Answer Key Atomic Structure

Solutions Slot – 1 (Chemistry) Page # 1
ATOMIC STRUCTURE
EXERCISE – I SINGLE CORRECT (OBJECTIVE QUESTIONS)

Sol.1 For Lymen series 1 3
= 109700 ×
1  1  λ 16
= RHZ 2 1 − 2 
λ  n  1
 2 = 20568.75
λ
 1  λ = 4.861 × 10–5 cm
= 109700 1 − 
= 4863 Å Ans.
 16 
1 15
= 109700 ×  1 1 
λ 16 1  −
Sol.5 = RHZ2 n 2 2
1 λ  1 n2 
= 102843.75
λ 1 1
λ = 9.72 × 10–6 cm λ1 – λ2 = −
 1 1 1 1 
λ = 9.72 × 10–8 m Ans. RHZ 2  −  RHZ 2  − 
4 9 1 4 
Sol.2 rH(1s orbit) = 0.529 × 10–10m
re = 16 × 0.529 × 10–10 m 1 1  36 4 
10–9 × 133.7 = × −
= 16 × 0.529 Å RH 4  5 3 
1 KZe 2 1 9 1
T. E. = – 10–9 × 133.7 = −
2 r RH  5 3 
1 9 × 109 × 1× 1.6 × .1.6 × 10 −19 × 10 −19 1  22 

=– × 10–9 × 133.7 =  15 
2 16 × 0.529 RH  
⇒ – 13.6 × 10–20 J
⇒ – 1.36 × 10–19 J Ans. 1 133.7 × 15 × 10 −9
RH =
22
Sol.3 λ = 1093.6 nm ⇒ RH = 0.01096 × 10+9
= 1093.6 × 10–9 m = 1.096 × 107 m–1 Ans.
1  1 1 
 
= RHZ2  2 − 2
1093 .6 × 10 −9 3 n wight  1 1 1 
Sol.6 = 109700 × 4  4 − 16 
λ  
9.14 × 105  1 1 
= −  1 1 1 
10973000  9 n2  = 109700 × 1 − 4 
λ  
1 1
0.083 = – 2 1 3
9 n = 109700 ×
λ 4
1 1 λ = 1.21 × 10–5
2 = – 0.083 For Hydrogen
n 9
3  1
1 109700 × = 109700 × 1 1 − 2 
= 0.11 – 0.083 4  n 
n2
n2 = 35.93
n = 6 Ans. 1 3
=1–
1 1 1  n2 4
Sol.4 = 109700  −  ×12 n=2
λ  4 16 
i.e., transition from n = 2 to n = 1 Ans.
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Page # 2 Solutions Slot – 1 (Chemistry)
Sol.7 For visible region i.e. balmer series n1 = 2 and for min hc 2.18 × 10 −18
=
energy transfer = n2 = 3 λ 22
1  1 1 5
= RH  2 − 2  = 1.1 × × 107 m–1 6.6 × 10 −32 × 3 × 108 × 22
λ 2 3  30 λ=
2.18 × 10 −18
λ = 6.55 × 10–7 m = 36.46 × 10–8 m
hc 6.62 × 10 −34 × 3 × 108 = 36.46 × 10–6 cm
E= = = 3.7 × 10–5 cm Ans.
λ 6.55 × 10 −7
= 3.032 × 10–19 J Sol.11 E1 = – 2.17 × 10–11 erg.
For 1 gm atom = – 13.6 eV
Total energy = E × NA E2 = – 3.4 eV
= 3.032 × 10–19 × 6.022 × 1023 ∆E = E2 – E1
= 18.25 × 104 J = 10.2 eV
= 182.5 × 1 KJ
= 1.825 × 105 J/mol Ans. hc
∆E =
λ
hc 6.6 × 10 −34 × 3 × 108
Sol.8 E= = 1240
λ 854 × 10 −10 λ=
10.2
= 121.5 nm = 1215 Å Ans.
For 1 mole
6.6 × 10 −34 × 1018 × 3 × 6.022 × 10 23 Sol.12 r = 0.85 nm

E mole = = 8.5 Å
854
n2
6.6 × 107 × 3 × 6.022 8.5 = 0.529
= Z
854
= 0.139 × 107 J/mole 8 .5
n2 =
= 1.39 × 103 KJ/mole Ans. 0.529
n2 = 16 ⇒ n = 4
1 1 1  z
  V = 2.18 × 106 × m/s
Sol.9 −10 = 1.097 × 107  1 − 2  n
1026 × 10  n 2
n2 = 3 1
= 2.18 × 106 ×
4
n=3
= 5.45 × 105 m/sec Ans.
n=2
n=1
Induced Radiations Vel.of e− in'n'shell 1
(1) 3 →1 ⇒ λ1 = 1026 Å Sol.13 =
Vel. of light 275
(2) 3 →2 ⇒ λ2 = 6563 Å
(3) 2 →1 ⇒ λ3 = 1216 Å Ans.
3 × 108
Vel. of e– in ‘n’ shell =
Sol.10 n =2 to n = ∞ 275
= 0.0109 × 108 m/s
−12  21.7 × 10 −12 
− 21.7 × 10 = 1.09 × 106 m/s
∆E = − − 
∞2  22 
  z
i.e. 2.18 ×106 = 1.09 × 106
n
21.7 × 10 −12
=0+ 1 1.09
22 =
n 2.18
= 5.42 × 10–12 erg.
n = 2 Ans.
= 5.42 × 10–19 J
Tranisition from n = 2 + 1 = 3, to n=1
hc
∆E = 1  1
λ = RHZ  1 − 
λ  9
8 162.60 × 1028 e– return

ν = 109700 × = 10.2 × 162.60 × 1021 × 1.6 × 10–19
9
= 2653.6 × 102 J
= 97511.11 cm–1
= 9.75×104 cm–1 Ans. = 265.36 KJ
Energy released when one e– return from.
n = 3 to n = 1 ⇒ 1.51 + 13.6
1 1 1 = 12.09 eV
Sol.14 = 109700 × 9  − 
λ 1 9  When
292.6 × 1021 e– return
1 = 12.09 × 1.6 × 10–19 × 292.6 × 1021
λ=
109700 × 8 = 5660 × 102 J
= 1.139 × 10–6 cm–1 = 0.566 KJ
= 1.139 × 10–8 m–1 Total energy released = 265.36
113.9 Å Ans. = 566. 00
––––––––––––––––––
Sol.15 E1 = – 13.6 831.36 KJ Ans.
E2 = – 3.4 z2
∆E = –3.4 + 13.6 Sol.18 –3.4 = –13.6 ×
n2
= 10.2 eV n2 =4
1 1 1  nh 2h h
= RHZ  −  n = 2 (Angular momentum = = = )
λ 1 4  2π 2π π
h
1 3 Ans.
2   π
−6 = 109700 × Z  4 
3 × 10
Sol.19 Energy = Charge × volts
0.33 × 106 × 4 = 1.6 × 10–19 × 4.5 J
Z2 =
109700 × 3 hc
Z2 = 4.01 E=
λ
Z = 2 Helium Ans.
1.6 × 10 −19 × 4.5
ν =
Sol.16 For shortest wavelength Transition in Balmer series. 6.62 × 10 −34 × 3 × 108
n1 = 2 n2 = ∞ = 3.63 × 106 m–1 Ans.
1 1
ν = RH  4 − ∞  z
  Sol.20 Vel. of e– in n = 2 = 2.18 × 106 ×
n
1 1 = 1.09 × 106 m/s
ν = 109677  4 − ∞  Distn travelled in 10–8 sec = 1.09 × 106 ×10–8
 
= 1.09 ×10–2 m
1 Circum ference = 2πr
ν = 109677 × = 2 × π × 0.529 × 4 × 10–10
4
= 27419.25 cm–1 Ans. = 4.23 π × 10–10 m
1.09 × 10 −2
Sol.17 Atoms in 3rd energy level ∴ revolutions =
4.23 π × 10 −10
27
= 1.8 × 6.022 × 1023 × = 0.08 × 108 rev
100 = 8 × 106 rev Ans.
= 292.6 × 1021 Ans.
Atoms in 2nd energy level
V
15 Sol.21 frev =
= 1.8 × 6.022 × 1023 × 2πr
100
= 162.66 × 1021 Ans. 2.18 × 10 6 × 7
=
Energy related when one e– returns from 2 × 22 × 0.529 × 10 −10
n = 2 to n = 1 = – 3.4 + 13.6 = 10.2 eV
= 0.6556 × 1016 Hz
When
= 6556 × 1012 Hz Ans.
hc 1
Sol.22 E = Sol.24 ν1 = nm–1
λ 486.1
1240 = 2.05 × 10–3 × 107 nm–1
λ= = 26.27 nm = 2.05 × 104 cm–1
47.2
= 262.7 Å 1
ν2 = nm–1
410.2
1  1 1
= RHZ2  −  = 2.43 × 10–3 × 10+7 nm–1
λ 4 9
ν 2 – ν 1 = 0.38 × 104 cm–1
1  S  ∴ λ = 2.63 × 10–4 cm
−8 = 109677 Z2   = 2.63 × 10–6 m Ans.
262.7 × 10  36 
it belongs to IR region
∴ Brackett series. Ans.
36 × 108
Z2 =
262.7 × 109677 × 5
Z2 = 2.48 × 10
Z2 = 24.9 (App. = 25) 180690
Sol.25 Binding energy per e– = J
Z= 6.022 × 10 23
25
= 30004.9 × 10–23 J
= 5 (Boron)
30004.9 × 10 −23
z2 = eV
T. E. = – 13.6 × 2 1.6 × 10 −19
n
= 1.875 eV
= – 13.6 × 25
= – 340 eV Ans. 1240
λ = = 66.13 nm
We know 1.875
1 c
T. E. = P. E. = ν0
2 λ
∴ P. E. = 2(–340)
= – 680 eV Ans. 3 × 108
v0 =
1 1  661.3 × 10 −9
1
Sol.23 = 109677 × 4  −  = 4.53 × 10–3 × 1017
λ 1 4 
4.53 × 1014 sec–1 Ans.
1
λ=
109677 × 3 hc
= 3.03 × 10–6 cm Sol.26 E =
λ
= 3.03 nm
1240
1240 = = 5.16 eV per e–
E= = 40.92 eV 240
30.3 = 5.16 × 1.6 × 10–19 × 6.022 × 1023 J/mol
∴ K. E. = 40.92 eV = 49.78 × 104 J
= 40.92 × 1.6 × 10–19 J = 497.8 kJ/mol Ans.
1
K. E. = mv2 Sol.27 E = hv0 – Φ
2
E1 = h(3.2 × 1015) – Φ
2 × 40.92 × 1.6 × 10 −19 × 1031 E2 = h(2 × 1015) – Φ
v2 = E1 = 2E2
9.1
h(3.2 × 1015) – Φ = 2h(2 × 1015) – 2Φ
v2 = 14.38 × 10+12
Φ = h × 1015 [4 – 3.2]
v= 14.38 × 1012 Φ = 0.8 h × 105
= 0.8 × 6.6 × 10–34 × 105 × 6.022 × 1023
= 3.79 × 106 m/s
= 319.2 kJ/mol Ans.
= 3.8 × 106 m/s
= 3.8 × 108 cm/sec Ans.
hc λ
Sol.28 – Φ = K. E. Sol.32 V =
λ T
from here V = λ. ν
3 × 108 = λ × 5 × 1013
hc
– Φ = 1.8 × 1.6 × 10–19 3
800 × 10 −10 λ= × 10–5
5
hc = 0.6 × 10–5 m
– Φ = 4 × 1.6 × 10–19
700 × 10 −10
6.6 × 10 −34 × 3 × 108
hc  1 1  E=
 −  = 1.6 × 10–19 (1.8 – 4) 0.6 × 10 −5
10 −8  8 7  ⇒ 33 × 10–21
hc 1 330
× = 1.6 × 10–19 × 2.2 No. of photons =
10 −8
56 33 × 10 −21
hc = 1.6 × 22 × 56 × 10–27 = 1022 photons Ans.
1.6 × 2.2 × 56 × 10 −27

h= hc
3 × 108 Sol.33 Ephoton =
λ
= 65.7 × 10–35
6.57 × 10–34 J/sec Ans. 1240
= = 2.25 eV
550
Sol.29 P. E. = qv
= 1.6 × 10–19 × 20000 10 −17
no. of photons =
E = 32000 × 10–19 J 2.25 × 1.6 × 10 −19
hc = 0.277 × 102
=E = 27.7 photons
λ
= 28 photons Ans.
6.62 × 10 −34 × 108 × 3
λ=
32000 × 10 −19 8RT 8 × 8.314 × 300
Sol.34 navg = =
1.24 πM 22 / 7 × 4
= × 10 −10 m
2 = 39.83 m/sec
= 0.62 × 10–10 m
6.62 × 10 −34
= 0.62 Å Ans. λdebrogli =
39.83 × 0.21× 10 −24
Sol.30 K. E. max = eV0 = 7.9 × 10–11
m
1.6 × 10–19 × 3.06 J = eV0 = 0.79 × 10–10 m
⇒ 0.79 Å Ans.
1.6 × 10 −19 × 3.06
V0 =
1.6 × 10 −19
6.64 × 10 −34
= 3.06 Volt. Ans. Sol.35 λdebrogli =
mv
Sol.31 Total energy = 3.15 × 10–14
6.64 × 10 −34
hc V=
Energy of one photon = 500 × 10 −10 × 9.1× 10 −31
λ = 1.45 × 104 m/sec
1240 1/2 mv2 = eV0
=
850 1
= 1.45 eV × 9.1× 10 −31 × 1.45 × 108 × 1.45
2 = V0
3.15 × 10 −14 1.6 × 10 −19
No. of photon = V0 = 5.97 × 10–4 Volts Ans.
1.45 × 1.6 × 10 −19
= 1.35 × 105 photon Ans.
1 νreq. = 17115.67 – 485.7

Sol.36 Velocity of proton = × 3 × 108
10 = 166258.67 cm–1
= 3 × 107 m/sec
hc
∆V = 3 × 105 m/sec ∴ E = = hc ν
λ
h = 6.62 × 10–34 × 3 × 108 × 16625867
∆V. ∆x =
4πm = 3.3 × 108 × 108 × 10–34
= 3.3 × 10–18 J Ans.
6.62 × 10 −34
∆x =
4 × 3.14 × 9.1× 10 −31 × 3 × 10 5 × 1840 Sol.40 Let absored e– be n1
and emitted e– be n2
6.62 × 10 −8
= n2hc 47
4 × 3.14 × 9.1× 1840 E×
λ2 100
⇒ 1.05 × 10–13 m Ans. =
n1hc E
λ1
6.62 × 10 −34
Sol.37 10–10 =
m n2λ1 47
=
n1λ 2 100
6.62 × 10 −34
V= n2 47 × 5080
1840 × 9.1× 10 −31 × 10 −10 =
= 3.95 × 103 m/sec n1 100 × 4530
1 n2
mv2 = eV0
2 n1 = 0.527 Ans.
1
× 1840 × 9.1× 10 −31 × 3.95 × 3.95 × 10 6 192000
2 = V0 Sol.41 Energy required per atom =
6.022 × 10 23
1.6 × 10 −19
= 31883.09 ×10–23 J
V0 = 81640.08 × 10–6 V
= 0.0816 Volts Ans. 31.88 × 10 −20
=
1.6 × 10 −19
Sol.38
1S
0 AM =
h
2π
( ( + 1)) = 0 = 19.92 × 101
= 1.992 eV
= 2 eV
2S
0 AM = h × 0 = 0 Ans. hc
2π λ =
E
2p h 1240
OAM = × 2 Ans. = = 623.11 nm
2π 1992
h ⇒ 6231.1 Å Ans.
=
2π
3d h 0.01× 6 × 10 23
OAM = × 6 Ans. Sol.42 no. of photons =
2π 0 .2
3p = 3 × 1022 Ans.
h
OAM = 2 Ans.
2π Molecules reacting
Quantum yield =
quanta absorbed
Sol.39 λ = 58.44 nm
24300
1 107 Sol.43 Energy per molecule =
ν = = cm–1 = 17115.67 cm–1 6.022 × 10 23
λ 58.44 = 40.35 × 10–20
6.62 × 10 −34 × 3 × 10 8 = 15 × 10 − 4
40.35 × 10–20 =
λ = 0.0387 Å
–7
λ = 4.9 × 10 m Ans. = 3.88 pm Ans.
Sol.44 Energy required per molecule = 450530 J
6.62 × 10 −34 × 3 × 10 8 hc
= Sol.47 λdebroglie =
−9 mv
253.7 × 10
= 0.078 × 10–12 J 6.62 × 10 −34
= 0.078 × 10–17 × 1023 × 6.02 J/mol =
6 × 10 24 × 3 × 106
= 0.46 × 106 J/mol
K. E. = 470 – 430.57 = 0.368×10–64 m
= 39.43 KJ = 3.68 ×–65 m Ans.
39.43
% = × 100 h
470 Sol.48 ∆X ∆P =
= 8.38% Ans. 4π
6.62 × 10 −34
∆P =
c 4 × 3.14 × 5000 × 10 −10
Sol.45 ν = a(z – b) = = a (29 – b)
λ = 0.105 × 10–27
3 × 108 ∆P 0.105 × 10 −27

or = a (29 – b) =
15.42 × 10 −9 P 200 × 10 −3 × 10 −29
or 13.94 × 107 = 1 (29 – b) .............(1) ∆P
also, = 1.75 × 10–29 Ans.
P
3 × 108
= a (29 – b) Sol.49 ∆V = (100 – 99.99%) of 40
7.12 × 10 −9
0.01
⇒ 20.52 × 107 = a(29 – b) ..............(2) = × 40
100
Dividing eq. (1) and (2)
h
13.94 29 − b ∆x. ∆V =
= 4πm
20.52 42 − b
Solving we get 6.62 × 10 −34
∆x =
60 4 × 3.14 × 4 × 10 −3 × 9.1× 10 −31
b= = 1.27
47
0.132 × 10 −31
20.52 × 10 7 = m
∴a= = 0.5 × 107 9.1× 10 −31
( 42 − 1.27) = 0.0145 m Ans.
3 × 108
⇒ = 0.5 × 107 (z – 1.27)
22.85 × 10 −9
11.45 × 107 = 0.5 × 107 (z – 1.27)
z = 22.9 + 1.27 ≈ 24 Ans.
150
Sol.46 λ = Å
volt
150
=
100 × 103
EXERCISE – II MULTIPLE CORRECT (OBJECTIVE QUESTIONS)

n2 = 3 × 208
hc n = 24.92
Sol.1 E=
λ n = 25 Ans.
1240
λ= 1 KZe 2
68 T. E. = –
λ = 18.23 nm 2 r
= 18.23 × 10–9 m
1 K3e2 × 4π2 × 3e 2 x 208me
=–
1  1 1 2 n2h2
−9 = 109677 × z2  − 
18.23 × 10 4 9
 2K 2e 4 π2m  9 × 208
 ×
10 9 9−4 –  2 
= Z2    h  n2
18.23 × 109700  36 
9 × 208
107 × 36 = – 13.6 × eV..
Z2 = n2
18.23 × 5 × 109700
(T. E. )1 = – 13.6 × 9 × 208
Z = 36 × 107 × 10–7
2
= – 25459.2 eV
Z= 36 = 6 Ans. (T. E.)3 = – 2828.8 eV
∆E = – 2828.8 + 25459.2
z2 = 22630.4 eV
K.E. = 13.6
n2 1240
22630.4 =
= 13.6 × 36/1 λ
= 489.6 eV Ans.
1240
1 λ=
= 109677 × 36 22630 .4
λ = 0.054nm = 55.2 cm Ans.
λ = 2.53 × 10–7 cm
= 25.32 Å Ans. Sol.3 (i) K.E. (max) = charge × (potential)
= 2 × 1.6 × 10–19 × 2 × 106
Sol.2 Please check it = 6.4 × 10–13 J Ans.
nh Kq1q2
mvr = ............(1) (ii) P. E. =
2π r
3ze2 mv 2 9 × 109 × 2e × 47e

2 = .........(2) =
r r 5 × 10 −14
We get solving
9 × 109 × 94 × 1.6 × 1.6 × 10 −38
2Kze 2 π 2Kz3e2 π =
V= = 5 × 10 −14
nh nh
= 433.16 × 10–15
n2h2 = 4.33 × 10–13 J
r= K.E. = K. E. (max) – P. E.
4π2kze 2m = (6.4 × 10–13) – (4.33 × 10–13)
Substituting the values = 2.07 × 10–13 J Ans.
n2h2
r = Ans. (iii) K.E. (max) = P. E.
4π K × 3e2 208me
2
Kq1q2
K. E. (max) = r

 h2 
× n
2 min
r=  2 2  3 × 208
 4π mKe  9 × 109 × 94 × 1.6 × 1.6 × 10 −19
rmin =
n2 6.4 × 10 −13
0.529 = 0.529 × = 3.44 × 10–14 m Ans.
3 × 208
1 1
Sol.4 T.E. = P. E. Sol.8 E2 = 4 × = 1 Rydberg
2 4
∆E = – 1 + 4
1 Ke 2 = 3 Rydbergs
= ×
2 3r 3
6.62 × 10 −34 × 3 × 108
Ke 2 3 × 2.18 × 10–18 =
T. E. = ...........(1) 3 × 2.18 × 10 −18
3
6r = 3.036 × 10–8
we know that = 303.5 Å
= 303.6 Å Ans.
n2h2
r= z2
4π2Kze2m E = – 13.6 × eV
n2
Putting in (1)
4 × 1.18 × 10 −18
n6h6 = 13.6 × z2
E= Ans. 1.6 × 10 −19
384m3K 2e 4 π6 2
z = 4.0085
z=2
Sol.5 Energy of n = 1 ⇒ 13.6 eV 1 Kze2

E=
2 r
hc 1240
∴λ= m= 1 2 × 9 × 109 × 2.56 × 10 −38
E 13.6 4 × 2.18 × 10–18 = ×
= 911 Å 2 r
i.e., uv region Ans.
9 × 109 × 2.56 × 10 −38
r=
4 × 2.18 × 10 −18
Sol.6 Energy of n = 4 ⇒ – 0.85 eV = 2.64 × 10–11 m
∆E = – 0.85 + 13.6 = 2.64 × 10–9 cm Ans.
= 12.72 eV
hc
1240 Sol.9 − Φ = K. E.max
λ= λ
12.75
= 97.25 nm 1240
− 25 = K. E.max
= 972.5 Å Ans. 12.4
100 – 25 = K. E.max
Sol.7 Let quantum no. be ‘n’ KEmax = 75 eV Ans.
2.7451 × 104 150
λdebrogli = Å
1 1  K.E.
 1 1
= RH × 4  2 −  – RH × 4  2− 
 n ∞   n (n + 1)2  150
= Å
25
1 1 1 
 2 −0− 2 +  = 2 Å
= 27451 = 4RH  n n (n + 1)2 
 = 1.414 Å Ans.
1 27451 h
= ∆x . ∆P =
2 4 × 109677 4π
(n + 1)
6.62 × 10 −34 × 7
(n+ 1)2 = 15.98 = 16 ∆x =
∴ n=3 6.62 × 10 −28 × 4 × 22
= 0.079 × 10–6
1 1 1
= RH(z)2  2 − 2  1
λ 3 4  = × 10–6
4π
1 7 ∆λ 1
= 109677 × 4 × ∆x . =
λ 36 × 4 λ2 4π
λ = 4.689 × 10–5 cm–1
= 4689 Å Ans.
∆λ 1
10–6 × 0.079 × = 90 1
2 × 10 −20
4π ≡ × × 1.6 × 10 −19
∆λ = 2 × 10–14 m Ans. 3.1× 1.6 × 10 −19 3
90
Sol.10 ∴ energy of emitted photons cannot be greater than = = 9.78 amp = 10 amp Ans.
3.1× 3
13.6 eV as it will ionise He+
∴ Single e– species should be hydrozen
z=1 Sol.13 Ψ(x) = K1. e −r / K 2 (r2 – 5K3r + 6K32)
∆E = E3 – E1 ∴ is quadratic in ‘r’ and is a f(σ)
= – 1.51 + 13.6 ∴ it certainly represents
= 12.09 eV 3 → sheell
He+ T. E. s → subshell
n = 1 –13.6 × 4 A→n=3
n = 2 –13.6 → E1 B → ang. nodes = 0
C→l=0
−13.6 × 4 −13.6 × 4 D → (n + 5)s → 8S → 8
n=3 n=4
9 16 (n + 5)p → 8P → 9
−13.6 × 4 i.e., 6f, 2d, 5g
n=5 h
25 E → 0 i.e., ( + 1)
−13.6 × 4 2π
n=6 = 1.51 → C2 Ans. −r / K 2
36 F → Ψr = K1 e (r 2 − 5r + 6)
1
nh mvr
= (6 − 5σ + σ2 ).e −σ / 2
Sol.11 mvr = , n= × 2π 9 3 .a03 / 2
2π h
−34 solving is quadratic
3.1652 × 10 × 2 × 3.14
n= σ2 – 5σ + 6 = 0
6.626 × 10 −34 σ2 – 2σ – 3σ + 6 = 0
n=3 σ(σ – 2) – 3(σ – 2) = 0
 1 σ = 3, 2
1
= RH (1)2 1 −  code is = 300303 Ans.
λ  9
8 Sol.14 1233.00
ν =  9  RH Ans.
1
Sol.15 R35 = (6 − 6σ + σ2 )e −σ / 2
Sol.12 a 3a03 / 2
For spherical nodes.
R35 = 0
120º 6 – 6σ + σ2 = 0
σ2 – 6σ + 6 = 0
The photons will strike the metal like only on shaded σ ± 36 − 24

σ=
part and rest photons will escape out. 2
∴ Part Qd circular disc where
6±2 3
120 1 =
photons will strike = = 2
360 3
=3± 3
1
∴ rd part the disc.
3 2r
Total energy = 90 J per sec. σ = na
0
1240
Ephaton = = 3.1 eV 2r
400 3± 3 = 3a
90 0
No. of photons =
3.1× 10 −19 × 1.6 1± 3 3
r= a0
90 1 2
No. of photo e– ejected = ×
−19 3
3.1× 1.6 × 10 9+3 3 9−3 3
∴ Magnitude of Photocurrent r= a0 , a0 Ans.
2 2
EXERCISE – III SUBJECTIVE QUESTIONS

Sol.1 3 eV
Sol.11 B
Corite Actual
Correct option 1 1 
= RH.4  − 0
hc x 4 
K.E. max = −φ
λ 1
=8–5 RH =
x
= 3eV
∴ V0 = 3 eV 1 1 1 
= RH × 9  − 
λ  9 16 
Sol.2 Na+, Co+2, Cr2+, Fe+3
M. M. (µ) = n(n + 2) 1 1 16 − 9 
= ×9  
λ x  144 
we get Na+, Co+2, Cr2+, Fe+3
1 1  7 
Sol.3 Zero = ×9  
Refrence level is Ist orbit λ x 144 
itself T. E. = 0 1 7
Ratio becomes zero =
λ 16 x
Sol.4 Photons or quanta 16 x
λ=
7
Sol.5 D
hc Sol.12 B
E=
λ 1
= 109677 × 9
1 λ
E ∝ λ = 1.01 × 10–6 cm
λ
E1 4000 λ2 6.62 × 10 −34 × 3 × 108
E=
E 2 = 2000 ⇒ i.e. λ1 = 2 1.01× 10 −8
= 19.66 × 10–18 J
Sol.6 D 1
r= ∞ ⇒ mv 2 = 19.66 × 10–18
2
Sol.7 D 39.32 × 10 −18

Is → As it is the ground state V2 =
9.1× 10 −31
Sol.8 B V2 = 4.32 × 1013
Balmer means transition V2 = 43.2 × 1012
to n = 2 V = 6.57 × 106
1. line → 3 to 2 6.62 × 10 −34
2. line → 4 to 2 λdebroglie =
3. line → 5 to 2 9.1× 10 −31 × 6.57 × 10 6
= 1.17 × 10–10 m
Sol.9 B = 1.17 Å
h
O.A.M. = ( + 1) Sol.13 A
2π Mass of α particle = 4 (mass of proton)
here l = 0 Mass of proton = 1840 (mass of e–)
OAM = zero Let
Mass of e– = m
Sol.10 D ∴ Mass of p+ = 1840 m
Spin and mass of α particle = 7360 m
1 5 / 24
meV2 = 16 E ratio = = 3.5
2 7 / 120
32E
Ve2 =
m Sol.16 D
8E R 0.529 × 4
Vp2 = =
1840 m R' 0.529 × 9
E 9R
Vα2 = R’ =
4
7360 m
= 2.25 R
Sol.14 A
IE1 + IE2 + IE3 = 19800 Sol.17 A
IE2 + IE3 = 19800 – 520 1  1
IE2 + IE3 = 19280 = RH 1 − 
λLymen  4
Sol.15 B
4
1  1 λLymen = 3 R
1 −  H
λ1 = RH  4 
1 1 1 
 − 
1 3 λBalmer = RH × 4  4 16 
λ1 = RH × 4
16
4 λBalmer = 8 × 3R
λ1 = 3 R H
H
λLymen 4 / 3RH 1
9 = =
λ2 = 8 R λBalmer 4 / 3RH 1
H
1:1
1  9 16 
λ1 – λ2 =  −  Sol.18 B
RH  8 15 
We know that, for wave no.
1  32 − 27  ν3 = ν1 + ν2
=  
RH  24  1 1 1
= +
1 5  λ 3 λ 2 λ1
=  
RH  24 
Sol.19 C
9/8
λ2 = R (n22 − n12 ) = 8
H
(n2 – n1) (n2 + n1) = 8
16 ∴ (n2 – n1) = 8/4
λ3 = 15R n2 – n1 = 2
H
n2 + n1 = 4
1 4 9 –––––––––––––––––
λ2 – λ3 =  −  ∴ n2 = 3
RH  3 8 
n1 = 1
1 135 − 128  1  1
=   = RH × 4 1 − 
RH  120  λ  9
1 7 9
= R × λ = 32 R
H 120 H
Sol.20 B
∆λ 1
∆x . =
10
First Excited level = 2 λ2 4π
9
ninth level = 10
8 λ 1
7 ∆x = ×
6 ∆λ 4π
5
4 (5 × 10 −7 )2
=
Total line = 6 10–12 × 4π
Ans. 0.0199 m
Sol.21 B
Bohr Sol.25 B
x → y + 2He4
Sol.22 C y → 8O18 + 1H1
––––––––––––––––––––
6.62×10−34 Adding both eq.
λ debroglie =
200×10−3 ×5/3600 x → 2He4 + 8O18 + 1H1
= 2.3 × 10–30 By conservation of mass
X = 4 + 18 + 1 gm
Sol.23 D = 23
23 gm → (2 + 10) moles neutrons.
1 1 1 
= RH × 4  −  12
λ  9 16  1 gm → neutrone
23
1 7 12 46
= RH × 4.6 gm → × = 2.4 neutrans
m 36 23 10
1 36  1
= × 16   Sol.26 C
λ required 7m 9 
hc
E=
1 36  1 λ
= × 16  
λ required 7m 9  1240
= = 40
7m 31
λreq. = K.E. max = 40 – 12.8
64
= 27.2 eV
Sol.24 B 1
mv2 = 27.2 × 1.6 × 10–19
h 2
λ=
mv 54.4 × 1.6 × 10 −19
V2 =
h 9.1× 10 −31
p=
λ V2 = 9.56 × 1012
V = 3.09 × 106 m/sec.
dp d L
=  
d λ dλ  A  Sol.27 C
dp −h 1
= mV2 = 6 × 1.6 × 10–19
dλ λ 2 2
h 12 × 1.6 × 10 −19
dp = .∆λ V2 =
λ2 9.1× 10 −31
V2 = 2.10 × 1012
h h
∴ ∆x . ∆λ ≥ V = 1.44 × 106 m/sec
λ2 4π
6.62 × 10 −34
λ= Sol.36 D
1.44 × 106 × 9.1× 10 −31
= 0.5 × 10–9 Sol.37 A-P, B-PQS, C-PR, D-QS
A → R.N. = 3
∆λ 1
∆x . = P
0.25 × 10 −18 λ B → R.N. = 3
PQR
7 ∆λ 1
× 10 −9 × −18
= D → A.N. = l
22 0.25 × 10 4 π QS
0.25 × 10 −9
∆λ = Sol.38 A-S, B-R, C-Q, D-P
4
= 0.0625 × 10–9 150
A → λdebroglie = (S)
= 0.625 Å 13.6
Sol.28 CD
z 2.18 × 10 6
B → Vel. = 2.18 × 106 × (R) = m/s
n 3
Sol.29 B C
z2
C → Energy = – 13.6 × = – 13.6 × 9
n2
R. N. = 3 – 1 – 1 = 1 n2
D → r = – 0.529 ×
z
r
P = 0.529 Å
Peaks = 1 + 1 = 2
Sol.39 A
Sol.30 AC Mass ↑ λdebrogli ↓
Sol.40 C
Sol.31 AC
λdebrogli h → costant
=
mv
Sol.32 BCD 1
λα
z v
Vα
n z
and v α → costant
1 n
∴Vα
n
1
2
∴vα
n n
rα ∴ r α n2 i.e. transition from
z
n = 1 to n = 3, n = 2 to n = 6
1 n = 3 to n = 9
P. E. α − A V
r
Sol.41 A
1
K.E. α h
r r
∆x, ∆mv =
4π
Sol.33 CD h
∆V, ∆mv =
1 4π
ν ∝
λ multiplying by m
Sol.34 B hm
(∆mv)2 =
4π
Sol.35 A
Sol.42 A Sol.44 B
1  1 1  1
= 109677 × 1 1 −  1 − 
λ  9 λ1 = RH  4 
1 8 4
= 109677 × λ1 = 3R
λ 9
H
λ = 1.025 × 10–5 cm
= 1.025 × 10–7 m 1 1 1 
= R  − 
λ2 H  4 10 
6 × 10 −34 × 3 × 108 × 107
E=
1.025 16
= 1.76 × 10–18 J λ2 = 3R
H
Sol.43 C 16 4
6 λ2 – λ1 = 3R – 3R
5 H H
4
3 12
2
= 3R
H
1
4
= R
H
Sol.45 C
n1 + n2 = 4
n1 – n2 = 2
_____________________________
n1 = 3
n2 = 1
 1
ν = RH × 9 1 − 9 
 
= 8 RH
EXERCISE – IV ADVANCED SUBJECTIVE QUESTIONS

Sol.1 6.3 × 106 m/s = 0.0409
1 mole → 436 kJ energy
1 Kq1q2 0.0409 → 0.0409 × 436
mαV2 = r = 1783 kJ
2 min
Also
1 9 × 109 × 2e × 29e Energy needal to excite 1 e–
× 6.7 × 10–27V2 =
2 10 −13 1

18 × 109 × 58 × 1.6 × 1.6 × 10 −38 × 10 40 = 13.6 1 −  = 10.2 eV
 4
V2 =
6.7 = 10.2 × 1.6 × 10–19 J/e–
V2 = 398.9 × 1011 Total energy
V2 = 39.89 × 1012 = 10.2 × 1.6 × 10–19 × 0.0409 × 2 × 6.022 × 1023
V = 6.3 × 106 m/se = 8036 kJ
Total Energy = 17.83 + 80.36
Sol.2 [Ar]3d1 = 98.19 kJ
1.73 = n(n + 2) Sol.12 D
Sol.13 D
1.73 × 1.73 = n2 + 2n
Sol.14 C
n=1
Co 1s2 2p6 3s2 3p6 4s2 3d7
It should have one unpaired e–
Co+2 1s2 2p6 3s2 3p6 4s2 3d7
∴ 23V4+ ⇒ 1s2 2s2 2p6 3s2 3p6 3d1
↑↓ ↑↓ ↑ ↑ ↑
Sol.3 A
n=1 → –13.6 eV Magnetic moment= 3(3 + 2)
n=2 → – 3.4 eV
= 15
n=3 → –1.51 eV
n=4 → – 0.85 eV Sol.15 D
n=5 → – 0.544 eV Sol.16 r0 = 2a0
radial node
Sol.4 A,B,C
ψ 2s
r0
Sol.5 B 2– a = 0
0
Sol.6 A r0 = 2a0
Sol.17 –35
Sol.7 A, D 6 . 6 2 × 1 0
6.62 × 10 −34
λ=
Sol.8 B 160 × 10 − 3 × 100
λ = 6.62×10–35
Sol.9 C Sol. 18 A
Sol.19 3.34×10 –10 m/sec
Sol.10 A Sol 20. (A) Vn = P. E.

y rn → rad.
E → T. E.
x Kn → K. E.
We know
1
K. E. = − P. E.
2
P.E.
=–2
Sol.11 98 KJ K.E.
1× 1
Moles of H2 =
0.0821× 298
Sol.27 (D)
1 Kze2
(B) T. E. = − hc 1
2 r Ephoton (eV) = ×
λ e
1
E ∝
r −34 8
x=1 6.626 × 10 × 3 × 10
=  300 × 10  × 1.602 × 10−19 
− 9
n2    
(C) r ∝    
z
= Ephoton(eV) = 4.136 eV
1 Ephoton > φ (work function)
r=
z ⇒ Photoelectric effect will take place
r ∝ (z)–1 So, Only metals, Li, Na, K, Mg will show photoelectric
y=–1
effect here.
(D) Lowest Energy = ‘s’ energy level i.e., l = 0
⇒ No. of metals = 04 Ans.
h
O.A.M. = ( + 1) = 0
2π Sol.28 C
Sol.21 A–QR; B–PQRS; C–PQR; D–PQ nh

mvr =
2π
Sol.22 A
2 2
solution hint for Q.23,24,25 nh
m2 v2r2 =
spherical S 4π
2
one radial node n=2

=2S nh ×Z
2 2 2
h
2
EH= –13.6 eV 1 2
mv = 4π2 × 2 × m(r n2 )2 = 32π2ma2
E2s(Li2+) = –13.6×9/4 =–13.6×2.25 2 0 0
one radial node 2s or 3p

But energy is same as H
z2 /n2]=1
n=3
Sol.23 B
Sol.24 C
Sol.25 B
Sol.26 0009
Total e– with n=3 ⇒ 18
with S=–1/2 ⇒ electrons are 9

Answer Key Atomic Structure

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Solutions Slot – 1 (Chemistry) Page # 1

EXERCISE – I SINGLE CORRECT (OBJECTIVE QUESTIONS)

1 9 × 109 × 1× 1.6 × .1.6 × 10 −19 × 10 −19 1  22 

6.6 × 10 −34 × 1018 × 3 × 6.022 × 10 23 Sol.12 r = 0.85 nm

8 162.60 × 1028 e– return

1.6 × 2.2 × 56 × 10 −27

1 νreq. = 17115.67 – 485.7

Sol.44 Energy required per molecule = 450530 J

3 × 108 ∆P 0.105 × 10 −27

z = 22.9 + 1.27 ≈ 24 Ans.

EXERCISE – II MULTIPLE CORRECT (OBJECTIVE QUESTIONS)

3ze2 mv 2 9 × 109 × 2e × 47e

Sol.5 Energy of n = 1 ⇒ 13.6 eV 1 Kze2

The photons will strike the metal like only on shaded σ ± 36 − 24

EXERCISE – III SUBJECTIVE QUESTIONS

Sol.7 D 39.32 × 10 −18

EXERCISE – IV ADVANCED SUBJECTIVE QUESTIONS

Sol.10 A Sol 20. (A) Vn = P. E.

Sol.21 A–QR; B–PQRS; C–PQR; D–PQ nh

one radial node n=2

one radial node 2s or 3p

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