Ecuaciones utilizadas

∑ 𝑽 = 𝒂 + 𝒃 ∑ 𝒏𝑯𝟐𝑶 + 𝒄 ∑ 𝒏𝟐 𝑯𝟐𝑶 + 𝒅 ∑ 𝒏𝑹−𝑶𝑯 + 𝒆 ∑ 𝒏𝟐 𝑹−𝑶𝑯 + 𝒇 ∑ 𝒏𝑯𝟐𝑶 ∗ 𝒏𝑹−𝑶𝑯

∑ 𝑽 ∗ 𝒏𝑯𝟐𝑶 = 𝒂 ∑ 𝒏𝑯𝟐𝑶 + 𝒃 ∑ 𝒏𝟐 𝑯𝟐𝑶 + 𝒄 ∑ 𝒏𝟑 𝑯𝟐𝑶 + 𝒅 ∑ 𝒏𝑹−𝑶𝑯 ∗ 𝒏𝑯𝟐𝑶 + 𝒆 ∑ 𝒏𝑯𝟐𝑶 ∗ 𝒏𝟐 𝑹−𝑶𝑯

+ 𝒇 ∑ 𝒏𝟐 𝑯𝟐𝑶 ∗ 𝒏𝑹−𝑶𝑯

∑ 𝑽 ∗ 𝒏𝑹−𝑶𝑯 = 𝒂 ∑ 𝒏𝑹−𝑶𝑯 + 𝒃 ∑ 𝒏𝑯𝟐𝑶 ∗ 𝒏𝑹−𝑶𝑯 + 𝒄 ∑ 𝒏𝟐 𝑯𝟐𝑶 ∗ 𝒏𝑹−𝑶𝑯 + 𝒅 ∑ 𝒏𝟐 𝑹−𝑶𝑯 + 𝒆 ∑ 𝒏𝟐 𝑹−𝑶𝑯

+ 𝒇 ∑ 𝒏𝑯𝟐𝑶 ∗ 𝒏𝟑 𝑹−𝑶𝑯

∑ 𝑽 ∗ 𝒏𝟐 𝑯𝟐𝑶 = 𝒂 ∑ 𝒏𝟐 𝑯𝟐𝑶 + 𝒃 ∑ 𝒏𝟑 𝑯𝟐𝑶 + 𝒄 ∑ 𝒏𝟒 𝑯𝟐𝑶 + 𝒅 ∑ 𝒏𝑹−𝑶𝑯 ∗ 𝒏𝟐 𝑯𝟐𝑶 + 𝒆 ∑ 𝒏𝟐 𝑯𝟐𝑶 ∗ 𝒏𝟐 𝑹−𝑶𝑯

+ 𝒇 ∑ 𝒏𝟑 𝑯𝟐𝑶 ∗ 𝒏𝑹−𝑶𝑯

∑ 𝑽 ∗ 𝒏𝟐 𝑹−𝑶𝑯 = 𝒂 ∑ 𝒏𝟐 𝑹−𝑶𝑯 + 𝒃 ∑ 𝒏𝑯𝟐𝑶 ∗ 𝒏𝟐 𝑹−𝑶𝑯 + 𝒄 ∑ 𝒏𝟐 𝑯𝟐𝑶 ∗ 𝒏𝟐 𝑹−𝑶𝑯 + 𝒅 ∑ 𝒏𝟑 𝑹−𝑶𝑯 + 𝒆 ∑ 𝒏𝟒 𝑹−𝑶𝑯

+ 𝒇 ∑ 𝒏𝑯𝟐𝑶 ∗ 𝒏𝟑 𝑹−𝑶𝑯

∑ 𝑽 ∗ 𝒏𝑹−𝑶𝑯 ∗ 𝒏𝑯𝟐𝑶

= 𝒂 ∑ 𝒏𝑯𝟐𝑶 ∗ 𝒏𝑹−𝑶𝑯 + 𝒃 ∑ 𝒏𝑯𝟐𝑶 ∗ 𝒏𝑹−𝑶𝑯 + 𝒄 ∑ 𝒏𝟑 𝑯𝟐𝑶 ∗ 𝒏𝑹−𝑶𝑯 + 𝒅 ∑ 𝒏𝟐 𝑯𝟐𝑶 ∗ 𝒏𝑹−𝑶𝑯

+ 𝒆 ∑ 𝒏𝟑 𝑹−𝑶𝑯 ∗ 𝒏𝑯𝟐𝑶 + 𝒇 ∑ 𝒏𝟐 𝑯𝟐𝑶 ∗ 𝒏𝟐 𝑹−𝑶𝑯

𝝏𝑽
( ) = −𝒃 − 𝟐𝒄𝒏𝑯𝟐𝑶 − 𝒅 − 𝒆 ∗ 𝒏𝑹−𝑶𝑯
∆𝑿𝑯𝟐𝑶 𝑷,𝑻,𝑿
𝑹−𝑶𝑯

𝝏𝑽
( ) = 𝒃 + 𝟐𝒄𝒏𝑯𝟐𝑶 + 𝒅 + 𝒆 ∗ 𝒏𝑹−𝑶𝑯
∆𝑿𝑹−𝑶𝑯 𝑷,𝑻,𝑿
𝑯𝟐𝑶

𝝏𝑽
̅ 𝑯𝟐𝑶 = 𝑽 − 𝑿𝑹−𝑶𝑯 ∗ (
𝑽 )
∆𝑿𝑹−𝑶𝑯 𝑷,𝑻,𝑿
𝑯𝟐𝑶

𝝏𝑽
̅ 𝑹−𝑶𝑯 = 𝑽 − 𝑿𝑯𝟐𝑶 ∗ (
𝑽 )
∆𝑿𝑯𝟐𝑶 𝑷,𝑻,𝑿
𝑹−𝑶𝑯
TABULACIÓN DE DATOS

TABLA 1
Nº V (ml) V (ml) V (ml) MOLES DE MOLES DE XA XW
AGUA ALCOHOL MEZCLA AGUA ALCOHOL ALCOHOL AGUA
1 10 50 58,75 0,66666667 0,82153245 0,55203127 0,44796873
2 20 40 58 1,2 0,65722596 0,35387507 0,64612493
3 30 30 58,5 1,73333333 0,49291947 0,22141217 0,77858783
4 40 20 59 2,26666667 0,32861298 0,12661949 0,87338051

CONSTANTES
A B C D e f
119,6858 -0,57998 -15,534466 50,672039 79,6656 -0,0010447

V. molar mez. DV/Dx1 DV/Dx2 V. molar V. molar

(EXP) parcial 1 parcial 2
39,8484826 -3,18703861 3,18703861 41,6209002 38,4338616
31,9835516 6,10876108 -6,10876108 29,7896244 35,8983854
26,2809716 15,4045608 -15,4045608 22,7854643 38,1900251
22,9535365 24,7003605 -24,7003605 19,6926872 44,3930476

TABLA 2
Nº V (ml) V (ml) V (ml) MOLES DEL MOLES DEL XA XW
AGUA ALCOHOL MEZCLA AGUA ALCOHOL ALCOHOL AGUA
1 11 50 60,05 0,72222222 0,82163664 0,53219673 0,46780327
2 21 40 59,5 1,25555556 0,65730931 0,34362559 0,65637441
3 31 30 59 1,78888889 0,49298198 0,21604289 0,78395711
4 41 20 60 2,32222222 0,32865466 0,1239796 0,8760204

CONSTANTES
A B C D e f

117,8291 0,004417 -0,01186 0,17925 3,69E-05 0,0300033

V. molar. (ecua) DV/Dx1 DV/Dx2 V. molar parcial 1 V. molar parcial 2

38,89604256 0,16358344 -0,16352282 38,808984 38,9725391

31,10517685 0,17185883 -0,17181033 31,0461218 31,2179488
25,85597665 0,18013423 -0,18009785 25,8170599 25,9971656
22,6340199 0,18840962 -0,18838537 22,6106609 22,7990493

TABLA 3
Nº V (ml) V (ml) V (ml) MOLES DEL MOLES DEL XA XW
AGUA ALCOHOL MEZCLA AGUA ALCOHOL ALCOHOL AGUA

1 10 51 60,05 0,66888889 0,83806937 0,5561331 0,4438669

2 20 41 60 1,20222222 0,67374204 0,35914439 0,64085561
3 30 31 59 1,73555556 0,50941472 0,22691379 0,77308621
4 40 21 60 2,26888889 0,34508739 0,13201627 0,86798373

CONSTANTES
A B C D e f
13,4701 15,01928 -2,556 9,52486E-7 -14,8726 13,72906

V. molar mez. DV/Dx1 DV/Dx2 V. molar V. molar parcial 2

(EXP) parcial 1
3,18703861 41,6209002 38,4338616
39,8484826
-3,18703861
-6,10876108 29,7896244 35,8983854
31,9835516 6,10876108
-15,4045608 22,7854643 38,1900251
26,2809716 15,4045608
-24,7003605 19,6926872 44,3930476
22,9535365 24,7003605