“Twinning Engineering Programmes (TEP) & nmasat English Programme of Engineering (TEPE) Faculty of Engineering, «University Thai “Thamona: ‘Undergraduate Examination 29 Semester of 2011 (Final) SC 173 Fundamental Chemisty ‘All Sections Date 23 April 2012 Time: 9.00 ~ 12.00 Coordinator: Suksit Tantrawong, Name Roanuanes 1Dno._____ Seat no.__ Instructions = 1. The test contains 50 questions, percentages. Before doing the test, make sure that you have got.all the problems X on the answer sheet, in the box corresponding to your answer. Remember identification number (ID), and seat number clearly on your 9 pages (this page inclusive), forthe total of 30 2. Write an to print your name, answer sheets. Scientific calculator is not allowed. No program in any form may be taken into the examination room. Also, calculators with facilities for storing and retrieving text, graphical calculators, personal 1s, dictionaries, thesauruses and computer are not allowed. organi: 5, Other communicating devices such as mobile phones, pagers, textbooks, short notes and relevant material, etc., are not brought into the test room. 6. Please hand in swer sheet separately. WARNING Cheating is a serious misconduct! . Stiff penalty will be imposed to a cheater. Before entering the examination room, make stire that you do not to bring any disallowable. materials into the examination room, intentionally or unintentionally. If proctors have found. them in your occupation, you will be seriously punished by suspending your study for one ear and receiving a Fail) grade in this subj ject. 2g) vybox of the best answer in the answer sheet dium carbonate (substance:A) and catcit, solution of B were prepared and the uit iy, 2.00 rere Ths Instruction: Put an X in the : Fic ratio in whi trie the stoieiometre aii ies u Msolution of A an¢ oo meet as shown in the ble BIO - 88 ~ 2 20.0 3 \390 : (40.0 j *50.0 a - 60.0 \ 70.0 ' f ; 80.0 / oD ; 90.0 ~ How many the following items are correct? ie ; V IY Stoichiometric ratio for thie reactions YX > 2) Maximum amount of precipitate occurs between experiment no, 3 and 4% V \ (3) Amount of precipitate increases from experiment no. | to experiment no. 6 ”X 2 4) Amount of precipitate decreases from experiment no. 4 to experiment no. 9x is the limiting agent from experiment no. 7 to experiment naD/ Bsiems — / | -B) Substance 7 Bites ©. items dSitems | D 2. Suppose the equimolar concentrations of solutions D and E were mixed at various amounts by keeping the {otal volume constant. The result was obtained as shown in the graph below. What is the balanced chemical equation for this reaction? i i ey 7 2 g | J z | + e | I d L ~ 10 20 30 4 30 @ 10 80 90 100 Z Votume of SoletionDYmL) . a Dean £2600) ~ Fe) b.2D (ag) + E (ag) + F(s) _ © D(a) + 3E (ag) —» F(s) 4.3D (cg) + E (ag) — F(s) ‘Which one of the following choices isfores) for the experiment of stoichiometric determinations? ‘made to the nearest 0.01 mL. frre yminture should be immediately filtered ater mixing. > ‘cannot use to determife the stoichiometric ratio of the reactions 4. The method of continuous variations With no precipitate, . XY v (2) All eadings of the burets shoul 7K. lel each cite offiter paper should be weighed the renee OO, J er coool¥ : — ‘4. Which one of the following choice isncorrest for|filtering and drying precipitates? 7 i A stirring rod can be a guide for running the solution into the glass funnel. / Vv A stream of distilled water from the wash bottle can be tsed to help the transfer of precipitate. Gyre glass funnel should be filled more than approximately half-full at a time. > -¢___ 4 Awwatch glass containing the filter papers was transferred to the 110.°C oven. ‘S"What apparatus is not used in the experiment of stoichiometric determinations? a. Beaker . Cylinder ¢. Glass funnel J. Stirring rod — Y6, Which of the following’cations reacts with aqueous potassium dichromate (K2CrO4) to produce a yellow precipitate? Ag b. Hey" » oN Pb” d_ Both Ag’ and Pb" J, Which of the following result can be observed when mixing ammonia with HgClo? a. black precipitate b. white precipitate = . yellow precipitate 4d. none of correct answer _ eee 'B? Which of the following cations can be ‘precipitated in the presence of aqueous'potassium iodide (KI), be Hes d. Both Ag’ and Pb?" . . 9! Ifyou had got a mixed solid sample of PbCh and AgCl in your test tube, how could you Separate this sample? 4. Dissolving with hot H,O b. Dissolving with NH3 ¢. Dissolving with HNO; 4. Dissolving with KMnOx {0! Which of the following compounds can be dissolved with ammonia? N E a. HgCh b. AgCcl ¢. PbCh d: Both AgCl and PbCh. VI! Which set of dnions is provided to'work on the determination of anion? sulphates phésphates nitrate, carbonate; chloride; bromide and Todide,, ulphate, nitrate, carbonate, chloride, bromide and iodide. c. Sulphate, phosphate, njtrite, carbonate, chloride, bromide and iodide. d. Sulphate, phosphate, sulphide, carbonate, chloride, bromide and iodide. 123 Which statement isTatse? 7 V a. Sulphate/ phosphate“and carfionaé give the precipitate with barium chlo: b: The barium salts of phosphate, nitrate and carbonate‘ar c. Sulphate is identified with the formation of white preci under acidic condition / . The precipitates of halide ions are obtained from the reaction of a silver nitrate solution and : theions> __ 33, Which statements ae? i. Carbon dioxide gas is liberated from the decomposition of carbonic acid.” - Heating=up acidified of iron(11)Sulfate with nitrate ion solution evolves. pitrogen(LY) oxide gas, x ____ tii. fodide is oxidized to iodine with potassium nitrite in acid solution a ~ iv. The precipitate of silver chloride is not soluble in ammonia solution. 4 b. ii, ii, iv 4. only i ‘The following data, reagents and color of precipitaté are used to answer question 14 and 15. ammonium phosphomolybdate vii. yellow precipitate potassium permanganate solution VV. potassium nitrite solution pd (ammonium molybdate \evi. diluted sulphuric acid je solution. luble in acidic solution. e with barium chloride solution ™ jerky Z v x a2 © iand iii “sc arm, pil wane ay So Bile ya phot grok| tai joey 1 viii, diluted nitric acid solution vii, diluted acetic acid solution | diluted vee in methylene chloride solution iy ovfor in methylene chloride solution nnn nethylene chloride solution ' ix. violet col x. yellow-orang colorless in ™ ie erate yellow precipitate OF ABBE ion > Which set of data Goncems;with the phosphate ion? 5; W : ¢ of data con ith thé bromide ion? al ov 1s: ear fd ta Goncems W! b. vii, ix, x v e 7 a d. viii, xi, xii . i Redox Rea ‘ments oF ions wergiod included in the 16: In the Redox Reaction experiment, which compounds or €! experiment? gy | 'a. Sodium Jon, silver ion and manganese ion : b, Permanganate ion, ferrous ionand zine metaly c. Copper metal, potassium thioeyanate and icon({¥) sulfate 4. Tin(I1) chloride, NaOCl and iodine, 7 17. Which compound was used to dissolve the.hal Jogen out of the aqueous mixture just to observe the Zolor of the halogen in the compound? a. Aniline * b. Boron trichloride ¢. Chloromethane 4. Dichloromethane fa solution of sodium bromide (Bro + 2¢ = 2B¢ ; 1.07 V) is mixed with a solution of zinc nitrate Meee (0.76 ¥), is there any redox reaction in-tiis mixture? Why? f a. Yes. Because the reaction potential is positive b. Yes. Because the reaction potential is negative. ¢.No. Because the reaction potential is positive. d.No. Because the reaction potential is negative. 19, What is the purpose of adding’écid ito the potassium permanganate solution? ‘a. The reaction works better in higher pH environment. b. The acid acts as catalyst. ©. The acid helps dissolving the products. 4d. The reaction in aqueous solution need more hydrogen atom. 20. From the standard eleétrode potential table in the redox reaction experiment, which ion or elem has the highest potential? a. Hypochlorite ion b. Dichromate ion . Permanganate ion d. Oxygen 21. Which change is not inclided in the-eolligative properties? a. Change in boiling point b. Change in osmotic pressure. c. Change in freezing point. d. Change in atmospheric pressure. 22. Which variable isthot necessary ih caléulating'the molecular weight of the unknown? ‘a. Molality b. Weight of unknown 7 ©. Weight of stirrer d. Onset temperature 23. Which compound was used as Solventiin the Golligative experiment? a. Naphthalene b. Naphthaloni¢ acid aa wneteembalamineg a d. Naphthalinic chloride ich component is the “Molar Freezing Point Constant” for? a. Solute b. Solvent ©. Solution d. Unknown rentorg = Ke mw Yat an ew of saat : Wek fee hy 1.10 be ows} than the actual . calculated molecular 25. In what situation would lead to th molecular weight? a. Weight of unknown is too high b. Melting temperature of the solution is too high. Number of mole of unknown is too high: 4. Amount of the solution is too high. 26. What principle is used to explain the molecular weight of volatile liquid experiment? a: Ideal gas law, b. Le Chatelier’s principle ¢. First law of thermodynamics d. Stoichiometry 27. How to determine the volume of gas presented in Erlenmeyer flask? il an Erlenmeyer flask with tap water and read the volume at the flask label. By Il an Erlenmeyer flask with tap water and weight the flask using balance. duate cylinder and read * the volume. 1 an Erlenmeyer flask with tap water, transfer water to a g 4, Fill an Erlenmeyer flask with tap water, calculate the volume of the flask by ‘mathematical calculation niethod. . 28. Why an Erlenmeyer flask needs to te covered with pin-holed aluminum foil? a. To maintain the experimental condition at constant temperature. b. Pressurized the volatized gas and atmospheric pressure. ¢. To keep the system at constant pressure. : ‘0 release the volatized gas. Ye. Determine the molecular weight from the following experimental results; (Gas constant = 0.0821 L atm mol K"') __ Experiment Result No.1 [Result No.2 Weight of the flask + foil + copper wire Wg | _—*t0g. ‘Weight of the flask + foil + copper wire + condensed 12g Bg liquid _ _ when the Erlenmeyer flask volume is 1000 ml, whole liquid vaporized at 127°C at atmospheric L % Pressure of 760 mmHg. Weight of gas (g) Molecular weight (g) PV = H&T ; No. 1 No. 2 No.1 No.2 (4) COOH. For 60.0 milliliters of the vinegar, 10,00 milliliters of 0.1 M NaOH colenas was required. What was the percent by weight (% W/V) of acetic acid in the vinegar solution? 0.6 % 6.01% XG 41.0% Rate Law” in this experiment. The 6.6.0 % The reaction (1) shown below was selected for the study of 4 rate of this reaction was indirectly measured by another react amount of sodium thiosulfate ( Na,S,0,) and a trace of soluble starch, tion (II) which required a small Oo) ,0,(aq) + 21" (aq) +2H,0" (aq) -» I,(aq)+4H,0@) ~ 42629) + 28,0F" (aq) > S,O% (0g) + 31 (aq)... pwatch to determine the rate of the reaction? (1) How did you know when to stop your sto a. when the solution tumed blue. b. when pH of solution changed to become basic. When the solution tured yellow due to the presence of I, © 4. when the temperature of solution started to increase. which of the following is the expression of 42. From the chemical equation shown in Q.4l (reaction 1), its rate law? a Rate =k H,O,)- P LA,0°P b. Rate= KH,0,}"U" JH,"(i t,OV _ (HO, PU d. Rate= KU, )"(H,0" In this experiment two factors were investigated to see their effects on the rate of the c. Rate = Feaction, 43. What were they? . pH and concentration of the reactants. b. concentration of the reactants and catalyst. ¢- temperature and concentration of the reactants. © 4. concentration of the reactants and inhibitor. Q.41 that a trace of soluble starch was added into the mixture. What was the 44. As mentioned in function of this starch solution? f: Asan indicator to indicate the end of the reaction (I), b- Asallimiting agent to conteol the extent of the reaction ©. © Asa catalyst to speed up the reaction (1), 4. Asa reactant needed for the reaction (1) 45. To study the rate ofthe reaction (I) (in Q.41), wi lone otherwise the rate of the reaction could not be determined? 2 Adding H,50,— KI Na,S,0, —> H,0-> starch» HO, b. Adding 1,50, > Na,S,0, > KI > starch -» H,0> H,0, > KI > 0 > starch 11,0, required substances must be added in suitable order. hich of the following orders could not be di Adding Na,S,0, -» #,0, 4. Adding H,50, — 1,0, -> KI > Na,5,0, -> starch» H,0 h 2,4-dinitrophenylhydrazine (2,4-DNP)? b. Cyclohexene 4. Ammonia 46. Which chemical reacts wit a. Ethyl alcohot ©. Acetaldehyde 47. Which chemical reacts with the Benedict’s reagent? a. Ethyl alcohol b. Acetaldehyde €: Glucose d. Acetic acid 48. Whien you want to test ifthe unknown chemical is acid or amine, what chemical do you use for the testing? a. NaHCO, b. 2,4-DNP ©. KxCr0; d. Cuso, fe When you want to test ifthe unknown chemical is aldehyde or ketone, what chemical do yqu use for the testing? a. NaHCO, b. 2,4-DNP. & KxCr,0, 4. CuSO, 50. Which aleohol reacts with the sodium metal at the fen rate? a. Methyl alcohol b. Ethyl alcohol ©. Isopropyl alcohol 4. ter-Butyl alcohol