Waite the TUPAC name of the following compound: ¥jC—TH— CH —CH—CH—CH,OH CHS OH CH; Arrange the following compounds in an increasing order of their acid strengths: (CHy)) CHCOOH, CH; CH) CH(Br)COOH, CH; CH(Br) CH) COOH ‘Write a chemical reaction in which the iodide ion replaces the diazonium group in a diazonium salt. Explain as (0 why haloarenes are much Tess reactive than haloulkanes towards nucleophilic substitution reactions ‘Which compound in each of the following pairs will react faster in S32 reaction with —OH? Why’ ()_CHBr or CHI (i) (CH) ,CC1 or CHCl {@) Stato the TUPAC name of the Following compound: ne W poe ‘Complete the following chemical equation: peroxide (CH,CH,CH=CH, + HBr ———> . ‘Name the reagents which are used in the following conversions: (A primary alcohol to an aldehyde (if) Butan-2-one to butan-2-ol (iii) Phenol to 2, 4, 6-tribromophenol ‘Account for the following observations: (0. pK, foraniline is more than that for methylamine, (i, Methylamine solution in water reacts with ferric chloride sol Inydroxide, (iii) Aniline does not undergo Friedel-Crafts reaction. to give a precipitate of ferric (@ Compicie the following reaction statements by giving the missing starting material, reagent or product as required: o mao “ SQCHCHS xiao, (i ce Z ‘KOH, heat a How would you account for the followi () Aldehydes are more reactive than Ketones towards nucelophiles. (ii) The boiling points of aldehydes and ketones are lower than of the corresponding acids, (iti) The aldehydes and ketones undergo a number of addition reactions. Describe the following reactions: @ Cannizaro reaction (W) Cross aldol condensation ‘Wilts the TUPAC name of the following compound: C,COCH. COCH.~ Complete the following reaction equations: (@ CgHsNoQ+ KI —> HA con wo =CQ + By 4 we (i) Why is it that haloalkanes are more reactive than haloarenes towards nucleophiles. (ii) Which one of the following reacts faster in an Syl reaction and why? a . & Ae - ~ (a) How will you bring about the following conversions? (Ethanol to acetone ii) Benzene to acetophenone (iii) Benzoic acid to benzaldehyde (b) Describe the following giving a suitable example in each case: ( Decarboxylation (ii) Cannizaro’s reaction ‘An onganie compound contains 69.77% carbon, 11.63% hydrogen and the rest is oxygen. The molecular mass of the compound is 86. It does not reduce Tollens’ reagent but forms an addition compound with sodium hydrogen sulphite and gives positive iodoform test. On vigorous oxidation it gives ethanoic and propanoic acids. Deduce the possible structure of the ‘organic compound. ‘State reasons for the following: (J) Monochloroethanoic acid has a higher pKa value than dichloroethanoie acid, Gi) Bllknwie avid iy # weaker acid Ua benvic avid, Give the TUPAC name of the following compound: H,C=CH—CH—CH,—CH,—CH, ou ‘Arrange the following compounds in an increasing order of basic strengths in their aqueous solutions: 1 NH, CHyNH), (CH,)NH, (CH) \N Which one in the following pairs undergoes Sy, I substitution reaction faster and why? a a a aN oe aK 4 M ARE ew AO ‘Complete the following reaction equations: CH; 0 OT oe (ii) CH3CH,CH= CH) +HBr >‘Complete the following reaction equations: ° Il () R-C-NH, HAL, 1,0 (i) CgASN-CI + H,PO;+10 —> (iii) CgGNFs + Bry (ag) —> Explain the following observations: (@ The boiling point of ethanol is higher than that of methoxymethane, (Gi) Phenol Gii) o-and p-nitrophenols are more acidic than phenol more acidic than ethanol. (@) Write chemical equations to illustrate the following name bearing reactions: (@ Cannizzaro’s reaction (ii) Hell-Volhard-Zelinsky reaction (b) Give chemical tests to distinguish between the following pairs of compounds: (@ Propanal and Propanone (i) Acctophenone and Benzophenone (Git) Phenol and Benzoic acid (@) How will you bring about the following conversions: (@ Ethanol to 3-hydroxybutanal (i) Benzaldehyde to Benzophenone. (6) An organic compound A has the molecular formula CgH,gO.. It gets hydrolysed with dilute sulphuric acid and gives a carboxylic acid B and an alcohol C. Oxidation of C with chromic acid also produced B. C on dehydration reaction gives but-L-ene. Write equations for the reactions involved. ‘Complete the following resetion equations: ( CHsN,Cl + CH;COCL —> (i) CHNH, + C,H,80;C1 —> (ii) CHNH, + HNO, —> (a) Give chomical tots to distinguish between compounds in the following pairs of substances: ( Ethanal and Propanal (i) Benzoic acid and Ethyl benzoate () An organic compound contains 69.77% carbon, 11.63% hydrogen and rest oxygen. The ‘molecular mass of the compound is 86. It does not reduce Tollen’s reagent but forms an addition compound with sodium hydrogenstlphite and gives positive iodoform test. On vigorous addition, it gives ethanoic and propancic acids. Derive the stucture ofthe compound ‘A’. 5 ) Arrange the following compounds in an increasing oeder oftheir indicated prope ( Benzoie acid, 4-Nitobenzoie acid, 3,4-Dinitrobenzoic acid, 4-Methoxybenzoie acid (acid strength) Gi) CHCH,CH(BCOOH, CHyCH(Br) CH;COOH, (CH,);CHCOOH, CH,CH,CH-COOH (acid strength)How would you bring about the following conversions: (@ Propanone to Propene (ii) Benzoic acid to Benzaldehyde (iii) Bromobenzene to 1-phenylethanol