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NOTE 3—Some methods of loading or delivery of fly ash or natural Loss on ignition, %5~A/B!3100 (2)
pozzolan, particularly from an airstream or conveyor belt, may create
stratification or segregation in the material stream. Sampling techniques where:
must be designed to ensure that the sample is representative of the material A = loss in mass between 105 and 750 °C (221 and 1382
shipped. °F),
B = mass of moisture-free sample used.
8. Preparation and Storage of Samples
8.1 Prepare composite samples for the tests required in SILICON DIOXIDE, ALUMINUM OXIDE, IRON OXIDE,
Section 9, by arranging all grab or regular samples into groups CALCIUM OXIDE, MAGNESIUM OXIDE, SULFUR
covering the period or quantity to be represented by the TRIOXIDE, SODIUM OXIDE AND POTASSIUM OXIDE
sample. Take equal portions from each, sufficient to produce a
15. Procedure
composite sample large enough for the tests required. Mix the
composite sample thoroughly. 15.1 Determine the percentages of these oxides as required
8.2 Samples shall be stored in clean, airtight containers in accordance with the applicable sections of Test Methods
identified with the source and lot or period of time represented. C 114 for materials having an insoluble residue greater than
Untested portions of the sample shall be retained for at least 1 % (Note 4). Analysts performing sodium oxide and potas-
one month after all test results have been reported. sium oxide determinations shall observe the precautions out-
lined in the applicable section of Performance Specification
9. Testing Frequency C 1157 (refer to the section on Test Methods). Most pozzolans
9.1 General—When required, the purchaser shall specify dissolve completely in lithium borate fluxes.
the amount of testing for available alkalies, reactivity with NOTE 4—Rapid and instrumental methods may be employed similar to
cement alkalies, drying shrinkage, and air-entrainment. Make those in Test Methods C 114 and D 4326.
all other tests on regular or composite samples chosen as
specified in Table 1. AVAILABLE ALKALI
metric flask. Wash thoroughly with hot water (eight to ten DENSITY
times).
19. Procedure
NOTE 6—At times it may be necessary to break the vial and peel off the
plastic from the solid cake. In such cases, care should be exercised to 19.1 Determine the density of the sample in accordance
avoid the loss of material and to remove all solid material from the with the procedure described in Test Method C 188, except use
fragments of the vial. If the cake is too hard to break up and grind in the about 50 g of fly ash or natural pozzolan instead of approxi-
casserole, a mortar should be used. mately 64 g of cement as recommended in Test Method C 188.
16.3 Neutralize the filtrate with dilute HCl (1 + 3), using 1
FINENESS, AMOUNT RETAINED WHEN WET-SIEVED ON
to 2 drops of phenolphthalein solution as the indicator. Add
A 45-µm (NO. 325) SIEVE
exactly 5 mL of dilute HCl (1 + 3) in excess. Cool the solution
to room temperature and fill the flask to the mark with distilled
20. Procedure
water. Determine the amount of sodium and potassium oxides
in the solution using the flame photometric procedure, de- 20.1 Determine the amount of the sample retained when
scribed in Test Methods C 114, except that the standard wet-sieved on a 45-µm (No. 325) sieve, in accordance with
solutions shall be made up to contain 8 mL of calcium chloride Test Method C 430, with the following exceptions.
(CaCl2) stock solution per litre of standard solution, and the 20.1.1 Calibrate the 45-µm (No. 325) sieve using a cement
standard (SRM 114). Calculate the sieve correction factors as
solution as prepared shall be used in place of the solution of
follows:
cement.
CF5std2obs (5)
NOTE 7—The standard solutions made up with 8 mL of calcium
chloride (CaCl2) stock solution contain the equivalent of 504 ppm of CaO. where:
Tests have shown that this amount closely approximates the amount of CF = the sieve correction factor, %, (include a negative
calcium dissolved in the test solution. sign when appropriate),
std = the certified residue value for the SRM, %, and
17. Calculation and Report obs = the observed residue value for the SRM, %.
17.1 Calculate the results as weight percent of the original 20.1.2 Calculate the fineness of the fly ash or natural
pozzolan to the nearest 0.1 % as follows:
sample material. Report as equivalent percentage of sodium
oxide (Na2O), calculated as follows: RC5RS1CF (6)
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drying shrinkage of the control specimens is larger than the W = weight of the specified 400 mL of mortar (see Test
average drying shrinkage of the test specimens, prefix a minus Method C 185), g,
sign to the increase of drying shrinkage of mortar bars Wc = theoretical weight per unit of volume, calculated on
reported. an air-free basis and using the values for density and
quantities of the materials in the mix, g/mL,
SOUNDNESS P = percentage of mixing water plus Vinsol resin solution
based on weight of cement, and
24. Procedure D = density of fly ash or natural pozzolan in the mixture,
Mg/m3.
24.1 Conduct the soundness test in accordance with Test
Method C 151, except that the specimens shall be molded from STRENGTH ACTIVITY INDEX WITH PORTLAND CEMENT
a paste composed of 25 parts by weight of fly ash or natural 27. Specimens
pozzolan and 100 parts by weight of a portland cement
conforming to Specification C 150. 27.1 Mold the specimens from a control mixture and from a
test mixture in accordance with Test Method C 109/C 109M.
The portland cement used in the Strength Activity Index test
AIR-ENTRAINMENT OF MORTAR
shall comply with the requirements of Specification C 150 and
with the alkali and strength limits given in the section on
25. Procedure
Materials. In the test mixture, replace 20 % of the mass of the
25.1 Using portland cement conforming to the requirements amount of cement used in the control mixture by the same mass
for Type I or Type II of Specification C 150, prepare a test of the test sample. Make six-cube batches as follows:
mixture in accordance with Test Method C 185, using the 27.1.1 Control Mixture:
following proportions:
34. Procedure
WATER REQUIREMENT 34.1 Compare the length change of mortar bars with abso-
lute expansion limits or compare the length change of mortar
31. Calculation bars made with a control cement with the length change of
31.1 Calculate the water requirement for the Strength Ac- mortar bars made with fly ash or natural pozzolan and a test
tivity Index with Portland Cement as follows: cement, in accordance with Test Method C 1012, as modified
Water requirement, percentage of control = in the following paragraphs. Results shall be evaluated using
(Y/242 3 100) (12) absolute limits (Procedure A) or the relative expansion limits
where: (Procedure B) in Specification C 618, Table 2A.
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mixture for Procedure B as required in Test Method C 1012 PRECISION AND BIAS
with the cement that is proposed for use in the project or a
36. Precision and Bias
cement that through performance or definition (Specification
C 150, Section 1) is expected to give satisfactory results (or a 36.1 Strength Activity Index Test:
cement for which the contribution to sulfate resistance is 36.1.1 Precision was determined from two interlaboratory
known and is satisfactory). studies involving two Class C fly ashes, two Class F fly ashes,
and one Class N pozzolan. Participating laboratories numbered
NOTE 13—The control cement should be chosen to give sulfate resis- 12 and 7 in the two studies.4
tance for the expected level of sulfate exposure. Experience has shown
36.1.2 The single-operator standard deviation for the
that Type II cements are often used for moderate levels of exposure. Type
V cement is commonly used for severe exposures (see X2.2 of Appendix Strength Activity Index test has been found to be 3.7 % (1s).
X2). This does not appear to vary either with material or with test
age, over the range of 7 to 28 days. Therefore, results of two
34.5 Test Mixture for Using Fly Ash or Natural Pozzolan for properly conducted tests by the same operator on the same
Procedure B—Make the combined quantity of cement plus fly material should not differ by more than 10.5 % (d2s) of the
ash or natural pozzolan, by mass, the same as the total cement average of the two results.
used in the control mixture. The proportion of fly ash or natural 36.1.3 The multilaboratory standard deviation for the
pozzolan may be varied from 15 % to 50 % of the total cement Strength Activity Index test has been found to be 4.5 % (1s).
plus fly ash or natural pozzolan by mass. Any type of portland This does not appear to vary either with material or with test
cement may be used to prepare test mixtures. age, over the range of 7 to 28 days. Therefore, results of two
34.6 For either Procedure A or B, store and measure properly conducted tests in different laboratories on the same
specimens as required in Test Method C 1012 for at least 6 material should not differ by more than 12.7 % (d2s) of the
months. average of the two results.
NOTE 14—Evaluation of the sulfate resistance of cementitious materials
36.1.4 Since there is no accepted reference material suitable
for use in certain situations or critical structures may require longer for determining the bias for this procedure, no statement on
periods of storage and additional length measurements. Refer to Test bias is being made.
Method C 1012 for guidance on this matter. 36.2 Chemical Analysis:
36.2.1 Precision and bias estimates for the test methods in
35. Report C 114 when applied to the analysis of pozzolans were calcu-
35.1 In addition to the information required in Test Method lated from an interlaboratory study involving 7 laboratories
C 1012, report the following information for each mixture each analyzing 4 NIST SRM fly ashes. A research report
comparison made: describing the results of this study is available from ASTM.5
35.2 For Procedure A, the age and expansion as a specific 36.2.2 Precision—Within-laboratory (W/L) and between-
amount, laboratory (B/L) estimates of standard deviation and estimates
of maximum differences expected between duplicate determi-
35.3 For Procedure B, the age and expansion as a percent of
nations in 95 % of comparisons6 are summarized in Table 2.
the control mixture at that age,
36.2.3 Bias—Statistically significant bias was found in the
35.4 The identification and chemical analysis including C3A determination of CaO and MgO. CaO determinations averaged
content of the cements used in both the control and test
mixtures,
35.5 The identification and chemical analysis of the fly ash 4
Supporting data have been filed at ASTM International Headquarters and may
or natural pozzolan used in the test mixtures, be obtained by requesting Research Report RR: C09-1001.
5
Supporting data have been filed at ASTM International Headquarters and may
35.6 The mass percentages of the fly ash or natural pozzolan
be obtained by requesting Research Report RR: C09-1008.
based on the total mass of cement plus fly ash or natural 6
These values represent, respectively, the (1s) and (d2s) limits as described in
pozzolan in the test mixture. Practice C 670.
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APPENDIXES
(Nonmandatory Information)
X1.1 Test procedures in Section 32 are designed to deter- delineate any increase in expansion. The fly ash or natural
mine the effectiveness of fly ash, or natural pozzolan, in pozzolan percentage used may need to be sufficiently high to
preventing excessive expansion resulting from a reaction demonstrate that the percentage exceeds the pessimum if such
between certain aggregates and alkalies in portland-cement pessimum exists for the combination.
mixtures. Tests are made in accordance with Test Method
C 441 using: X1.6 Selection of the Low Alkali Control Cement—The test
procedure in this test method and requirements in Specification
X1.1.1 400 g of portland cement or a combined total of
C 618 are designed to measure the relative effectiveness of the
cement plus fly ash or natural pozzolan of 400 g,
fly ash or natural pozzolan in reducing expansion due to
X1.1.2 900 g of borosilicate glass, and
alkali-silica reactions. The effectiveness is a function of both
X1.1.3 Sufficient water to obtain a flow of 100 to 115 %.
the alkali content of the cement used in the test mixture and the
X1.2 The control mixture is made with a low-alkali percentage of fly ash or natural pozzolan. The higher the alkali
portland cement. The test mixture, made of a test percentage of content of the test mixture cement and the lower the percentage
the fly ash or natural pozzolan, can be made with the same of fly ash or natural pozzolan used, the more effective the fly
cement or any other cement having an equivalent alkali content ash or natural pozzolan. This test procedure and the 100 %
greater than 0.60 %. criterion of Specification C 618 can be used as a guide to
enhance field performance of job mixtures if it is assumed that
X1.3 Interpretation of Results—The fly ash or natural use of the low alkali control cement will prevent excessive
pozzolan should be considered “effective” when used at expansion in service with materials proposed for use in the job.
percentages equal to or greater than the percentages used in the This is the situation when the aggregates proposed for use
test mixture with cements having alkali contents that do not contain rapidly reactive constituents but do not exceed 0.05 %
exceed by more than 0.05 percentage points the alkali content expansion in three months or 0.10 % expansion in six months
of the cement used in the test mixture. when tested with the control cement in Test Method C 227. In
such instances the control cement used in this test method
X1.4 Selection of the Percentage of Fly Ash or Natural should have an alkali content as required to control the
Pozzolan—It may be necessary to make test mixtures with expansive reactions of the aggregates being used, for example
several percentages of fly ash or natural pozzolan to determine in the 0.50 to 0.60 % range. See the appendix to Specification
the minimum amount necessary to be considered “effective” in C 33.
reducing expansion to the level produced by the “control”
low-alkali cement. The minimum amount of fly ash or natural X1.6.1 Certain reactive aggregates have been identified
pozzolan should be 15 % by weight of cementitious material. which produce deleterious expansion after many years of
service when used with cements with equivalent alkali contents
X1.5 Selection of the Alkali Content of the Cement Used in well below 0.60 %. Often these reactive aggregates do not
the Test Mixture—In some instances it may not be necessary to produce expansions in Test Method C 227 exceeding those
demonstrate that the fly ash or natural pozzolan will reduce discussed in the appendix of Specification C 33 until a much
expansion, but rather that it will not increase expansion. In this later age, perhaps one or two years. In such instances the use
instance the test and control mixtures should be made with the of a control cement with an alkali content significantly less
same low alkali cement used in the control mixture to better than 0.60 % is appropriate.
X2.1 The test procedures in Section 34 are designed to addition of fly ash or natural pozzolan influences sulfate
evaluate the performance of particular fly ashes or natural resistance. However, as referenced in Test Method C 1012,
pozzolans in contributing to the resistance or durability of research has indicated that mortars meeting the expansion
concrete in a sulfate environment. Tests are made on mortars in criteria will perform adequately. Under Procedure B, the fly ash
accordance with Test Method C 1012. or natural pozzolan will be considered to be able to contribute
to sulfate resistance if the expansion of the test mixture does
X2.2 The control mixture should be made with a cement
not exceed that of the control mixture at an exposure time of at
that by performance or definition (Specification C 150, Section
least 6 months. It is recommended that the proportion of fly ash
1.1) is expected to give satisfactory results for the anticipated
or natural pozzolan used in the test mixture be the same one
level of sulfate exposure. ACI 201.2R recommends Type II
proposed for use in the project 6 2 %, and that the C3A content
cement when the sulfate content, expressed as SO4, is 0.10 to
of the project cement be equal to, or less than, that which was
0.20 percent in soils or 150 to 1500 ppm in waters. ACI 201.2R
used in the test mixtures. See Appendix X1, Technical Back-
recommends Type V cements when the sulfate content, ex-
ground, Test Method C 1012.
pressed as SO4, is 0.20 to 2.0 % in soils, or 1500 to 10 000 ppm
in waters. The test mixtures for both procedures may be made
with varying percentages of fly ash or natural pozzolan. Test X2.4 Selection of the Percentage of Fly Ash or Natural
mixtures can use cements with equal or higher or lower C3A Pozzolan—It may be necessary to make test mixtures with
contents that might not have given satisfactory results when several percentages of fly ash or natural pozzolan to determine
used alone. the amount necessary to obtain adequate resistance to different
concentrations of sulfates. Percentages used in a project should
X2.3 Interpretation of Results—The absolute expansion be within 2 % of those that are successful in the test mixtures
limits used in Procedure A make it difficult to ascertain how the or should be between two percentages that are successful.
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