Adva PI Sol PDF

1 AITS-CRT-IV-(Paper-1)-PCM(S)-JEE(Advanced)/14
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ANSWERS, HINTS & SOLUTIONS
CRT –IV
(Paper-1)
Q.
ALL INDIA TEST SERIES
PHYSICS CHEMISTRY MATHEMATICS

No.
1. A B C
2. A A D
3. B D A
4. D C A
5. C C A
6. D B D
7. D A A
8. D C A
9. B A D
10. C C A
11. B, C C, D A, B, D
12. A, B, C A, C A, B, D
13. A, B A, B, C, D A, B
14. B, C A, D B, D
15. A, D A, D A, D
1. 8 2 2
2. 0 3 2
3. 2 3 4
4. 4 3 1
5. 1 8 4
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AITS-CRT-IV-(Paper-1)-PCM(S)-JEE(Advanced)/14
2
Physics PART – I
1. There will be no change.

 h = h h

2. =
0
 
vA – vB = (b)  (a)
0 0
Q
 W = Q(vA – vB) = (b  a)
0
3.  = 0 + 1  10 = 10 rad/sec2
 v = r = 1  10 = 10 m/s
 q(v  r )  qv
B 0 3
 | B |= 0 2
 r 4r
7
10  0.1 10
B= = 10-7 T
(1)2
4. conservation of momentum
M 2gh  m 2gh =MV1 + mV2 (1)
V1  V2
1  (2)
2 2gh
V2  3 2gh
V22
h'   9h
2g
1 1 1
5.  
C C1 C2
x a b  x
= 
0 A 0 A
0 A
 C=
ab
6. FBD of ‘B’ and ‘C’
T T
B a C a
2g 3g
 T – 2g = 2a . . . (i)
and 3g – T = 3a . . . (ii)
12g
T=
5
for A
T=2T
A a
mg
 T = mg
12g
2 = mg  m = 4.8 kg.
5
/2
mgR
7. W =  f.Rd  = 1 joule.
0 2
v  g  a   m  g  a  2
9. a= = 20 m/s
m
2h
t= = 1 sec
a
nh
11. Angular momentum =
2
1
kinetic energy  2
n
h
De-broglie wavelength  = so as v increases  decreases.
mv
14. Relative velocity of B w.r.t. A along vertical direction should be zero

20 sin  = 10
 sin  =1/2
1
x = 20 cos 30  = 5 3m
2
15. Change in angular momentum = angular impulse
L = 5
ma2
I=
3
L2 752
K= 
2I 2ma2
Section -C
1    3
1. Conservation of energy mv 2  mg  mg  m 3  2 g
2 2 2  2 
v  8g 60
2. Potential across capacitor is zero, hence energy stored is zero.
3. vA – vB =  E. dx = 10 (1)
= 10 volt.
4
4. Z= R 2  X 2 = 9  X2
R 3
but cos  = 
Z 5
X = 4 .
E
5. = E – ir
2
E
 i= . . . (i)
2r
2E = i(3 + r) . . . (ii)
r=1
Chemistry PART – II
SECTION – A
1. Kc = 4 × 10-19
1


  Ag  CN 2 
Ag  2CN 
0.03 0.1 0
1


 Ag  CN   
 Ag  2CN

 2
t0 0.3 0 0.04

0.03  x x 0.04  2x
2
x  0.04  2x 
Kc   4  1019
0.03  x 
0.04  2x  0.04
0.03  x  0.03
2
x.  0.04 
Kc   4  1019
0.03
x = 7.5 × 10-18
2. PV = nRT
As PV constant
n1T1 = n2T2
n1 . 300 = n2. 400
300 3
n2 = n1  n1
400 4
4. Energy of e in H-atom = - E
Energy of e in Li+2 = - 9E
1
Energy supplied by photon = IE  mv 2
2
IE | E |
1
 Ep  9E  mv 2
2
2  Ep  9E 
v
m

9. FeSO4   Fe2 O3  SO3  SO2
1
12. H  e    H2 Eo  0.0 v
2
0.059 1
E  EH /H  0  log 
2
1 H 
 0.059  7  0.413
So, EH /H  ENi2 /Ni
2
Ni will deposit at cathode

2H2 O  2e   H2  2OH
6
0.059 2
E  0.83  log OH 
2
 0.83  0.059  7
= - 0.417
13. Both have Cr+3(d3), and C.N. is 6. Hence d2sp3.
Pd+2(d8) complexes with C.N. is 4 are square plannar and magnetic moment is zero.

14. FeCl3   FeCl2  Cl2
Dil. CuCl2 is blue due to [Cu(H2O)4]2+ PH3 is obtained by heating white P with NaOH
All are reducing because of weak P – H bond.
SECTION – C
1. CH3 Br CH3
A = H2 C C=
Br CH3 Br
CH3 CH2 Br CH
3
H3C
B= E=
Br Br D= inactive
H Br
1 1
2. KNO3  KNO2  O2 NaNO3  NaNO2  O2
2 2
2 Pb( NO3 ) 2  2 PbO  4 NO2  O2 Ca  NO 3 2 , Sr  NO 3 2 ,
NH 4 NO3  N 2 O  2 H 2 O Pb(NO3 ) 2 do not respond to the test.
2 Ca ( NO3 ) 2  2SrO  4 NO2  O2
2 Mg NO 3 2  2 MgO  4 NO2  O2
3. O O
H O S S OH
O
4. Tb  K b  m  i
2.08 = 0.52 × 1 × i
i=4
K 3 Fe   CN 6 
5. Cl Cl HO OH O


  
Cl Cl HO OH
 X Y Z O
8
Mathematics PART – III
1 1
 x 1   1   1 dx 
1. I 
2
 x 1  0  1 dx
1
   1
f x , if 0  x 
2

 1 1
2. Here, g  x    f   , if  x 1
2 2

3  x , if 1  x  2
A A
4. Let  CAD  
3
By m – n theorem, 2 
(1 + 1) cot  = 1 cot 2 – 1cot 

B D C
6. Here, z2 – z3 = i(z1 – z3)


 ACB 
2
13
 AC  ; AC = BC
2
9. (0, 0) lies on the director circle
x 1 x 1
10. 2/3 1/ 3
 1/ 2
 x1/ 3  x 1/ 2
x x 1 xx
 1 1
3  
ab 1 1 1 a b
12. x  y  z  3 ;   
 2  x y z 2
14. Here, f –1(x) = a  x  a
SECTION – C
1. Equation of tangent is y    f '    x  

  f '   
Also,  
2
f '   1
dy 1  y2  x 2 
Thus,   
dx 2  xy 
Thus, equation of curve is x2 + y2 – 2x = 0
1 
2. Equation of normal is y  an   x  a
nan1
4. Here, 1 = d(a1 – a2)(a2 – a3)(a3 – a1) = –2d4

4
Also, 2 = –2d
2 2
5. sin x[sin x + sin x + 2] = 0
 sin x = 0, where x = 0, , 2, 3

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1 AITS-CRT-IV-(Paper-1)-PCM(S)-JEE(Advanced)/14

PHYSICS CHEMISTRY MATHEMATICS

1. There will be no change.

14. Relative velocity of B w.r.t. A along vertical direction should be zero

2. Potential across capacitor is zero, hence energy stored is zero.

t0 0.3 0 0.04

Ni will deposit at cathode

Mathematics PART – III

6. Here, z2 – z3 = i(z1 – z3)

9. (0, 0) lies on the director circle

14. Here, f –1(x) = a  x  a

1. Equation of tangent is y    f '    x  

4. Here, 1 = d(a1 – a2)(a2 – a3)(a3 – a1) = –2d4

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