TCVN TIEU CHUAN QUOCGIA TCVN 6426 : 2009 Xuat ban lan 5 NHIEN LIEU PHAN LUC TUOC BIN HANG KHONG JET A-1 - YEU CAU KY THUAT Aviation turbine fueis Jet A-1 — Specifications HA NOI - 2009Loi néi dau TCVN 6426 : 2009 thay thé TCVN 6426 : 2007. TCVN 6426 : 2009 do Tidu ban kj thuat tiéu chudn quéc gia TCVNITC28/SC4 Nhién ligu hang khéng bién soan dya trén co s@ tai ligu ky thuat AFQRJOS phién ban 24-2008, Téng cuc Tiéu chudn Do lvong Chat lvgng d& nghj, BO Khoa hoc va ‘Céng nghé céng bé. TCVN 6426 : 2009TCVN 6426 : 2009 Loi gidi thigu Tiéu chun nay hoa toan tvong duong vé mat ky thuat v6i tai ligu ky thuat AFQRJOS phién ban 24 - 2008 Yéu céu chét lugng cia nhién ligu hang khéng ding cho Hé théng hoat déng chung voi mét s6 thay adi bién tap cho phép. Tai ligu AFQRJOS qui dinh cac yéu cau chat Iugng cla nhién ligu cung c4p cho hé théng hoat déng chung, 4 dugc nhét tri cla cdc hang: BP, Chevron, ENI, ExxonMobil, Kuwait Petroleum, Shell, Statoil, va Total. Tiéu chudn nay dya trén cdc chi tiu ky thuat ng&t nghéo nhat clia hai tiéu chudn sau: a) Tig chu&n cla B Quéc phéng Anh DEF STAN 91 - 91/ 6, Sia ddi 1, ngay 25 thing 8 nam 2008 di voi Nhién ligu tuéc bin, Nhién liu hang khong dang dau héa, Jet A-1, NATO code F-35 va AVTUR b) _Tiéu chudn ASTM D 1655-08a Nhién ligu tudc bin hang khong Jet A-1 Néi chung, nhién ligu Jet A-1 phi hgp véi tiéu chudn nay 1a phi hop véi cd hai tiéu chudn trén. Cac chi tiéu ch&t lwong nhién ligu hang khéng Jet A-1 duge qui dinh trong Bang 1 TCVN 6426, khi ap dung can két hop cac Chi thich tur 1 dén 22 ciia tiéu chudn nay, cdc chu thich lam rd thém cc tai ligu fién quan d&n cac théng s6 kf thuat cia tiéu chudn Vé nguyén tac, sy ph hyp voi AFQRJOS khéng chi phu hop voi Bang 1 TCVN 6426, ma yéu cau phai phi hgp chi tiét c hai tiéu chudn BO Quéc phdng Anh DEF STAN 91 - 91 va ASTM D 1655, tuy nhién cho phép 4p dung mét sé phuong phap thir khéng diing chung di véi ca hai tigu chudn 68 néu. Ly do la: (1) ¢6 sy khéc nhau gitva cac phwong php thir néu trong DEF STAN 91 - 91/6 va ASTM D 1655, (2) tai c4c khu vyc khdc nhau trén thé gidi, viée 06 s&n thiét bj thir cling khdc nhau, va (3) khuyén khich 4p dung céc phuong phép tién tién hon. Vi vay, nhién ligu thir nghigm theo céc phwong phap 44 néu trong TCVN 6426, phi hgp céc yéu cau a6i véi nhién ligu hang khéng cung cdp cho Hé théng hoat déng chung, khéng nhdt thiét phai phd hop véi cc yéu cau chi tiét vé phwong php thi cua hai tiéu chudn DEF STAN 91 - 91 va ASTM D 1655. Xem Chi thich 22 vé huéng dan céng bd sy phi hgp voi tiéu chudn nay. Tiéu chudn DEF STAN 91 - 91/6, Stra adi 1 yéu cau truy tim ngudn géc sn phdm dén tan noi ché bién.TIEU CHUAN QUOC GIA TCVN 6426 : 2009 Xudt ban fan & Nhién ligu phan Iwe tuéc bin hang khéng Jet A-1 — Yéu cau ky thuat Aviation turbine fuels jet A-1 - Specifications 1 Pham vi ap dung Tiéu chudn nay qui dinh céc chi tiéu chat lveng nhién ligu ding cho déng co’ phan Ive tuéc bin cilia tau bay sau Gay goi la nhién ligu phan lye tuéc bin hang khéng Jet A-1 2. Tiéu chudn vign dan Cac tai ligu vién dan sau [a can thiét khi ap dung tiéu chudn nay, Béi v6i cdc tai ligu vién dan co ghi n&m céng bé thi ap dung ban duge néu. Béi véi cac tai liéu vién dn khéng ghi nam céng bé thi 4p dung phién ban méi nhat, bao gdm cd ban stra déi (néu 06), TCVN 2685 (ASTM D 3227) X&ng, dau héa, nhién ligu tuéc bin hang khéng va nhién ligu chung cAt - Xéc dinh lu huynh (thiol mercaptan) (phyong phép chudn a6 dién thé). TCVN 2694 (ASTM D 130) S4n phdm dau mé - Phuong phap phat hién 46 an man ding theo 6 xin cia tam déng. TCVN 2698 (ASTM D 86) Sdn phdm dau mé - Phuong phap xac dinh thanh phan c&t ap suat khi quyén. TCVN 2708 (ASTM D 1268) San phdm dau mé - Phuong phap xac dinh ham Iwong lu huynh (Phuong phap ét den), TCVN 3171 (ASTM D 445) San phdm dau mé dng va khong trong suét —- Phuong phap xac dinh 8 nhét dong hoe (tinh toan d nhét dong lye) TCVN 3891 San phdm dau mé - Béng rét, ghi nhdn, van chuyén va bao quan. TCVN 4354 (ASTM D 156) San phim dau mé — Xac dinh mau Saybolt (Phuong phap so mau Saybolt) TTCVN 6593 (ASTM D 381) Nhién liéu I6ng - Phuong phép xéc dinh ham lugng nhya thyc té - Phuong phap bay hoi.TCVN 6426 : 2009 TTCVN 6504 (ASTM D 1298) Dau thd va sn phdm dau mé dang léng - Phuong phap xéc dinh khéi lwgng ring, khdi leg riéng tong 46i (ty trong) hoac trong Ivgng API - Phuong phap ty trong ké. TCVN 6608 (ASTM D 3828) San phdm dau md - Phuong phdp xdc dinh diém chép chay céc kin bang thiét bj thir c6 kich thuoe nhé. TCVN 6609 (ASTM D 2624) Nhién ligu chung ct va nhién liéu hang khéng - Phuong phap xc dinh 4 dan dién. TCVN 6701 (ASTM D 2622) San phdm ddu mé - Phuong phap xée dinh ham lwgng luu huynh bang phé tia X. TCVN 6777 (ASTM D 4057) San phdm dau mé - Phuong phép ldy mau thii cng. TCVN 7170 (ASTM D 2386) Nhién ligu hang khéng ~ Phuong phap xac dinh diém bang. TCVN 7272 (ASTM D 3948) Nhién ligu tuéc bin hang khéng - Phuong phap xéc dinh tri sé tach nuéc bang may do logi xach tay (Separometer). TCVN 7330 (ASTM D 1319) San phdm dau mé dang lng - Phuong phdp xac dinh hydrocacbon bang hap phy chi thi huynh quang. TCVN 7418 (ASTM 01322) Nhién ligu tuéc bin hang khéng - Phuong phép xéc dinh chidu cao ngon lira khong khéi. TCVN 7419 (ASTM D 3242) Nhién ligu tudc bin hang khéng ~ Phuong phép xéc dinh axit ting. TCVN 7485 (ASTM D 56) San phim ddu mé — Phuong phép xéc dinh iém chép chay bang thiét bj thir céc kin Tag. TCVN 7486 (ASTM D 4952) San phdm dau mé — Phuong phép phan tich dinh tinh hgp chat lwu huynh hoat tinh trong nhién ligu va dung méi (Doctor Test). TCVN 7487 (ASTM D 3241) Nhién liéu tuéc bin hang khéng — Phuong phap x4c dinh 46 dn dinh ‘6xy hoa nhigt (Qui trinh JETOT). TCVN 7760 (ASTM D 5453) Hydrocacbon nhe, nhién ligu dng co danh Iva, nhién liu 6ng co 6iézen, ddu d6ng co - Phuong phap xéc dinh téng lu huynh bang huynh quang ti ngoai TCVN 7989 (ASTM D 1840) Nhién ligu tuéc bin hang khéng ~ X4c dinh hydrocacbon naphtalen - Phuong phap quang phé ti ngoai. ASTM D 1655 Standard specification for aviation turbine fuels (Tiéu chudn yéu cau ky thuat 46i véi nhién ligu tuédc bin hang khéng). ASTM D 2887 Standard test method for boiling range distribution of petroleum fraction by gas chromatography (Phuong phap xac dinh dai séi cia phan doan dau mé bang sac ky khi). ASTM D 3338 Standard test method for estimation of net heat of combustion of avi (Phuong phép tinh toan nhiét lvgng riéng thc cia nhién ligu hang khéng). tion fuels 6TCVN 6426 : 2009 ASTM D 4052 Standard test method for density and relative density of liquids by digital density meter (Phwong phép xéc dinh khéi long riéng va khdi Iveng riéng tuong déi clla cdc chat ling bang déng hd do khdi lvgng riéng). ASTM D 4294 Standard test method for sulfur in petroleum and petroleum products by energy- dispersive X-Ray fluorescence spectrometry (Phuong phdp xac dinh lvu hujnh trong dau mé va san phdm dau mé bang phé huynh quang tan xa tia-X). ASTM D 4809 Standard test method for heat of combustion of liquid hydrocarbon fuels by bomb calorimeter (Precision method) [Phuong phép xéc dinh nhiét long cla hydrocacbon Iéng bang bom nhiét lugng (Phuong phap 46 chum)] ASTM D 5001 Standard test method for measurement of lubricity of aviation turbine fuels by the ball-on-cylinder lubricity evaluator [Phong phép xéc dinh tinh béi tron cila nhién ligu tuéc bin hang khéng (@4nh gié d6 boi tron cia vién bi trong xi lanh. BOCLE)). ASTM D 5006 Standard test method for measurement of fuel system icing inhibitors (ether type) in aviation fuels [Phuong phdp xac dinh phy gia we ché déng bang trong hé théng nhién ligu (loai ete) cia nhién ligu tuéc bin hang khéng} ASTM 5452 Standard test method for particulate contamination in aviation fuels by laboratory filtration (Phuong phap xc dinh nhiém ban tap chat dang hat trong nhién ligu hang khéng bang phurong phdp loc trong phéng thi nghiém).. ASTM D 5972 Standard test method for freezing point of aviation fuels (Automatic phase transition method) (Xa dinh diém bang ota nhién ligu tudc bin hang khéng (Phuong phap chuyén pha ty d6ng). ASTM D 6045 Standard test method for color of petroleum products by the automatic Tristimulus method (Phuong phap xac dinh mau cia san phdm dau mé bang phuong phap Tristimulus). ASTM D 6379 Standard test method for determination of aromatic hydrocarbon types in aviation fuels and petroleum distillates — High performance liquid chromatography method with refractive index detection (Phuong phdp xac dinh ham Iueng hydrocacbon thom trong nhién ligu hang khéng va cac san phdm chung cét dau mé - Phuong phap sac ky ldng cao 4p cé phat hién bang chi s6 khiic xa). ASTM D 7153 Standard test method for freezing point of aviation fuels (Automatic laser method) (Kéc dinh diém bang ca nhién ligu hang khéng - Phuong phap laze ty d6ng) ASTM D 7154 Standard test method for freezing point of aviation fuels (Automatic fibre optical method) (X4e dinh diém bang cua nhién ligu hang khong — Phuong phap sgi quang ty dng) IP 16 Petroleum products - Determination of the freezing point of aviation fuels (San phdm dau mé ~ Phuong phap xac dinh dim bang cia nhién ligu hang khéng)TCVN 6426 : 2009 IP 30 Detection of mercaptans, hydrogen sulfide, elemental sulfur and peroxides - Doctor Test method (Phat hign mercaptan, hydro sulfua, lu hujnh nguyén t6 va peroxit - Phuong phap Doctor Test). IP 57 Petroleum products - Determination of the smoke point of kerosene (San phdm dau mé - Phuong phép xac dinh chiéu cao ngon lira khong khdi cla dau hod). IP 71 Petroleum products - Transparent and opaque liquids ~ Determination of kinematic viscosity and calculation of dynamic viscosity (San phdm dau mé - Chat dng trong sudt va khong trong suét - Phuong phap xéc dinh 46 nhét va tinh toan 49 nhét déng).. IP 123 Petroleum products - Determination of distilation characteristics at atmospheric pressure (San phdm dau mé - Phuong phap xéc dinh thanh phan cat tai ap sudt khi quyén), IP 154 Petroleum products - Corrosiveness to copper - Copper strip test (San phdm dau mé ~ An mon déng - Phép thir manh déng). IP 156 Determination of hydrocarbon types in petroleum products - Fluorescent indicator adsorption method (Xac dinh loai hydrocacbon trong san phdm dau mé ~ Phuong phap h4p phy chi thi huynh quang). IP 160 Crude petroleum and liquid petroleum products — Laboratory determination of density - Hydrometer method (San phdm dau mé dang dng va dau thd ~ Xac dinh kh6i Ivgng riéng trong phéng thir nghi¢m ~ Phuong phép Hydrometer). IP 170 Petroleum products and other liquids - Determination of flash point - Abel closed cup method (San phdm dau mé va chat lng khac - Xac dinh diém chép chy - Phuong phap céc kin Abel). IP 274 Petroleum products ~ Aviation and distillate fuels - Determination of electrical conductivity (San phdm dau mé - Nhién ligu chung cat va nhién ligu hang khéng ~ Xdc dinh 46 dan dién). IP 323 Petroleum products - Determination of thermal oxidation stability of gas turbine fuels - JFTOT method (San phdm dau mé - X4c dinh 46 én dinh éxy hoa nhiét cia nhién ligu tude bin hang kh6ng - Phuong php JFTOT). IP 336 Petroleum products — Determination of sulphur content - Energy-dispersive-X-Ray fluorescence method (Sn phdm dau mé — Xéc dinh luu hujnh ~ Phuong php phd huynh quang tan xa tia-X). IP 342 Petroleum products — Determination of thiol (mercaptan) sulfur in light and middle distillate fuels - Potentiometric method (San phim dau mé - Xée inh lwu huynh mercaptan trong nhién ligu chung cdt nhe va trung binh — Phuong phap dién thé), IP 354 Determination of the acid number of aviation turbine fuels - Colour-indicator titration method (Xéc dinh tri s6 axit cia nhién ligu tuéc bin hang khéng - Phuong phap chudn 46 bang chi thi mau).TCVN 6426 : 2009 IP 365 Crude petroleum and petroleum products - Determination of density - Oscillating U-tube method (San phdm dau mé va dau thé — Xéc dinh kh6i leg ring - Phuong phép rung éng chi U). IP 406 Petroleum products — Determination of boiling range distribution by gas chromatography (San phm dau mé ~ Phuong phap xac dinh dai s6i bang séc ky khi). IP 423 Determination of particulate contaminant in aviation turbine fuels by laboratory filtration (Xac dinh chat nhiém ban dang hat trong nhién ligu tudc bin hang khéng bang phuong phap loc trong phong thir nghiém). IP 424 Determination of fuel system icing inhibitor content of aviation turbine kerosenes by high performance liquid chromatography (Xée dinh ham long chat tre ché déng bing trong hé théng nhién ligu ca nhién ligu tude bin hang khéng bang s&c ky Idng cao dp) IP 435 Determination of the freezing point of aviation turbine fuels by the automated phase transition method (X4c dinh diém bang cla nhién ligu tuéc bin hang khéng bang phuong phap chuyén pha ty d6ng). IP 436 Determination of aromatic hydrocarbon types in aviation fuels and petroleum distillates ~ High performance liquid chromatography with refractive index detection (X4c dinh hydrocacbon thom trong nhién ligu hang khéng va cdc sén phdm chung cdt dau mé - Phuong phap sac ky léng cao 4p 66 phat hién bang chi sé khuc xa). IP 523 Determination of flash point - Rapid equilibrium closed cup method (Xdc dinh dim chép chay — Phuong phap céc kin can bang nhanh). IP 528 Determination of the freezing point of aviation turbine fuels — Automated fibre optic method (Xae inh diém bang cia nhién ligu tuéc bin hang khong — Phuong phdp quang s¢i ty d6ng). IP 529 Determination of the freezing point of aviation fuels — Automatic laser method (Xéc dinh 4i8m bang ca nhién ligu hang khéng — Phuong php laze ty dng). IP 540 Determination of existent gum content of aviation turbine fuel - Jet evaporation method (Xéc dinh ham ivgng nhya thyc t8 cia nhién ligu tuéc bin hang khéng - Phuong phép bay hoi) IP 564 Determination of the level of cleanliness of aviation turbine fuel - Laboratory automatic particle counter method (Xé¢ dinh 8 trong, sach cia nhién ligu tuéc bin hang khéng — Phuong phap ty dong dém hat tap chét trong phong thi nghiém) IP 565 Determination of the level of cleanliness of aviation turbine fuels - Portable automatic particle counter method (Xée inh 46 trong, sach cia nhién liu tubc bin hang khéng — Phuong phap ty dong dém hat tap chat bang may xach tay). DEF STAN 91 — 91 Turbine fuel, aviation kerosene type, Jet A-1 (Nhién liéu tudéc bin, nhién ligu hang khéng dang dau héa, Jet A-1)TCVN 6426 : 2009 3 Yéu cdu ky thuat Cac chi tiéu chat Ivgng cia nhién ligu phan lye tuéc bin hang khéng du¢c qui dinh trong Bang 1 u phan lye tuéc bin hang khéng Jet A-1 Bang 1 - Chi tiéu chdt lugng nhién Phuong phap thir Xem_ Tan chi tigu Moclyeu cau ~ 1P | TGVNIASTM | chi thich 1. NGOAI QUAN Quan sat Trong, sang, khong ob hat ran va nude khéng hoa tan & nhigt 46 moi trong Mau Ghi két qua TCVN 4354 1 (0 156)/D 6045} Tap chat dang hat, mg/t max 1.0 423 0 5452 2 Hat tap chat, tai noi san xudt, 564 2 sé hat tich Idy trong dung éng ISO code. hose 4 um(c) Ghi két qua 565 26 pm(c) Ghi két qua 214 wm(c) Ghi két qua 221 um(c) Ghi két qua > 25 um(c) Ghi két qua 5 30 nm(c) Ghi két qua i2. THANH PHAN. 3vad Axit tng, mg KOH/g max 0.015 364 | TCVN7419 (0 3242) Hydrocacton thom, % thé tich max 25.0 156 | TCVN7330 (0 1319) Hoge ting hydrocacbon thom.% thé ich max 26,5 436 06379 5 Luu huynh téng, % khéi Itong max 0.30 336 | TCVN2708 |hoac ASTM| (D1266y | Daze4 TCVN 6701 |hoac TCVN| (0 2622) _|7760(08483)| Luu huynh mercaptan, % Knéi long = max 0,0030 342 | TCVN 2685 (0 3227) Hoe Doctor Test amtinh 30 | TCVN 7486 6 (0 4952) ‘Thanh phan nhién ligu qua qua Ghi két qua 7 trinh hydro hod, % thé tich ("khong hoac 100 %) ‘Thanh phan nhién ligu qua qué trinh Ghi két qua 7 hydro hoa kde nghiet % thé tich khong” hoac 100 %) is. TINH BAY HOT ‘Thanh phan cAt 123 | TCVN2608(086)) 8 idm s6i dau, °C Ghikét qua lhoac IP 406| Nhién ligu thu di |hoac ASTM) 10 % thé tich, °C max 205.0 0 2887, 50 % thé tich, °C Ghi két qua 9 90 % thé tich, °C Ghi két qua idm sbi cui, °C max 300,0 én, % thé tich max 15 Hao hut, % thé tich max 15 ‘Bim chop chy, °C min 38,0 170/ | TCVN 7485 10 523 | (0 56) /TCVN 6608(D 3828) Kn6i luong riéng & 15 °C. kg/m? min 75,0 160/ |TCVN 6594 dén max 840.0 365_|(01298)/D 4052 10TCVN 6426 : 2009 Bang 1 (tiép theo) Phuong phép thir Tén chi tiéu Maclyéu clu Pp TCVNIASTM | chi thich (4. TINH CHAY Bidm bing, °C max} -47,0 16hoa | TCVN7170 1" |435/528/529| (D 2386) hoae Dss72 07153 ho&e 07154 BO nhét & - 20°C, mm*is (cSt)” max 8,000 1 TCVN 3171 (0445) 5. TINH CHAY Nhit long rigng thyc, MJ/kg min 42,80 3338 12 D 4809 Chidu cao ngon tira khong knéi, mm min 25.0 87 TCVN 7418 Hoge (0 1322) Chidu cao ngon liva khéng khéi, mm — min. 19,0 87 Toe)” \Va ham iuvong naphtalen, % thétich_ max 3,00 TCVN 7989 (D 1840) ls. TINH AN MON An mén manh dng, logi (2hz5min, & 100°C 41°C) max 1 154 TCVN 2694 (0.130) 17. TINH ON ®INH 180 én dinh Oxy hoa nhigt (JETOT), 323 TCVN 7487 8 Nhiet 66 the, °C min 260 (0 3241) ‘Chenh lech 4p sudt qua mang loc, 25,0:7,50063x10° Pa (mmHg)? max (250) Mac cn éng, (nhin bang mat max | Nnd hon 3, oan thudng) khong 6 mau ‘con dng hoac mau bat thong Is. TAP CHAT Ham lweng nha thyc té, mg/100m!_ max 7 540 TCVN 6593 (0.381) 6 tach nuée (MSEP): TCVN 7272 14 (0 3948) Nhién ligu c6 phy gia chéng tinh ign min 70 Hoge Nhién ligu khong ¢6 phy gia chéng min 85 tinh dign jo. BO DAN BIEN 8 dain dign, pSim min 50 274 TCVN 6609 18 dén max 600 (D 2624) 110, TINH BOI TRON Dudng kinh vét mai min BOCLE, mm _™&% 0.85 D4 mmis = 1 St. ®) 4 Pa = 7,50063 x 10° mm Hg. "TCVN 6426 : 2009 Bang 1 (két thic) Phong phap thi Xem Ten chi tieu Mec Nee asym | chi thich }11. PHY GIA (tén va ky higu theo tieu Jchudn Quéc phong Anh DEFSTAN 91-91/5 néu trong chung chi ch&t wong). chéng dxy hoa, mg/l trong nhién igu qua qué trinh hydro min 17,0 7 hoa va nhién ligu téng hop (bat bude) aén max 24,0 trong nhin ligu khong qua qua ‘rink hydro hod (khong bat bude) — mi 240 cchéng hoat tinh kim logi, mg/l 18 (khong bat budc) max 87 ‘chéng tinh dign, mg/! Pha lin dau Stadis® 450 max 3,0 Pha idn sau 19 Phy gia chéng oxy hod trong nhién ligu da qua qué trinh hydro hod va nhién ligu téng hgp la bat buds va phy gia nay phai cho vao ngay sau qua trinh hydro hod hoge qué trinh t8ng hep va trude khi_ sn phm hogc thanh phn duge chuyén sang bao quan, 68 ngZin sy peroxy hoa va tao nhya sau ché bién. Khong cho phép dung phu gia chéng dong bang néu knong co sy hat tri cba tét c& cae thanh vién trong hé théng chung (xem Loai va ham lugng céc phy gia 68 sir dyng phai néu trong Chang cht chat wong hoae cae tai ligu khdc lién quan chat lugng. Khi cdc phy gia nay duoc pha long véi dung méi hydrocacbon 8 cai thien tinh bao quan, thi truéc khi pha phai ghi ndng 40 géc cla phy gia trong bao cao. Cha thich 20). Xem Cho thich 21 v8 céc yéu cdu quan \j é6i voi sy thay Adi trong Phu gia te ché an mon/Phy gia ci thign tinh boi tron duge cho Nha may loc dau. vao nhién ligu ma khéng can sy chép thuan truéc cia cac thanh vin trong he théng chung (xem Chai thich 18) Ce Chi thich trong bang CHU THICH 1: Phai ghi két qud mau Saybolt tai noi ché bién, tir 46 xdc dinh duge suv thay di mau trong qua trinh phan phi. Trong trudng hgp mau cia nhién ligu dugc xac dinh bang phuong phap Saybolt, thi ghi igi mau 68 quan sat dugc. Nhong mau bat thuéng hoac khéng ign hinh can duge cho ¥ va kim tra tim nguyén nhan, Xem thém céc théng tin v8 tm quan trong cia mau trong Phy Ive C. CHU THICH 2: Chi tigu nay chi dp dyng tai noi ché bién. Cac thong tin cy thé vé tap chat dang hat dugc neu trong Phy Ic D. Hudng dan vé cc gi¢i han nhiém ban khi cap nhién liu vao tau bay tham Khao Huéng din vé vat ligu tai Phan 3, phat hanh 6 cia Hiép hoi Van tdi Hang khong Quéc té (IATA). Bat dau ap dung chi tiéu tap chat dang hat ti ngay 30 thang 6 nam 2009, nhung dé gidp cho qué trinh thu thap sé liu, cn bao céo két qua lién quan truéc ngay 30 thang 6 nam 2009 (dé gidp viée phan tich théng ke, bao cao bao gdm cd sé do tich dy cing nhy ISO code). Muc dich cua diéu nay Ia thay phyong php thir bang cach loc qua mang trong luc bang phuong phap dém hat tap chat ngay tt giai doan dau CHU THICH 3: Tiéu chudn DEF STAN 91 - 91 va ASTM D 1655 44 chdp nhan nhién ligu phan luc ban tang hop (SSJF) do Oil SASOL san xudt. Cac yéu cau thé: nghiém bd sung cho SSJF, ap dung va vign dn theo DEF STAN 91 - 91/ 6, Stra G4i 1, Nhién liéu phan Iyc ban téng hyp co thé dugc chang nh@n pho hyp véi cc yéu cau cia titu chudn nay. 12TCVN 6426 : 2009 CHU THICH 4: Khong chap nhan ndng do este metyl axit béo (FAME) ln hon hoac bang 5,0 mg/kg. idu nay khong bat bude phaii thir nghiém cho tung 1d, néu tai noi ché bién cé 4p dung cdc bién phap quan ly chat lugng pha hyp. CHU THIGH §: Chuong trinh tht nghiém lin phong 48 xae nhan sy tuong quan gitza t8ng ham izong ch&t thom xac dinh theo TCVN 7330 (ASTM D 1319)/IP 186 va ASTM D 6379/IP 436. 86 chéch cla hai phwong phap phai 18 céc gidi han chénh Iéch tong dong 48 qui dinh. Céc phong thir nghiém duoc khuyén khich thye hign va bao céo téng ham Ivong chAt thom theo hai phirong phap dé kiém tra xae nhan su tong quan. Trong trudng hop c6 tranh chdp, phuong phap TCVN 7330 (ASTM D 1319V/IP 156 1a phuong phap trong tai CHU THICH 6: Phuong phap Doctor Test cing I phuong phap dé xac dinh ham lugng lu huynh mercaptan. Trong trong hop co sy mau thudn gitra céc két qua lwru huynh mercaptan va Doctor Test thi cong nhan két qué luu huynh mercaptan. CHU THICH 7: 86i v6i nhién igu Jet A-1, trén Chang chi chét lugng ciia nha may oc dau phai ghi ro phan tram thé tich thanh phan nhién ligu 8 qua qué trinh hydro hoa va qué trinh hydro hod khde nghist (bao gdm c& "khong" hoge 100 %) vao Bang 1, didu nay lién quan aén a) phy gia chéng Oxy hod - khong thé xac dinh duoc ham lugng phy gia chéng oxy hoa néu khong biét ty le nhin liu 68 qua qué trinh hydro hod, vi vay céc nha cung tng Jet A-1 khéng thé kiém tra hoge xac nhan duge sy pha hop cia nhién ligu voi tity chudn, néu khong 6 thong tin nay trén Ching chi chdt wong ciia nha may loc dau b) yéu cu bo cdo phan trim thé tich cdc thanh phan da qua qua trinh hydro hea kh&c nghiét nhy ka mot phan cia yéu cdu vé tinh bdi tron trong tiéu chudn DEF STAN 91-91. Cho y Ia “qua trinh hydro hod" bao ‘gdm qui trinh xi ly bang hydro, lam sach bang hydro va hydrocracking. Cac thanh phan & qua qué trinh hydro hod khde nghiét duoc xée dinh I& hydrocacbon dau mé duoc ché bién chiu ap sudt riéng cla hydro len hon 7000 kPa (70 bar ho&c 1015 psi). CHU THICH 8: Trong tigu chuan IP 123 va TCVN 2698 (ASTM D 86) tat cd cdc nhién ligu duge danh gia phi hop v6i tigu chudn nay duoc phan loai la nhém 4, v6i niet 4d ngung ter O°C dén 4 °C. CHU THICH 9: Co nhng yéu cau khac nhau khi si dung IP 406 hoac ASTM D 2887 vi co phuong phap thi khac gia ASTM D 1655 va DEF STAN 91 -91/6. Tiéu chudn ASTM cho phép st dung tryc tip cac két qua chung cét mé phéng theo céc gidi han khéc nhau, trong khi tigu chudn DEF STAN yéu cdu chuyén di cdc két qua chung c&t d& md phéng sang céc két qua theo IP 123, sir dung IP 406. Cac tiép can khac nhau nay nghiéng vé thao tac nhiéu hon [a ky thuat, do vay khéng danh gia su tiép can nao la khat khe hon. Cé thé ap dung IP 123 48 tinh ning lwgng rieng. CHU THICH 10: Go thé chap nhan két qua khi xéc dinh theo TCVN 7485 (ASTM D 56) (Tag) & nhigt 40 t6i thiéu bang 40 °C. CHU THICH 11: Cho phép 4p dung cae phuong phap ty dong. Phuong phap thir theo TCVN 7170 (ASTM D 2386)/IP 16 la phuong phap trong tai CHU THICH 12: Co thé ap dyng tieu chudn ASTM D 4529 hoac IP 381 13TCVN 6426 : 2009 CHU THICH 13: Kiém tra éng gia nhigt 68 xéc dinh mize can éng bang thiét bi Tuberator trong vong 120 min Ghi mire can éng. Cha : DEF STAN 91 ~ 91 qui dinh chi dung éng gia nhiét 44 duc phé chuan, CHU THICH 14: DEF STAN 91-91 4a néu: “Khong co sn cac sé ligu vé > chum cho nhién ligu c6 chia ‘SDA; néu thir nghiém MSEP trong qua trinh phan phéi khong phir hgp tigu chudn, thi két qua 46 khong duge coi la ly do duy nhat 48 loai bd san pham’. CHU THICH 15: Theo tiéu chudn DEF STAN 81 - 91/6, Sia di 1, gi6i han 49 d&n dign cia s8n phdm bat bude phai phi hop véi tiéu chudn nay. Tuy nhién cing phai chdp nhén rang trong san xudt cGing nhw trong hé théng phan phéi, thyc t& ngudi ta chi pha phy gia chéng tinh dign (SDA) & giai doan cui. Trong cdc truéng hyp nay, trén Ching chi chat lugng cia Io hang cé thé néu: “San phdm pha hep voi TCVN 6426 (AFQRJOS 24), trav chi tidu 46 d&n dign”. Trong mot sé truong hyp, 46 dan dign cé thé gidm nhanh va viec pha phy gia Stadis 450 sé khong cn tac dung. Trong trveng hyp nay, nhién lieu c6 thé dug cung cAp vai 0 dan dien giém t6i thiéu dén 25 pSim voi didu kign nhién ligu d& dugc kiém tra toan bd theo tiéu chuan nay va duge ghi trén phiéu xuat la “San phdm cung tng co 9 dan din thdp hon 50 pSim*. CHU THICH 16: Yéu cdu nay xuat phat tir tiéu chudn DEF STAN 91 - 91/6. Yéu cau vé xac inh tinh b6i tron chi ap dung cho nhién ligu chiza hon 95 % nhién ligu qua qué trinh hydro hod, trong dé it nhdt 20 % la qua qua trinh hydro hod khdc nghiét (xem Chd thich 6) va cho tat c& cdc nhién ligu cé chia cdc thanh phan tng hyp. Giéi han nay chi ap dung tai noi ché bién. Théng tin chi d&n quan trong v8 tinh b6i tron cla nhién ligu tuéc bin hang khéng dug qui dinh trong Phy luc B. CHU THICH 17: Phu gia chéng 6xy hod duge qui dinh trong Phy luc A (A.2.4). Khi giao hang, tren Chung chi chét lveng cia nha may loc dau phai ghi ré ching loai phy gia chéng oxy hoa da cho vao nhién ligu theo ding ky higu qui inh RDE/A/XXX. CHU THICH 18: Phy luc A (A.3) ligt ké danh myc cac phy gia chéng hoat tinh kim loai da dug chap nhan (MDA), RDE/A/650. Xem thém A.3.1 vé sy can thiét phdi bdo c4o 66 dn dinh Oxy hod nhiét trude va sau khi Jet A-1 bj nhiém ban do bat ky vét kim loai nao da néu trong phu luc nay ma chua duge chirng minh, Chi ¥ trong Phu luc A.3.3 qui dinh tai noi ché bién, ham Igng pha t6i da lan du la 2 mgil. CHU THICH 19: Mac pha thém cia phy gia chéng tinh dién, tinh bang mg/l, max: Téng ham long Stadis® 450 (RDE/A'621) 5.0 Khong 18 long pha dau: Ham wong them vao Stadis® 450 (RDE/A/621) 2,0 CHU THICH 20: Néu ham Iugng phy gia be ché déng bang cia nhién liéu (FSII) nhé hon 0,02 % theo thé tich thi co thé bd qua, khéng can phai thod thuan/théng bdo. Sy tan thanh cho phép ham lvong nhd FSSII (khng cn thoa thu@n/thong béo) tao diéu kién dB dang cho vige thay di tt nhién ligu co chiva FSI ‘sang nhién ligu khéng chira FSII, khi phy gia nay con luu lai trong hé théng nhién liéu trong mét thoi hen nhat dinh, Diéu nay khong cho phép pha thém lién tuc FSII & ham lugng thdp, CHU THICH 21: Tigu chudn DEF STAN 91 - 91 va ASTM D 1656 luu y vé viée can theo d6i, quan ly cdc thay 66i trong nha may ché bién nhién ligu phan lye. Xem xét céc thay déi trong bdo quan, diéu kién ché bién hod phy gia ddi voi chat lvgng sdn phdm cudi cling va yéu cau vé tinh nang (vi du, kinh nghiém cho thay mot s6 cng nghé pha phy gia cé thé gay anh hu-dng dén chat lugng cia nhién ligu hang khong). 14TCVN 6426 : 2009 CHU THICH 22: Thong thong trén Chung chi ching nhgn sy phi hop néu: “Ching nhan céc mau da urge tién hanh thir nghiém theo céc phuong phap thir qui dinh va ching nhan cac Io hang clia cdc mau 4ai dign phi hop vdi titu chudn TCVN 6426 (AFQRJOS phién ban 24). Cac ching chi cia cac 16 hang cng c6 thé khang dinh su phi: hop véi DEF STAN 91 - 81 (phién ban moi nhat) va ASTM D 1656 (phién ban moi nha) Tren chung chi chat lugng I hang cia nha méy loc dau phai bao gém t6i thibu cde thong tin sau = S6 higu tiéu chudn, tén tiéu chudn yéu cau ky thuat va sé higu ban siva d6i (néu c6); - Ten va gia chi cia phong thir ng! - 86 16 va sé nhan dang; = S6 long nhién ligu cua 16; = Cc chi tigu tién hanh thir nghiém, bao gdm cd mite qui dinh trong yéu cdu kj thuat, phuong phap thir va két qua thir; - Cac phy gia, bao gdm vign d&n chung chi chat Ivong va long pha vao; = Ho ten va cite danh cia nguéi cé thm quyén ky ching chi thir nghi¢m hoac chtr ky dién tt; - Ngay cp chizng chi. 4 Phwong phap thir 4.1 L4y m&u theo TCVN 6777 (ASTM D 4057). 4.2. Phuong phap thi: Cac phuong phap thir Gng voi tig chi tiéu cho nhién ligu phan Ive tudéc bin hang khéng durgc qui dinh trong Bang 1 5 Bong rot, ghi nhan, van chuyén va bao quan Theo TCVN 3891 15TCVN 6426 : 2009 Phy Iyc A (qui dinh) Danh myc cac cht phy gia 44 dugc ch4p nhan AA Théng tin chung vé cdc chdt pha loang hyhrocacbon va phy gia A.1.1. Mot vai loai phy gia 48 dugc chdp nhan, bao gdm chat pha lo&ng hydrocacbon ding nh dung méi va Ivgng cho vao duge tinh dya trén co sé phy gia duge thiva nhan. Cac phy gia nay bao gém phy gia chéng tinh dign va phu gia cai thién tinh bdi tron. AA.2 Cc phy gia khaéc duge chp nhan dya trén co sé ham Iugng thanh phan hoat tinh 4a néu. Cac phy gia nay bao gdm phy gia chéng oxy hoa, phy gia chéng hoat tinh kim loai, phy gia ire ché déng bang trong hé théng nhién ligu (FSI), va phy gia phat hign rd ri. 1.3 Néu can phai pha long phy gia cho myc dich bdo quan, c4c dung mé6i sir dung phai la hydrocacbon dan xuat tir cc ngudn géc théng thurdng, bao gdm dau thd, condensat khi ty nhién héa Iéng, dau nang, dau 64 phién (dau dugc ldy ra tir 64 phién sét). Trong truéng hop nay nha cung c&p phai c6 cac huéng dan tinh cac ham lugng cho vao. Théng tin trén duge ghi trong cchizng chi phan tich hoc trong tai igu chat lugng cua phy gia A2 Phy gia chéng dxy hoa A.2.4 Phu gia chéng éxy hod hoac hén hyp céc phy gia chéng Oxy hod duge néu chi tiét trong diu A.2.4, duge pha vao nhién ligu (hodc thanh phan) vi ham Iugng pha cy thé qui dinh trong didu A.2.5, cdc phy gia nay 44 qua qué trinh hydro hod (qué trinh ché bién cé sir dyng hydro nh xt ly bang hydro, lam sach bang hydro, hydrocracking v.v...) hoe duge téng hgp. Cac phy gia nay phdi duge pha ngay sau khi xt ly bang hydro hode téng hgp dé tranh bj peroxit hoa va tao nhya (keo) sau ché bién, A.2.2_ Néu nhién ligu xudt xuéng la hdn hop cla nhidu thanh phan khac nhau, yéu cau bat bude ve pha phy gia chéng xy hod chi 4p dung cho phan nhién ligu ca hin hop 44 qua qua trinh hydro hod, trong truréng hyp nay, phai ghi r6 ty I ph&n nhién ligu 48 qua qua trinh hydro hoa cia hén hop. A.2.3 Kh6ng bat budc phai pha thém phy gia chéng éxy hoa déi véi nhién ligu (hay thanh phan ca nhién ligu) khéng qua qué trinh hydro hoa. A.2.4 Cu tao va ky hiéu cdc phy gia chéng dxy hod 48 duge chép nhén la: 16TCVN 6426 : 2009 Cau tao Ky higu qui djnh a) 2,6-ditertiary-butyl-pheno! RDE/A/606 b) 2,6 - ditertiary-butyl-4-metyl-phenol RDE/A/607 ¢) 2,4-dimetyl-6-tertiary-butyl-phenol RDE/A/608 d) Téi thiéu 75 %, 2,6-ditertiary-butyl-phenol RDE/A/609 Téi da 25 %, tertiary va tritertiary-butyl-phenol e) Téi thidu 55 %, 2,4-dimethyl-6-tertiary-butyl-phenol RDE/A610 Téi thidu 15 %, 4 metyl-2,6-ditertiary-butyl-phenol 86 cén lai, t6i da 30 % la hn hep monomethyl va dimethyl- tertiary-butyl-phenols f) T6i thiéu 72 %, 2,4-dimetyl-6-tertiary-butyl-phenol RDE/A/611 T6i da 28 %, hdn hgp tertiary-butyl-methyl-phenols va tertiary-butyl dimethyl phenols A.2.5 Ham lugng cc chat phy gia chdp nhan duc quy dinh nhw sau: A.2.8.1 Nhién ligu ho&c céc thanh phan nhién ligu 48 qua qué trinh hydro hoa: Téng ham lveng cdc chat phy gia hoat tinh trong nhién ligu, ho&c phan cia hén hep nhién ligu 4 qua qua trinh hydro hoa khéng dug nhé hen 17,0 mg/l. Téng ham lugng chat hoat tinh trong 16 san phdm cuéi cung khong vugt qué 24,0 mg/l. A.2.8.2 Nhién ligu khéng qua qua trinh hydro hoa: Téng ham Iveng cae chat hoat tinh khéng vugt qua 24,0 mg/l, va duge ghi trén ching chi chat lugng. A.2.6 Ham lugng chat chéng oxy héa cho vao nhién ligu dv¢c quy dinh nhu sau: A.2.6.1 Nhién ligu ho&e cdc thanh phan hén hop nhién ligu 44 qua qua trinh hydro hoa va qua trinh hydro hod khde nghiét, ning 46 chat hoat tinh cho vao phan hén hop nhién ligu da qua qué trinh hydro hod duge ghi trén ching chi chat Ivgng. Néu chat chéng oxy héa cing urge cho vao phan nhién ligu chwa qua qua trinh oxy héa, thi ndng 46 chat hoat tinh cho vao phan nhién ligu nay durge ghi riéng mét dong trén chieng chi chat lvgng. A.2.6.2 Nong do cla bat ky chat chéng oxy héa nao cho vao nhién ligu chua qua qua trinh hydro hod phai duge ghi trén chizng chi chat lugng. A3 Phy gia chéng host tinh kim loai (MDA) A.3.1 Néu cé bao cdo va ban chdt cia sy nhiém ban, thi cé thé pha vao nhién ligu phy gia MDA 7TCVN 6426 : 2009 néu & A.3.2, v6i ham lung néu & A.3.3, 48 han ché anh hung d6 én dinh nhigt cla céc kim loai 44 biét nhu déng, cadimi, sét, coban va kém. Khi cha xdc dinh dugc nhiém ban kim logi, c thé st dung MDA 48 phyc hdi 46 Sn dinh nhigt, voi didu kién phai tién hanh theo phyong php JFTOT (chitiéu 7 - Bang 1) truéc va sau khi pha MDA, va duge ghi trén bao c4o thir nghiém. ‘A.3.2 Phy gia chéng hoat tinh kim logi 8 duc chap nhan: Tén sin phim ky higu qui djnh NN’ - disalicyliden 1,2 - propan diamin. RDE/A/650 A.3.3 Ham lugng phy gia chéng hoat tinh kim loai dugc pha |dn dau vao nhién ligu khong vuot qué 2,0 mg/l. Téng ham lugng pha phy gia MDA khi pha thém khéng vurgt qua 5,7 mg/l. Cac yeu cau qui dinh & A.3.1 sé phai tuan thi khi pha hodc pha thém phy gia. A.4 Phy gia chéng tinh dign (SDA) ‘A.4.1 Phy gia chéng tinh dign SDA néu & A.4.2, voi ham long néu & A.4.3, dug pha vao nhién liu 8 truyén 66 d&n dién theo chi tiéu 9 cla Bang 1 A.4.2. Phu gia 48 duge chdp nhan: Tén san phim Hang san xudt Ky higu qui djnh Stadis® 450 Innospec LLC RDE/A/621 A.4.3 Ham lugng va mirc pha thém phy gia: ‘A.4.3.1 Nhién ligu méi ché bién ho&c pha lan dau, ham Ivong phu gia SDA khéng vuet qué 3,0 mg/l. A.4.3.2. Téng ham lugng SDA cho phép khi pha thém vao nhién ligu 48 duy tri 6 dln dién khong vot qué 5,0 mg/l. A.5 Phy gia cai thign tinh béi tron (LIA) (Truéc day goi I phy gia we ché an mén/cai thién tinh béi tron) 8.1 LIA c6 thé duoc pha vao nhién ligu theo ham lugng qui dinh & didu A.5.4 48 cai thign tinh bdi tron cia nhién ligu. Cac théng tin chi tiét vé tinh bdi tron cla nhién ligu tude bin hang khong duge néu trong Phy luc B. A.8.2 Do phy gia LIA tdn tai can bang voi bé mat kim loai cla hé théng phan phéi nhién ligu va he théng nhién ligu cda tau bay, vi vay viéc c4p nhién ligu chudn cho tau bay dugc dam bao la nhé sy can bang cla hé théng pha LIA hode nho hé théng phun phy gia tai dlém nap nhién ligu cho tau bay. 8TCVN 6426 : 2009 A.8.3 Cac chdt 68 dugc chép nhan, céc kj higu qui dinh tong tg cua ching, céc yéu clu bao am chat lugng va ham lugng 4p dyng tai thoi dim giao hang cho bén mua, dugc néu trong QPL 68-251, ham lugng va ky higu qui dinh dugc néu du6i day. Trong sir dung dan dung cé thé ding céc cht phy gia khac khi dugc chp thuan cia co quan cé thdm quyén va phu hep voi nha ché tao déng co tau bay va déng co tong tng, A.5.4 Cac phy gia dugc chap nhan tai cdc ham lung qui dinh sau: ‘Ten san phim Hang san xudt a ‘au an an Apollo PRI-18 Apollo Technologies Intl. Corp ROE/AE60 18 23 Hitec 580 Afton Chemical Ltd. ROE/AIG61 15 23 Octel DCI-4A Octal Starreon LLC ROEIAIG62 9 23 Octel DCI-6A Otel Starreon LLC ROEIAIGGS 9 9 Naleo 403 Naleo Chemical Co. ROE/AG64 2 23 Tolad 4410 Baker Petrolite ROE/AI65 8 23 Tolad 351 Baker Petrolite ROE/AIG66 8 23 Unicor J Dorf ketal chemicals ROE/A‘G67 8 23 A.6 Phy gia tec ché déng bing trong hé théng nhién ligu (FSII) A614 Phu gia tc ché déng bang (FSI!) dugc néu & A.6.2 va voi ham lwong dugc néu 6 A6.3 theo thod thuan gira bén mua va bén cung cdp nhién ligu. CHU THICH: Néu ham lugng nhé hon 0,02 % thé tich thi c6 thé bé qua, khOng can phai thoa thugn/thong bdo. Sy tan thanh cho phép cho long nhé (FSII) (khéng can thod thuan/th6ng bao) tao didu kin dé dang cho viée thay 46i tir nhién ligu cé chiva FSII sang nhién liu khong chira FSII khi phy gia nay con lwu lai trong hé théng nhién ligu trong mot thoi han nhat dinh. Biéu nay khong cho phép pha thém lién tuc FSII & ham Iuong thép. A.6.2. Phy gia duéi day due ch4p nhan va phai phi hop voi DEF STAN 68-282: Tén san phim Ky higu qui djnh Diethylene Glycol Monometyl Ete RDE/A/630 A.6.3. Khi bat buéc, phy gia cho vao ¢6 ham lugng khong nhé hon 0,10 %, va khong qua 0,15 % thé tich, tai thoi diém phan phéi cho bén mua hang. Ap dung IP 424 va ASTM D 5006 dé xéc dinh ham Iwong phy gia nay. A.7 Hén hyp phy gia A.7.4_ Khi sty dyng ddng théi phy gia cai thién bdi tron (LIA) va phy gia we ché déng bang (FSI) 66 thé pha hén hgp LIA véi FSII vao nhién ligu 19TCVN 6426 : 2009 7.2. HOn hop phy gia nay dugc kiém soat theo DEF STAN 68-150, Mac du qui trinh tron duoc chap nhan, nha cung tng van phai théng bao voi khach hang vé ham lugng chinh xac cla phy gia da pha déng nhat. A8 Phy gia phat hign ro ri A.8.1 Khi cdn thiét, phy gia phat hién rd ri c6 thé pha vao nhién ligu 48 gitp phat hign va xac inh vj tri rd ri & bé chira, trong hé théng xudt nhap va phan phéi nhién liéu. A.8.2 Chat phy gia duge chdp nhan: Tén san phdm Hang san xuat Ky higu qui djnh Tracer A (LDTA-A) ‘Tracer Research Corporation RDEVA/640 A.7.3 Ham luong phy gia Tracer A khéng vugt qua 1,0 mg/kg. A9 Sw nhiém ban do céng nghé pha phy gia ‘A.9.4_ Kinh nghiém cho th4y cdc phy gia céng nghé loc dau, vi du phy gia ire ché an mon c6 thé 6 & dang vét trong nhién ligu hang khéng trong qua trinh ché bién cia nha may. Trong mét vai trudng hop, didu nay ¢6 thé gay anh hudng hé théng nhién ligu cia tau bay. Tham chi cdc phy gia nay o6 thé gay anh hudng tai cac misc 49 ma khéng phat hién dugc bang cdc phép thir 43 néu & Bang 1. Vi vay céc phy gia khéng dugc phé duyét thi khéng dugc phép pha, viéc xac dinh mirc "khéng" cing chua phai la Gugc, dac biét khi: a) kj thuat phan tich hién dai cé khd ning phat hién mirc cyc th4p cia hoa chat; b) trong 46 c6 thé tn tai nhidu chét, va ©) trong nhidu truéng hyp khéng cé cdc sé ligu va Anh hung cia cae phu gia trong hé théng clia tau bay a4 xdc dinh duge mirc v6 hai. A.9.2 Do vay 86 khéng thye té khi tigu chudn nay yéu cau phan tich hod hoc cy thé cho tirng 16 nhién ligu hang khéng theo céc chi tiéu 4 néu. Thay vao dé ngudi ta khuyén cdo cdc nha ché bién phai dam bdo rang ho 06 day dui céc qui trinh ddm bao chat lveng va quan ly duge cac thay 48i, 48 khang dinh viée sir dyng céng nghé pha phy gia cia nha may loc dau la hoan toan xac dinh va kiém soat duge. Tt cd cdc thay déi trong thanh phan cac phy gia/ngudn ché bién hoac cc tinh trang céng nghé cia nha may dau phal duge danh gid ri ro, nh&m dam bao viée duy tri chat lveng san phdm cuéi cing. 20TCVN 6426 : 2009 Phy lye B (tham khao) Théng tin vé tinh béi tron cla nhién ligu hang khéng B.1_Nhing phan chuyén déng cia hé théng nhién ligu tau bay/d6ng co va cac thiét bj kiém soat nhién ligu duge béi tron bang chinh nhién ligu. Téc dung béi tron cla nhién liéu phan lye trong cae thiét bj dugc coi la “tinh b6i tron”. Sy khac nhau vé vat ligu va thiét ké chi tiét d&n dén sy khac nhau vé d nhay cla cdc thiét bj déi vi tinh bdi tron ciia nhién ligu. Tuong ty, cc loai nhién ligu phan lye efing c6 tinh béi tron khac nhau. Kinh nghiém thyc té cho thay tir viée gidm Iwu Iuong bom aén. nhiing sai sét co hoc bat ngé lam ngirng hoat dong cia déng co dang bay. B.2 Cac tinh chat hoa, ly cla nhién ligu phan Iie lm cho né tré thanh chat kém béi tron & didu kién nhiét d6 va tai trong cao. Qua trinh hydro hoa khdc nghiét lam mét yéu t6 vi lveng cia nhién ligu, [am cho nhién ligu c6 tinh bi tron th4p hon nhién ligu chung cat tryc tiép hay nhién ligu d& qua qué trinh lam sach khéc. Cc chét phy gia cai thign tinh béi tron duge stv dung phé bién voi nhién ligu cho tau bay quan sy. Véi nhién ligu hang khéng dan dung, tréc day trong mét s6 truéng hgp, phy gia nay tam thoi dugc str dyng dé khdc phuc nhiing tdn tai ky thuat trong thoi gian cai tién céc bO phan cia hé théng nhién ligu tau bay, va trong qué trinh hoan thién chat lwgng nhién ligu. Do ban chat phan cye, cdc phy gia nay co thé anh hudng dén hé théng loc va c4e dc tinh tach nhién ligu/nuée. B.3 Cac b6 phan trong hé théng nhién liéu cia mét sé tau bay hién dai da dug thiét ké thich hop véi tinh bdi tron th4p cuia nhién ligu. Vi sy tham gia cla nganh céng nghiép hang khéng quéc t6 SAE AE - 5B 4 soat xét Iai qui trinh thi tinh bdi tron & nhiét 46 thdp cho hé théng born nhién ligu cho dong co tau bay, ARP 1797. Qui trinh hién hanh qui dinh si? dung chat léng chudn kiém tra 88 tao ra duéng kinh vét mai mén (wsd) trong khodng 0,85 mm dén 0,96 mm, xac dinh theo ASTM D 5001. Yéu cau tinh bdi tron qui dinh duéng kinh vét mai mén (wsd) max 0,85 mm 48 dua ra giéi han tinh béi tron cla nhién ligu, giéi han nay dm bao theo qui trinh ARP 1797, trong str dung, tinh béi tron khéng lién quan dén sy truc trac clia thiét bi. Yéu cu nay chi ap dung cho cdc nhién ligu chira hon 95 % da qua qué trinh hydro hoa, trong dé it nhat c 20 % duge xiv ly qua qua trinh hydro hod khdc nghiét. Tat cd cdc nhién ligu cé thé gay anh huéng can phai duge tap hop vao nhém nay. Luu y rang khong phi tat ca cdc nhién ligu chwva thanh phan qua qué trinh hydro hoa khdc nghiét c6 dudng kinh vét mai mén (wsd) lén hon 0,85 mm va diéu nay 4 duge nghién ciru khi dua ra gidi han qui dinh. B.4_ Céc linh kign cia hé théng nhién ligu ci ca tau bay hién Gang sir dung la nhay cam hon so v6i tinh b6i tron cla nhién ligu. Trong nhteng trong hep nay tho may cia tau bay can lay y kién cla nha may sén xuat inh kign va nha cung cp nhién liéu 68 quyét dinh bién phap x¢r ly t6t nha, c6 thé bao gdm ca viéc str dung cac chét phu gia béi tron da phé duyét dé tang tinh bi tron cla nhién ligu cu thé, véi mirc 64 qui dinh sn trong tiéu chun. 241TCVN 6426 : 2009 Phy lye C (tham khdo) Théng tin vé mau Saybolt cila nhién ligu hang khong C.1 Mau Saybolt c6 thé 1a ddu higu hitu ich biéu hién chét lugng cla nhién ligu. Mau nhién liéu sim lai hoac thay adi co thé do nhién ligu bi nhiém ban hode tinh én dinh kém. G.2_ Sy thay ddi d mau Saybolt tt luc méi sdn xudt ra 16 hang én Ic phai diéu tra nghién clu nh sau: Mau Saybolt ban dau tai noi san xudt Thay déi dang ké > 25 >8 $25, nhung > 15 >5 <15 >3 €.3 Théng thuéng dai mau olla nhién ligu tir mau nu@e cét trong, sang (khéng mau) één mau vang rom (vang xém). Nhing mau khac cla nhién ligu c6 thé la do dac tinh cia dau thé hoac c6ng nghé ché bién. Néu mau khéng binh thuéng xudt hién tai thei diém san xudt, 46 mau sé dugc ghi trén chtng nhan phan tich chat lveng 16 hang dé cung cp théng tin cho nguéi sw dung. Cac mau bat thudng khac nhu mau héng, 46, xanh hode luc, ma khéng téc dong lon dén s6 mau Saybolt cing phai durgc didu tra nghién ctu dé xdc dinh nguyén nhan 22TCVN 6426 : 2009 Phy luc D (tham khdo) Théng tin vé nhiém ban hat tap chat D.1_Kiém tra mau sc nhién ligu bang mat thuéng [a mét phuong php kiém tra tét vé sy nhiém ban hat tap chét, va la yéu cau then chét 441 véi nhién ligu khi cho phép nhap vao hé théng phan phéi. Tuy nhién, yéu cau ngoai quan co thé do ban chat chi quan cUa sy danh gia bang mat thuong. Vi vay mét giéi han cé tinh dinh long 4& dug thiét lap cho sy nhiém ban hat tap chat. Hat tap chat téi da la 1,0 mg/l, khi dugc thir theo phuong phap ASTM 5452/1P423 chi ap dung tai nha may ché bién nhién ligu. 1.2 Nhivng nhién ligu chiva hat tap chat nhin thdy hodc ham Iuong tap chat lon hon 1,0 mg/l sé yéu cau bd sung thém céc quy trinh trong giao nhan vi dy nhw tang thém thdi gian lang hoac tién hanh I9c. D.3 Khi nhién ligu due xudt nap cho tau bay, xem cac théng tin twong tng vé gidi han nhiém ban trong tai ligu huéng d&n cla IATA cho nhién ligu phan luc tuédc bin hang khéng - Phan Ill - BO sach va giao nhan. D.4 Day 1a xu huéng 48 mé réng pham vi 4p dyng mire gidi han nhiém ban hat tap chat qua hé théng phan phéi sau nay. 23TCVN 6426 : 2009 Phu luc E (tham khdo) Sy twong duong vé kf thuat giira cdc tiéu chudn ISO va IP/ASTM Phuong phap thir IP/ASTM Phuong phap thir ISO IP S7/ASTM D 1322 Iso 3014 IP 71/ASTM D 445 Iso 3104 IP 123 Iso 3408 IP 154/ASTM D 130 Iso 2160 IP 160/ASTM D 1298 ISO 3675 IP 170 Iso 13736 IP 243 Iso 4260 IP 336 180 8754 IP 342/ASTM D 3227 Iso 3012 IP 365/ASTM D 4052 Iso 12185 IP 367 1s0 4259 IP 447 Iso 14596 [1p 923 ISO 3679 _ 24TCVN 6426 : 2009 Thu muc tai ligu tham khao [1] ASTM D 4082 Standard test method for density and relative density of liquids by digital density meter (Phuong phap xe dinh khéi lwgng riéng va khdi lvgng riéng tuong déi cla san phim dau mé bang déng hd do khéi lugng riéng). [2] ASTM D 4529 Standard test method for estimation of net heat of combustion of aviation fuels (Phuong php tinh todn nhiét Ivgng riéng thyc cla nhién ligu hang khéng). [3] IP 303 Determination of closed flash point - Rapid equilibrium closed cup method (Xée dinh diém chép chay kin - Phuong phép cdc kin can bang nhanh). [4] IP 381 Estimation of net heat of combustion of aviation fuels (Xac dinh nhiét lugng riéng thyc cia nhién ligu hang khong) [5] IP 423 Determination of particulate contaminant in aviation turbine fuels by laboratory filtration (Xée dinh chat nhiém bAn dang hat trong nhién ligu tude bin hang khéng bang phyong phap loc trong phéng thi nghiém). [6] DEF STAN 68-150 Mixture of fuel system incing inhibitor and lubricity improving additive JSD: AL-48 (Hdn hgp chat tre ché déng bang trong hé théng nhién liéu va phy gia cai thién tinh bdi tron JSD: AL-48). [7] DEF STAN 68-251 Fuel soluble lubricity improving additives for aviation turbine fuels (Phy gia cai thign tinh bdi tron ca nhién ligu 61 véi nhién ligu tuéc bin hang khéng). [8] DEF STAN 68-252 Fuel system icing inhibitor (Chat te ché déng bang trong hé théng nhién liéu).. QPL 68-251 Qualified products list of aircraft materials to DEF STAN 68-251 (Danh myc cac sn phdm 48 duge chap nhan déi voi cdc vat liéu cho tau bay theo DEF STAN 68-251). 25