LAMPIRAN PERHITUNGAN

1. Pembuatan isomer trans-kalium bisoksalatodiakuokromat (III)

Diketahui : Massa 𝐾2 𝐶𝑟2 𝑂7 = 1.0031 gram
Massa 𝐻2 𝐶2 𝑂4 . 2𝐻2 𝑂 = 3,00 gram
Mr 𝐾2 𝐶𝑟2 𝑂7 = 293.8 gram/mol
Mr 𝐻2 𝐶2 𝑂4 . 2𝐻2 𝑂 = 126 gram/mol
Mr 𝐾[𝐶𝑟(𝐶2 𝑂4 )2 (𝐻2 𝑂)2 ] = 302,9 gram/mol
Ditanya : Massa 𝐾[𝐶𝑟(𝐶2 𝑂4 )2 (𝐻2 𝑂)2 ]
Penyelesaian :
(1,4296+1,6763+1,9862) 𝑔𝑟𝑎𝑚
Massa trans yang didapat =
3
= 1.8754 gram

𝑚𝑎𝑠𝑠𝑎 𝐾2 𝐶𝑟2 𝑂7 1.0014 𝑔𝑟𝑎𝑚

𝑀𝑜𝑙 𝐾2 𝐶𝑟2 𝑂7 = = = 0.0034 𝑚𝑜𝑙
Mr 𝐾2 𝐶𝑟2 𝑂7 293.8
𝑚𝑎𝑠𝑠𝑎 𝐻2 𝐶2 𝑂4 . 2𝐻2 𝑂 3.0114 𝑔𝑟𝑎𝑚
𝑀𝑜𝑙 𝐻2 𝐶2 𝑂4 . 2𝐻2 𝑂 = = = 0.023 𝑚𝑜𝑙
Mr 𝐻2 𝐶2 𝑂4 . 2𝐻2 𝑂 126

7𝐻2 𝐶2 𝑂4 . 2𝐻2 𝑂 + 𝐾2 𝐶𝑟2 𝑂7 ⟶  2𝐾[𝐶𝑟(𝐶2 𝑂4 )2 (𝐻2 𝑂)2 ] + 6𝐶𝑂2 + 7H2 O

m : 0,023 mol 0,0034 mol -

r : 0,023 mol 0,0034 mol 0,0068 mol

s : - - 0,0068 mol

𝑚𝑎𝑠𝑠𝑎 𝐾[𝐶𝑟(𝐶2 𝑂4 )2 (𝐻2 𝑂)2 ] = 𝑚𝑜𝑙 × 𝑀𝑟

= 0,0068 𝑚𝑜𝑙 × 302,9 𝑔𝑟𝑎𝑚⁄𝑚𝑜𝑙
= 2,0597 𝑔𝑟𝑎𝑚
𝑚𝑎𝑠𝑠𝑎 𝑦𝑎𝑛𝑔 𝑑𝑖𝑑𝑎𝑝𝑎𝑡
𝑝𝑒𝑟𝑠𝑒𝑛 ℎ𝑎𝑠𝑖𝑙 𝑘𝑟𝑖𝑠𝑡𝑎𝑙 = × 100 %
𝑚𝑎𝑠𝑠𝑎 𝑠𝑒𝑐𝑎𝑟𝑎 𝑡𝑒𝑜𝑟𝑖

1,8754 𝑔𝑟𝑎𝑚
= × 100 %
2,0597 𝑔𝑟𝑎𝑚

= 91,05 %
2. Pembuatan isomer cis-kalium bisoksalatodiakuokromat (III)
Diketahui : Massa 𝐾2 𝐶𝑟2 𝑂7 = 1.0014 gram
Massa 𝐻2 𝐶2 𝑂4 . 2𝐻2 𝑂 = 3.0016 gram
Mr 𝐾2 𝐶𝑟2 𝑂7 = 293.8 gram/mol
Mr 𝐻2 𝐶2 𝑂4 . 2𝐻2 𝑂 = 126 gram/mol
Mr 𝐾[𝐶𝑟(𝐶2 𝑂4 )2 (𝐻2 𝑂)2 ] = 302,9 gram/mol

Ditanya : Massa 𝐾[𝐶𝑟(𝐶2 𝑂4 )2 (𝐻2 𝑂)2 ]

Penyelesaian :
(1,9497+1,6763+1,6920) 𝑔𝑟𝑎𝑚
Massa cis yang didapat =
3
= 1,7727 gram

𝑚𝑎𝑠𝑠𝑎 𝐾2 𝐶𝑟2 𝑂7 1.0014 𝑔𝑟𝑎𝑚

𝑀𝑜𝑙 𝐾2 𝐶𝑟2 𝑂7 = = = 0.0034 𝑚𝑜𝑙
Mr 𝐾2 𝐶𝑟2 𝑂7 293.8
𝑚𝑎𝑠𝑠𝑎 𝐻2 𝐶2 𝑂4 . 2𝐻2 𝑂 3.0016 𝑔𝑟𝑎𝑚
𝑀𝑜𝑙 𝐻2 𝐶2 𝑂4 . 2𝐻2 𝑂 = = = 0.0237 𝑚𝑜𝑙
Mr 𝐻2 𝐶2 𝑂4 . 2𝐻2 𝑂 126

7𝐻2 𝐶2 𝑂4 . 2𝐻2 𝑂 + 𝐾2 𝐶𝑟2 𝑂7 ⟶  2𝐾[𝐶𝑟(𝐶2 𝑂4 )2 (𝐻2 𝑂)2 ] + 6𝐶𝑂2 + 7H2 O

m : 0,023 mol 0,0034 mol -

r : 0,023 mol 0,0034 mol 0,0068 mol

s : - - 0,0068 mol

𝑚𝑎𝑠𝑠𝑎 𝐾[𝐶𝑟(𝐶2 𝑂4 )2 (𝐻2 𝑂)2 ] = 𝑚𝑜𝑙 × 𝑀𝑟

= 0,0068 𝑚𝑜𝑙 × 302,9 𝑔𝑟𝑎𝑚⁄𝑚𝑜𝑙
= 2,0597 𝑔𝑟𝑎𝑚
𝑚𝑎𝑠𝑠𝑎 𝑦𝑎𝑛𝑔 𝑑𝑖𝑑𝑎𝑝𝑎𝑡
𝑝𝑒𝑟𝑠𝑒𝑛 ℎ𝑎𝑠𝑖𝑙 𝑘𝑟𝑖𝑠𝑡𝑎𝑙 = × 100 %
𝑚𝑎𝑠𝑠𝑎 𝑠𝑒𝑐𝑎𝑟𝑎 𝑡𝑒𝑜𝑟𝑖

1,7727 𝑔𝑟𝑎𝑚
= × 100 %
2,0597 𝑔𝑟𝑎𝑚

= 86,06 %