ene Product Safety Data Sheet prepared in accordance with Annex I ofthe REACH Regulation EC 1907/2006, Regulation (EC) 1272/2008 and Regulation (EC) 45872010. Version 1 Revision Dato 01.10.2018 7 Kintification of the subatancelmivture and of the companyTundertaking 1a Product identifier Product name Calcium oxide. ‘Synonyms. ‘Guickime, Lime, Burtime, Unestaked Time, Building ime, Cacia, Fatlime, Chemical ime, Fluxing ime, Hara burt lim, Sof burt lim Pebble lime, Calcium oxide, Calcun monoxide ‘Guickiime, Calened limestone. Poace note that this lst may nt be exhaustive, Trade name Galelum oxida ‘Chemical Name Formula (Galcum oxide - CaO- [eAS.No. 7505-78-83 EINECS.Na. 215-7389 Moleculr weight 56,08 gimot REACH Registration Number (01-211 087 65-36 12 Relevant identified uses ofthe substance or mixture and uses advised against Find hereunder a general description of uses. Wastewater Treatment No uses are advised againstCotter 1 Datals of te Suppor ofthe safety data shoot ‘Company Rasvess Taephone Taiefa [Ta Emergency wk wumbe Emergency telephone number (Company) 2. Hazards Wdentfcation 2.1.1 REGULATION (EG) No 1272/2008 'STOT SE3, 1335, Exposure: Inhalation ‘Skin nit2, H815, Exposure: Dermal Eye Dam.1, Hata, 2.4.2 Classification according to EU Directives GTIS4GIEEC or 1988/45IEC. i erat RST, RGB: RAT 27.3 Further information: For the ful text ofthe H-Statomants mantoned Ini SocUon, soo Seon 16. For the ful ext ofthe R-phrases mentioned inthis Section, see Section 16.22 Label elements 22.1 REGULATION (EC) No 127212008 OD Danger Hazard statemen 316: Causes skin itaton. 310: Causes eerious eve damage, 335: May cause respraary ination. Precauonary statements 102: Kaop out of reach of cildren 280; Wear protective gloves/ protective cothing! eye protection face protection. 305 + P51 + P336: IF IN EYES: Rinse cautiously with water for several minutes. Remove ‘contact lenses if present and easy to do. Continue rinsing, 310: Immediately call a POISON CENTER or doctor physician 302 + P52: IF ON SKIN: Wash with plenty of soap and water. 26%: Avoid breathing dust! {una gas! mist! vapourel epra. 904 + P40: IF INHALED: Remove victim to fresh alr and Keep a restin a postion ‘comfortable for breathing. S01: Dispose of contentsloantainer in accordance with local regulation. ZZ2 Recarding to European Directive GTISASIEEC as amended. Jicafon of dangat te tant ‘Reohrasels) RF: ritating to respiratory system, R38: ritatng to skin. Rt: Risk of serious damage to eyes. ‘S-ohrasels) "52: Keep out of the reach of cildren. 525: Avoid contact with eyes, 520: n ease of contact wit eyes, rnge immestately win plenty of water and seek mesial vice, 537: Wear suitable gloves. $530: Wear eyetface protection. 23 Other hazards “The substancs docs not moat the etera Yor PAT or vPvB subetance: No ther hazards identified3. Compositionfinformation on ingredients Substances Dare gry Noni eve ecto ns ub Fist aid measures = “Ei Description of fist ad measures SeneraLadvioe No known delayed effecs CConeulta physician forall exposures except for minor instances, Thslaion Move source of dust or ove person to esha Cbtain medica ttonton Immediate ‘Skincconiast Garey and genly bush the contaminated body surfaces n order to remove all races of product ‘Wash affected area immeciataly wih plenty of water. Remove contaminated clothing. skin irtaton persists, call a phystien Ringe immediately wih peniy of weter and sek oF medical advice. ES Tegestion ‘Clean mouth wth water and dink aerwards leny of water Do NOT induce vomiting (Obtain medical attention. “£2 Most important symptoms and effect, both acute and delayed ‘The eubetance is not acutely tox va the oa, dermal, or ination route, The subetanc=Ts fed as rating fo ekin and the respiratory Wack, and enalsavisk of seross damage to ye. There fs no concem for adverse systomic effects because local effec (pH+-flect are the major hear hazard “a indication of any immediate medical attention and special treatment needed Fallow the advice given in secton 4.1. 3. Firotighting measures Figen eer ‘Sulable exinguising media “The products nat combustible. Us a dry ponder foam oF COs fre extinguisher to exinguish the ‘surrounding fre. Use extinguishing measures that are appropriate te local croumstances and the surounaing fenironment salable exingulahing media Avoid umiaicaton. DONOT use water[2 Special hazards arising from the substance ormisture | Calcium oxide reacts wth water and generates heat. This may Cause risk to Rammable mater ‘Bi Advice for refighters ‘Avoid dus formation. Use breathing apparatus. Use extinguishing measures that are appropriate fo local droumstances and the surrounding environment 5, Accidental release measures 6:4 Personal precautions, protective equipment and emergency procedures 8.4.1 Advice for non-emergency Ensure adequate vetlation personnel ‘Keep dust evel to a minimum. Keep unprotected persons away. ‘Avold contact wih skin, eyes, and dothing — wear ‘ultable protective equipment (see section 8). ‘Avoid Inhalation of dust ensure that sufficient ‘entiation or stable respiratory protective ‘equipment is used, woar sulable protective ‘equipment (see section 8). ‘Avoid humifcaion. 8.1.2 Advice for emergency See soaon 617 responders (6.2 Environmental precautions ‘Contain the spilags. Keep the material dry Tf possible. Cove areal possble to avoid tionnencaney fist hazard, Avold uneonteled sls ta watercourses are drains (pM rising) Any large spllage Ito watercourses must be alerted to the Environment Agency or other Fegulatory body. ‘6. Mothode and materiale Tor containment and cleaning up ‘void dust formation, keep the material dry if possible. Pek up the product mechanically in a dry way. Use vacuum suction unit or shovel nto begs. {6.4 Reference to other sections: or more information on exposure contolelpereanal protean ar dlposal considerations, seat {7-4 Precautions foreafe handling TAs Protective measures ‘Aveid contact wih skin and eyes. For personal protection see sector 8. Keep dust levels fos mirimum. Minimise dust Jganeraton, Enciose dust sources, use exhaust entiation (dust collector at handirg points).Handling systoms should preferab y bo enclosed ‘When handling bags usual precasone should be ald fo the risk outined nthe Councl Directive S0768rEEC. " 7:42 Adviee on general occupational | Avoid inhalation, ingestion and oo iacl wih Sin hygiene and eyes General occupational hygiene mezsures ae eajuired o ensure eafe handling © the substance, ‘These measures Involve good personal and housekeeping pracices (ve. raguler decning with suable cleaning devices), no drinting, eating and ‘smoking at tho werkplace: Shower and change lathes at end of work hit. Do not wear ‘contaminated ching at home. 7.2 Conditions for safe storage, Including any incompatibiies ‘Sore aay place, inimise expoaure to air and molsture to avoid degradation, ‘Bulk storage should be In purpose designed sos. Keep out ofthe reach of chidren. Keep away from acids, significant quantities of paper, straw and nitro compourds. DO NOT use aluminium for anspor and storage there isa risk of contact wih water. 7.3 Specific end use(s) lease check te entiied uses in abla Tof the Appendixof he SDS For more information please see the relevant exposure scenario, avaliable vis your supple. 3, Exposure controleipersonal protection 3.1 Control parameters ment cones | SRee ae — cast ceamain [mean | ella [meni | py | cee Sett cnn | common [amicwome] age | Se" | 5 kata el = a aati coe pn mea cee ee oe | et [cute [cme [seem [aca | aero | it |, ‘SZ Exposure controls To contol potential exposures, generation of dst should be avoided. Furr, appropriate protective equipment Is recommended. Eye protection equipment (0g. goggles oF visors) must be worn, unless potential contact wih the aye can be excluded by the nature and typeof applieaon (Le, closed process). Addionally, face protecton, protective clothing and safety shoes are required to be wom as appropiate. Please check the relevant exposure scenario, given nthe Appendixavalabe via your supplier, ‘82.1 Appropriate enginosring controls | Handing systems should preteraby be enclosed or sultable vetlation installed to maintain. Smospheric dust below the OES, i not wear tilabhe protedive expen. ‘322 invidual protection measures, such as personal protective equlpmiont ‘32.2.1 Eyelface protection ‘Do not wear contact Tenses. Far poniers, ight ting goggles wit Side shields, or wide vision ful goggles. It Is also advisable to have naividual Docket eyewash. ‘82:22 Skin protection ‘Use approved alite Impragnated Goves hhaving CE marks Use clothing fully covering skin fl length pants, long siooved averats, with lose {ting at openings. Footwear resistant to caustics and avoiding dus! penetration ‘82.23 Respiratory protection ‘Local ventlaon to Keep levels below tablished threshold valuoe ie fecommended. A sulable parle fiter mask i recommended, depending on tho ‘expected exposure levels please check the relevant exposure scenario, given in the Appendfavalable via your supplier. ‘82.28 Thermal hazards The substance does not representa Termal hazard, tus special consideration $not required.‘32.3 Environmental exposure controls | Allvenilation systems shouldbe Hered Bator Aischarge to atmosphere. Contain the epilage. Keep the materia dry it possible. Cover area If possible to avoid Unnecessary dust hazaré, Avoid unconitalled ‘pills to watercourses ard drains (OH rising). ‘Any large spllage ino watercourses must Be flared fo the Environment Agenss or oer Feguatory body. For more information please S20 the relevant exposure scenario, avalible va your suppl 9, Physical and chemical properties information on basie physical and chemical properties ‘Appearance: ‘Colour white, ofPwhite, Begs Frm: Solid material of varying sizes: lump, ‘granular oF fine powder. ‘ious ‘Odoutess ‘Odour Threshois Nol applicable pH 72,3; 20°C; sauraied solution ‘eling port > 450°C; suey sul, EU A.1 mato Boing point ‘Not applicable (so witha meting point 450°C) Flash point ‘Not applicable (sod with melting point> 450°C), ‘Evaporation rate Not applicable (soid witha meling point > 450°C) Flammability: The products not fammable,; study result, EU Ax@method Explosive properties: TNon explosive (void of any chemical sructures ‘commonly associated wilh explosive properties). ‘Vapour pressure ‘Not epplcabl (sald witha melting point > 460 °C) Vapour density. Not applicable Density: 331 glen’, sudy rosul, EUAS method ater elaine 7.337,6 mal; study resul, EU AS nethod, Parton coefciont mocanol water Not applicable (inorganic substance), ‘ulin temperature 'No relative seigniton temperature below 400°C (ctudy result, EU A.16 method) ‘Decompostion temperature: Not applcabia ‘Not applicable (Said with a meling point > 450°) ‘Viscosity, Kinematic: ‘Oxiizing properties. 'No axalsing properties. (Based onthe chemical sructre, the substance does not contain a surplus of exygen or any structural groups known {o be comtelaod wih a tendency toreact ‘xothermally with combustible materia) Buledanaly [POO FOO KT ZO™ 70. Stabiiy and reactviy Oat Reactivity Callum oxide reacisexathermically wih water to form calcium dnydronide 0.2 Chemica stability Under normal eonalions of use and storage (ary condlfons), the products sable.70.3 Possibly of hazardous reactions "The product eacla exohermially wih adds, 0.4 Conditions to avoid Tinimiza exposure to airand malate to ave degradation. 10.5 Incompatible materials ‘Callum oxide reac sxathericaly with water efor caldum Ghvaronde, (G30 +140 Ga(Ol)a* 1155 kileg CaO |The product reacts exothermicaly with acids to fom sal. Reacts with aluminium and brassin the presence of moisture leading to the production of hydrogen, CaO #2A1+7HO + CafAl(OH)de+ 3 He 70.6 Hazardous decomposition products None Further information: CCalclum oxide absorbs moisture and carbon éloxide from arto form calcium caibonate, which {sa common material in the nalute, 7H, TexTeotogieal information “is lnformation on toxicological effects ‘ate toxicity ‘ora Upso > 2000 malig bw (OECD 425, rat) Dermal LD50 > 2500 malkg bw (calcium dinyraxde, OECD 402, rabbit), by ead across these resus are also applicable to calcium oxide, since in contact with !moiture calcium hydroxide is formed. Inhalation no data avaiable CCalclum onde is not actly txt. ‘Classification for acute tilly isnot warranted. ‘Skin corresionfiritation ‘Calcium onda is intating to skin (In vivo, rabbi. Baved on experimental recut, calcum ove requires lasliicaton as tating to skin [RE iitaing to skin; Skin lt 2 (H346 ~ Causes skin itaon)] Serious eye damageleye iitation CCalcum oxide entalls a risk of serious damage tothe eye (eye itation studies jn vivo, rabbit, Based on experimental results, the product requires cassifation a severely irtating tothe eye [Rat Risk of serious damage to eye; Eye Damage 1 (H318 - Causes serious eye ‘damage Respiratory or skin sensitisation No dala avalable. “The producti considered not tobe a skin sensiser, based on the natu shift) and the essential requirement of calcium for human nution Claseication for sensitisation Is not warranted ofthe fat (pH‘Germ cell mutagentaliy Bacterial reverse mutation assay (Amos test, OECD 471): Negative Inview of the omnipresence and essontialty of Ca and ofthe physiological non-selevance of ‘any pH shift induced in equeaus medi, calclum oxide Ie obviuely void of any genotoxic, potent, Induding germ cell mutagenicity. ‘Cassifeation for genotoxicity is not warranted Garcinogenicity Galcum (administered 2s Ca-latate) Is not carcinogenic (experimental result at). The pH ‘effet ofthe product does not give fie to a arcinogenic risk. Human epidemioogical dat Suppor lack of any earenagenie potential of the product. Classtation fr carcageniay fe not warranted. Reproductive toxicity Callum (administered as Ca-carbonato) Is nt toxc to reproducton(experimertal result, ‘mause). The pH effect does not giverise toa reproductive risk Homan epidemiological dala support lack of any potent for reproductive toxity ofthe product Both In animal studies and human clnical studies on various calcium sas no Fprodictve of developmental effects were detected. Also see the Scenic Cammites on Food (Section 10.6). Thus, the products no! xo for reproduction andlor development Classlcation for reproductive toxety aecorlng to regulation (EC) 1272/2008 isnot required. ‘STOT - single exposure From human data ite concluded that clclum oxide is ieitating tothe respiratory tract [As summarised and evaluated inthe SCOEL recommendation (Anonyvous, 2008), based on human cata calclum oxide Is classified asiitting to th respratory system [7, Intating to respiratory aystom, STOT SE 3 (H395 ~ May cause respiratory ination) STOT- repested exposure “Tania of callum via tha orl ruta is adrasel by upper Intake levels (UL) for adults determined by the Scene Committoe on Food (SCF), being UL = 2500 mgld, corresponding to 38 mgfkg bwid (70 kg person for calcium. ‘Toxo of te product va the dermal routes not considered as rlevantin view of the nicpated inigicant absorption tough skin and duet local ation as the primary he teffect (oH shit). ‘Toric ofthe product va inhalation (local effec, tation of mucous membranes) is addressed by an @-h TWA determined by the Scintifc Committee on Occupatonal Exposure {mits (SCOEL) of t mal” respirable dust (see section 8.) ‘Therefore, clascaton ofthe produc! fr oxy upon prolonged exposure is not requted. ith Aspiration hazard ‘The products not known to present an aspiration hazard, 2, Ecological information [2 Toxicity HAA Toxicity w feh {{050 (Goh) for eahwater ah 50.6 mg (elcurt sinyéroxde) {EC80 (06h) for marine water fish: 487 mg. (calcium ainyeoxide)“2A2 Toxiety to aquatic Invertebrates] ECS (4ah) for Feshwater Iericbrates! 40.1 mg. (caldum ainydroxie) UC0 (Gah) for marine water Invertsbrates: 158 gl (celelum dhyaroside) "EAS Chron toxieiy C50 (72h) or freshwater algae’ TEST ma ‘aquatic plants (caloum ainycroxde) NOEC (72h) for freshwater algae: 48 gi. {caloum dinydroxide) "TEA Toxicity to mieroorganieme7 | Athigh concenivatio, through tha tee of Toxicity o bacteria {emperature and pH, th productis used for ainfecion of sevage sludge. 72:18 Tonllty to daphnia and NOEC (144) for marine water inveriabratosr other aquatic ivertobrates ‘2m (calelum dhydroxsde) 42.4.6 Toxiolty to soll ECTO/LC10 of NOEG for soll macrooganion= dwelling organisms 2000 mfg sol dw (calcium dinydroxde) ECHOILC10 oF NOEC for soll miccoorganisms: "72000 mg/kg sol dw (caleum dihyeroxde) TBAT Taniety to teresical plants | NOEC (216) for terest plants: 1050 maka (calcium dinysroxde) TAB Oiher effects Acute pFreffect Athough tis predicts use Correct water acai, an excess of nore than 1 gh. may be harmful to squat Ife. pri-alue of> 12 vil rapily decrease as result of dlston and carbonation. "2.1.9 Other information ‘The resuls by read across ave alco appeable calelum oxide, since in contact with moisture Calcium hyde is formed. "Taz Persistence and dogradabiliy - Hot elevant for organic substan. "723 Bioacsumulative potential [Notrelevantforinowaniosubslanoos “2a Mobily soi sla with water andlor carbon dlonde io form respectively caldum calclum carbonate, which are sparingly soluble, and presen alow mobility 42.5 Rasulla of PBT and vPvB assessment Tat alevant Yor inorganic substances. 2.8 Oiher adverse effects TNo other adverse affects are ented"5. Disposal considerations 713.4 Waste treatment mothods Disposal ofthe product should be a accordance wih local and national agitation, Processing, use or contamination of Ws product may change tne waste management options Digpose of container and unused contents in accardanca with applicable member state and local requitements “The used packaging Is only meant for packing this roduc it shoud not be reused for other purposes. "Td Tranaport information Cal oxide not classified as hazardous fr waneport (ADR (Road), RID (Ral) “7a UN number UN 1910 EUW proper ppg nae Gaim one 43 Tanopon arava Sas] Gass e(arAC} Stes (bo) {it runber 1910 std IMD (Avance 2-08) Ta Packing rou [Group (ATA) {Group Ii (MDG) “14 Environmental hazards ‘None +146 Special precautions for usor “Avoid any release of dust during vanaparaon, by uang air ht tanks Tor ponders and ‘covered Tucks for pebbles. [747 Transport tn bull according to Annex W of WARPOL TSI7e arate wt wade] mol regulated 5. Regulatory information 15: Saf, health and vrnmental vogulansTogaalon spel ore substance or mixture -Authorsatons Not required Resticions on se. None ‘Other reguiabons (European Union) |The productis nota SEVESO substance, natan ‘ozone deplating substance and nota persistent frganie pola. ‘atonal requiatory information ‘German legisiaton on water endangering substances Vi WS slighly water endangering (WGK 1) [18:2 Chemical Safety Assessment =| ‘A Chemical Safely Assessment has been cared oul for tis subSlano. 16. Giker Information ‘Data are based on our lalet knowledge but do nol consis a guaratea for any epectic prodict features and do not estaish a loglly vala contractual relationship.net “6 Hazard statements SIS: Causes anita: Hata: Causes eerous eve damage. 335: May cause respiratory lato. 16.2 Precautionary statements YOR: Koop oul of reach of len, 280; Wear protective gloves! protective othing! ‘ee protection! face protection, P05 + P31 + P36: IF IN EYES: Rinse cautously ‘ith water for eaveral minutes. Remove contact lenses If present and easy o do, Continue rinsing. F310: Immediately calla POISON CENTER of doctor physician 302 + P352: IF ON SKIN: Wash wth plenty of '09p and water 261: Avolé breathing dust fume! gus! mist vapours! epray. F304 + P340: IF INHALED: Remove victim to ‘tosh ar and keop at rest in a positon comfortable for breathing, P50!: Dispose of contentsfcontanerin accordance wit local reguation. 76.3 Rephrase(e) RST: rating fo respiratory ystems. a8: rating to sk Rt: Risk of serous damage to eyes. Tea S-phrasele) ‘SE, Reon out of ie reach of cher. 1825: Avoid contact ith eyes. ‘526: In ease of contact wth eyes, rinse immeciataly with plenty of wator and advice, 37: Wear sulable gloves. $38: ‘Wear eyeace protection 65 Abbreviations NEL Darived no effect evel ECS0: median effective concentration LLcS0: median lethal concentation LLD50: median lethal dose NOEC: no observable effect concentration (EL: occupational exposure limit PBT: persistent, bioacoumulatve, toxic chemical NEC: predicted no-ffect concentration SDS: Safely data sheet 'STEL: chor-ierm exposure limit STOT: speci target organ toxicity TWA ime weighted averege PVE: very persistent, very bloaccunulatve chemicalamore 76.6 Literary reference “Anonymous, 2006: Tolerabe uppar Tak levels for vianine and minerale Scent ‘Commities on Food, European Food Safety Aubhorty, ISBN: 62-9199-014-0 [SCF document] ‘Anonymous, 2008: Recommendation fam the Scientific Committee on Oceupatonal Exposure Units (SCOEL) for calclum oxde (Ca0) and ealcium dinydrovie (Ca(OH)2), European ‘Comntssion, DG Employment, Social Aas and Equal Opportunies, SCOELISUMVS7 February 2008 16:7 Additions, Deletions, Revisions = ‘Changes sie te st version are ghia rH arg Ts varson Teas al TEVOTE Disclaimer "This safety data shoot (SDS) s based onthe legal provisions ofthe REACH Reputation (EC 1907/2008; aisle 31 and Annex is are Inlended as 2 guide to the _apptoptate precautionary handling ofthe materi tis the responsiblity of recipients ofthis SSDS to ensure thatthe information contained theran is propery read and undettood by all People who may use, handle, dispose orn any way come in contact withthe produc. Information and instructions provided inthis SOS are based onthe current sat of eclentiic ‘and technical krowledge a the date of issue incited, I should not be construed as any ‘uaranioe of technical performance, sultaily for paricular applications, and doos not ‘establish a legally valid contracualrelalionship. This version a the SDS eupersades all previous version. APPENDIX: EXPOSURE SCENARIOS FOR EUROPE AVAILABLE ON REQUEST End of Safety Data Sheet