INO. CHEMISTRY) as Resonence Educating for better tomorrow TARGET : JEE (Main + Advanced) 2017 Course : VIKAAS (JA) This DPP is to be discussed in the week (14.12.2015 to 19.12.2015) DPP No. # 46 (JEE-ADVANCED) Total Marks : 48 Max. Time : 28 min. Multiple choice objective ('-1" negative marking) Q.1 to 0.5 (4 marks, 2 min.) [12, 06] Integer type Questions ('-1' negative marking) Q.06 to 0.09 (4 marks 3 min.) [16, 12] ChemiNFO : § Questions ('-1" negative marking) Q.10 to Q.14 (4: marks, 2 min.) [20, 10] ANSWERKEY DPP No. #46 (JEE-ADVANCED) 1. (AB) 2. (ACD) 3. (AB) 4. (ABC) 5. © 6. 5 7 4 & 5 8 1 02 © 4 © 2 A B O MM W 1. Which of the following are correct (A) BH, reacts with excess of ammonia at low temperature to form an ionic compound. (@*) Borax, when heated with oxides of certain transition metals, forms coloured beads. (C) One mole borax in aqueous solution will require one mole HCI for titration (0) B,H, can be methylated completely to give B,(CH.), fre A att ger we #7 (AY) BH, Fr aT we ore ona 8 Arar awed ea arafew ah ae 8 G1) sa ata a GU vor arg stgengNl B eM Re Gren 8 a Es ATT aT e | (©) et Rota A ga te ae | sig | ARIE 1 Hts HCI AY Tae ee (0)8,H, 41 phe Archaea eh B,(CH,), Sort Frat aT TAT | Sol. (C) One mole borax will require two moles of HCI for complete reaction. (D) The bridging hydrogens can not be methylated in BH, Fa (0) fifteen & fay gw ate ates a Zara HCL a oraerom et (O)B.H, a ag BEST aT Ars aE ae THe EL 2. Which of the following can produce B,O, ? (A*) Heating borax with cone. H,S0, (®) Passing CO, through aq. NaBO, (C*) Combustion of diborane, 8H, (©*) Warming H,BO, crystals tl red hot. Fr 3 8 ah BO, a seule oy tam 8? (A) aH,S0,3 we aaa a TH aE (© wetANaBO, HF CO, Haris ae (©) erga, BH, Ges (OY H.B0, Praca 8 ars at ow orl eb 3. Which ofthe following are correct about B,H,? (A*) each 'B' atom is sp? hybridised (B*) It consists of two-"3 centre 2 electron bonds" (C) The two bridging H-atoms are in the plane of the molecules (O)Alllofthese BiH an a Prey a a wd 8? (Ay ste BAY spPeiaita seen HS) BY ga a, de Sad-gtagin we aa El (C2 dq Hawa om ae HA ad COyanrar wh Sol. _‘A’and'B' are correct on the basis of structure of B,H,. BH, wt tian & oma oe ‘A'S Bat #1 Resonance nalawar Road, Kola (Raj) 324005 Educating for better tomorrow D4. Which of the following hydrides react with water ? fry 4a ateeh aeES Oe } wer PM awa B ? ABH, (6) NH, (C)NaH OCH, Sol. BH, +H.0 —> H,80,+H, NH, + HO —> NH,OH NaH + H,0 —> NaQH +H, CH, +H,0 — no reaction, siftfivan =€ at | 5. Which of the following oxides are acidic fro A a aie sfangs oti (cao ®)Na,o (9B9, (00, 6. __Inboraxion how many B-O-B bonds present ates orem 4 fir} 8-0-8 da Ans. 5 7. Indiborane maximum how many 2¢—2e bonds present erga H setter Fre) 2o— 20 ae @ Ans. 4 8. How many oxides in the following are basic in water: fre 8 8 fa stags viet A arta aha B,0,,Al,0,, CO,, SO,, NO, CaO, Na,0, K,0, Cr,0, CaO 5 Ans. 9. Basicity of H,B0, is H,BO, a separ @ Ans. 1 TG EST NES |e WER Tone Wan CET TSM ay Ne | ofkectures) | sket pen| wo 61 (5) vn L*_[sutesia Ex.1 (0) - iL ust catbontamy — [Ez(0} x ae 2 Prob. BZ) El ExIG) 7 Le [sa 110) 700 use| rvorrecn c= Fert x ams * Ex2 (I) Prob. 2M) El 61 (5) x | R003 Ex1 (0) ™ XL Lss | 50, sicate, iscussion ["Ex2 (0) x 5] Ake 2 Prob. BZ) x Resomance errs ames: 2 Tove A682, Nw Cy Wa ave Rows Kt) 2 De FV TOSI Educating for better tomorrowemINFO. [= )mele Gm ‘Self-Study Dosage for mastering Chemistry Group 13 & 14 Elements ALUMS ; M,SO,. M’, (SO,),. 24H,0 or MM’ (SO,),. 12H, ‘Alums are transparent crystalline solids having the above general formula where Mis almost any univalent positive cation (except Li* because this ion is too small to meet the structural requirements of the crystal) and M’is al trivalent positive cation (AI, TF, V, Cr, Fe, Mn, Co™, Ga etc.) Alums contain the ions [M(H,0),]' IM'(H.O),P” Jand SO,* in the ratio 1:1: 2. Some important alums are () Potash alum K,SO, .Al,SO,),..24H,0 i) Chrome alum K,S0,. Cr,{S0)),.24H,0 (i) Ferric alum K.SO, . Fe,(S0,),.24H.0 (vy) Ammonium alum (NH),80,.Al(60,),.24H.0 ‘Alums are double salts which when dissolved in water produce metal ions (or ammonium ions) and the sulphate ions. Preparation : ‘A mixture containing solutions of M,S0, and M‘SO)), in 1 : 1 molar ratio is fused & then the resulting mass is dissolved into water. From the solution thus obtained, alums are crystallised Uses : Itis used 1, Asamordant in dye industry. The fabric which isto be dyed is dipped in a solution of the alum and heated with steam. Al(OH), obtained as hydrolysis product of fl(H,0),}* deposits into the fibres and then the dye is absorbed on Al(OH), 2. _asagermicide for water purification. 3. Asa coagulating agent for precipitating colloidal impurities from water. [Memorize this theory as soon as you get the DPP, Revise it regularly and master this concept by practice. 10. Which mixed sulphate is not an alum: (A) K,80, Al,(SO,)5.24H,0 ®)K,S0,Cr(S0,),.24H,0 (C) Na,SO, Fe,(SO,),.24H,0 (0") CuSO, Al,(SO,),.24H,0 Sol. Mis divalent, it should be monovalent according to the formula of alum. 11. Alumis used by dyer for {A) for fre-proofing fabrics (©) as first aid for cuts (C)for softening hard water (0°) as mordant Sol. Asa mordant in dye industry. The fabric which is to be dyed is dipped in a solution of the alum and heated with steam. Al(OH), obtained as hydrolysis product of [Al(H,0),|" deposits into the fibres and then the dye is absorbed on Al(OH), 12, Alums contain the ion [M(H,O),]", [M'(H,0),]"° and SO, in the ratio aytst:2 Byaits4 (22121 (1:22:14 43, In question no. 12, Mion can not be (aut BK (NHS wyare 14, Alums are (A*) double salt (B) single salt (©) Triple salt (O) none of these Resonance nalawat Road, Kola (Raj) 324005 ducating for better tomarrow