NERACA MASSA

NERACA MASSA
Kapasitas pabrik = 43,000 ton/th

maka, kapasitas produksi propilen glikol tiap jam adalah

43000ton 1000kg tahun hari

   
tahun ton 330hari 24 jam
 5429,2929kg / jam

5,429.2929 kg/jam

Tabel Berat Molekul

komponen Rumus molekul Massa Relative
Propilen Oksida C3H6O 58.08
Air H2O 18.02
Methanol CH4O 32
Asam Sulfat H2SO4 98
Kapur padam CaO 56
Propilen Glikol C3H8O2 76.1
Kalsium Sulfat CaSO4 136.1406

No Arus 1 Propilen Oksida

Total Flow Rate 1342.79 kg/jam
komponen F, kg/jam X massa
C3H6O 1336.07605 0.995
H2O 6.71395 0.005
CH4O 0 0
H2SO4 0 0
CaO 0 0
C3H8O2 0 0
Total 1342.79 1

No Arus 2 Methanol
Total Flow Rate 1229.4667435187 kg/jam
komponen F, kg/jam X massa
C3H6O 0 0
H2O 24.5893348704 0.02
CH4O 1204.8774086483 0.98
H2SO4 0 0
CaO 0 0
C3H8O2 0 0
Total 1229.4667435187 1

No Arus 3 Asam Sulfat

Total Flow Rate 1342.79 kg/jam
komponen F, kg/jam X massa
C3H6O 0 0
H2O 26.8558 0.02
CH4O 0 0
 H2SO4 1315.9342 0.98
CaO 0 0
C3H8O2 0 0
Total 1342.79 1

No Arus 4 Air
Total Flow Rate 4028.37 kg/jam
komponen F, kg/jam X massa
C3H6O 0 0
H2O 4028.37 1
CH4O 0 0
H2SO4 0 0
CaO 0 0
C3H8O2 0 0
Total 4028.37 1

NERACA MASSA DI REAKTOR

Propilen oksida
Methanol
Asam Sulfat REAKTOR
Air

C3 H6O  H2O HC3 H8O2

2SO4

C3H6O bereaksi 0.92

komponen F masuk, kg/jam F masuk, kmol/jam

C3H6O 1336.07605 23.0041
H2O 4086.5290848704 226.7774
 CH4O 1204.8774086483 37.6524
H2SO4 704.2130597439 7.1858
CaO 0 0.0000
C3H8O2 0 0.0000
Total 7331.6956032626 294.6197494847

6627.4825435187 287.4339
165.687063588 7.1858475484
NERACA MASSA DI NEUTRALIZER

CaO

Propilen glikol
Propilen oksida
Air NEUTRALIZER

Asam sulfat
Methanol

CaO( s )  H 2 SO4 ( aq )  CaSO4 ( s )  H 2 O( l )

komponen F masuk, kg/jam F masuk, kmol/jam

C3H6O 106.8861 1.8403
H2O 3713.3709 206.0694
CH4O 1204.8774 37.6524
H2SO4 704.2131 7.1858
CaO 402.4075 7.1858
C3H8O2 1610.5605 21.1637
CaSO4 0.0000 0.0000
Total 7742.3155 281.0976
NERACA MASSA DI FILTER

Calcium Sulphate
Propilen glikol
Propilen oksida
FILTER
air
Methanol

Calcium Sulphate

komponen F masuk, kg/jam F keluar total, kg/jam

C3H6O 106.8861 106.8861
H2O 3842.8599 3842.8599
CH4O 1204.8774 1204.8774
H2SO4 0.0000 0.0000
CaO 0.0000 0.0000
C3H8O2 1610.5605 1610.5605
CaSO4 978.2856 978.2856
Total 7743.4695 7743.4695

NERACA MASSA DI MENARA DISTILASI

Propilen glikol
propilen oksida

MD-01
 air MD-01
Methanol

komponen F masuk, kg/jam F keluar atas, kg/jam

C3H6O 106.8861 106.8861
H2O 3842.8599 24.1368829603
CH4O 1204.8774 1204.8774
H2SO4 0.0000 0
CaO 0.0000 0
C3H8O2 1610.5605 0
CaSO4 0.0000 0
Total 6765.1839 1335.9004

Propilen Glikol
evaporator
Air

komponen F masuk, kg/jam F keluar, kg/jam

C3H6O
H2O 271.4641768965
CH4O
 H2SO4
CaO
C3H8O2 5157.819361034
CaSO4
Total 5429.2835 5429.2835379306

alkohol Cuma saat startup,

air di recycle 295.6010598568
propilen oksida recycle 106.8861

KAPASITAS PABRIK= 5,429.2929

PROPILEN GLIKOL= 5429.2835379306
FAKTOR PENGALI= 1.0000017244
1 tahun operasi = 330 hari kerja
1 hari kerja = 24 jam
basis = 1 jam operasi
BM F, kmol/jam X mol
58.08 23.0041 0.9841
18.02 0.3726 0.0159
32 0.0000 0.0000
98 0.0000 0.0000
56 0.0000 0.0000
76.1 0.0000 0.0000
23.3766 1.0000

BM F, kmol/jam X mol
58.08 0.0000 0.0000
18.02 1.3646 0.0350
32 37.6524 0.9650
98 0.0000 0.0000
56 0.0000 0.0000
76.1 0.0000 0.0000
39.0169770042 1

BM F, kmol/jam X mol
58.08 0.0000 0.0000
18.02 1.4903 0.0999
32 0.0000 0.0000
 98 13.4279 0.9001
56 0.0000 0.0000
76.1 0.0000 0.0000
14.9182329634 1

BM F, kmol/jam X mol
58.08 0.0000 0.0000
18.02 223.5499 1.0000
32 0.0000 0.0000
98 0.0000 0.0000
56 0.0000 0.0000
76.1 0.0000 0.0000
223.5499445061 1

Propilen glikol
Propilen oksida
Air
Asam sulfat
Methanol

F bereaksi, kmol/jam F keluar, kmol/jam F keluar, kg/jam

21.1637 1.8403 106.886084
21.1637 205.6137 3705.1585065763
 0.0000 37.6524 1204.8774086483
0.0000 7.1858 704.2130597439
0.0000 0.0000 0
-21.1637 21.1637 1610.5605442941
21.163739084 273.4560104007 7331.6956032626

Calcium Sulphate
Propilen glikol DIASUMSIKAN CaO masuk
Propilen oksida H2SO4 bereaksi
air konversi reaksi =
Methanol

mula-mula
bereaksi
sisa

F bereaksi, kmol/jam F keluar, kmol/jam F keluar, kg/jam

0 1.8403 106.8861
7.1858475484 213.2553 3842.8599
0 37.6524 1204.8774
7.1858475484 0.0000 0.0000
7.1858475484 0.0000 0.0000
0 21.1637 1610.5605
7.1858475484 7.1858 978.2856
281.0976 7743.4695
 Propilen glikol
Propilen oksida
LTER
air
Methanol

F keluar arus bawah, kg/jam F keluar arus atas, kg/jam fraksi massa komponen
106.886 0.0157994351
3842.860 0.5680347978
1204.877 0.1780997271
0.000 0
0.000 0
1610.561 0.23806604
978.2856 0.000 0
978.2856 6765.184 1

Alkohol 98%
Air 2%

KOMOSISI KELUAR MD-01

 komponen F keluar arus atas, kg/jam
C3H6O 106.886
H2O 3842.860
CH4O 1204.877
H2SO4 0.000
P.G CaO 0.000
H2O C3H8O2 1610.561
CaSO4 0.000
Total 6765.184
F keluar bawah, kg jam

5429.2835

Air
5%

orator

Propilen Glikol
95%
 Arus 1

komponen F, kg/jam X massa

C3H6O 1336.07605 0.995
H2O 6.71395 0.005

Arus 2

komponen F, kg/jam X massa

CH4O 1204.8774086483 0.98
H2O 24.5893348704 0.02

Arus 3

komponen F, kg/jam X massa

H2SO4 1315.9342 0.98
H2O 26.8558 0.02

Arus 4

komponen F, kg/jam X massa

H2O 4028.37 1
 Propilen oksida air methanol
massa 43.04 802.8 71.87
2499.7632 14466.456 2299.84
 mol 1 5.787130557 0.9200231446
1229.22088894

9.8581457828

sebanyak mol H2SO4 yang akan dinetralkan 1. bikin reaksi h2so4+CaO

100% 2. Bikin neraca massa
1 3. cari kelarutan CaSO4 dalam air
4. cari bubble point calculation, de

CaO + H2SO4 CaSO4 +

7.1858 7.1858
7.1858475484 7.1858475484 7.1858475484
0.0000 0.0000 7.1858475484

CaO+H2O 410.619859909
H2O impurities dalam CaO 8.2123971982
fraksi propilen oksida terhadap alkohol 8.1482740295 %

air keluar MD atas 24.5893348704

air+alkohol+PO 1336.353

KOMPOSISI PRODUK ATAS MD komposisi

air 0.0184003314 1.8400331383 %
alkohol 0.9016162377 90.1616237746 %
propilen oksida 0.0799834309 7.9983430872 %

Kemurnian alkohol 98 %, jadi fraksi alkohol

fraksi air
fraksi massa komponen F keluar atas, kg/jam komposisi atas MD
0.0157994351 0
0.5680347978 24.5893348704 1.8400331383
0.1780997271 90.1616237746
0 0 7.9983430872
0 0 0
0.23806604 0 0
0 0 0
1 1336.353
BM F, kmol/jam X mol
58.08 23.0041 0.9841
18.02 0.3726 0.0159

BM F, kmol/jam X mol
32 37.6524 0.9650
18.02 1.3646 0.0350

BM F, kmol/jam X mol
98 13.4279 0.9001
18.02 1.4903 0.0999

BM F, kmol/jam X mol
18.02 223.5499 1.0000
n reaksi h2so4+CaO
n neraca massa
kelarutan CaSO4 dalam air
bubble point calculation, dew point calculation melibatkan antoine

H2O

7.1858475484
7.1858475484
0.98
0.02
Konversi H2SO4 adalah 100 % 100.00%

Komponen IN, kmol/j OUT, kmol/j BM IN, kg/j

C3H6O 1.8403 1.8403 58.08 106.886084
H2O 206.0694175236 220.4411126204 18.02 3713.3709037745
CH4O 37.6524190203 37.6524190203 32 1204.8774086483
H2SO4 7.1858475484 0 98 704.2130597439
CaO 7.1858475484 0 56 402.4074627108
C3H8O2 21.163739084 21.163739084 76.1 1610.5605442941
CaSO4 0 7.1858475484 136.1406 0
Total 281.0975958624 288.2834 7742.3154631715

% Error 1.6873895227

kebutuhan Cao = 7.1858475484 kmol/jam 272.9184898885

BM Cao = 37.98
 CaO( s )  H 2 SO4 ( aq )  CaSO4 ( s )  H 2 O( l )
OUT, kg/j
106.886084
3972.3488494191
1204.8774086483 kmol/jam BM kg/jam
0 CaO 7.1858475484 37.98 272.91849
0 H2O 7.1858475484 18.02 129.488973
1610.5605442941 Ca(OH)2 7.1858475484 56 402.407463
978.2855967486
7872.9584831101

kg/jam
s)  H 2 O( l )
Padatan tersaring sebagai hasil bawah : 100.00% massa
Cairan terbawa padatan ke hasil bawah : 100.00% massa

komponen IN, Kmol/j OUT, kmol/j BM IN, kg/j

C3H6O 1.8403251377 0 58.08 106.886084
H2O 213.255265072 0 18.02 3842.8598766
CH4O 37.6524190203 0 32 1204.87740865

H2SO4 0 0 98 0

CaO 0 0 56 0
C3H8O2 21.163739084 0 76.1 1610.56054429

CaSO4 7.1858475484 0 136.1406 978.285596749

Total 281.0975958624 0 7743.46951029

OUT, kg/j
0
0
0
0.00%
0
0
0
0