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Mercury Pool Boiling Under The Influence of A Horizontal Magnetic Field
Mercury Pool Boiling Under The Influence of A Horizontal Magnetic Field
‘O
Printed m Great Britain 0 1981 Pergamon Press Ltd
Abstract-Experimental results for the pool boiling of pure mercury and mercury plus wetting agents in the
presence ofa magnetic field are presented. The results indicate that a significant reduction in the heat-transfer
coefficient occurs as the magnetic field is increased, the incipient boiling heat flux is lowered, and the
transition to film boiling is encouraged. Data are presented for magnetic fields of 0.4,0.8 and 1.26 T at the
saturated pressures of 0.0066, 0.026 and 0.1 MPa.
635
636 LORRY Y. WGNEK and PAW S. L\~o~~Ixs
VENT
VENT
--NITROGEN SUPPLY
The system was initially prepared by cleaning all the was located at 20mm above the boiling surface.
stainless steel components in an acid bath and then After the data were established with pure mercury,
flushing with distilled water. The boiling surface was 10 ppm titanium and 200 ppm magnesium were added
then prepared and the apparatus assembled. At this to the liquid as wetting agents. The same data acqui-
point, the system was flushed with trichloroethylene sition procedure was used and the experiment
and then flushed again with distilled water. The repeated.
calibration procedure for the heat losses was perfor- A schematic of the instrumentation is shown in Fig.
med and then the system was pressure and vacuum 3. The PDP 11103 minicomputer was programmed to
tested. The boiler was now ready for the initial boiling read the signals over a selected time interval, take an
tests with water. Several runs were made to check the average, display the voltage readings, and then reduce
surface characteristics and provide experience with the the data to engineering values (pressure, temperature.
apparatus and instrumentation. When the water tests etc.). This system enabled the experiment to be moni-
were finished, the boiler was again filled with tri- tored continuously, while also providing a current
chloroethylene and flushed with distilled water. This analysis of the data.
completed the preliminary tests and the system was The heat flux through the surface was the only
ready for the boiling mercury runs. The boiler was parameter that was not directly measured. The total
filled with quadruple distilled mercury to a level of heat input was known from the heater voltage and
40 mm and pressure and vacuum tested again. current readings, however, the losses through the
During the course of the experiment a standard insulation had to be determined. Two methods were
procedure was used to take the data. A saturated used to do this. The first way was to calibrate the
pressure was established in the system and then the energy loss with the heater temperature. At a given
heat flux woud be varied from zero to the maximum power input with the boiler empty and evacuated, the
with the system stabilized at each power level for energy loss through the insulation is the total power
20G30min. The magnetic field was then set and the minus the surface radiation. Therefore, at this heater
procedure was repeated. This was done for each temperature, the insulation loss is known. When the
magnetic field setting (0.4,0.8 and 1.26 T) and then the boiler is filled with mercury, it is estimated that the
zero field data were repeated. The final check of the same energy is lost through the insulation when the
data consisted of picking several heat fluxes and then heater reaches the calibrated temperature. In this way
varying the magnetic field from zero to 1.26 T and back the heater temperature can be used to calibrate the
to zero. The results of this process indicated that the energy losses in the system. The second way, employed
data were very repeatable and that the nucleate boiling the direct calculation of the heat transfer through the
in the system was stable. For each system pressure, a insulation. The temperature field of the boiler as-
traverse of the entire fluid depth was made at 3 hea.t sembly was calculated by a relaxation method 1231
flux levels in the nucleate boiling regime. The results of with the thermocouple temperatures in the insulation
these measurements indicated that the temperature used as input. The calibration technique was used in
variation in the pool was less than 1“C for 0.1 MPa and the on-line data analysis, while the more accurate heat-
as great as 4°C for a saturated pressure of 0.0066 MPa. transfer calculation was used for the final data analysis
For the bulk temperature measurements, the probe For a heat flux of 35 kW/m’ the maximum loss was
HEATER CuRRENTHSHUNTl
TRANSDUCER
II
ACOUSTIC STORAGE
TRANSDUCER OSCILLOSCOPE
SPEAKER
15% and at the maximum flux of 310 kW/m’ the heat nucleate boiling results obtained at this time represent
loss was 5%. Further details are available in [24]. the “pre-aged” data.
As the surface “aged” over the first two months of
operation, there was a gradual increase in the
THE RESULTS superheat for a given heat flux. This is shown by the
The first nucleate boiling data were obtained with translation of the data to the right. After this time, the
water at a saturated pressure of 0.1 MPa. The data can system remained unchanged and the temperature data
be seen in Fig. 4 along with the water results from were repeatable to within k 2.5%. The results of stable
several other liquid metal boilers [19, 25, 261. The nucleate boiling for the pre-aged and aged states are
heat-transfer rates from this experiment are seen to be presented in Fig. 5. Bonilla et al [18], Michiyoshi et al.
in agreement with those obtained by the other [13], Takahashi et al. [16], and Lyon et al. [26] also
investigators. boiled pure mercury on stainless steel, however, only
The initial experiments in mercury indicated that the first two systems were able to achieve stable
film boiling was present. (This type of non-wetting film nucleate boiling. This data is presented in Fig. 6 along
boiling has been reported in the literature [17,18,26].) with the present work. The agreement at 0.1 MPa is
Due to the poor wetting conditions that existed reasonable, while at 0.0066 MPa the similarity is
between the mercury and stainless steel, it was re- remarkable considering the differences in surface
latively easy to form a vapor blanket. In the first 60 s of preparation.
heating at 46 kW/m’, the surface temperature rose to When a magnetic field is applied, the data indicate
100°C above the saturation temperature (356.6”(Z) that a significant reduction in the heat-transfer co-
before the power was reduced to protect the system. efficient occurs. The results in pure mercury for the
After approximately 20 h of continuous operation, saturated pressures of 0.1 MPa (760mmHg),
nucleate boiling began to appear. This regime was 0.26 MPa (200 mmHg), and 0.0066 MPa (50 mmHg)
stable up to a heat flux of 82 kW/m’, at which point are presented in Figs. 7, 8 and 9 respectively. For a
film boiling reappeared. As the wetting improved over given superheat, a magnetic field of 0.4 T will reduce
the next 10 h of operation, the nucleate boiling regime the heat-transfer coefficient by 20% while at 1.26 T the
was stable at progressively higher heat fluxes (up to reduction is on the order of 55%. The results of
310 kW/m’), and film boiling did not reappear. The Takahashi et al. [16] are also included in Fig. 9 as
a comparison. While trends in the heat-transfer re-
5-
-
Tsat = 356 OC
>_ - P sat = 0.1 MPa
A
2
IO' 0
<3-
I3- 08A
_ T- A
r 7- : CT 4
: 6-
0-
5-
CO A
3 0
8 A o Pre-Aged
2 A Aged
CO&
IO’- 30
IO’
6
I I II
7 8 9 IO
I
20 30
(“Cl
ATsot = Tw - Tsot (“Cl
= T, - Tsot
ATSat
FIG.5. Heat flux vs superheat for the pre-aged and aged data
FIG. 4. Heat flux vs superheat for boiling water in pure mercury.
LORRY Y. WAGNER and PAIJI S. LYKOU)IS
640
3-
IO3 l’l”1 I I ‘I
z--
7-
I I
Bonilla et al. 2-
6-
5-
4-
@I: IO2 -
”3 ,“-
7
:
D 6-
5-
N^ IO2 - 4-
E -
i-
‘;
’ 7-
6-
::
w 5- 0.0 7 I
4
0.4
0.6 T 1
: I
3
I
1.26 T
2 O I
lOlL--J--J
o This Work - 0.1 MPa I IO 20 30 40 50
A This Work - 0.0066 MPa AT,,, = Tw - Tso+ PC)
1011
2 3 45 7 10 20 30 50
ATsat T, - TSa+PC)
q
Frc,. 8. Heat flux cs superheat for pure mercury m the
presence of a magnetic field.
FIG. 6. Heat flux vs superheat for pure mercury
4
T sat = 356.6 “C
P = 0.1 MPa 3
0
2 0 2
0 qA
&A
A
IO2
9 O0A IO2
c,-
A
00 eI-
A 7
0 - E
qA “E
\
: ,-
0
r3 4I-
0
z
qA CJ- : i-
0 3
0 0.0 T
0 0.4 T
0 0.4 T ; >_
0 qA
A I.26 T
t”‘6w 6C I
IO
IC
Tw - TSo+ (“C) T, - T,,+ PC)
FIG. 7. Heat flux vs superheat for pure mercury in the FIG 9. Heat flux vs superheat for pure mercury in the
^.. oresence of a magnetic field.
presence ot a magnetic held.
Mercury pool boiling under the influence of a horizontal magnetic field 641
The phenomena of natural convection-nucleate [14]. Even though the geometries of each of these
boiling bumping is also illustrated in Figs. 8 and 9. The systems are different, the fundamental process is the
heat-transfer mode did not make a smooth transition same.
from natural convection to nucleate boiling. As the The pre-aged data for pure mercury at 0.0066 MPa
heat flux was increased during natural convection, a clearly show the effect a magnetic field has on initiating
point was eventually reached where this heat-transfer film boiling. During the first experimental runs at this
regime was not sufficient to remove all the energy. At pressure, nucleate boiling was established at each
the same time, the heat flux was not great enough to point for 15 min and then the data were recorded.
support stable nucleate boiling. The surface tempera- However, when the heat flux reached 220 kW/m’, a
ture would gradually increase above the liquid satu- new phenomenon occurred that was distinctly different
ration temperature until a boiling burst occurred. At from all previous results. Initially, nucleate boiling was
this point the temperature dropped rapidly and the established without the magnetic field, but when it was
process was repeated. The bulk temperature also applied an abrupt transition in the boiling process
followed the same pattern. It would superheat and resulted. The surface temperature rose from 27O.l”C to
then after the burst, drop to the saturation level. The
lower portion of the curve represents the bumping
regime, whereas the upper part describes stable nuc- ‘-
leate boiling. This phenomena was reported in the
literature for other liquid metal systems [17,21]. When
the transition from bumping to stable boiling occurs,
the temperature driving force actually decreased. This
forms the basis of the characteristic S-shaped curves as
reported by Ore11 [27]. As the heat flux is raised, the 0 Qn
frequency of bursts increases, and eventually a point is IO2- 0 0 A.0
reached where stable nucleate boiling can be sustained. 9- 0 O.OT
- Q
At this time the surface temperature actually drops N< 7 -
a 0 0.4 T ~ah
00
with an increase in heat flux (above 80 kW/m’). A large 3 6 - 0 0.8 T
number of nucleation sites have become available and _ 5- a 1.26T a c%
:
the heat-transfer process is more efficient. In order to
CT 4- 00 Q
maintain the heat-transfer rates at a given heat flux, the
3-
superheat must decrease. Ultimately, a heat flux is
0 OQ
reached where any subsequent increase is accom-
panied by an increase in superheat and stable nucleate 2-
1
The effect of a magnetic field on the incipient boiling 0 0
heat flux can be seen in Fig. 11. As the magnetic field
0 0.1 MPo
0.4 _j
increases, boiling bursts occur at a lower heat flux than
A 0.0066 MPo
in the absence of a magnetic field. During the natural 0.2
over 495’C in 5 min, indicating that film boiling was progressively higher heat fluxes. After a period of two
present. If nucleate boiling had existed with only the months, the system was completely aged and the data
normal reduction in heat transfer due to the magnetic remained unchanged. It is believed that the large
tield, the surface temperature would have been appro- number of nucleation sites promoted stable nucleate
ximately 285°C. Since the surface temperature in film boiling after only 30 h, whereas in the case of pre\ious
boiling at this heat flux could be several hundred work, several weeks were necessary before this occur-
degrees higher [16,18] the decision was made to red. While the exact relation between surface rough-
!erminate the experiment at this point. Therefore, the ness and wetting is not discernible, it appears that ;I
data in Fig. 12 for film boiling do not represent a stable rough surface promotes early nucleate boiling with
value, but only a transition point into the film boiling pure niercurq.
regime. Nevertheless, it is clear from these experiments The data from all of the experimental runs clearly
that the magnetic field caused film boiling to occur indicated the complexity of the boiling procesh in
when stable nucleate boiling previously existed. liquid metals. The key factor that determined the
existence of any given heat transfer mode was the
wettability of the liquid surface combination 41 a
An experiment has been performed that clearly given heat flux and superheat any one of the three hea-
shows the effect of a horizontal magnetic field on transfer regimes (bumping, stable boiling or film
nucleate boiling heat-transfer rates. Pure mercury apd boiling) could have been present. depending upon th<
mercury plus wetting agents were boiled on a horizon- wetted or aged state of the system. It sas also shown
tal surface in a reflux-type boiler at saturated pressures that the stable boiling attained in an aged system could
of 0.0066, 0.026 and 0.1 MPa under magnetic tields of be readily obtained in a fresh system by providing
0.4,0.8 and 1.26T. Data were presented that showed additi\,es (magnesium and titanium I IO the mercul-t
the magnitude of the heat-transfer reduction in nuc- When the magnetic field was turned on, the main effect
leate boiling was as much as 55”, at a field of 1.26T. was one of reducing the heat-transfer coefficient.
Additional data were provided that showed the in- However. at certain points in the natural convrctioI1
cipient boiling heat flux was reduced as the magnetic and film boiling regimes, it was possible to promote the
field increased. This reduction is on the order of 50’:,, onset of nucleate boiling and film boliing, respectively.
when compared to the zero field case. The presence of a Further work is required in order to define the
magnetic field also causes the transition to film boiling conditions that lead to the transition of one heat-
to occur when nucleate boiling was initially present. transfer mode to another, whether It be b> aging.
A description of the aging process in this experiment wetting or the application of magnetic field.
was presented that showed how the heat-transfer
regimes change over time. For the initially non-wetted Ack!lo~ledgemenrs- The authors wish to acknowledge the
system, film boiling was predominant, however, as the helpful advice of Dr W. Leidenfrost for rhe many suggestion\
in the design of the experiment. In addition, we would like to
system aged, stable nucleate boiling appeared at
thank George lirbanus for his help and expertise in C~Q-
strutting and calibrating the resistance thermometer>
4 The support of the National Science Foundation under
I I ’ I ‘I’ll
Grant ENG77-26971 is gratefull! acknowledged.
3-
O0 v-r--A
2-
$ now Stable to this point 1. A. P. Fraas. Conceptual design of the blankel and sineId
region for a full scale toroidal fusion reactor. USAE<
4$ Lz
Report ORNL-TM-3096 (19731.
@ n 2. Y. Fujii-e and T. Suita, IAEA workhhop on fusion reactor
IO’- 0
9- Tsot = 235.5 “C design problems, Paper No. 14. (‘ulham (1974).
0
a- 0 n ? J. H. Pendergrass, L.. A. Booth. D. R. Peterson and S A.
7- P = 0.006E MPa
sat W Gerstl, The lithium holler : d 1 SO0 to 2OCG K fusion
“E
\ 6- A reactor blanket concept for prl,cess heat and,or rlectrlc
5- * n
3 power generation, LASL Report LA-UR-79-1316 (19791.
5 4. J. Hartmann and F. Lazarus, Hg-dynamics II, experimen-
: 4%
D
tal investigations on the How of mercury in a homil-
3- geneous magnetic field, Dr. Kg/I. Dtrnsk Videnskcih ‘;ri-
0 0.0 T skuh. Math-f&s. Mrdd. l!?(7). 1 (1937).
0 1.26 T 5. R. A. Gardner and P. S. Lykoudls. Magneto-fluid-
mechanic pipe flow in a transverse magnetic field, ./. !- lu:ri
Me&. 48, Part I, 129. 141 (19711.
6 E. C. Brouillette and P. S. Lykoudis, Magneto-fluld-
mechanice channel flow. 1. Experiment, P~v\~c\ Fluids
10(5), 995 1007 (1967)
7. P S. Lykoudis, Bubble growth m rhe presence l>f a
ATSat= Tw - Tsa+PC) magnetic field, Int. .I. IIerrr .IJtrsv 7‘r1rt1,@ 19, Ii57 I?61
(1976).
~.‘Ic;. 12. Heat flux vs superheat for pure mercury the 8. L. Wagner and P. S. Lykoudis. The effect 01 I~quld mertla
transition to film boiling. on bubble growth in the presence of a magnetic field,
Mercury pool boiling under the influence of a horizontal magnetic field 643
A.1.Ch.E. Sym. Ser. 73, No. 164, 1422147 (1977). Nuclear Society (1976).
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magnetic field, in Proceedings of the 8th Symposium on mud and A. Ramachandran, Pool boiling heat transfer
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2075-2077, IEEE Pub. No. 79CH1441-5 NPS (1979). 51-57 (1957).
10. V. J. Lunardini, An experimental study of the effect of a 19. N. Madsen and C. F. Bonilla, Heat transfer to sodium-
horizontal magnetic field on the nucleate pool boiling of potassium alloy in pool boiling, Chem. Engng Prog. Sym.
water and mercury with 0.02% magnesium and 0.0001% Ser. 56, No. 30, 251-259 (1960).
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Transfer 23, 27-36 (1980). 27. A. Orell, On S-shaped boiling curves, Znt. J. Heat Mass
17. 0. Dwyer Boiling Liquid Metal Heat Transfer. American Transfer 10, 967-971 (1967).
R&.mn&-On prlsente des risultats experimentaux sur l’tbullition en reservoir du mercure pur et du mercure
avec des agents mouillants en presence dun champ magnetique. Les resultats montrent qu’une reduction
sensible du coefficient de transfert thermique so produit lorsque le champ magnetique augemente, le flux de
debut d’ibullition est diminut et la transition a l’ebullition en film est favor&e. Des don&es sont presentees
pour des champs magnetiques de 0,4,0,8 et 1,26 T aux pressions de saturation de 0,0066,0,026 et 0,l MPa.
Zusammenfassung-Es wird der Einflug eines waagerechten magnetischen Feldes auf das Behaltersieden von
reinem Quecksilber und Gemischen aus Quecksilber und oberfllchenaktiven Stoffen untersucht. Wie die
Versuchsergebnisse zeigen, nimmt der Warmeiibergangskoeffizient stark ab, wenn die Starke des magneti-
schen Feldes zunimmt : Die anfangliche Warmestromdichte beim Sieden wird kleiner, und der Ubergang
zum Filmsieden wird gefordert. Versuchsergebnisse werden fiir magnet&he Felder von 0,4; 0,8 und 1,26 T
und fur Dampfdriicke von 00066; 0,026 und 0,l MPa mitgeteilt.