JEE PREPARATORY TEST (JPT-5) (JEE MAIN PATTERN) TARGET : JEE (MAIN+ADVANCED) 2014 DATE : 23-03-2014 COURSE : JP, JF, JR, JCC, ER, EP, EF HINTS & SOLUTIONS (a@a va eal) A Resonence Educating for better tomorrow Hindi, arn she yet ge a ert Bre ree PART-A MATHEMATICS, Let, number of people who like only cricket = n(C) rhumer of people who like only tennis = nT) 244 10+124+14+ x4 7 > ae e y= 88 > xty=t4 umber af people who ke bth tennis and ercket=NC--T) 0 n(@)240=n(eT) Se, n(C)=40-10=90 5 HBP a Pye 65 =0 en) +n (C7) nen) = 25 Ba aon dra Prke tee wet aa a aio =) wean a re = 1 oo alee eee eae = Dre 100+ 144+ 196 +32 + ¥%) 04 Ben ar Bg we aT A He =n(C 07) 7 n(@)=40-n(eaT) =16 sy (¢)=40-10=30 = Mees yh=7 x00 65=90 en) +n (C7) = dey t00 w nen) = 25, 2 2 we PePeQey?-ay 2 Genes a prime < 10 ny. xin @ ett <10 x= £2,3,5,7) Observe the truth table of p> @ R= (KH) x= 2,3,5,7) p> qa wom sre we fae wR = U2, 8) (8, 27), (6,125), (7,343) 3. Let and y be the remaining two observations, then Pur puaye=po~epu@ Ca = Cpr a@in~ Pe lPn=do~P Bea MONIZ E14 x 7 Let be the angle between the lines represented by sexe y= 66 art PHS gre GeReia anal F mer wie Ft = oxtyeta , : > variance =16 0 + Dey see 0 +yF=0 4 “ = Leese ite utes yy- — - fae 2y{(h? - ab) 6 a+b 1 — Ieatt = A aet6 + 100+ 144+ 196 +12 +04 tenge GORD 7 ’ 2 “1 6 ss 420 por iaieaes Hence the ange between he Ines represented by (1) 80. = keh at00 “ aa: (are vaftia Rais F mea wie os) Now _ PR Resonence SOLIPTSMAIN250314-1 —ax9-12 Equation of chord AB is 2x + By = 2(x 2) - By +3) + 1220 7. Radius of circl ‘0 a axe 720 om -42)+7 eyfadentys i220 4 wi 4 vis 4 1 winal, ger ah Brom = JEFO=TD = 1 fiat AB wt sneer 2 2x + By = 2(x = 2) = Bly + 3) +1220 b+ 34 16=0 w By (8) NN Resonsnce — AQ SSR Sine SOLIPTSMAIN250314.2 —Hina, aren Re A a STEN SN aT a Pe I 7 ato wh re aero or A Pe coe foe ae 1 ray ner Para eS 2 Pas ty2os 6 = 1-Poe=0}208 = 1-"C, PPI =P 208 = 2s 2023 (cosectag (11 1 < cos x< 1) } or (sin ~ sin?3x) + (ein?2x ~ sin?aw eee al a | = sin 2k [sinax + sinéx] = 0 > sin?x anK e = 2sinax sin Sx cos beowcet = sms or sinsk = 0 . or oe > 4 _ 16. ox ) (1996 )*" 4996 \ f{_).( 2) are sumatroa = f[ —— + 4], (7306) (1996 Hence 3 solutions ( 997.) | / 998.) { 999.) (4996 ) *'( 41996 ) “'( 1996 ) 20. (TVA A-T oT @ VF)AFST (1995) of 988 Paret (4996 : 998 1 a. t= (1996 } \2) Cleary, f(0) an f(-2) are not defined STEN: (0) se 2) RT HB AT. Required ways tite aah = (@t-1)(2—1) = 560 eee ‘Fafbe f HT = RYO, -2) 18. Suppose the coins tossed n times. Let x be numberof eee manne heads obtained, then x follows @ binomial citibuton . oa ge ora wih parameter n& P= x- 2 yan > yet 2yex=1 x wehave Pers 1) 208 = 1-Px=0)208 an ype 2H = 1-0, P91 PP 208 1-x tL f(x) _ 2d-x)4+2x4+4 3 ax (= xF (1=xF - DRResonense SOLIPTSMAIN2305143BARR Rud? 28, In (@ option, Domain of fans. is same OC and fi) = 900 aRb;2—bisdivisible by®. (@Rb;a—b, 98 Pentre fret (6), gmt AIT eoTeT E he te) = 90 eao02+% a. par Pee%2+0 “ae” ae xis multiple of 3 and range is also muttiple of 3. ae x 321 7H 8 en ae A FH ED (ten ate? RFF, PAGE, oe C3, C/E 0%, ae 1, 3%), 6, 640", 9%), 1 12, 3), 12, 6), (12, 9%), + . V2 Let zextly 2 SEMEL KD# HP KEE Z+4_ (x44) +iy eee SR FHC, 2.90% soo 2z+i 2x+i(2y+1) 7 . =i 2 (x44) +iy Beit} ee eet 1 vn. n 2x+i(2y+1)) | 2x-i(2y +1) enemas t J 2 2 ne (244), 2xx+4)+yl2y+1)_ 1 (224i) P+ Qy +P = Re Be Pe yes r geet say = 16x+2y=1+4y = 2y=16x-1 28, . ‘which represents equation of straight ine wea a & whore wh ore aT v-o( A. f2)#0,12-0}"1-120,12+0)=0-020 lax] f-2)=0,-2-0)=0-1=-1 = eis cominuous atx = 2 but nota of degra two, (ret 2 ca &) fo), x= 208 wa 8 eg x22 aE 20, fa? etc? ab be ca) +a? 1-204 b+ 1-2 +ert—-2020 28. Coetteent of varation= SD. . 400 7 AM = (a= by + (b- oF + (e~ a)? + (a t+ b-1Fse-1F=0 =am=—__8D._, 409 bevisenn Coeff. of variation = a - Wf nos, ate equal & non-zero, they are both in AP. & CAM = 5100295 er. fg seen) a aT aL aA wR a PNR (2AM. = eet aint 4 er | ~ UN Besonence SOLIPTSMAIN23051444NBA Pare 37. Sensitivity of(@) 8, = eure) \When shunts connected in paral, senstvty vil be 31. tary of input A and B is 2eo, then the code cones (=) 2 } So. vith that input wl be in forward bias, So wil behave the & CAR. +8) 100 shot eeu, so output wil be 260. ifbath A an input are 1 (+5 vt then any ofthe code wi A not conduct eurent R,+S 100” 999 £01080 pa, across the resistor IR Oso output votage wil be +5 vol (high) aR ARB AS fh AA ame eu fw arte ara rem (a) 3h guia s, Ae fxg orm eh ay ore ae gue eer oH mer wen 8 Fatty Per oa ee wa we wore A gsr & quan ah aR AaB eri arm 1 (65 aice) 8 ww aE oA arts NBA coe ae | c )( ae | oat aftr ow a Fore a ety / IR—> ORR Fria fad +5 ice (sem) 81 eee) 32, During postive oyele soe wil be in forard bias i wil act lke @ shot ekcut. So AV across the code wil be zero. But BB Act Age t2 cling negative cycle of input, the dade wil bein reverse Aon An 4 bias, So twill act ike an open etc, $0, Voupu® Vag ees corer oc aap ater ahs oem eh et ate ae (65 A Ags 8 ET Ay #4) rete tae at ae ard wt) ae: ahs aT AV 3 oT) ats oma & sone ae Seem ahs m= An 4 - 50% eq SRA A amy oat ae ga aoe A aE CRETE Ae 8 RT| BABE Vege * Vent Frequency of side bands are (2 f,) coed tre A argh dehy & x8. 1000 =f, = 908 Ke 1000 fy = 1002 KH faa ke 438, Compare gen eg with standard modulates wave Rea ao(19K2)_ 4p Ft) =e + Ay Sn Ot) sin ct Ra KO A modulation index w= A™ = 0.6 Wane = (40) W)ag = 40 # 10 mV = 400 mv Ae @on§ whem ah mae sigh wen wh Te 36. For detection of ight caret gH oh Fe) x = maw hoe, 1 = c+ Ay sn Ont) sin Oct 1240. = 400 a atev>ey igen germ us OT = 08 ~ UN Besonence SOLIPTSMAIN230514.540, 19MSD= 20 VSD Msp tc- MSD 20 cL MSD = Le «20 (025 « 20 mt Sm a Displacement ofthe body in 2 second is (22ers # neq my Rei) 11 oe s=0+ 3445 (2% =1m par Work done =F (va en ard J s=3e1=3y) M 42. For activity, check MY forall fe carina ME atin 48, Loss in PE, = AU= math —h) (Reataa Sai Hah Al 1th h) ) 49, Net displacement = 0 (a freer Total distance = OP + PA + 00 (RT gf = OP + PA'+Q0) (1 ext 4 ST km 3.57km 40/60hour +i}km = 21.42km/hr 55, 57. 60. PVS® = constant Pera (PV) V28 = constant PF icomnt# OC off] Aso + 100°C (steam) Rete of heat given by steam = Rate of heat taken by ice am & am fag gon as 3 a Ae oT dQ _ KA(100 dt eM) mM at ’ at K 1000.36 _ 4.8«3.36x10° Ot 60x60 K=1.24Jimis"C 270 cael = miPtdg r= 2 dg Natural requency of pendom (2) is equa othe fering frequency. isin resonant constons Soits amplitude maximum rer) op ag oe arg a sre orate aren #81 ete ET a if am) Statement-1 ie True.Statement-2 is True; Statement2 is @ correct explanation for Statement-4 vemnete we 8, eRe we fy wR eR opr a aioe 6 Statement-1 js True Statement2 ie True; Stetement2 is [NOT a correct explanation for tatement-1 ae eB, wa. ea BAZ TATA ioe at NN Resonsnce — AQ SSR Sine SOLIPTSMAIN250316.6,61. PART-C CHEMISTRY A 8 a ° 0 ax x from graph at time = 30 min 20 min fh = ax For 1 order reaction Kt= 2,303 | Ro = 2308109 Rh Keo = 002310 mi" A> 8 a ° sare @ a= 30 mini t= 2.202 0g le Ri (30) «2.208 og —9 “ aiz k= 0.02310 min” «2, 63, 64, roast in air cus > Cu:0 + 50; roast without air cus + 20150 > 6cu+ SO; 3 sft cus TEA, cu,0+50, cus + 204,0 BEA aT A HHI, goys s0, (On increasing temperature, chemisorption fistly Increase then decrease rors 8 yf er ora shoo oR GT t em 8) (1) 8+ HNO, (cone) —+ H,80, + NO: +2H.0 © + 4HINOs (Cone) —+ 4NO2 + 24:0 + 003 2° + 1OHNOs (¢one:) —> 2H:PO, + 10NO +240 e+ 1OHNOs (cone) —+ 2HI0s + 10ND, + 44:0 (2) (HPOs)s is cyclovimetaphosphoric acid and oxidation slate of Pis +5. F @) Xe0,F, (see-saw) F F (4) XeF (near), FE 1 ws . (1) $+ BHNO, (=FE)—> H,S0, +6NO; + 24,0 + 4H1NO, (HF) —> 4NO; + 24,0 + COs 2° + OHNO, (HE) —» 2HPO, + 10ND, + 24,0 n+ 1OHNOs (arm) —> 2HIOs + 10NO; + 44:0 NN Resonsnce BS ESISSIFG Gr tete tomorow SOLIPTSMAIN250314.7 —(2) (HPOs)s arrergirerateaten sme & cen ete aA attettares semen +5 tet 1 & xeOFe-sgR) (a) Ket atm iy Ger of ‘ Electrolysis of concentrated aqueous solution of NaCl gives Hp at cathode, Cl; at anode and NaOH is formed. oH Increases due te the formation of NaOH. ‘enfira eta Nacl farm fega seme 8 chee RH, ete we Ch dar B NAOH THe B1 NAOH Fai core pH meh 81 2g + Big to 77 0 os: Aten. 05 3015 For every unit rise in the concentration of C, there will be three-fold rise in concentration of D. [O)=15*3+05=5M Py + Biy SE Cy + Bey 0022 0 05. Ategm 05 30 18 (or ah orem * sft amd ofa foe Dot orem Hm apf gfe er [O]=15*3+05=5M or. 70. INH,CI (Gat + NH.OH (weak base) = Bosie Suter ‘CH.COOH (weak acs) + CH:COONa sat = Aide Butter NACN (4 miimole) and HCI 2 mitimole)on reaction give 2 mllmole of HCN (weak acid) and 2 mimo of NACN (sat) ate let which acts as acide bute. NNH,OI GIN + NHLOH (gis = eee aR CH.COOH (Gat EH + CH.COONa ra = sna ae NaCN (4 frefehay a HOI (2 rah Prat ae 2 Frcs far 8 a HON (aa 2 Pct de we oA ot oT are ee oof wef) ‘The size of hydrated species of alka metal ions decreases: down the group. Therefore, the correct decreasing order of ‘ze ofthese hydrated ions is [LH O)A" > KCHLOM > [O5(H-ODT antes erg sre a ah hat a ore ah A oe Hee 81 Fe eM reefer rah eb seme a ‘eth raed) aon [HOT > KHOI > [C5(H:0} Due to inet pair effect TI is more stable. in soa a eee Tr es weg eB) A= cep = (comers + face centres) B= oct, voids = (Edge ~ centres + body centre) passes a — a= (seinen) + (aecooues:*)-2 o- (onecates:t) sone Simplest formu AB R:221:0), IN Resonsnce SOLIPTSMAIN250314-8A=ccp ee) a= wenaata Raa = GR -de +o Fe) Shaded plane P8208 through aR & tan oe ama oe (camara aA RR FRM, (CHyAN = OF sf af ee 8) (2) em ers a TEM, (SIH NH ae By (2) XeFs Xe, 3a ER YH eT Ne TT con) ait PH wd 8 sae MT XeF A 9 eT 2 Maton aid Carbon subonide hte a artreastengs 75. ‘Maximum work of expansion wl be done in reaction in which WHA GSB 2:21: increase In volume is greater. ‘ae tren see Fy er ard et Fe rere 1 493 a aie ott ett 7. 72. Allow, High T Fore) n nana, |= 26 tractive forces = Almost negligible For(@)n=2andp=08,i= 1-6 + fn,i=08 VVanderwall equation Idea! gas equation For (a) fret Poem To BPonnn = BP sven? Ty and Se {orate soliton molanty MT fr (@)=1.8* KO. sesalelnlod Uni Rxaas for (0) =26 *K,0.2* 052K for(6)*06~K,02*012K 74, (1) Dus o absence of dora (CH) = O dosst exist. LC Se LS order of aT, 8 (0> d>9>0), SOB Pane(d> d>2>6) (2) Due to back bonding (SiH) is less basic. silly FP josey * FP sour and Te Ken (9) lm XeF> Xe has 3 one pairs and each F atom has 3 lone order of AT; is (b> ¢> a >c), SOF Pasvin > 3> 420) pairs lone pais in compound XeF> wil be 9. smi rescue (a) =ICRT OOH order of (b> a> a>0) mH ho Large the number of moles of solute, lesser wil be vapour ‘COOH pressure of soltion Malone acid carbon suboxie eer ~ UN Besonence SOLIPTSMAIN230514.9m 78. (@% Pun=sae=02, (> feyn=Sama=04,i= (o fu n= 2p =08, (9% Fea=o,i= BP soi ® BP. sonet + ATe Wen ate iki cg for & fg sem = ston (0) Fae aT, = 18 «Ke 0.1 =0.18 Ky a fae a 16 «K0.2= 052 K (0) FFU AT,= 06» K02=0.12Ke (9% fay ATV 1 KO4= 040K AT, THB (D>d> 970), TEBP pe (D> d>a>e) FAL TTT FP tn) = FP een ATH and ate ken ATV HB (D>d>a>0), AHF Preay (er a> d>b) [RTERTT En) SICRT nm BH Bs (D>d>a>c) fda a atch A sor Fert afte Soh, fore er are ‘em sen @ on em) ‘ai at (¢>a>d>b). {Wy Only le form wit be optically active (i) One trans and two cis isomers will be formed. (wy sera weer eos anf eT S| (oy We foo ger Serres ere aA Ionization enthalpy increases on moving trom Ie to right ‘across the period a the size decreases and decreases on moving top to bottom in 8 group as the size increases. Ne has the maximum value of LE, since tis a noble gas. So, the ‘correct order of increasing fst ionization enthalpy is K < Na < OF , oe Beckman Rearrangement TE.) (i) KOH, a (iy? ‘COOH NH, “The enol content offketo aldehyde is very high because of conjugation & intramolecular hydrogen bonding pact vemes a Gis ae EU aT ome oT arash aa oe BR ST aH 81 oN (CHg)¢-CH-CHO > t t 1 ene ey oH, IN Resonsnce SOLJPTSMAIN250314-10 —nd 9 or ae “ , 1 1 to, to, 86, Since ~CH:O"is a strong base so they can undergo E2 reaction C-H bond fs weaker than C-D bond acho ow a a 81 galt Te EZ Shion oor if C4 sie, C-D ae a gor gia erat 81 Non polar > Complete octate > apposite charge > same charge (-ve and lone pair) spf > new i> fits ster > A ste (ve ae vor ecg, oH Cy” 0.7? os, Kind. PhMgBr OH Ho. 7 HO” a eine Cold. alk. Ph KMnO, ‘OH ‘OH oH CY KMind, Ph PhMgBr oH H,SO, | aatogea| Saari Ph Ph ost erga, ‘OH KMino, ‘OH ‘The reagents NH. / KOH will not interfere reduce) C= © and—OH groups onthe DC = © evn wl be reduced to DH, soup, in clonmenson eductonC # ¢- 8 O8 wil also react N:He KOH aiftente C = C cen - OH Bag wT arated ae men 8 a fr DC=0 mE mt LCH, TE A anata ae aon 8) fever ara Ac = C -aen- OH gE AN APY sh aA 8 ” NN Resonsnce — AQ SSR Sine SOLJPTSMAIN250314-11 —PN Resonance JEE PREPARATORY TEST (JPT-5) Edueating for better tomorrow (JEE MAIN PATTERN) TARGET : JEE (MAIN+ADVANCED) 2014 DATE : 23-03-2014 COURSE : JP, JF, JR, JCC, ER, EP, EF ANSWER KEY CODE_0, 4 ib = (t=O) GO) Gt) O- -@) 44-6) a ) Oe Oh tT 0) 19 20 ete) 2 (1) 23), Ht) 2. 1) 3) Ht) 8), HHL) 3.) 87.) 8) HY, Ht) 4.) 4) BL) Ba) BH) 50. @ «51. (3) 52 (4). (1) BA.) 55H. 57 (1) 58H (1). HQ). 64. 3) 65.) 8G), 4), 1) 7, m1. @ «72 @) 73%) 4) 7H) HL) 7H). 7. (1) 7% «© 8) 8). 85. (1) 868.) 87.2) 8B. (4) 8.4) 80.4) — DR Bes onen se ecteratncststete