SUI,IT 4541/2

SULIT
Namer

Class:

MAJLIS PENGETUA SEKOLAII 1\trA.LAYSIA

NEGERI SEMBII,AN

PROGLAM PENINGI'{TAN AKADEMIK TINGKATAN 5

SEKOLAII.SEKOLAH MENENGAE NEGERI SEMBILAN 2017 454U2

CHEMISTRY
Kertas 2
Ogos / September
1
21 iam l)ua lam tiga puliLh minit

JANGAN BUIi{ KERTAS SOALAN INI SEHINGGA DIBERITAIIU

Arahan: Llntuk Keg1n(u Petneikr.t

l. T,-Llis Darna dan kclas rnda pada rua gan Kod Pcmeri
lang cliscdiakan. Rahagl,n
Markah Nlarkah
Penuh Diperoleh
I 9
2. Kertas soalan adalali dalanr
d* ibrhasa. 2 9

3 10

Soalan dtrlarn bahasa Inggeris I t0

mc dahului soalali yang sepadan dalam
5 tl
bahasa N.1c1ay u.
t1

1. Calon dibcnarkan nlen jatab keseluf uhan

1 ,0
B
ntaLL sebahaqian soalan salra rda dillam 8 20
bahasa Irrggeris atau bahasa Nlelalu.
9 20
(,
l0 20
5. Calon dikehenclaki nlenbaca tnaklumal
dihalar'rlan belakane kcrtas soalan ini. Junnah

Kerttls taaloii i]1i filengdnrltmgi 26 hulonan bercelak dun 2luluntd ticluk l)ercetdk

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SI]I,IT
SLI-IT 2 151112

Section A
Bahagian A

160 marksl
160 narkahl

Answer all questions

Jowab semta soolan

(a) Tabie I shows the proton number and the mrmber ofrcutrons for atoBs P, Q aod L
Jadual Ie ulljukk.tn kombor protofl dan bilangan neutron bdgi atom-atom ?, Q
danR.

Atom Proton nunrber \umber of neutrons

Atotn Bilangan neutron
P 4
O 16 t'7
R 16 16
Table 1

Jaduall

(1) \\rdle the electron a[angement for atom P-

Tttlitkan susunan eleklran bagi dtotnP.

fmarkl
1
[1 ndrkah)
(ii) State thc valcnce eleckon for P.
Nldlokan elektron valen bdgi P.

l1 malkl
11 ntctrkahl
(r) Write the symbol for atom Q in the lbnn ,X.
Tllis simltol hagi aront Q rldtdm bentuk 2X.

ll
markl
l1 narkah)
(c) (i) Which atorns are isotopes of an element.
Atofi alonl .l,Llt1g
t11tlnakdh adalah isotop b@gi suotu unsur?

[i mark]
I narkaltl

{5,11/2 @ 201, MPSMNeq.n S:mbila

SULIT
 SULIT 454u2

(ii) Cive a reason for your ansrver in l(r.)(i).

Berikon alason hugi lau,apan ondu di l(c)(.rl-

II markl
ll tna&uhl

(4 Diagram I shows a graph ofrcmperature against ti1ne Ii)r thc melting of solid X.
RLti.lh I me LtniLtkkun graf suhu mdannn ntasa bugi pelebnan pepejalX.

Temperaturc ('C)
Suhu ("C)

150

0 Timc (s)
Masa (s)

Diagram I
Rajoh 1

(i) Slate thc mclling point of X

Nydktkdtl tdkat lebur bdgi X-

[1 mark]
11 markahl
(iD What is the physical statc of X at AB and BC.
Apakah keadetan lizik bdgi X ?ad':t AB dar BC.

AB:...

BC:
[2 marks]
f) narkah)
(iii) Explain why the temperaturc rcmains Lrnchansed liom ti to tr.
To'angkan ntengetpa suhu tiddk be]'Lth.th d.lt.i i ket2,

[2 marks]
l2 norkah)

,15,11/2 l?j :017 NJPS\I \egei S.mlihn It-ihat halaman sebelah

SUI,IT
SULIT 1541t2

IJiagram 2 sho\\,s part of the Peiodic Table of [le]ients. P. Q,R,S and T are not thc
actual smbols ol the elements.
Rajoh ) menttnjtrkkun \eb.iktl<iLtn daripada Jalual Dttktla Unsur. P.Q.R.SfurT
b u kan n en unj t r klean s i tn bo I s e h en u t u nstr r.
t

Diagram 2
Ruiuh 2

(., (i) Which element is a transition elemcntl

Lirsu r,vang n d nt k ah u ns u r perct I ihot'l

mark]
[1
ll markahl

(ii) Stale one special charactcristic oftransilion elemenr.

l\ \\t tdk.ot set u c i r i i s l l ntettu n tto' pera l i han
t t -

mark]
[1
l7 markahl

(b) (i) Wlich element exisls as monoatomic gas?

Ltntur nutnokah ),ang \,ttju.l scbdgdi gat monoatom)

[1 mark]
I narkahl

(ii) Givc a reasorl to your answcr ln 2(b)(i).

Bo ikern sebttb liepudo iardlnn dndd di 2(b)(i).

,1s41/2 a0 201? MPSM Negei Serbilan

SULIT
 SULIT 4541D

(r') ,\torric size of (l

is biggel rhan atonric size of P.
Erplain whl.clcrrent Q rs tnorc rcaclive than P.
Stri- atont Q aluloh ltbih hesur daripttdo sti. Ltto t P.
Terdngkan ncngopu totstr Q lehih tuliif dn].i|t1dd l,

[1 rnalk]
l1 tnarkoh)

(./) lllement P reacts $.ith clement S to lonn a contpound with a clteDical fonnula pts.
L'Dsttr P bcrrinlalr bulat lengan ttnstu.S unruk ntt: rhentlk vdtu sebe.tiLt (lengLln
lit'ntttIa leinio PtS.

(i) State thc type ofcornpound formcd.

NyLltakatl ie]1is scbdtion yLtn! tcln\il.

l1 markl
ll morl; l
(ii) Dra\\' thc cleclroll arranecmelt ofthe compound li)Ined.
Lukiskan ytrtunan elch )n bLlgi sehatidn .tdnq tetbentlft.

[2 marks]
12 narkahl

i511/? la20ll MPSM Negeri Sunbilln

I[-ihat halaman sebelnh
suL '
SULIT 6 454 2

Diagram 3 sho\\,s t$o scts of cxpcrirncnts to inl.cstigate the chemical properlies of

hydrochloric acid. Zinc po$dcr and copPcr(ll) carbonate polvder are added to each test
tube Iespectively-
Ralerh 3 ntenrnjrrkkon dtru sel eksperi,ttt) ttit!ri;: t)).n.\id:L1t tifut-silil kimid dsitl
hitlnklorik. Serbtrk zink dcut yrbuk kuttrunttllt i:.r;,;'r,,;-r .rl'rrr;rr,llzri li. lol.ut s.n tl
ldbung uj i 1asihg-n]sing.

Set 1 Set 2

Zinc pouder Coppcr(ll)

Serbuk zink carbolrate powdcr
Serbuk lcuprun(Il)

Ilydrochlo c acid Hvdrochloric acid

Diagram 3
Raiah 3

(a) State the name ofthe gas released in:

N)'atdhln numa Eas )ung lerbehos di:

Setll

[2 marks]
[2 markah)

(l) Dcscribc bricfll a co tinnatorv tcst fbr thc sas released in:
Iluraikon sean-o ringkas ttjian pengesalmtt bttgi gos terbehas tl!:

Set l

Set 2

[4 marks]
14 markahl

.1541/2 lrr 201, MISM Ncecii Scnbil.n

SULIT
 SULIT 4541/2

(c) ol solution formcd in :

Statc the colour
N)dluka yurna larutL l ),.lng terbenhft di :

Setl:
Set2:
[2 marks]
[2 morkah)

(./) \\r-ite a bdlanccd chemical cquation lir-reaction in Sct 2.

Trlb persdmeon ki i.t.))dng seimbd gbdgi tintlatcktttts JiSet2_

[2 marks]
12 nteu'kah)

!,sal/2 (r 2017 MPSM Negei Sembilan

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SULIT
 1511t2

Diasram ,1sho\!s ihe structural lbrrtrula oicornpourd X.

Rdlull l nknllni kkan fbrnulLt sfiuklur b Lli sebdliun X

HHHH
ttlt
H-C-C=C-C-H
lt
HH

Clompound X

Co pound X is onc of the components in petrol. Thc oxidation of X prrrduces compound Y.

The tbllorvrng chclnical equiriion sho\\'s the oxidation of X to produce compound Y.
Sehdti.ii X t enpokdn tuloh .;utu kontpotrcn ydnL< terdop(tl di LLtlunt petrol. Pengoksitlddtl
\ebdidn x ntnghu.\ilkun .rchatian \.
Per:dtnudn kimid herikut menunjukkon pengaktiddan X u luli ntenghasilkan sebutian Y.

HHHH
tttt
H*C-C:C-C-H + HrO + [O] Y
IA -->

(a) (i) Statc thc suitablc oxidrzing agent uscd in this rcacrion.
N\,,:tt{tk,:tn,:tgen pe gokidaun l,tutg:;estai digun kan ddltltll tilddk bdlds ini.

[1 ma ]
ll tnarkah)

(ii) Statc the coloul ch nge rcaciion in ,lGr)(i).

1br thc
Nlurakan perubahan trurnu tltlunt tindok holu li 4ktli).

llmarkl
ll narkah)

1541/2 (i 2017 MPSM Negeri Senbila.

SI]LIT
SULIT 9 4541t2

(iii) Dra\\, the structural fornrula ofcompoLrnd Y.

Ltrkiskun fortnrla strtknr ;ebdtion Y.

mark]
[1
11 markahl
(D) Cornpound X has isomcrs.
Sebdtian X tnempLotydi isoner-

(ij L)ra$ the strucrural fbn'nula olone isornel ofcompound X.

Ltrkiskun Jbrtnula str klur hLtgi sdtu i.tat11!t- \ebati0n X.

Imalk]
ljl ntarkahl

(ii) State the nanie ol the isomcr in 4(D)(i) according lo IUpAC liomenclaturc.
Nyatokdn notnu itontu-dalant 4(b1l) ntengikln ?e da lUPAC. d

markl
11
ll markahl

(.) l0 g of compound X bumt completcly in e1icess oxygen_

lO tebulitlli X terbdkor lengkap di dulan oksigen herlt:hihan.
-q

(i) Writc a balanced chcmical equation for combustion ofcompound X.

Tt.liskan per.;untaan lcinio scimhLtltg h.tgi penbdkaran scbatian X.

[2 rrarksl
12 markoh)

(ii) Calculate the voluntc of oxr,gen sas used lar complete combustion of
coltlpound x.
lRelati\e atomic mass: H- l. (:l2l
ll mole ofgas occlrpicd 2.1 dltrr at room corldilions]
Ilitungkan iti pctdu gds ak.\ i€:!n ydtlg digunLtken untuk pcmbukaron lengkt4t
t(bdtid X.
LJisitll Lttont reldlif: I I:l . C:ll]
I I nol gas ntenenpati 21 <h-l; poda keaduan bilikl

[3 marks]
13 narkuhl
.15,11/2 @ 2017 MPSNI Neseri Scmbilan
ILihat halaman sebelah
ST]LI]'
SULIT t0 4s4 2

hperiment I, II and III are carried out to in\.estisatc the tbctols allicting the rare of
1eac1io11.
fable 5 shows the reactants inYolved in the experimcnts.
Ek.tpcrincn l- ll dan lll dijulaukan uutuk tnengkuji laktor liktor tung ncnqcngd]-uhi
kadar tindak balas.
Jctdtra/ 5 menu ilkkttn bdllLtn linddk hdlLts to g terlib,:!l ddlanl eksperi ol to-.\.huI

Experiment Reactants
Ekspe rrrerl Bahan-bahan tindak balas
f.\cess agnesium

t po\\, der 25 cmr of0.l mol drrir h-vdrochioric acid

Serbuk tnagne.ritttrt )5 ctnl ct.:;id hidroklot-ilr 0.1 mol dm r

Excess magnesir.Lm
powder 25 cmr of0.1 mol dm I sLrlphuric acid
II SerLtuk tnognesiunt 25 cmt dsitl su//urik 0.1 moi dm l

Excess magnesium 25 cmr of0.l mol dm I suiphuric aciLl

po$de1 + copper(ll) sulphatc solutiolr
III SerhtA nugne.;iun 25 crtl asid wlfidk A.l mol dm r
+ lal'ulm kltpr1o11ll|) suUot
Iable 5

Diar|anr 5 shou,s thc rcsults ofexperiments I. II and lll.

tultth 5 nenunjukkan kepltlusdn bdgi elrsperinen I.ll don lll-
Volume ofhydrogen gas i cml
lsi pttclu gus hidrogen icnl

Time / s
Masa / s

Diaglam 5
Rujoh 5

!,s{1/2@201? MPSM Nesei Sembilan

SULIT
 SULTT 1l 4511t2

(/r) Stale ore factor that aflects late ol reaction.

N),otdh1n satt litktot \)ung mo4)e g[1ruhi kekldr tint]Ltk bdlos.

[1 ark]
lt nturkahl
(D) (D Give a leason u,hy the cLlNe ll is steepel than cutve L
BerikLrt alasan nengopa lengleung ll lebih ctrrLtn LlariTtado ltngknry l.

It markl
11 marlcah)

(ii) Besidc adding coppcr(ll) sLrlpharc, suggest onc \fav tu obrain cLrr\e lll from
cuNe ll. The \'olLlmc and concentration ofsulphuric aciclarc ulchanged.
Selain doripatlo ]ne onbuhkd l.tnttan klc)ntn(lll \ulJAt, cddun:1kdn s^tu
cL!]'.t rolh.tk nlctnperoleh lengkung III doripada lenghug Il. tsi paLfu Llon
liepekdtan asid sullio-ik ticlak benLbdh.

! markl
lt tntn.koh)

(.) Erplain \\,hJ, d1e total \,oiume (]1-hydrogcn gas relcased in Expcrimellt II is double
the tolal volulne ol h)drogcn gas releascd jn Ixperintent L
Terongkan ntenqo|ta jutl1lLl1 isip.t.lLt got hidrogen ))ang dibehatkdn dolanl
Lk\?etinkn Il adoluh chn kali guntlet junlah isi pd.lu gos hitlrogen dibebuskan
dalant Eksperinen l.

12 rnarksl
12 ntarluhl
(c, Bascd on [.\perirncrt ll.
B erdo vu'kan Llcsperint en II.
(i) \\ri1e thc chemioal equation lbr the reaction occurrcd.
luli\k.tn pc]-sLrtladn kiniu bagi tindak bult.; _tang herloktt.

.l1 markl
ll nurkehl

J5,11/2 ,-rt :017 N,JPSV Ncgeri S.nbrlrr ll-ihat halaman sebelah

SULIT
SULIT 12 454u2

(ii) calci ate the tolal \ollLme olhydrogen gas released.

r]
lMolar gas volume at room conditioli is 24 dmr mol
hittrngkan jtrmlah isi putlu gts hidrugen rrtng terbebas-
rl
Itsi pddu nolar gat lotlo tuotluon bilik iatai 2,1dmr mol

marksl
13
13 ntarkahl

(a) If ihe cllange ir mass of magnesium during thc reaction is measured. skctch thc
graph ofrnass ofmagnesium againsr tine for Expcriment L
..lika penthahan dalam jisin fidgnesilo semasa tinduk bulas diukr. lakarkatt
graf jisin magnesillt nlplL fin ndtd bagi Eksp.rinen l-

marksl
12
12 ntarkahl

4541/2 @ 20l7 NlISIl Neeei Sembilan

SULIT
 SULIT t3 4541/2

Dianranr 6 shotvs the apparatus set-Llp to detcrmine the heat ofdisflacement.

Rajah 6 ntt'rtunjtlckun \ stt ain ruale$ untltk tnenetjtt.lfin hdbd pen|e\Lffdn.

Excess zinc po\\,det

Setbuk zink herlebihon

Polvstyrene cup rrol dm i coppcr-(ll) sulphate solurio

50 cnrr 0.2
Cd\,dt| lilisteri d 50 cml laruttt kupnrru(Il) srrfal0 2 nrol dmr

Ditrgranr 6
Rojuh {:

Based on thc caperimcnt.

Bertla.^co kan ektperimen ini^

(.r) stirtc the 1neanirrg ofheat ofdisplacemcnt.

ti)\idkLln tdksud hubtl penlc.tLl- n.

[1 mark]
U ndrkoh)
(i) give one rcason rvhy pol.vsrlrene cup is used in thc experimcL.it.
heriktn situjebdb nengdpa ((1\\:an polisterina digunctkan dalatn ekspel.ime lltL.

markl
|1
ll markahl

.1541/2
@ 20 l7 MPSM Ncsen Se,n}ilntr ll-ihat halaman sebelah
SI]LIT
SULIT 1,1 4s4|2

(.r) The fiermocliernical equation belo\ replesents the dispiacemeit reaction.

P.rs.ntndn tert okirlia di hoyoh ntt:v,erkili tilkldk bdla\ ])t ie drat ini-

Zn+CuSOr+ZnSOr+Cu AH: 210kJmofr

Celcuiatc:
Hittrng:

(i) the numbcr ofinolcs oicoppcr(ll) ion.

bilangtut tnoI Lon kt4tt urt(ll).

[1 mark]
11 narkahl

(ii) the heat released during the reaction-

luba yong dibebaskan semdstl tinddk bdlLls-

[2 narks]
12. narkah)

(iii) the change oftempelatlrre in the experiment-

lspccitic hcat capacity ofsolution :.1.2 J g "C
r,

densitl ofsolution: 1 g cm r]
1,.'t'1,h4Jln't ,t ltt, d.tlont rA,lr nttt, ,t tn,.
lli :
ata hdbd te tu ldrutdn 1.2 ! g I .C t.
ketufipatd ldruldn: I g ct11))

! markl
ll tnarkahl

,1541D a4 20 L? I\,JPSNI NeSeri Sembilin

SULIT
 SUI,IT t5 4541t2

(t) The experiment is repeatecl using magncsium po\lder to replace zinc po$dcr.
The volune and concentration ofcopllcr(ll) sulphate used is rcmain unchanged.
Ektperinten diulang dengan nenggunaktu serhtk ntognesitun tnengganlikdn

Isi padt.r dan laruran kttltnrn(ll) sul/itt yang digunakan adalah sona.

(i) Prcdict thc hcat ofdisplacemenl lbr the reaction.

lianttlkon huhu penvesuren bagi tindtk balas ittt.

[1 mark]
ll markah)

(iD (iivc a leason lbr \our ans|er in 6(/)(i).

I'leriLdn sehab liogi j.tynpan annu di 6(d)(t).

llmarkl
ll markah)

(e) Draw an cnclgy 1e\'el diaglam lor the reaction.

Lttkis gamhar rajoh erat ten1Lqd bagi ti ddk htlLls ini.

l2 rnatksl
[2 rnurkah]

4s4l /2 (0 2! I 7 NIISM Neeeri Scmbila.

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SI]LIT l6 454112

Section B
Bahagian B

[20 marks]
120 tnarkuhl

Ans\1'er one questiul in this scctio11.

.Ju',r,ub satu soalan dolom bohogiun bti.

7 (o) CompoLrnd Q consists o1 54.5,19; carbon. 9.09'r; h),dr-ogen and rhe resL rs o\\g(n
bv mass. The molar mass ol the compound X is 88 g mol r.
[Relati\,e atomic mass: II: I, C: 12 and O: l6]
SebdliL l Q tetdiri dor\Lldu 51.51'li kdrbon, 9 -lrt"/o hirh-ogen ddn selellihna
adalah oksigen bertlasot kdli.jisin- .Jisinl nolLtr bagi sebatiLtn X arla/a/r 88 g mol r.
lJi.tint aton rcloli[: I I:1. C:12 r/r:rr O: l6]

Detcnninc the empirical for-mula. molccular lbrmula and lame of compound e.

Tenluka]1.forn1lla etnpirik, fornltla nolekul dLut n.tn,:t bLei sehdtian Q.
[8 marks]
lE ndtkuh)
(i) Tablc 7 shows the characteristics ofcompound X, Y and Z.
Jadual T menttnj ukket ciri ciri sehatian X. Y ddn Z.

Compound Properties
Sebatiafl Sifat
Consist ol3 carbon atoms
Tertlit i ddripado 3 dtt)l11 kdrl)t j
Dissohc in waler
x
(ltange blue Iitmus paper to rcd
lllentlkL!] kdn kltlct\ littnus bint kc neft t

. X
Has samc nuntbet ofcarbon atonts as coltlpound
|u[emptmlui bilangon utun korhctn yung sdtno Llengdn
\t hdtian X
Y . Miscible in water
'Ierlttrul campur dalutn ai-
. Bum! in excess Lx],gcn \1.'llho[t soot pr-oduccd
Terbukar tunpd.ieldgLt di ddant oksigen herlebihan

. fornled tln'ough thc rcaction bet\\,ecn cotnpounds X and Y

Terbenluk ntelahti tifid hctlds dntato sehLtiqtl X ddtj

Z . InsolubLe in \ratcr
Tiduk larut tli tlolant air
. S$ cct snlc1l
I'lerbau harunt
Table 7

45/,1/2 (r 20l7 MPSM Negen Senrbilar

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SULIT t7 .1S-11 l

(i) Bascd oninfornatioll in Table 7,

Berddsarkan maklumat dalcon Jadual '7,

. state the homologous scr-ics and the functional group tbr cach
compounds.
n))rlakdn.\iri honolog tlem kumpulan betftmgsi bdgi setidp sebdlic l.
[6 marks]
[6 tnarkahl

o write the chcmical equation to shows the production ofcompound Z.

htlis persLtfiddn kimid untuk menLtniukkatl penghasilan sebatiun Z.
12 marksl
12 narkahl

(ii) lf you are supplied with compounds X arld Y are not labelled. dcscribc horv
you can diffcrentiate both compounds by using suitable reagent.
Sekiranya andu dil:ekulka dengdn X clcn \ ),dng tidak herlahel,
"^.bLttitln
huraikan bagaimtnu tmda dupt menbezokdn kethto-tlua sebatian dengan
ntenggunakcm reagen yo g sesltai-
14 marksl
l4 ntarkaltT

,15.11i2 iai l0LT luPS\'r \egeri Se.rbiix

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SULIT t8 454172

(.7) Diagram 1j.1 shorvs the apparatus set up tb1 the eleotrol_vsis of 0.5 moi dmr
copper(ll) chloride solution using carbon clcctrodes.
Rajah 8.1 nenuttlukkat tusututt radds itnl k elekn-olisis ktl.Lndn kte|.u1t1lll\
f,/orirla 0.5 nroltlnr r rlengon nenggunakan elektrod korbon.

Cas

0.5 mol dm r copper(ll) chloriclc

Gas

solution
0.5 rnol d.nl ldrutdti kuprun(ll)

Diagrarn 8.1
Rajuh E.t

Bascd on Diagram 8.1- cxplain thc reacli(nls at anode and cathodc. Your
explanation shoLrld irlclude the following:
Berdasarkan Rqjah 8-1, terangkan tindak hctlu di tnctcl ddn kotod. Penero gdn
anda pcrl uh ntengotldtfigi p.rkar.l berikLtl

List ofions attracted to cach clcctr-ode

Se drdi ion-iui ,-ang lerldrik ke setiol clektrol

Names ofthe ions arc sclcctcd to be discharqcd at aach electrode

Nand ian-i(n 1)en:q di)ilih untll( diti),Lll1.dtkan li setidp elektt.od

Reasons lbr the ions arc sclcctcd to be discharged

Scbob n-ion rlipilih tntuk dintahcaskdn

I Iall equalion for each rcaction

Setengah persamaan ba74i setiap tindak l:tlus

(Jbscr\ations at each electl'odc

PenerhotiLln di ptiap elekhrd

!0 marksl
|0 markahl

'15Jlr2 i{ lrllr XIIS\1 \.gcri S.o,hrlr.

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SULIT l9 4541/2

(r) Diagram E.2 sho*s the apparatus sct-up to inlesrigarc clcctron tftrnslcr ill .1

distance in redox reactions.

Rdjdh E.2 lo|u]ljLlkkd sLts tlatl t a,:l/]s Ltnhtk mengk,:iji pemindLlxt elektron
poda suotrt jorak duletnl titiddk bdlds redoks.

Carbon
Karbon

Pctassium chloride solution Itr) sulphate solution

I urutun kalium kloriiu Ldrutdt| fbt Lt n(lll) .tLtIfdI

Dilutc sulphu c acid

U-Tube
,1.t i tl tu /llrrik c ait'
Titb U
Diagram 8.2
Rajah 8.2

(i) Bascd or Diagram 8.2. state negativc teminal ofthc U-tube, direction of
electr-on flo\1' and obscr!ation al potassium chloride solLltion.
Namc the o\idizing agent in ihc rcaction.
Be rdavrkau Rcrjolt 8-2, nyiokdn tenli al egLii:f lucla ti b U, drdh
pengalirun eleklron dan penwhatian puda larutan kalitun klorila.
Nanokan agen pengoksidaun ddlan tindctk balas tersehur.
l'1 marksl
[1 nto koh)

(ii) Explani the oxidatiorr and roduclior proccsscs in term of thc clcchon
tlensi'el tliat oocurs at thc ncgativc and positive tcnninals i11 Diagram 8.2.
lerangkan pt'otes pengolesidaan dan penunntan clari segi pentinlahan
elektntn ),on'1 herluku di teniinal negdtiI LlLn tenllitcl positif LlLtlau Rujah
8.2.
[J rrrrl,
11 martuh)

(iii) Drarv xliother apparatus sct-up to shou, thc oxidation and rcd ctio
proccsscs in eleclron transfer at a distance by using the sa e oxidizing
agent and rcducing ageit in Diagram 11.2.
Lrtkiska sttsttnan tdat loin tnttuk ntenuniukkan proses pengok.titloun tlan
l(nurundn dalom penirulahan t'lektron puda satu ]oak tlcngan
nenggunttkan ugen pengoksiddan dcn agen penurunun tung sond dalon
R.,,44'(.1.
f2 marksl
[2 ntarktthl

4s41r2 4,,20 L7 MPSM NeEeri Scmbilan

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SI]I,IT
SULIT 20 454u2

Section C
Bahagian C

120 nrarksl
120 tnarkuhl

Answcr one rlucstjo in this section

.Javdb satt toolan iulant bahagian ini

(a) feflilisel is a substance Lrsed fir the growth in plants. A fcrtiliser can be prepared
frofi ille reaclion bet\leen am onia and an acid.
lJajo iLloh hohun tutg digunukun dalutn tLtntbesdrLut tuntbuhan- Btla holeh
di\ediakdn ddtildd tintluk krlas antara untnnnia lan a,'it|.

l'able 9 sho\\.s tro t)pcs of ammoniLUr salt liltilisers. Iet1ilisel X anrl fertiliscr Y
prepar'ed through thc reaction bctwccn arnmonie a d dillerellt lype ofacid.
\ tdng
Jtdual 9 ntenuniullctut dltd jenis bLtjd gardn L!t11t11ot1ilon, boja X dan hdict
diseiiokan ntclului tintlok halqs antara nnnto]tid don duo lenis osid ttnq herbe:tt

Reactants Fertiliser
Bahan tindak halas Baia

Amllronia I Monopetic acid

At tnonia + llsid t)tolto!)totik
x

Ammonia + Diprotic acid

Awmonia + Asid diprotilc

Table 9
.la.luolr)

(i) Susgcst thc na1nc alld chcmical lbnnulae oflertilise| X and feniliscr Y.
Cadangkun namo dar1li)n]1tlct kinli4 bdja Xe/on bojaY-
[,] marks]
ft tnarkahl

(ii) Detelmine ttich fcftiliscr is bctter. Explain your a11swer.

Tenurkun baja nanakdll ),dng lebih bdik. 7 erangkan.jtitttptu ctncla.
lRc]ativc atonic mass: ll.l;N. 1'1t O, 16: S,32; CI.35.51
llisin dtot11 lelotif: II,l;N. l4: O. l6; S.32t CI, 15.51

[4 ma*s]
14 markahf

45,1rl2 @2017 MPSM Ncgcri Sembilx.

SULI'I'
SULIT 2t 1511/2

(D) Diagram 9 sho*.s a conversation in a hardl,arc siore.

Raioh 9 neaunjukkat? pctblldltn tli ddlanl keLlai perkokosurt-

I\4isler. whal is the tliffer-ence bet*cen nail O

and nail R?
Encik. apaleah pctbe:dan onlo] Lt palu () dun
pala Rl

Ohl Nail Q is r-ust lesistant

nails mcanwlile nail R is non-
rust resistant nails.
Ohl Pdlcu Q atlalah paku tahan
kdrot ndndkald pdku ll tiddk

Diagranr 9
Rajah t)

( i) By using your- chcmistry kno$,lcdgc. suggest the lliime ofnail Q dnd nail l{.
Describc a laborltorv c\pcrimcnt to rrvestigate lhe Iale of rusting of thc
nails.
Your ansrver shoLrkl inclLrLle the tollo\\,ingl
. List ol lnatarials and apparalus
. lrocedure ofthe experiment
. Obscrvation
Deu,gun mettgguttalra pengeldlltkltl kintio mtlct. cuddngk(tn tfi ia paku Q
dan paktr R.
Ll i.dik@t s.ht cksp(] inrcn unttlk DleA,iLtsul kutlur ltengarotan paku tertcbut.
Jatupun ontLt perlu t en!d .lungi pe*atu herikttl
. Scntrti hohon tlan ralat
. Ptosultn al6peri)]ten
. Penerhdtian
[12 rnarksl
ll2. mL!rkdhl
(ii) Suqgcst two \!ays io pre\ent rusti11g.
Cadangkan duu cara untl!k mencegLll pengatrataltl.
12 rnarks I

[2 nttn kdhf

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St] I-IT
SULIT 22 454t/2

l0 (.r) Table 10 shows thc pll valucs lbr solution ofacid A and acid B which havc thc
satle conceilration.
.lqductl 10 pnLtnjltkkL l nilai pl) hagi ldnt,:tn tid A dan osid lt yang
ne ot pLt tlvti kepekdtatti \:tlng sd ]na-

Acid pH value
Asid flilai pH
I

B )
Tabl. l0
.ladual l0

Suggcst ol1e exanple for acid A and acid B.

Explain {,hv thc pH values ofacid A and acid B are clif}erent.
Cadd gkLul satu conbh untuk asid A dan osid B.
Terongkan mengapu nilui pll dsid A dcot asidll adakh berheza.
16 marksl
16 narkahl

(,) Ali was stung by a jellv-fish- Thc sting is alkaline in nature and causes pain.
Sugecst onc substance rvhich Ali can app1"v on his skin to rclieve the pain rvithout
causing lu her iniury.
Givc hyo reasois lbr your suggcstiorl.
1li teldll disengdt t)leh obor obor. SengdtLtll obor oh.r-l)e6i/at dllktli dd
tneq'ebahkan ketakian-
Cotlanglcon satr lnhun ydtlg ,7li bdeh s,:tplt puda lslihlyo unttlk tnengurangkon
ke.tqkilan tdnpd fienyebubkan ketederaot seterusnra.
Berikan dta sebctb bagi cadangan anda.
[3 rnarks]
[3 tnatkahl

.ls{l/2 iO 20lr NTPSIi Nes.ri sonbilxd

SULIT
SULIT 23 4541t2

(.) Diagram 10 shows a series ol rcaction fbr sall S. Sirlr S is hcatcd strongl-v- k)
produce cortlllound T and sas lJ.
Conrpound f reacts $ilh slLlphuric aci.l to tbnn coioured solution ofsalt \\-
Rajah l0 nenutlukkotl \otu \i-i tinddk bLll(t,\ bdgi gurun S- Gurant S dipanaskan
dettgdfi kuat u]1luk nlcnghd:ilkdn .\ehL idn T tlLut gas U.
Sebatian T btttindak balas dengan asicl sulfilik tnefibent k lcorttan berwama

Pass through lirne \\'ater'

llir ntelaltri air kapto'

(lolourcd solLLrion ol sall \\i Limc rvatcr ums cloudy

Lerrtrton hert arno gut ont \\ Ait- kdptt neni&li keruh

Diagram 10
Rcrjah lA

Based on Diagrarr 10.

Betda*rkan Raiah 10.

(i) identifl, salt S, compound T, gas U and salt W.

kendlpLtsli gdrdn S,.tehatiun T, gat U dan getrcotW.
[4 marks]
14 narkohl

(ii) wrile a chemical cquation fbr thc reaction betrveen compound T and
sulphuric acid.
tliiskan leraillctdti kimia bagi tindak balas LntLt o sebutian T tlcm asid
sullitrik.
[2 marks]
[2 markah]

(iii) describe the brieflv chemical tcst to..edly d1e cation and anion in colouled
solution of salt W.
huruiketn ,^ecara ringkas Ltjian kinid unu* fiengesdhkdti k.iian ILM atnion
J,lant l.ttttt.t'l h, tu.t a r:l r.i/,, U
[5 nlarks]
[5 markah]

END OF QUESTION PAPER

KERTAS SOALAN TAMAT

15ilt/2 (rl20l7 MPSM Ndgen Se.rbila [Lihat halaman sebelah

SI]LIT
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