAl g 121.26 121.26 121.26
Tinicial (solo agua fria) ºC 21.4 22.5 21.2
Taluminio ºC 97.3 97.3 97.3
Tfinal ºC 30.5 31.9 30.2
CAl J/(mol*K) 20.137 21.246 20.201
CAl J/(gK) 0.746 0.787 0.749

ud Media Desv. Std

CAl J/(mol*K) 20.528 0.623
CAl J/(gK) 0.761 0.023
 Réplica
ud I II III
m calorimetro g 834 834 833
m calorimetro + 250mL(F) g 1087 1085 1085
m calorimetro + 250mL(F) + 250mL(C) g 1339 1337 1338
mf (agua) g 253 251 252
mc (agua) g 252 252 253

Réplica
ud I II III
∆t-fria ºC 15.6 15 15.9
∆t-caliente ºC -14.8 -14.7 -15.1
∆t-calorímetro ºC 15.6 15 15.9

Réplica
ud I II III Promedio
Ccalorimetro J/K 58.212 16.891 49.041 41.382
ccalorimetro J/(gK) 0.070 0.020 0.059 0.050
K g agua 13.923 4.040 11.730 9.898

Réplica
ud I II III
Tinicial (solo agua fria) ºC 20.6 20.3 20.4
Tagua caliente ºC 51 50 51.4
Tfinal (mezcla) ºC 36.2 35.3 36.3
Desviación std
21.699
0.026
5.190
neutralizacion

Replica ud I II III
m calorimetro 837.00 837.00 837.00
m calorimetro + 150mL(naoh) 993.00 994.00 995.00
m calorimetro + 150mL(naoh) + 150mL(hcl) 1147.00 1147.00 1149.00
Tnaoh 26.70 26.50 26.20
Thcl 22.40 22.40 22.40
Tfinal 31.00 30.90 31.10
Ti 24.55 24.45 24.30
m w naoh 154.00 153.00 154.00
m w hcl 156.00 157.00 158.00
mw 310.00 310.00 312.00
cw 4.18 4.18 4.18
Ccal 64.64 64.64 64.64
moles 0.15 0.15 0.15
∆rH J/mol 56992.6478 57365.1488 60454.5033
∆rH KJ/mo56.9926478 57.3651488 60.4545033
descomposicion

Replica ud I II III
m calorimetro 837 837 837
m calorimetro + 250mL() 1092 1093 1093
m calorimetro + 250mL(naoh) + 50mL(fe(no3)3) 1142 1144 1144
Th2o2 22.4 23.4 23.7
Tfe 22.5 23.2 23
Ti 22.4163934 23.3673203 23.5856209
Tf 36.5 37.4 37.1
m 250 255 256 256
m 50 50 50 50
mw 305 306 306
n 0.20604 0.206848 0.206848
Ccal 64.6446923 64.6446923 64.6446923
∆rH J/mol 91583.7503 76818.3869 73526.1703
∆rH KJ/mol 91.5837503 76.8183869 73.5261703
M(h2o2) 0.808 mol/L

23.1231115
 Replica Réplica T(NaOH) T(HCl)
ud I II III 1 26.7 22.4
m1 g 837 837 837 2 26.5 22.4
m2 g 993 994 995 3 26.2 22.4
m3 g 1147 1147 1149

sosa

Replica Réplica T(H2O2) T(Fe(NO3)3)

ud I II III 1 22.4 22.5
m1 g 837 837 837 2 23.4 23.2
m2 g 1092 1093 1093 3 23.7 23.0
m3 g 1142 1144 1144

oxigenada
Tf Moles ∆rH (KJ/mol)
31.0 0.154 59.542 60.872
30.9 0.153 59.931
31.1 0.154 63.143

desviacion Z N
1.9758447709 1.96 3

+- IC (95%)
3.1074512985

Tf Moles ∆rH (KJ/mol)

36.5 0.206 95.745
37.4 0.207 80.939
37.1 0.207 77.470

desviacion Z N
9.7059541325 1.96 3

+- IC (95%)
10.83756066
Ccal J/K 64.6446923 Magua 18
Cw Jg/K 4.181

E1-15 E2-20 E3-30 E4-45

m calorimetro g 839 839 839 839
m calorimetro + 250mL(AGUA) g 1086 1086 1085 1086
m calorimetro + 250mL(agua) + XmL(etanol) g 1098 1101 1108 1121
To-etanol C 26.1 26.5 26.3 26.3
To-agua C 25.2 25.7 25.6 25.8
Tfinal C 27.6 28.3 29.3 30.8
m agua g 247 247 246 247
m etanol g 12 15 23 35
m total g 259 262 269 282
∆t etanol C 1.5 1.8 3 4.5
∆t agua C 2.4 2.6 3.7 5
∆t-cal C 2.4 2.6 3.7 5
moles agua mol 13.7222222 13.7222222 13.6666667 13.7222222
moles etanol mol 0.26086957 0.32608696 0.5 0.76086957
moles totales mol 13.9830918 14.0483092 14.1666667 14.4830918
fraccion molar etanol adim 0.01865607 0.02321183 0.03529412 0.05253502
∆Hmez (H-H*) J -2708.9021 -2966.0014 -4333.2206 -6145.266
∆HsolHb J/mol -10384.125 -9095.7376 -8666.4411 -8076.6353
∆Hmez/n J/mol -193.72697 -211.12871 -305.87439 -424.30622
 Metanol 46

E5-65 E6-85 0
0.01 0.02 0.03 0.04 0.05 0.06 0.07 0.08 0.09 0.1
839 839
1086 1085 -100
1136 1150 f(x) = - 5876.9489599031x - 91.4023062679
-200
26.4 26.4 R² = 0.9886422952
25.8 25.6
-300
32 32.6
247 246 ∆Hmez -400
50 65
297 311 -500
5.6 6.2
6.2 7 -600
6.2 7
13.7222222 13.6666667 -700

1.08695652 1.41304348 Xb
14.8091787 15.0797101
0.07339749 0.09370495
-7974.2605 -9337.1378
-7336.3197 -6607.8206
0
-538.46743 -619.1855 0.01 0.02 0.03 0.04 0.05 0.06 0.07 0.08 0.09 0.1

-2000

-4000
∆HsolHb

-6000
f(x) = 43142.7395756638x - 10495.303589586
R² = 0.9125733074
-8000

-10000

-12000
Xb
.07 0.08 0.09 0.1
-5876.949 -91.402306 Calor diferencial B -5968.3513
314.954356 17.7515506 Calor diferencial A -91.402306
0.9886423 20.84083

07 0.08 0.09 0.1 2801.66359 -10391.371 ∆HsolHb_INFINITO -10391.3708150332

451.064364 376.554306
0.90605775 457.974929
38.5793526 4
8091673.37 838964.142
 ud E1-15 E2-20
m calorimetro g 839 839
m calorimetro + 250mL(agua) g 1086 1086
m calorimetro + 250mL(agua) + XmL(etanol) g 1098 1101

ud E1-15 E2-20
m agua g 247.00 247.00
m etanol g 12.00 15.00
moles agua mol 13.72 13.72
moles etanol mol 0.26 0.33
moles totales mol 13.98 14.05
fraccion molar etanol adim 0.019 0.023

ud E1-15 E2-20
To-etanol ºC 26.1 26.5
To-agua ºC 25.2 25.7
Tfinal ºC 27.6 28.3
∆Hmez J -2708.9 -2966.0
∆HsolHb KJ/mol -10.384 -9.096
∆Hmez/n KJ/mol -0.194 -0.211
E3-30 E4-45 E5-65 E6-85
839 839 839 839
1085 1086 1086 1085
1108 1121 1136 1150

E3-30 E4-45 E5-65 E6-85

246.00 247.00 247.00 246.00
23.00 35.00 50.00 65.00
13.67 13.72 13.72 13.67
0.50 0.76 1.09 1.41
14.17 14.48 14.81 15.08
0.035 0.053 0.073 0.094

E3-30 E4-45 E5-65 E6-85

26.3 26.3 26.4 26.4
25.6 25.8 25.8 25.6
29.3 30.8 32 32.6
-4333.2 -6145.3 -7974.3 -9337.1
-8.666 -8.077 -7.336 -6.608
-0.306 -0.424 -0.538 -0.619
 R 8.314472

mmHg Pa
P_eb P_eb T lnP 1/T
268.3 35770.39053 73.2
284.2 37890.21613 76.1 10.5424482 0.0131406
321.2 42823.14364 79.6 10.664834 0.01256281
329 43863.05809 80.2 10.6888277 0.01246883
406.4 54182.20914 83.3 10.9001079 0.0120048
421 56128.71567 85.6 10.9354028 0.01168224
516.9 68914.33047 89.9 11.1406194 0.01112347
527.9 70380.87648 90.4 11.1616769 0.01106195
627.1 83606.45509 94.8 11.333876 0.01054852
654.1 87206.15895 95.9 11.3760302 0.01042753
716.7 95552.139 98.3 11.4674273 0.01017294

11.6

11.4 f(x) = - 319.7270353206x +

R² = 0.9940911794
11.2

11

10.8

10.6

10.4

10.2

10
0.01 0.0105 0.011 0
 Chart Title
800

700 f(x) = 12.5324629558 exp( 0.0412373175 x )

R² = 0.9934199914
600

500

400

300

200

100

0
65 70 75 80 85 90 95 100

Chart Title
11.6
-319.72704 14.7041791
11.4 f(x) = - 319.7270353206x + 14.7041790916
R² = 0.9940911794 8.71508561 0.1007395
11.2 0.99409118 0.02642601
11 1345.9081 8

10.8

10.6

10.4

10.2

10
0.01 0.0105 0.011 0.0115 0.012 0.0125 0.013 0.0135
75 x )

0 95 100

incrH/R -319.72704
IincrH_vapo -2658.3615